JEE Physics Single Choice Questions

JEE Main_25-07-2021_Shift-01
PHYSICS
Single Choice Type
This section contains 20 Single choice questions. Each question has 4 choices (1), (2), (3) and (4) for its answer,
out of which Only One is correct.
1. A monoatomic ideal gas, initially at temperature T 1 is enclosed in a cylinder fitted with a frictionless piston.
The gas is allowed to expand adiabatically to temperature T 2 by releasing the piston suddenly. If l1 and l2
T1
are the lengths of the gas column, before and after the expansion respectively, then the value of will
T2
be
2 2
l l l 3 l 3
(1) 2 (2) 1 (3)  2  (4)  1 
l1 l2  l1   l2 
Ans. (3)
Sol. For adiabatic process
 1
T1  V2 
 
T2  V1 
5 / 3 1 2/3 2/3
V   A   
=  2  =  2  =  2 
 V1   A 1   1 
2. Some nuclei of a radioactive material are undergoing radioactive decay. The time gap between the
instances when a quarter of the nuclei have decayed and when half of the nuclei have decayed is given
as: (where  is the decay constant)
3
ln
2 1 ln 2 ln 2 2 ln 2
(1) (2) (3) (4)
 2   
Ans. (1)
Sol. N = N0e–t
3N0
 N0 e   t 1
4
4
n 
t1   
3

 n2
t2 

4
n 
t2 – t1 =
n2
– 3
 
3
n 
= 2

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3. Match List-I with List-II
  
(a) C  A  B  0 (i)
  
(b) A  C  B  0 (ii)
  
(c) B  A  C  0 (iii)
  
(d) A  B  C (iv)
Choose the correct answer from the options given below

(1) (a)  (iii), (b)  (ii), (c)  (iv), (d)  (i) (2) (a)  (iv), (b)  (iii), (c)  (i), (d)  (ii)
(3) (a)  (i), (b)  (iv), (c)  (ii), (d)  (iii) (4) (a)  (iv), (b)  (i), (c)  (iii), (d)  (ii)
Ans. (2)
  
Sol. (I) A  C  B
  
(II) A  B  C  0
  
(III) A  B  C  0
  
(IV) A  B  C  0
4. A particle of mass 4M at rest disintegrates into two particles of mass M and 3M respectively having non
zero velocities. The ratio of de-Broglie wavelength of particle of mass M to that of mass 3M will be
(1) 1 : 3 (2) 3 : 1 (3) 1 : 1 (4) 1 : 3
Ans. (3)
h
Sol. 
P
here momentum is same for both
 2m 1

m 1
5. A ray of laser of a wavelength 630 nm is incident at an angle of 30° at the diamond-air interface. It is
going from diamond to air. The refractive index of diamond is 2.42 and that of air is 1. Choose the correct
option.
(1) angle of refraction is 30º (2) angle of refraction is 24.41º
(3) refraction is not possible (4) angle of refraction is 53.4º
Ans. (3)

Sol.
Vacuum
(=1)
30° diamond
(=2.42)
 1 
Critical angle C = sin–1   = 24.4°
 2.42 
Given Incident angle 30° > C
So there is TIR at interface
ray will not get refrected
6. In amplitude Modulation, the message signal

Vm(t) = 10 sin(2 × 105t) volts and
Carrier signal
VC(t) = 20 sin(2 × 107t) volts and
The modulated signal now contains the message signal with lower side band and upper side band
frequency, therefore the bandwidth of modulated signal is  kHz. The value of isis :
(1) 50 kHz (2) 200 kHz (3) 100 kHz (4) 0
Ans. (2)
Sol. Band width = 2fm
= 2 × 105 Hz = 200 kHz
7. The half-life of 198Au is 3 days. If atomic weight of 198Au is 198 g/mol then the activity of 2 mg 198Au is [in
disintegration/second]
(1) 2.67 × 1012 (2) 6.06 × 1018 (3) 32.36 × 1012 (4) 16.18 × 1012
Ans. (4)
m 2  103
Sol. No. of Nuclei = .NA   6.02  1023
M 198
0.693 2  103
A0 = N0 =   6.02  1023
3  24  60  60 198
1618 × 10–8  1018 = 16.18 × 1012
8. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A: Moment of inertia of a circular disc of mass ‘M’ and radius ‘R’ about X, Y axes (passing
through its plane) and Z-axis which is perpendicular to its plane were found to be Ix, IY & IZ respectively.
The respective radii of gyration about all the three axes will be the same.
Reason R : A rigid body making rotational motion has fixed mass and shape.
In the light of the above statements, choose the most appropriate answer from the options given below :
(1) Both A and R are correct and R is the correct explanation of A.
(2) Both A and R are correct but R is NOT the correct explanation of A.
(3) A is not correct but R is correct.
(4) A is correct hut R is not correct.
Ans. (3)

