Vidyamandir Classes: Innovating For Your Success

SOLUTIONS
Joint Entrance Exam | IITJEE-2021
18th March 2021 | Morning Session

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 Vidyamandir Classes: Innovating For Your Success

Joint Entrance Exam | JEE Main 2021

PART-A PHYSICS

SECTION-1
1.(4) i  i max sin( t  )

at t  0, i  i rms

irms  2(irms )sin 



4
 
i  i max sin  t  
 4 
at t  t1, i  irms

 
i max  i max sin  t1  
 4 
 
t1  
4 2

t 1 
4
2 
t 
T 1 4
T
t1 
8
1 1  1 1 
t1     
8  f  8  50 
1000
t1  m s  2.5 ms
400
2.(4) P = Fv
P = mav


P dt  m v dv

v2
m  Pt
2
1/2
 2Pt 
v 
 m 
1/2
dx  2 Pt 
 
dt  m 
1/2 3/2
 2P  t
x  
m  3/2

x  t 3/2
3.(1) B A  0nI  3T

1
BC  0n
3
BC  1T

4.(3) Conceptual

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1 1 L R
5.(3)  ,Q  , Band width 
LC R C L

6.(2) He can’t see distance object = Myopia

Can’t see mesh (mis orientation of axis)
= Astigmatism
7.(4) Using angular momentum conservation

L i  MR 2

L f  ( MR 2  2mR 2 )

 M 
   
 M  2m 
 R l 2d
8.(1)   
 R l d
 V I l 2d
   
 V I l d
  0.1 0.01 0.1 0.01 
%    2   100
  5 2 10 5 
= 2 + 0.5 + 1 + 0.4 = 3.9%
9.(2) Distance between 1st and 3rd maxima will be 3
D 0.5
 2  2  5890  10 10 
d 0.5  10 3
 11780  10 7m

10.(1)

11.(4) T 2  R3
2 3 2
 T2  R   T2  3 T2
     2      9   27
T
 1  R1   T1  T1

dN A
12.(2)    B N A  C N A
dt
 (  B  C )N A  eq N A

eq   B  C

ln 2 ln 2 ln 2 1 1 1
    
Teq T1/2B T1/2C Teq T1/2B T1/2C

T1/2B  T1/2C
Teq 
T1/2 B  T 1/2C

13.(3) VP  4Ve

h

P

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P 2 h /p p
 
e 1 h / pe

2 Pe m e  ve
 
1 Pp m p  4ve

8m p  m e

14.(2) E = CB

E  3  108  2  10 8
E=6
  
Direction of v is E  B

i  j  k


So E  6 ĵ

4
15.(3) V    (0.2)3 cm 3
3
m = density × volume
4
m    (0.2)3  10 3  9.81
3

 n  1.67  10 19  3.55  105

n  1.73  1010

16.(4)   u  at (straight line positive slope)

1 2
S  ut  at (upward parabola)
2
P1V1  P2V2
17.(3)
 1
5
(100  2  200  3)  500 J
2
18.(4) As per law of equipartition of energy.

l 10 3
19.(3)  100   100  1%
l 0.1
T 1
 100   100  1%
T 100
g l 2T
 
g l T
g
 100  3%
g
m
20.(3) E  EH
me

E  m1
E   (207) (13.6 eV )

SECTION-2
1
1.(10) mg h  mv 2
2

2  10  5  v 2  v  10 m /s

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I C
2.(100) 
I B
2
I C R0 P
 Power gain  0
2 Pi
I B Ri

P R
2  0 i
Pi R0

2  106  10 2
  100
3.(70) Let the voltage required be x
Then the current through battery = x/10
100
Req of parallel combination = 
7
Thus applying KVL we get
100 x
x   170
7 10
17
x  170
7
 x  70 V

4.(20) Pix  P fx  10 3  10

Piy  P fy  10  10  10  10

v2  20

 v2  u 2  100  0.1
5.(10) F  m  
 2s  2  1/2
 
= – 10 N
0 A .85  100 885
6.(161) Ceq     161
d2 5  0.5 5.5
d1 
k
7.(32) Given 2 A   B

2f F B
A 
Aa  16 Aa 

A 1

B 32

q
8.(2) Initial VC   10 Volts  VR
C
V R
 2 A
R
9.(5) Net speed of summer along river flow is zero
10 cos120  VR  0

