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ALL INDIA TEST SERIES

PART TEST – III

JEE (Advanced)-2021
PAPER –1
TEST DATE: 20-12-2020

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A
1. C
Sol. If the mass is displaced by x and has speed v spring will extend by x/2
& M 2 will have speed v/2
Energy of this system can be written as
2 2
1 x 1 v 1 x v/2
M1gx  M1v 2  M2 g  M2    K   = constant
2 2 2 2 2 2
x/2
x
1 x 1 1
M1gx  M1v 2  M2 g  M2 v 2  Kx 2 = constant M1 k
2 2 8 8
Differentiate w.r.t. time v
dv M2 g 1 dv 1
M1gv  M1v  v  M2 v  Kx.v  0
dt 2 4 dt 4
dv M2 g M2 dv 1
 M1g  M1    Kx  0
dt 2 4 dt 4
 M2  dv K M2 g
 M1  4  dt   4 x  M1g  2
 
dv  K  2(2M1  M2 )g
a   x 
dt  4M1  M2  4M1  M2
K
Here 2 
4M1  M2
2 4M1  M2
T  2
 K

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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 2

2. B
1 T
Sol. use f 
2 

3. A
Sol. For total internal reflection at face BC, 90o –  > C B E
90o – C >  ..... (1)
For refraction at surface BC
3 6 4
sinC  sin 90  sinC 
2 5 5 n1 = 3/2 n2
90 = 6/5
C = 53o ..... (2)
From 1 & 2  90o – 53o >   37o > 

A C D

4. C
Sol. If R0 be the initial activity of the sample, then R1  R0 e t1 and R2  R0 et2
1
Where   { Mean life T = 1/}
T
R 2 e t2
   e ( t1  t2 )
R1 e t1
t t 
 R 2  R1 exp  1 2 
 T 

5. C
1H  1H  1 H  p
2 2 3
Sol.

1 H2  1H3  2 He4  n
31H2 2 He4  p  n
  
m  m 2 He4  m(p)  m(n)  3m 1H2  
 m   4.001  1.007  1.008  3(2.014) u
m  0.026u
 |E| = c2|m|
 E = (9  1016) (0.026  1.67  1027)
 E = (931.5) (0.026) MeV
 E = 3.87  1012J
1040
As each reaction involves 3 deutrons, so total number of reactions involved in the process 
3
. If each reaction produces an energy E, then
1040
Etotal  E  1.29  1028 J
3
Etotal = Pt
Time of exhaustion of the star
1.29  1028
t
1016
 t = 1.29  1012 s

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3 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021

6. D
P0
Sol. P  2(1  cos  ) 30 cm
4 R = 40 cm
P  3 
P  0 1   S  d=50 cm O
2  5
P0 2  103
P 
5 5
P = 4  10 watt
4

No. of photoelectrons emitted per second


4  104
ne  19
 5  108 photoelectrons/sec
5  1.6  10  10 6

Let after time ‘t’ the photoelectron emission will stop.


q n et
 vS  e  vS
40R 40R
9  109  5  108  1.6  10 19  t
3
0.4
30 5
t 
18 3
t = 1.67 sec
7. A, B, C
Sol.  = 1m
x
/4 = x
So, x = 25 cm
Maximum length of water column = 120  25 = 95 cm max
y = 3/4 = 75 cm
Minimum length of water column = 120  75 = 45 cm
Distance between the two successive nodes =/2 = 50 cm

min

8. B, C, D
Sol. Initial extension is 5cm and equilibrium is at the extension of 2 cm. So Amplitude of SHM is 3cm
9. B, C, D
Sol. For T.I.R. at interface of 1&2
i > C1  sin i > sin C1 ............ (1) 1
i
sin i > sin C1 2
i
Taking refraction at interface of 1&2 90i