9. A linearly polarized electromagnetic wave in vacuum is E = 3.1 cos [(1.8)z – (5.4 × 106)t] î N/C is incident
normally on a perfectly reflecting wall at z = a. Choose the correct option
(1) The frequency of electromagnetic wave is 54 × 104 Hz
(2) The reflected wave will be 3.1 cos [(1.8)z + (5.4 × 106)t] î N/C
(3) The transmitted wave will be 3.1 cos [(1.8)z – (5.4 × 106)t] î N/C
(4) The wavelength is 5.4 m
Ans. (2)
Sol.  = 5.6 × 103 
2f = 5.6 × 103
5.6  103 5.6  103
 f=   891.7 Hz
2 2  3.14
C = f
c 3  108
= =  3.36  105 m
f 891.7
Reflecting wave
E = 3.1 cos [(1.8)z + (5.4 × 106)t] î N/C
10. Two different metal bodies A and B of equal mass are heated at a uniform rate under similar conditions.
The variation of temperature of the bodies is graphically represented as shown in the figure. The ratio of
specific heat capacities is:
3 4 8 3
(1) (2) (3) (4)
4 3 3 8
Ans. (4)
Sol. Q = nCT
dQ dT
 nC
dt dt
Rate of heat is same for both gases
 dT   dT 
So, n1C1   n2C 2  
 dt 1  dt  2
 dT  90
 
C1  dt  2 90  3 3
  6  
C 2  dT  120 120  6 8
 
 dt 1 3

11. Two wires of same length and radius are joined end to end and loaded. The Young’s modulii of the
materials of the two wires are Y1 and Y2. The combination behaves as a single wire then its Young’s
modulus is
Y1Y2 Y1Y2 2Y1Y2 2Y1Y2
(1) Y  (2) Y  (3) Y  (4) Y 
Y1  Y2 2( Y1  Y2 ) 3( Y1  Y2 ) Y1  Y2
Ans. (4)
Sol.
Y1 Y2 Y
  2
K1K 2
K=
K1  K 2
Y1A Y2 A

YA
  
2 Y1A Y2 A

 
2Y1Y2
Y
Y1  Y2
12. The minimum and maximum distances of a planet revolving around the Sun are x1 and x2. If the minimum
speed of the planet on its trajectory is v0 then its maximum speed will be:
v 0 x 22 v0x2 v 0 x1 v 0 x12
(1) (2) (3) (4)
x12 x1 x2 x 22
Ans. (2)
Sol.
By angular momentum conservation

mv0 x2 = mvx1
v0x2
v=
x1
13. For a gas CP – CV = R in a state P and CP – CV = 1.10 R in a state Q, T P and TQ are the temperature in
two different state P and Q respectively. Then
(1) TP > TQ (2) TP = TQ (3) TP = 0.9 TQ (4) TP < TQ
Ans. (1)
Sol. At high temperature gas behaves has ideal gas.

14. Identify the logic operation carried out
(1) OR (2) NOR (3) NAND (4) AND

Ans. (4)
15. What should be the order of arrangement of de-Broglie wavelength of electron (e), an -particle () and
proton (p) given that all have the same kinetic energy ?
(1) e = p >  (2) e < p <  (3) e = p =  (4) e > p > 
Ans. (4)
h 1
Sol. =  
2mK.E. m
m > mp > me , so e > p > 
16. In the given figure, there is a circuit of potentiometer of length AB = 10 m. The resistance per unit length
of 0.1 per cm. Across AB, a battery of emf E and internal resistance r is connected. The maximum value
of emf measured by this potentiometer is :
(1) 2.25 V (2) 6 V (3) 5 V (4) 2.75V

Ans. (3)
Sol. At zero deflection
The maximum value of E that can be measured = VAB
6
VAB =  100 = 5 V
100  20
17. Water droplets are coming from an open tap at a particular rate. The spacing between a droplets observed
at 4th second after its fall to the next droplet is 34.3 m. At what rate the droplets are coming from the tap
? (Take g = 9.8 m/s2)
(1) 1 drop/second (2) 1 drop/7seconds (3) 2 drops/second (4) 3 drops/2seconds
Ans. (1)
1 2
Sol. Let next drop after t sec distance travelled by I st drop in 4 sec. is S1 = at = 78.4 m (t should be less
2
then 4 sec) distance travelled by succeeding drop in 4 – t sec
1
S2 = a (4 – t)2
2
S1 – S2 = 34.3
78.4 – 4.9 (4 – t)2 = 34.3
(4 – t)2 = 9 ; 4 – t = 3
t = 1 sec