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VR  5 m /s

  2
10.(6) t  and   ,  
 6 T
T 2 1
t    sec
12 12 6

PART-B CHEMISTRY

SECTION-1
1.(3) List-I List-II
CaOCl 2 Bleach

1
CaSO4 . H2O Plaster of paris
2
CaO Cement
CaCO3 Antacid

2.(4)

3.(2)

4.(4) Structure of trans - [NiBr2 (PPh3 )2 ]

Structure of meridonial - [Co(NH3 )3 (NO2 )3 ]

5.(2) List-I List-II

(Process) (Catalyst)
(a) Deacon’s process CuCl2

CuCl
2
(4HCl  O2  2Cl2  2H2O)

(b) Contact process V2O5

V O
2 5  2SO
(2SO2(g)  O2(g )  2(g ) )

(c) Cracking of hydrocarbons ZSM-5

(d) Hydrogenation of vegetable oils Particles ‘Ni’

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6.(2)

7.(1)

8.(4) Al 2O3 (alumina) is infusible (M.P = 2050°C), so it can’t be electrolyzed, So pure alumina dissolved in

molten cryolite (Na 3 AlF6 ) containing some CaF2 or NaF is electrolyzed at about 800°C – 1000°C.

(Cryolite decreases melting point and increases conducting) while CaF2 and NaF are added only to
increases conducting.
9.(2) Number of radial node = n – l – 1
Number of angular node = l
Ex  In 3s, number of angular node = 0
Number of radial node = 3 – 0 – 1 = 2
10.(1 and 3) Bonus
PCl3  H3PO3  2H2O

11.(3) Na > Mg > Al

Na   Mg 2  Al3 order of size

1.02 0.72 0.54
12.(3) During boiling the soluble is converted into insoluble Mg(OH)2

K sp of Mg(OH)2  K sp MgCO 3

13.(3) (i) Antifertility

(ii) Antacid
(iii) Tranquilizer
(iv) Artificial sweetener
14.(4) Reducing smog is mixture of smoke, fog and sulphurdioxide.
15.(4) hcp ; z = 6
TV = 2 × 6 = 12
But occupied are 2/3 rd
2
12 8
3
M8 A 6  M 4 A 3

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16.(4) 3° alcohol and benzyl alcohol reacts instantly to give turbidity.
17.(2) (a) Alcoholic KOH is used for  -elimination reaction
(b) Pd / BaSO4 is Lindlar’s catalyst

(c) BHC is obtained by addition reaction on benzene of Cl2

(d) Polyacetylenes have much higher conductance than metal conductors, these can be used to
prepare lighter and cheaper batteries.
18.(4) In acidic solution nitrite ions react with sulphanilic aid to form diazonium salt, which in turn reacts
with 1-naphthylamine to give red brown colour.
19.(4)

Shows functional group isomerism.

20.(3) (a) Chlorophyll contains magnesium
(b) Vit B12  cobalt

(c) Anticancer drug  cis platin

(d) Grubbs catalyst  Ruthenium

SECTION-2
1.(128)

 r H  B.E.C–C  6 B.EC–H  (B.E C C  4B.E.C H  B.EH  H )

= 347 + 6 (414) – (611 + 4(414) + 436)

 128 kJ mol 1
[CH3COONa]
2.(10) pH  pKa  log
[CH3COOH]

[CH3COONa]
5.74  4.74  log
1
1  log [CH3COONa]

[CH3COONa]  10 M

x 
3.(3) K 3 Cr(OX)3 
 

3+x–6=0
x = +3
Electronic configuration of Cr 3  [Ar]18 3d 3

 Total number of unpaired e1s  3

4.(15) Total number of electrons in AX must be 15 for bond order 2.5.
7
5.(18) C2H6  O  2CO2  3H2O
2 2
Given mass of ethane = 3g
3
Number of moles of ethane   0.1
30
1 mol of ethane produce H2O  3 moles
0.1 mol of ethane will produce H2O  0.3 moles