1 sin C1 = 2 sin 90o sin C1 = 2 ............ (2)
1
3
Form (1) and (2)

sin i > 2
1
For T.I.R. at interface of 2 and3 90o – i > C2
sin (90o – i) > sin C2cos i > sin C2 ............ (3)
Taking refraction at interface of 2 & 3

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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 4

3
1 sin C2 = 3 sin 90osin C2 = ............ (4)
1
From (3) & (4)
 
cos i > 3  1  sin2 i  3
1 1
 22 32
1 
12 12
12  22  32 and 12  32  22
Obviously, 12   22   32

10. A, C
Sol. To find unit vector along reflected ray use the two laws of reflection.

11. A, C, D
Sol. (A) O

B
A

(C) O

i
A B i
I

(D) Image is inverted  It should be real


12. A, B, C
Sol. Due to a convex mirror of focal length 2.5 cm, due to a concave mirror having its pole at (2 cm, 0)
real virtual pair.

SECTION – C
13. 01000.00
Sol. x = 10 tan 
N P
dx d
 10 sec 2  …(1)
dt dt I
when the mirror is rotated by angle  reflected ray will rotate
x
by angle 2, so i
i
d d
2 …(2) M 
dt dt
O
From (1) and (2) 10 m
dx d dx
 10 sec 2   2   20 sec 2   
dt dt dt
dx
 20 sec 2   2n when i = 37o,  = 53o
dt
2
dx 9 dx 5
 20 sec 2 53  2    20     2  9  1000 m/s
dt  dt 3

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5 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021

14. 00006.50
v 2 v 2 A
Sol. P0  1  0  PA  gh  2
2 2 v1 3m
( v 2  2g  5  10  v1 ) 1m
 v12 v 22 
    gh  (PA  P0 )
 2 2  4m
v 2 v2
(PA  P0 )  gh  2
2
10 3
103 10  10
PA  105   10  2  
2 2 2
PA  6.5  10 4 N/m2

15. 00002.50
Sol. (  1)t  2
2
t
(  1)
t = 25  107 m = 2.5 m

16. 00001.50
P02 Power
Sol. I
2v 4r 2
Put the values to get the answer.

17. 00007.50
2v (n = 2)
Sol. f1  …(i)
2L A C
B

6v
f2  …(ii)
2L
f2 6v / 2L
 3 B C
f1 2v A
2L (n = 6)
f2 = 3f1 = 3  100 = 300
Hz

18. 00022.40
2
D x 
Sol.  D  x   16
 
D x 
 4
D x 
x 3 3D 3
  x   140  84 cm
D 5 5 5
Focal length of the lens
D2  x 2
f
4D
(140)2  (84)2
f  22.40 cm
4  140
f = 22.40 cm

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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 6

Chemistry PART – II

SECTION – A

19. C
Sol. Oxidation number of Ni is zero and strong field ligands.

20. C
Sol. FeO  SiO2 
FeSiO3

21. D
Sol. Its autoreduction
Cu2 S  2Cu2O   6Cu  SO2
22. B
Sol. BeO  NaOH Na2BeO2
Cr  OH 3  NaOH  H2 O2  Na 2CrO 4  H2O
ZnO  NaOH 
 Na2 ZnO2  H2O
Al  OH 3  NaOH  Na  Al  OH 4 

23. A
Sol. XeOF4   8  6   7  4   42
 Isoelectronic
BrF5  7  6  42 

F F

XeOF4  sp3 d2 Xe

F F
O

F F

BrF5 
 sp3 d2 Br

F F
F
Both square pyramidal.