18. A parallel plate capacitor with plate area ‘A’ and distance of separation d is filled with a dielectric. What
is the capacity of the capacitor when permittivity of the dielectric varies as :
 d
(x) = 0 + kx, for  0  x  
 2
d 
(x) = 0 + k(d – x), for   x  d 
 2 
2 / kA
kA  kd  kA  2 0 
(1) (2)   0   (3) n  (4) 0
 2  kd   2  2  2 0  kd 
2n 0 
 2 0 
Ans. (1)
Sol.
d/2 d/2
x dx
1 dx
C eq
  A
d/ 2 d
dx dx
 
0
A( 0  kx )
 
d/ 2
A[ 0  k(d  x )]
1 1 d 
 n( 0  kx )0  n( 0  k(d  x ))d / 2 
d/ 2 1

A k k 
kd
0 
1 2  Ceq = kA
  2 n
Ak 0  2  kd 
2n 0 
 2 0 

19. Two billiard balls of equal mass 30 g strike a right wall with same speed of 108 kmph (as shown) but at
different angles. If the balls get reflected with the same speed then the ratio of the magnitude of impulses
imparted to ball ‘a’ and ball ‘b’ by the wall along ‘X’ direction is :
(1) 2 :1 (2) 1: 2 (3) 2 : 1 (4) 1 : 1

Ans. (1)
Sol. ratio of impulse
J1 P1 m(u  u)
  = 2 :1
J2 P2  u u 
m  
 2 2
20. In the Young’s double slit experiment, the distance between the slits varies in time as d(t) = d 0 + a0 sint
; where d0,  and a0 are constants. The difference between the largest fringe width and the smallest fringe
width obtained over time is given as :
2Da0 2D(d0 ) D D
(1) (2) (3) (4) a0
(d02  a 02 ) (d02  a 02 ) d0  a0 d02
Ans. (1)
D
Sol. Fringe width =
d
D
=
(d0  a 0 sinwt)
max – sin
D D
 –
d0  a 0 d0  a 0
 d  a 0 – d0  a 0 
 D  0 2 2

 d0  a 0 
2Da0
=
(d02  a 02 )

Numerical Value Type

This section contains 10 Numerical value type questions.
1. Student A and student B used two screw gauges of equal pitch and 100 equal circular divisions to measure
the radius of a given wire. The actual value of the radius of the wire is 0.322 cm. The absolute value of the
difference between the final circular scale readings observed by the students A and B is _____. [Figures
shows position of reference ‘O’ when jaws of screw gauge are closed] Given pitch = 0.1 cm.
Ans. 13
Sol. The difference between the two student reading
= difference between zero error.
= 5 – (–8) = 13
2. The value of aluminum susceptibility is 2.2 × 10–5. The percentage increase in the magnetic field if space
x
within a current carrying toroid is filled with aluminum is . Then the value of x is _____.
10 4
Ans. 22
Sol. r = 1 + 
r =  
also B  r
B = kr (k = constant)
B k( r ) 2.2  105
% change =  100   100 =  100 = 0.022
B k r 1
x = 22
3. A body of mass 2 kg moving with a speed of 4 m/s, makes an elastic collision with another body at rest
and continues to move in the original direction but with one fourth of its initial speed. The speed of the
x
two body centre of mass is m/s. Then the value of x is ______
10
Ans. 25

Sol. From linear momentum conservation
2 × 4 + 0 = 2 × 1 + m 2v2
From the definition of elastic collision
v2 – v1 = e(u1 – u2)
v2 – 1 = 1(4 – 0)
v2 = 5
8 = 2 + m2 × 5
m2 = 6/5
m1v1  m2 v 2 2 4  0
Vcm = = = 2.5 m/s
m1  v 2 2
6
5
x = 25

4. A particle of mass ‘m’ is moving in time ‘t’ on a trajectory given by r  10t 2 î  5(t  5) ĵ Where a and b
are dimensional constants.
The angular momentum of the particle becomes the same as it was for t = 0 at time t = _____ seconds.
Ans. 10