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 0.3  6.022  1023 molecules

 1.8066  10 23  18.066  1022

So, x = 18
6.(50) Tf  3.885

K f  1.85 K kg mol 1

Tf  ik f m
3.885 = i (1.85) (2)
i = 1.05
For dissociation of acid
HA  H  A
1  
1  

1    
i 1 
1
1.05  1  
  0.05

  50  10 3

7.(3)

23
 0.1 mole
230
1 mol of benzylamine reacts with methyl bromide = 3 moles
0.1 mole of benzylamine reacts with methyl bromide = 0.3 moles
 3  10 1
So, n=3
8.(3) Rate  k [NO]p [Cl 2 ]q

0.18  k [0.10]p [0.10]q ……(1)

0.35  k [0.10]p [0.20]q ……(2)

1.40  k [0.20]p [0.20]q ……(3)

Divide 1 by 2

0.18 k [0.10]p [0.10]q


0.35 k [0.10]p [0.20]q

0.51  (0.5)q
q=1
Divide 2 by 3

0.35 k [0.10]p [0.20]q


1.40 k [0.20]p [0.20]q

0.25  [0.5]p
p=2
Overall order =p+q
=2+1=3

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9.(45) 2Fe3   2I   2Fe2  I2 ……(1)

(–0.036  3)  (–0.440  2)
E 
1
= –0.108 + 0.88
= 0.772 V
For reaction (1)
Ecell  E  E
Fe3  /Fe2  I2 /I

= 0.772 – 0.539
= 0.233
G  nFEcell
G  2  96500  0.233
= –44969 J
= –44.96 kJ
 45 kJ
10.(16)

x
Number of moles of 3-hydroxypropanal 
74
x
Theoretically number of moles of acrolein produced 
74
x
Theoretical mass of acrolein produced =   56 g
74
Actual mass of acrolein produced = 7.8 g
Actual mass
% yield   100
Theoretical mass
7.8
64   100
 x 
  56 
 74 
7.8  100  74
x
64  56
x = 16.10 g
x  16 g

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PART-B MATHEMATICS

SECTION-1
 1/x ; x 1
 2
1.(3) f ( x )  ax  b ; 1  x 1
 1/x ; x  1

For the function to be continuous at x = 1 & –1
a+b=1
For the function to be differentiable at x  1
2a  1
1 
 a  ,  b
2 2
m  tan 
2.(3) Slope of the given line 
1  m tan 

Where m  3 2 and tan   2

3 2  2 4 2 2 2
Slope   or
1 6 5 7

4 2
Equation of the line y3  ( x  1)
5
2 2
y3  ( x  1)
7
One of the lines will be 5y  15  4 2x  4 2

 4 2 x  5y  (15  4 2)  0

 1 2 0
 
3.(2) A  2B   6 3 3  ……(i)
 5 3 1 
 
2 1 5 
 
and 2 A  B  2 1 6  ……(ii)
0 1 2 
 
1 × (i) –3 × (ii)
 1 2 0   6 3 15 
   
5( A  B )   6 3 3    6 3 18 
 5 3 1   0 3 6 
   
 5 5 15 
 
  0 0 15 
 5 0 5 
 
Trace of (A – B) = 2

4.(3) y 2  4a ( x  a )
2yy  4a  yy  2a

 yy 
 y 2  2yy  x  
 2 

 2yyx  (yy)2

 yy2  2yx  y

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5.(2) The magnitude of the vector is an invariant

 (3 p )2  12  ( p  1)2  10

 8 p 2  2p  10  4 p2  p  5

 4p2  p  5  0  ( p  1)(4 p  5)  0
5
So, p = –1 or
4
6.(1) Centre of the circles are
(0, 0)
(1, 0)
(1, 1)
(0, 1)
Which are the sides of a square

1  sin 2 x sin 2 x sin 2 x

2 2
7.(1) cos x 1  cos x cos2 x 0
4 sin 2x 4 sin 2x 1  4 sin 2 x
Applying transformation C1  C1  C2

1 sin 2 x sin2 x
 1 1  cos2 x cos2 x 0
0 4 sin 2 x 1  4 sin 2 x
Applying transformation R 2  R2  R1

