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11. Complete the following potential energy diagram by adding the following labels: an
appropriate label for the x-axis and y-axis, Ea(fwd), Ea(rev), ΔHr.
a. Is the forward reaction endothermic or exothermic?
b. Which has the higher potential energy, the reactants or the products?
What Is Required?
You need to label the given potential energy diagram, determine if the reaction is
exothermic or endothermic and indicate which has the higher potential energy,
reactants or products.
What Is Given?
You have an unlabelled potential energy diagram.
Draw and label a potential energy diagram for this reaction. Calculate and label
Ea(fwd).
What Is Required?
You need to draw a potential energy diagram labelling the x-axis and y-axis, the
transition state, and Ea(fwd).
What Is Given?
You know the balanced chemical equation for the reaction.
You know the activation energy of the reverse reaction: Ea(rev) = +34 kJ
You know the enthalpy change of the forward reaction ΔHr = +65 kJ
Draw and label a potential energy diagram for this reaction. Calculate and label
ΔHr.
What Is Required?
You need to draw and label a potential energy diagram for this reaction and
calculate and label ΔHr.
What Is Given?
You know the activation energy of the forward reaction: Ea(fwd) = +61 kJ
You know the activation energy of the reverse reaction: Ea(rev) = +150 kJ
What Is Required?
You need to estimate the values for Ea(fwd), Ea(rev), and ΔHr based upon the given
potential energy diagram and indicate if the reaction endothermic or exothermic.
What Is Given?
You have a potential energy diagram.
What Is Required?
You need to determine the value of Ea(rev) for a reaction and draw and label a potential
energy diagram.
What Is Given?
You know the activation energy of the forward reaction: Ea(fwd) = +19 kJ
You know the enthalpy change of the forward reaction: ΔHr = –392 kJ
What Is Required?
You need to determine the activation energy, Ea, and the enthalpy change, ΔHr, for the
reaction.
You need to draw a potential energy diagram for the reaction.
What Is Given?
You know the potential energies: activated complex, +112 kJ; reactants, +36 kJ;
products, +78 kJ.
What Is Required?
You need to write the thermochemical equation for the combustion of methane and
draw a reasonable energy profile diagram that could represent the process. Include a
molecular structure that could represent an activated complex in the potential energy
diagram.
What Is Given?
From Table 5.4, you know the molar enthalpy of combustion for methane:
o
DH comb = –890.8 kJ/mol
The products for complete combustion are H2O(ℓ) and CO2(g).
3Fe(s) + 4H2O(g) ¾¾
® Fe3O4(s) + 4H2(g)
¬¾
¾ ΔHr = –151.2 kJ
The activation energy for the reverse reaction, Ea(rev), is +200.71 kJ.
a. Calculate the activation energy for the forward reaction.
b. Draw a labelled potential energy diagram showing the enthalpy change, and the
activation energies for the forward and reverse reactions.
What Is Required?
You need to calculate the activation energy for a forward reaction.
You need to draw a labelled potential energy diagram showing the enthalpy change,
and the activation energies for the forward and reverse reactions.
What Is Given?
You know the enthalpy change of the forward reaction: ΔHr = –151.2 kJ/mol
You know the activation energy of the reverse reaction: Ea(rev) = +200.71 kJ
Draw a potential energy diagram for the reaction showing appropriate labels for both
axes, Ea(fwd), Ea(rev), and ΔHr.
What Is Required?
You must calculate the activation energy for the reverse reaction and draw a potential
energy diagram for the reaction showing appropriate labels for both axes, Ea(fwd),
Ea(rev), and ΔHr.
What Is Given?
You know the enthalpy change of the forward reaction: ΔHr = +55.3 kJ/mol
You know the activation energy of the forward reaction: Ea(fwd) = +55.3 kJ
A + 2CD + 85 kJ → G
What Is Required?
You need to calculate the activation energy of the forward reaction, Ea(fwd).
What Is Given?
You know the enthalpy change of the forward reaction: ΔHr = +85 kJ
You know the activation energy of the reverse reaction: Ea(rev) = +235 kJ