Sol. r  10t 2 î  5t  5ĵ
v  20t î  5 ĵ
  
L  mr  v 

 
L  m 10t 2 î  5(t  5) ĵ  20t î  5 ĵ 

at t = 0, L = 0
At any time t


L  m 50t k̂  100(t  5) k̂ 
0 = 50 m  [t – 2 (t – 5)) k̂
 t – 2t + 10 = 0
 t = 10 sec
5. An inductor of 10mH is connected to a 20V battery through a resistor of 10 k and a switch. After a long
time, when maximum current is set up in the circuit, the current is switched off. The current in the circuit
x
after 1 ms is mA . Then x is equal to ____. (Take e–1 = 0.37)
100
Ans. 74
20
Sol. i0 =  2A
10
i = i0e–Rt/L
10 10 3
 2
= 2e 10 10  3  = 0.74A
e
x = 74

6. A pendulum bob ha a speed of 3 m/s at its lowest position. The pendulum is 50 cm long. The speed of
bob, when the length makes an angle of 60° to the vertical will be (g = 10 m/s2)____ m/s.
Ans. 2
1 1
Sol. mu 2  mv 2  mg (1  cos 60 )
2 2
u2  v 2  2g(1 cos60)
9 = v2 + 20 × 1/2 × 1/2
9 = v2 + 5
v = 2 m/s
7. A particle of mass 1 mg and charge q is lying at the mid-point of two stationary particle kept at a distance
2m when each is carrying same charge q. If the free charged particle is displaced from its equilibrium
position through distance x (x << 1m). The particle executes SHM. Its angular frequency of oscillation will
be _____ × 105 rad/s if q2 = 10C2
Ans. 6000
q
Sol. x q
q
2m
Kq2 Kq2  4x 
Fnet =  = Kq2  
(1  x )2 (1  x )2

 1  x2
2

2


4Kq2 x
a=
m
Kq2 9  10 9  10
= 2 = 2 = 6000
m 10  6
8. In the reported figure, two bodies A and B of masses 200 g and 800 g are attached with the system of
springs. Springs are kept in a stretched position with some extension when the system is released. The
horizontal surface is assumed to be frictionless. The angular frequency will be ______ rad/s when k = 20
N/m.
Ans. 10
m1m 2 200  800
Sol.    160 g  0.16 kg
m1  m 2 200  800
k1 k 2 4k  k 4 4 N
Keq = = = k   20  16
k1  k 2 4k  k 5 5 m
K eq 16
= = = 10
 0.16


9. A circular conducting coil of radius 1m is being heated by the change of magnetic field B passing
perpendicular to the plane in which the coil is laid. The resistance of the coil is 2. The magnetic field
is slowly switched off such that its magnitude changes in time as
4  t 
B  103 T1  
  100 
The energy dessipated by the coil before the magnetic field is switched off completely is E = ____ mJ.
Ans. 80
dB
Sol.  = A
dt
4 103
 = (1)2 × 
 100
 = 4 × 10–5 v
When B = 0, t = 100
2 16  1010
Energy = t =  100 = 8 × 10–2 = 80 mJ
R 2  106
10. An electric bulb rated as 200 W at 100 V is used in a circuit having 200 V supply. The resistance R that
must be put in series with the bulb so that the bulb delivers the same power is ____
Ans. 50
V2
Sol. P=
R
(100)2
200 =
R
R = 50 
RL
100 V
200 V
Current through bulb
100
i=  2A
50
VL = 100
100
RL = = 50 
2

CHEMISTRY
Section : Chemistry Section A
1. Which one among the following resonating structure is not correct ?

 
 O  O
(1)  N (2) 
N
O O
 
 O  O
(3)  N (4) N

O O
Ans. (3)
Sol. Same charge on adjacent atoms.
2. Given below are two statements, one is labelled as Assertion (A) and other is labelled as Reason (R).
Assertion (A) : Gabriel phthalimide synthesis cannot be used to prepare aromatic primary amines.
Reason (R) : Aryl halides do not undergo nucleophilic substitution reaction.
In the light of the above statements, choose the correct answer from the options given below:
(1) (A) is true but (R) is false
(2) (A) is false but (R) is true
(3) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(4) Both (A) and (R) are true but (R) is correct explanation of (A)
Ans. (4)
Sol. Fact.
O
3. CH3CHO ‘P’ (i) I2/NaOH, Filter
(Major Product) ‘X’
NaOH (ii) Filtrate + HCl
Consider the given reaction, the product ‘X’ is :

O
OH O O O O O OH
(1) CHO (2) (3) (4)
OH OH
Ans. (4)
O O O OH
CH–CH3
Sol. CH3CHO (i) I2/NaOH, Filter OH
NaOH OH (ii) Filtrate + HCl