24. C
Sol. SO32   dil. H2SO4 
 SO2
SO 2  Ba  OH2 
 BaSO3 
 White turbidity 
SO2  K 2Cr2O7 / H  Cr 3   SO24

Green
SO 2  2H2 S  3S  2H2 O
 Yellowish white turbidity 

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7 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021

25. B, C, D
Sol. Facts.

26. A, B, C, D
Sol. CuSO 4  4NH3  Cu NH3  4  SO 4  blue solution 
FeCl3  K 4 Fe  CN 6   KFe Fe  CN6    blue 
FeCl2  K 3 Fe  CN 6   Fe 3 Fe  CN6 2    blue 
 
Na   x  y  NH3 
 Na NH3  x   e NH3  y 
 
Solvated cations  Solvated electrons 

blue solution

27. A, C, D
Sol. XeF4  s   Pt  s  
 Xe  g  PtF4  s 

 N  CH3  4    XeF5 
XeF4  s   N  CH3  4  F 

28. B, C, D
Sol. In negative deviation
H   ve, S   ve and intermolecular forces are more than in pure liquids.

29. A, C, D
Sol. NaCl  K 2 Cr2O7 
H2 SO4

 CrO2 Cl2  Na2 SO4  Cl2
Red vapour  Small amount 
CrO2 Cl2  NaOH 
 Na2 CrO 4  NaCl
 Yellow sol.
Na 2 CrO 4  AgNO3  Ag2 CrO 4 
Brick red
Na 2 CrO 4  Pb  CH3 COO 2 
 PbCrO 4 
 Yellow 

30. B, C
Sol. Osmotic pressure and boiling points of a solution decreases on increasing dilution of a solution
while vapour pressure and freezing point of solution increases on increasing dilution.

SECTION – C

31. 00071.68
nM
Sol. d
Nav  a3
1.95    6.25  108 
3
 6.023  1023
M 
4
 71.6848
 71.68

32. 00000.69
Sol. m1  0.1 kg, m2  0.012 kg
Tb of sol.  100.57o C Tb of water  100 o C .

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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 8

Molar mass of Ba NO3 2  261.3 g mol1


Tb  K bm  i
 0.012 / 0.2613 
0.57  0.52  i
0.1
i  2.3868  2.38

i  1   n  1 
2.38  1

 3  1
  0.69

33. 00065.00
Sol. 
Ecell  ECl
o
 |Hg Cl
2 2 |Hg
 EQo ,QH 
2 ,H |Pt
  0.0591
1
log
1
H  
 
0.0591
Ecell   0.280  0.6996    6.0
1
 0.065 V  65 m.volt
Ecell  65 m volt

34. 00067.84
Sol. Partial pressure of oxygen PO2  0.18 atm  
 0.18  1.01 10 Pa 5

= 18180 Pa
 
Partial pressure of N2 PN2  0.82atm
= 82820 Pa
18180
Fraction of oxygen dissolved in H2 O 
2.53  109
 7185.77  109
 7.186  106
82820
Fraction of nitrogen dissolved in H2 O 
5.47  109
 15.140  106

Amount of dissolved N2 15.140  10 6


  2.108
Amount of dissolved O 2 7.186  10 6
 2.11
2.11
 % N2   100  67.845
3.11
 67.84

35. 00005.76
2
Sol. S A  0.5Rn
1
= 2.88 Joule
Same for B, SB  2.88 Joule

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9 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021

 STotal  2.88  2.88  5.76 Joule

36. 00002.29
1 
Sol. AgCl  s   H2  g    H  aq   Cl  aq  Ag  s 
 

2
0.0591 H  Cl 
E  Eo  log  1/2
1 pH2
pH2  1 atm & H   Cl 
0.059 2
 E  Eo  log H 
1
0.493 = 0.222 + 2((0.0592) pH
 pH  2.29

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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 10

Mathematics PART – III

SECTION – A

37. C
Sol. Taking dot product with a, b, c , we get 5  a b c   a  a , 3  a b c   a  c and a  b  0
 2a  c  3d   a
So,  13, as d  a   1b   2 a  b   a  0
 a b c 

38. B
Sol. Let p be (, , ) so points A, B and C are (, , 0), (, 0, ) and (0, , ) respectively.
x y z   
So, plane passing through these points is    2 also   p
   a b c
If (x1, y1, z1) is foot of perpendicular from origin, then equation of plane
x1(x – x1) + y1(y – y1) + z1(z – z1) = 0
x y z
Comparing with    2 , we get 2x1 = 2y1 = 2z1 = x12  y12  z12
  