1 sin 2 x sin2 x
0 2 1 0
0 4 sin 2x 1  4 sin 2x
 2(1  sin 2 x )  4 sin 2x  0
 1  4 sin 2 x  2 sin 2x  0
 2 sin 2 x  1
1 7  11
sin 2 x   or 2 x  ,
2 6 6
7 11
 x  or
12 12
8.(4) 3x + 4y = 9 and y = mx + 1
3x + 4(mx + 1) = 9
 x (3  4m )  5
5
 x 
3  4m
For x to be an integer (3 + 4m) must be a factor of 5
 3  4m  1 or  5
 m  2 or m  1

(2 x  1)cos (2 x  1)2  5
9.(1)
 4x 2  4x  6
dx

 
(2x  1)cos  (2 x  1)2  5 
  dx
I 
 2
(2 x  1)  5
1
Let sin ( (2 x  1)2  5)  t
2

cos( (2 x  1)2  5 )
(2 x  1) dx  dt
(2x  1)2  5
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1
(2 x  1)2  5 )  c
I 
 dt  t  c  2 sin(
sin 1 x  tan 1 x  (sin 1 x  x )  x  tan 1 x 
10.(2) lim  lim   
x 0 3x 3 x 0 
 3x 3 
 3x 3 

Our good fortune that both the these limits can be evaluated independently by application of
L  Hopital’s rule
 1 
 1
 sin 1 x  x  2 1 1 x2
Let lim    lim  1  x 
  xlim
x 0 
 3x 3  x 0
  9x 2

0
( 1  x 2 )(9x 2 )
 
 

x2 1
 lim 
x 0 2
(1  1  x )( 1  x )(9 x ) 2 2 18

1
1
x  tan 1 x 1  x 2 lim x2 1
Let L 2  lim  lim 
x 0 3x 3 x 0 9x 2 x 0 (1  x 2 )9 x 2 9

1 1 1
L  L1  L 2   
18 9 6
 6L  1  2
11.(2) Domain of f is [0,  ) and g is ( ,1]
Domain of f + g = [0, 1] and f –g is [0, 1]
f/g is [0, 1) and g/f is (0, 1]
Common domain (0, 1)
12.(4) Assuming the continued fraction is convergent
1 1
x 3  x 3
1 4x  1
4
x x
x
 x 3
4x  1

 4 x 2  x  12 x  3  x

12  144  48
 4 x 2  12x  3  0  x  (Rejecting the negative value)
8
3  9  3 3  12
x  
2 2
13.(3) Sum of numbers

 3!(1  10  10 2  103 ).2  3(1  10  102  10 3 )(1  3)

= 12 (1111) + 12(1111) = 26664
14.(1) The circles have their centre as radii
C1  (5, 5) ; r1  3

C2  (11, 5) ; r2  3

C1C2  r1  r2

The circles touch externally.

15.(3) (100) (100) + (99) (101) + (99) (102) + ……+ (1) (199)
99 99

 (100  r )(100  r )   (100  r )(100  r )

r 0 r 0
99 100
  (1002  r 2 )   (1002  r 2 )
r 0 r 0

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99(100)(199) (100)(101)(201)
 (1002 ).100   (100)2  (101) 
6 6

 1003  (33) (50) (199)

  3 ;   (33)(50)

Slope Slope   550

2 2
16.(1) a z  z  z  d  0 or a z  z  z  d  0

Comparing this equation w.r.t. z  z 0  r

2 2
 (z  z0 ) (z0  z0 )  r 2 or z  zz0  z 0z  z 0  r2  0

a  d
or    a R
1 z 0 2
z0  r 2

z2
2 d 2
or z0 r2  or z0 
a a2

z2
d |  |2 d | 2 | ad
 r2   r2   
a2 a a2 a a2
or |  |2 ad  0

17.(1) (1  x  2x 2 )20  a 0  a1x  a 2 x 2    a 40 x 40

40

 ar  (4)20  240
r 0
40

 (1)r ar  220
r 0
18 18
 2  a 2r 1  240  220  220(220  1)   a 2r 1  219(220  1)
r 0 r 0
39
Now a 39 is the coefficient of x in

(1  x  2 x 2 )20  (1  x  2x 2 )(1  x  2x 2 )(1  x  2 x 2 )

 20C1  219  20  219

Required sum  219 (220  1)  20  219

 219 (220  21)