4. The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order :
(1) Al3+ < Mg2+ < Na+ < K+ (2) Al3+ < Mg2+ < K+ < Na+
(3) K+ < Al3+ < Mg2+ < Na+ (4) Na+ < K+ < Mg2+ < Al3+
Ans. (1)
Sol. K+ > Na+ {moving down the group size increases}
Na+ > Mg+2 > A3+ {Isoelectronic species}
Z 11 12 13
E 10 10 10
5. For the following graphs,
(a) (b) t1/2

Rate
Time Initial concentration

Concentration
Concentration
(c) (d)
Time Time
Rate
(e)
concentration
Choose from the options given below, the correct one regarding order of reaction is :
(1) (b) Zero order (c) and (e) First order (2) (b) and (d) Zero order (e) First order
(3) (a) and (b) Zero order (e) First order (4) (a) and (b) Zero order (c) and (e) First order
Ans. (1)
Sol. At = (A)0 – Kt. : Zero Oder
A 
t1/2 =  0 
 2K 
A = A0e– Kt ; First oder
 n2
t1/2 =
K

6. Given below are two statements :

Assertion I : None of the alkaline earth metal hydroxides dissolve in alkali.
Reason II : Solubility of alkaline earth metal hydroxide in water increases down the group.
In the light of the above statements, choose the most appropriate answer from the options given below:
(1) Statement I is incorrect but Statement II is correct.
(2) Statement I is correct but Statement II is incorrect.
(3) Statement I and Statement II both are incorrect.
(4) Statement I and Statement II both are correct.
Ans. (1)
Sol. Solubility of alkaline earth metal hydroxide in water increases down the group.
7. Which one of the following compounds of Group-14 elements is not known ?

(1) [SiF6]2– (2) [GeCl6]2– (3) [SiCl6]2– (4) [Sn(OH)6]2–
Ans. (3)
Sol. The main reasons are :
(i) six large chloride ions cannot be accommodated around Si4+ due to limitation of its size.
(ii) interaction between lone pair of chloride ion and Si4+ is not very strong.
The species like, SiF62–, [GeCl6]2–, [Sn(OH)6]2– exist where the hybridisation of the central atom is sp3d2.
8. The water soluble protein is :

(1) Myosin (2) Collagen (3) Fibrin (4) Albumin
Ans. (4)
Sol. NCERT (Globular proteins are water soluble)
9. The correct order of following 3d metal oxides, according to their oxidation number is :
(a) CrO3 (b) Fe2O3 (c) MnO2 (d) V2O5 (e) Cu2O
(1) (c) > (a) > (d) > (e) > (b) (2) (a) > (d) > (c) > (b) > (e)
(3) (a) > (c) > (d) > (b) > (e) (4) (d) > (a) > (b) > (c) > (e)
Ans. (2)
Sol.
Compound Oxidation state of metal
(a) CrO3 +6
(b) Fe2O3 +3
(c) MnO2 +4
(d) V2O5 +5
(e) Cu2O +1

10. Which one of the products of the following reactions does not react with Hinsberg reagent to from
sulphonamide :
CN CN
H3O
(1) + SnCl2 + HCl (2) + LiAlH4
CHO
CN CN
C2H5OH
(3) + H2 / Ni (4) + Na/Hg
CH3
NO2
Ans. (1)
CN CHO
Sol. + SnCl2 + HCl (does not react with Hinsberg reagent)
11. An organic compound ‘A’ C4H8 on treatment with KMnO4/H+ yields compound ‘B’ C3H6O, Compound ‘A’ also
yields compound ‘B’ an ozonolysis. Compound ‘A’ is :
(1) But-2-ene (2) Cyclobutane
(3) 2-Methylpropenene (4) 1-Methylcyclopropane
Ans. (3)
O3 H
Sol. CH3–C=CH2 CH3–C=O CH3–C=CH2
Zn, H2O Zn, H2O
CH3 CH3 CH3
12. In the leaching of alumina from bauxite, the ore expected to leach out in the process by :
(1) SiO2 (2) TiO2 (3) Fe2O3 (4) ZnO
Ans. (1)
Sol. Bauxite, usually contains SiO2, iron oxide and titanium oxide (TiO2) as impurities. Concentration is carried
out by digesting the powdered ore with a concentrated solution of NaOH at 473-523 K and 35-36 bar
pressure. This way, Al2O3 is leached out as sodium aluminate (and also SiO2 as sodium silicate) leaving
behind the impurities, iron oxide and titanium oxide.