  1
So locus is x12  y12  z12  
1

1 
  2p
 ax1 by1 cz1 

39. A
Sol. For non trivial (infinitely many solution)
bca c

ab  c  a  b  a  b  c 
(a + b – c)(b + c – a)(c + a – b) – abc = 0
But for distinct the values of a, b, c L.H.S is always negative. c
Let a > b > c so (a + b – c) and (c + a – b) > 0 and for it b + c – a  0 result is obvious for b + c > a
consider a, b, c as side of triangle
82  2 
L.H.S = 8(s – a)(s – b)(s – c) – abc =  4 R  4    R  = 4(2r – R) < 0
s  s 

40. C
 1 
Sol. Probability he gets atleast one head =  1  n  probability he gets head 3k times
 2 
 n
 2 
n 
 1   1      1     n 1
  2   2  1  2n  3   1
=   n =
 3 2  3  2n 
n 1
2n  3   1
So, required probability is
3  2n  1

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11 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021

41. A

Sol. Using rotation, we get complex number (4i) P


corresponding to P, Q, R as C

3 + (3 – 4i), 4i + 4i and –3 respectively Q


3  4i
So, centroid of PQR =
3 A B (3)

42. A
1 1 1 1
Sol. Let Tk 1  so , , are in Arithmetic progression
a  kd a  5d a  9d a  17d
1 1 1 1
     a = 7d
a  9d a  5d a  17d a  9d
1 1 1
 Tp  , T12  , Tq 
p  6 d 18d q  6 d
 182 = (p + 6)(q + 6) so maximum value of q is 30 (as p + 6  7)
So, minimum value of p + 6 = 9
 q + 6 = 36  q = 30

43. A, C, D
Sol. Let xy + yz + zx = –p, xyz = q
So, x, y, z are roots of equation t3 – pt – q = 0
 x3 = px + q, y3 = py + q, z3 = pz + q
So, x3y + y3z + z2x = p(xy + yz + zx) + q(x + y + z) = –p2 = –9
 p = 3
xy + yz + zx = xy – (x + y)2 = –(x2 + y2 + yx) < 0  x, y  R
if x = y, we get z = –2x, –3x 2 = 3, x =  1 or x = i

44. A, B, C, D
Sol. 6k + 4 is such number which leaves remainder 1 when divided by 3. So as a whole number of the
form 3k – 1 (i.e. 2, 11) should be used even number of times and of form (3k + 1) (i.e., 7) can be
used any number of time. So total cases = 3  (2  3 + 1  3) = 27
Number of divisors of n2 = 7  9  5  11
Number of divisors of n = 4  5  3  6
So, number of divisors of n2, which are not divisors of n is 7  9  5  11 – 4  5  3  6 = 3105
7  9  5  11  1
Number of divisor of n2 which are less than equal to n =
2
So, divisors of n2 which are less than n but does not divide n
7  9  5  11  1
  360  1373
2

45. A, D
Sol. (MN)2 = 3MN
 NMNMN M = 3NMNM
 (NM)3 = 3(NM)2  (NM) = 3I
1 1 1  1
P  I so, P  P2  .....    2  .....  I  I
3 3 3  2

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AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021 12

46. A, B, D
Sol. for 1 and 4 option we use P.I.E
36  3C1 26  3 20
Option 1 : 
36 27
3C2  26  2 
62
Option 2 : 6

3 243
for favourable cases in 3 and 4 we use exponential generating function
6!  e x  e x  e x  e  x  e x
Option 3 : favourable cases = coefficient of x6 in
4
 x
e e x   e x  e x  x 3 6  28  1
Option 4 : favourable cases = coefficient of x6 in 6!   1    e  1 
 2  2  4