18.(1) For the system of equation to have non-trivial solutions
  
   0
  

 (      )(  2  2   2       )  0
  0 or  Since a = 0  
      a ;       b

 a   3  b  3 2  a 2  92 ; b  32

a2
 3
b

cosec 1x
19.(2) f (x ) 
x  [x ]

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x  ( ,  1]  [1,  )  Z
100 100 100
1 1 1  1 1 
20.(2)  (2r  1)2  1   
(2r )(2r  2) 2   2r  2r  2 
r 1 r 1 r 1

11 1  1 200 25
     
2  2 202  2 2.202 101

SECTION-2
1.(6) if z1, z 2 and origin form an equilateral triangle, then either
/3 /3
z 2  z1ei or z1  z 2ei

 z 23  z13  0  z 22  z1z 2  z12  0

 ( z1  z 2 )2  3z1z 2

z1  z 2  a ; z1z 2  12

 a 2  36  a  6  |a |  6
2.(300) Number of times 3 will be listed
 3C19.9  3C2  2  9  3C3  3  1

= 300
3.(28) The given plane passes through (3, 0, –2)
Vector normal to the plane  (2, 6,6)
The plane 2(x – 3) – 6(y – 0) + 6(z + 2) = 0
 2 x  6y  6z  6  0  x  3y  3z  3  0

(a 2  b 2  c 2  d 2 )min  28
4 4 4
f ( x 2 ) dx  2 f ( x 2 ) dx  2 (4 x 3  g (4  x )) dx
4.(512)
  
4 0 0
4 4
I  8 x 3dx  2 g (4  x ) dx
 
0 0
4 4 4
Now
 g (4  x ) dx 
 
g( x ) dx   g (4  x ) dx
0 0 0
4 4
8  44
I  8 x 3dx   8  43  512

 g (4  x ) dx  0 So
 4
0 0
8 6
5x  7x 1
5.(4) f (x ) 
 ( x 2  1  2x 7 )2 dx ,(x  0), f (0)  0 and f (1) 
K
,

5 7

x6 x8 1 1
f (x ) 
1 1 
2
dx ; u 
x5

x7
2

 5  7  2
x x 
 5 7 
; du      dx
 x 
x8 
du 1 1

 u2  u  c  1

1
2
c

x5 x7

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x7
f (x )  c  f (0)  0  c
2x 7  x 2  1

x7
 f (x ) 
2x  x 2  1
7

1
f (1)   k 4
4
6.(4) OA  OB
1 1
  1  a 2b 2  1 ……(i)
2
a b2
2
1 1
2   
(a  b )  b a 
 1
4 4

(a  b )2 (a  b )2  16a 2b 2

 16  (a 2  b 2 )2  16

If a 2  b2  4

 a2  4
a2
 a 4  4a 2  1  0
4  20
 a2 
2
1
 a 2  2  5 ; b2   5 2
2 5
2
1  
AB 2  (a  b )2    
b a 
1 1 2
 a 2  b 2  2ab   
2 2 ab
a b
2 5  5 2 5 2 5 2
4 5
If a 2  b 2  4
1
 a2  4 0
a2

a 4  4a 2  1  0
4  16  4
a2 
2

a 2  2  5

a2  5  2

b2  5  2
2
1 1 
AB 2  (a  b )2    
b a 
1 1 2
 a 2  b 2  2ab   
a2 b2 ab

 5 2  5  2 5  2 5 2
4 5
Area of square 4 5

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Its square = 80
th
7.(35) Say the age of i teacher is x i
25
 xi 25
i 1
25
 40   xi  1000
i 1
24

24  xi  y
i 1
  xi  940 25
 39
i 1
 y  25  39  940  975  940  35
8.(4) Say the plane is x – 2y + 2z + c = 0
|1  4  6  c |
1  | c  3|  3
1 4  4
 c  0 or c  6
So, the plane is x – 2y + 2z = 0 or x – 2y + 2z – 6 = 0
a = 1, b = –2 ; c = 2 ; d = –6 yield a positive value of K = 4 .
1
9.(1) cot x  cot x 
sin x
Obviously cotx < 0
1
  cot x  cot x 
sin x
2 cos x 1
  
sin x sin x
1  2
or cos x    x   
2 3 3

10.(4) 22!  4
OR
No. of divisors of 5 × No. of divisors of 3
(16) 2

 222  16

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