Al2O3 .xH2O + NaOH NaAlO2
H2O
Al(OH)3 + NaOH
Al (OH)3 1200K Al2O3

(pure)
OH OH
––CH2 CH2 CH2––

13.
(1) Buna-N (2) Acrilan (3) Novolac (4) Neoprene

Ans. (3)
Sol. Novolac is linear polymer.
O (i) C2H5MgBr, dry ether

14. (ii) H2O, HCl
P
(Major Product)
Consider the above reaction, the major product ‘P’ is :
OH
OH OH OH
(1) (2) (3) (4)

Cl
Ans. (1)
15. Which one of the following species responds to an external magnetic field ?
(1) [Co(CN)6]3– (2) [Fe(H2O)6]3+ (3) [Ni(CO)4] (4) [Ni(CO)4]2–
Ans. (2)
Sol. Fe3+; 3d5
If will contain 5 unpaired electrons.
Thus it is paramagnetic and attracted in external magnetic field.

16. At 298.2 K the relationship between enthalpy of bond dissociation (in kJ mol –1) for hydrogen (EH) and its
isotope, deuterium (ED) is best described by :
1
(1) EH = ED (2) EH = 2ED (3) EH = ED – ED – 7.5
(4) EH ~
2
Ans. (4)
Sol. H–H bond desociation energy 435.90 KJ/mol
D–D bond desociation energy 443.40 KJ/mol
– ED – 7.5
EH ~
17. Which one of the following chemical agent is not being used for dry-cleaning of clothes ?
(1) H2O2 (2) CCl4 (3) Cl2C = CCl2 (4) Liquid CO2
Ans. (2)
Sol. NCERT Based.
18. Which one of the following compounds will liberate CO 2, when treated with NaHCO3 ?
O
 –  –
(1) (CH3 )3 NHCl (2) CH3–C–NH2 (3) CH3NH2 (4) (CH3 )4 N OH
Ans. (1)
Sol. HCl is stronger acid than H2CO3 (H2O + CO2)
19. Sodium stearate CH3(CH2)16COO–Na+ is an anionic surfactant which forms micelles in oil.
Choose the correct statement for it from the following :
(1) It forms non-spherical micelles with –COO– group pointing outwards on the surface.
(2) It forms non-spherical micelles with CH3(CH2)16 – group pointing towards the centre.
(3) It forms spherical micelles with CH3(CH2)16 – group pointing towards the centre of sphere.
(4) It forms spherical micelles with CH3(CH2)16 – group pointing outwards on the surface of sphere.
Ans. (3)
Sol.

OH OH
20.
Br
(Major Product)
The given reaction can occur in the presence of :
(a) Bromine water (b) Br2 in CS2, 273 K (c) Br2/FeBr3 (d) Br2 in CHCl3, 273 K
(1) (a), (b) and (d) only (2) (b) and (d) only
(3) (b), (c) and (d) only (4) (a) and (c) only
Ans. (3)
Sol. Phenol with bromine water give 2,4,6-Tribromo phenol while rest are give ortho or para bromophenols.
Section : Chemistry Section B
1. When 10 mL of an aqueous solution of Fe2+ ions was titrated in the presence of dil H 2SO4 using
diphenylamine indicator, 15 mL of 0.02 M solution of K2Cr2O7 was required to get the end point. The
molarity of the solution containing Fe2+ ions is x × 10–2 M. The value of x is………… (Nearest integer)
Ans. 18
Sol. Cr2O72– + Fe2+  Fe3+ + Cr3+
15 ml 10 ml
0.1 M
N1V1 = N2V2
15 × 0.02 × 6 = 10 × M × 1
15  0.02  6
M= = 0.18 = 18 × 10–2 M
10
2. CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO 2 exerts a
partial pressure of 0.835 bar then x m mol of CO2 would dissolve in 0.9 L of water. The value of x
is……………… (Nearest integer)
(Henry’s law constant for CO2 at 298 K is 1.67 × 103 bar)
Ans. (25)
Sol. PCO2  K H XCO2
PCO2 0.835
X CO2  
KH 0.835  2  103
XCO2  0.5 × 10–3

900
Number of moles of water =  50
18
nCO2
 0.5  103
nCO2  nH2O
( nCO2 in denominator is neglected as it is << 50)
nCO2 = 0.5 × 10–3 × 50 = 25 × 10–3 moles
= 25 milimoles
3. Consider the complete combustion of butane, the amount of butane utilized to produce 72.0 g of water
is………..×10–1 g. (in nearest integer)
Ans. (464)
13
Sol. C4H10 + O2  4CO2 + 5H2O
2
 3n  1 
CnH2n +2 +  O 2  n CO2 + (n + 1) H2O
 2 
 1 mole C4H10 produces 5 mole H2O.