47. A, B, C, D
3n 3n  3 3n  6
Sol. f(n) = coefficient of xn in n C0 1  x   n C1 1  x   n C2 1  x   .....
 coefficient of xn in ((1 + x)3 – 1)n
3n
 n 1
33
 f(n) = 3n, so f(ff(n)) = 33   27 
 3n 1
 28  13 , so remainder is –1 or 6

f f n   3 3
 n 1 nC1 2  nC2 22  .....  3 9 n C1  nC2 21  ..... nCn 2n 1 
3

 C1  C2 2  ..... Cn 2 
n n 1 n n 1
3 10  1 , so remainder is –3 if n is odd + 3 if n is even
n
f(n) 3n  1  2 so remainder is 1

48. A, B, C, D
Sol. a + 2b = 9c, c + 2d = 9a, 2ab = –4d, 2cd = –4b
 ac = 4, also a2 – 9ac – 4d = 0, c2 – 9ac – 4b = 0
adding two, we get (a + c)2 – 16(a + c) – 80 = 0
 a + c = 20 or –4

SECTION – C

49. 00012.00
  
Sol. Let x  , y  , z 
a b c
2
a b c
L.H.S. reduced to  a 2  b2  c 2     
  
Using wt. A.M.  wt. G.M.
1
a 2  b2  c 2
   2a 2b  2c  ab c
abc
a b c
   
1
    1 1 1  a b  c
abc  a b c
   
2
a b c
  a 2  b2  c 2        a  b  c 
3

  
So, (a + b + c) = 216, a + b + c = 6
3

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13 AITS-PT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2021

2
a2  b 2  c 2  a  b  c 
Using mth power inequality, we get    a2 + b2 + c2  12
3  3 

50. 00002.50
Sol. z3 + (–z1)3 + (–(1 – )z2)3 = 3z(–z1)(–(1 – )z2)
 z – z1 – (–1 – )z2 = 0,   R
So, |z| is perpendicular distance from (0, 0) to line joining the points (3, 4) and (1, –2)

51. 00000.00
Sol. As three planes have a common line of intersection so x1, x2 , x3 are coplanar
also 8x 2  x3  5x3  x1  3x1  x2  0

52. 04585.00
Sol. Case-1 > 1  i, j, k  10, sum is 11C3
Case-2 > 1  i  10 and 11  j, k  20, sum is (10C1·11C2)  4
Case-3 > 1  i, j  10, 11  k  20 sum is (10C2·10C1)  2
Case-4 > 11  i, 5, k  20, 11C3  23
So, total sum is 11C3 + 10C1 11C2  4 + 10C2  10C1  2 + 11C3  8 = 4585

53. 00000.50
Sol. 3xn1xn  xn xn1  1 . Let an  3n xn1xn
3n  2a1  3
an1  an  3n  an  (Telescopic sum)
2
3n  2a1  3 3n1  2a1  3
Hence, 3n xn xn1  , 3n1 xn1xn 
2 2
x 3   2a1  3 
n 1
 n1  n1 for sequence to be periodic 2a1 – 3 = 0
xn1 3  3  2a1  3 
3
 3x 0 x1 
2
54. 00000.50
Sol. A = UV
 1 1 1 
  11  2  12  1 0 0 0 . . 4 1  4
... 4 
   42 1 4  n  1
U   1  2  22  1 0 0 . . .
2
V 0 0 0 
   0 
    0 . 0 
 
  1  2  n  1 0 . . .
n 2 0 
 trace A 0 0 . 0 
 
So, VU   0 0 
 0 . 0 
Hence, A = UVUV = (trace A)UV = trace(A)·A
2

 An = (trace A)n – 1 A  trace(An) = (trace A)n


n
 2  n
trace A 
1
 1i  2i  1   
1  i 
1  2
1

1 

 2i  2i  1  2i  2i  1 
2 i1 4
 4i  1  i1 2 2

1
n   1i  1i1  1
= lim
n 2
  2  2    2
i 1  2i  2i  1 2i  2i  1 

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