5 mole (5 × 18) = 90 g.
90 g  58 g
 58  72 
72 g    = 46.4 g
 90 
= 464 × 10–1 g
4. A source of monochromatic radiation of wavelength 400 nm provides 1000 J of energy in 10 seconds.

When this radiation falls on the surface of sodium, x × 1020 electrons are ejected per second. Assume
that wavelength 400 nm is sufficient for ejection of electron from the surface of sodium metal. The value
of x is………. (Nearest integer)
(h = 6.626 × 10–34 Js)
Ans. (2)
Sol. Energy per second = 100 J
 hc   6.62  10  3  10 
 32 8

E = E0 + KE so E = E0 =   =  

  
 400  10 9


= 0.04965 × 10–17 J = 4.965 × 10–19 J
100
Number of of electron ejected by 100 J energy = = 20.140 × 1019 = 2.01 × 1020
4.965  1019

5. For the reaction

A+B 2C
the value of equilibrium constant is 100 at 298 K. If the initial concentration of all the three species is 1 M
each, then the equilibrium concentration of C is x × 10–1 M. The value of x is…………
(Nearest integer)
Ans. (25)
Sol. A + B 2C KC = 100
t=0 1 1 1
t = teq. 1–x 1–x 1 + 2x
Kc =
1 2x 2
(1 – x ) 2
100 =
1 2x 2 of [C]
(1 – x ) 2
10 =
1  2x 
(1 – x )
3
X=
4
3
Concentration of [C] = 1 + 2   = 25 × 10–1
4
6. At 298 K, the enthalpy of a solid (X) is 2.8 kJ mol –1 and the enthalpy of vaporisation of the liquid (X) is
98.2 kJ mol–1. The enthalpy of sublimation of the substance (X) in kJ mol–1 is……… (in nearest integer)
Ans. (101)
Sol. HSublimation = Hvap + Hfusion
= 98.6 + 2.4
= 101 K.Cal mol–1
7. Consider the cell at 25ºC

Zn|Zn2+ (aq), (1 M) || Fe3+ (aq), Fe2+ (aq) | Pt(s)
The fraction of total iron present as Fe3+ ion at the cell potential of 1.500 V is x × 10–2. The value of x
is……….. (Nearest integer)
0
(Given : EFe 3
/ Fe 2 
= 0.77 V, E 0Zn2  / Zn = –0.76 V)
Ans. (24)

Sol. Cathode = Fe3+ + e–  Fe2+ 0

EFe3
|Fe2
= 0.77 V
Anode  Zn(s)  Zn2+ (aq) + 2e– E0Zn2 | Zn = –0.76 V
– 0.059 [Zn2 ][Fe 2 ]2

Ecell = E0cell log
2 [Fe 3 ]2
2
 0.06  [Fe 2 ] 
1.5 = 1.53 – log 
2  [Fe 3 ] 
 
2
 [Fe 2 ] 
10 =  
 [Fe 3 ] 
 
[Fe 3  ] 1
2
= = 0.316
[Fe ] 10
[Fe 3 ] 0.316
Fraction of Fe3+ = 3 2
= = 0.24 = 24× 10–2
[Fe ]  [Fe ] 1.316
8. The number of sigma bonds in

H3C–C =CH–CC–H
H
Ans. (10)
Sol. 10, 3
9. Three moles of AgCl get precipitated when one mole of an octahedral co-ordination compound with
empirical formula CrCl3.3NH3.3H2O reacts with excess of silver nitrate. The number of chloride ions
satisfying the secondary valency of the metal ion is _______.
Ans. (0)
Sol. [Cr(NH3)3(H2O)]Cl3 + AgNO3  3AgCl 
White ppt.
The three chloride ions satisfies only primary valency.
10. A home owner uses 4.00 × 103 m3 of methane (CH4) gas, (assume CH4 is an ideal gas) in a year to heat
his home. Under the pressure of 1.0 atm and 300 K, mass of gas used is x × 105 g. The value of x is………..
(Nearest integer) (Given R = 0.083 L atm K–1 mo–1).
Ans. (26)
Sol. Volume of methane gas (V) = 4 × 103 m3 = 4 × 106 Lt
Pressure of the gas (P) = 1.0 atm
Temperature (T) = 300 K
PV = nRT
PVM 1 4  106  64
W= = = 25.7 × 105 g 26 × 105 g.
RT 0.083  300

MATHEMATICS
1. The area (in sq. units) of the region, given by the set
{(x, y)  R × R | x  0, 2x2  y  4 – 2x} is:
{ks=k {(x, y)  R × R | x  0, 2x2  y  4 – 2x} dk {ks=kQy ¼oxZ bdkb;ksa esa½ cjkcj gS%
7 17 8 13
(1) (2) (3) (4)
3 3 3 3
Ans. (1)
(–2,8)
(0,4)
• (1,2)
•
(–2,0) O (1,0)
Sol.
2x2 = 4 – 2x
x2 + x – 2 = 0
(x + 2) (x – 1) = 0
x = – 2, x = 1
1
2  4  1 –  2x 2dx = 3 – 2 = 7 square units
1
Required area =
2 0 3 3
2. The locus of the centroid of the triangle formed by any point P on the hyperbola
16x2 – 9y2 + 32x + 36y – 164 = 0 and its foci is:
vfrijoy;]16x2 – 9y2 + 32x + 36y – 164 = 0 ij fdlh fcUnw P rFkk bldh ukfHk;ksa ls cus f=kHkqt ds dsUnzd dk
fcUnwiFk gS :
(1) 16x2 – 9y2 + 32x + 36y – 36 = 0 (2) 9x2 – 16y2 + 36x + 32y – 36 = 0
(3) 16x2 – 9y2 + 32x + 36y – 144 = 0 (4) 9x2 – 16y2 + 36x + 32y – 144 = 0
Ans. (1)
Sol. Given
x  12 
(y – 2)2
1
9 16
Let x+1=X
y–2 =Y
X2 Y2
 1
9 16
a = 3, b = 4

5
b2 = a2 (e2 –1 ) e =
3
Focus (±ae, 0) X = ±ae, Y = 0
x + 1 = ± 5, y – 2 = 0
x = –6, 4, y = 2
Hence focus S(–6, 2), S(4, 2)
Let any point on hyperbola x + 1 = 3secy – 2 = 4tanP(–1 + 3sec, 2 + 4tan)
  6  4 – 1 3 sec 2  2  2  4 tan  
Hence centroid is   , 
 3 3 
–3  3 sec  3h  3
h  sec  
3 3 x= –1
3k – 6
 tan   y=2
4 C (–1,2)
sec2–tan2 = 1
 3h  3 
2
3k – 6  1
2
  
 3 16
9x  1 9(y – 2)2

2
Locus is  1
9 16
 16x2 – 9y2 + 32x + 36y – 36 = 0
S 4n
3. Let Sn be the sum of the first n terms of an arithmetic progression. If S3n = 3S2n, then the value of is:
S 2n
S 4n
ekuk ,d lekUrj Js<+h ds izFke n inksa dk ;ksxQy Sn gSA ;fn S3n = 3S2n, gS] rks cjkcj gS:
S 2n
(1) 6 (2) 8 (3) 4 (4) 2

Ans. (1)
S3n
3n
2a  3n  1d
Sol.  2 3
S2n 2n 2a  2n  1d
2
2a+(3n–1)d = 2[2a + (2n–1)d]
2a+(n–1)d = 0 ……(1)
S 4n
4n
2a  (4n  1)d
Now  2
S2n 2n
2a  (2n  1)d
2

22a  (4n  1)d


2a  (2n  1)d
S4n 23nd 
Put, 2a = –(n–1)d, we have, = 6
S2n nd
4. Let 9 distinct balls distributed among 4 boxes, B1,B2,B3 and B4. If the probability that B3 contains exactly
9
3
3 balls is k   then k lies in the set:
4
9
3
ekuk 9 fHkUUk xasna] 4 fMCcksa B1,B2,B3 rFkk B4 esa forfjr dh tkrh gSaA ;fn B3 esa Bhd 3 xasn gksus dh izkf;drk k  
4
gS] rks k fuEu esa ls fdl leqPp; esa gS \

(1) {x  R:| x – 1|< 1} (2) {x  R:| x – 2|  1}
(3) {x  R:| x – 3|< 1} (4) {x  R:| x – 5|  1}
Ans. (3)
Sol. The numbers of ways of distributing 9 distinct balls in 4 boxes B1, B2, B3,and B4,is = 49
When box B3, contains exactly 3 balls then number of ways = 9 C3 (3)6
9
36 28  3 
Probability = 9 C 3    
49 9 4
28 1
Hence k  3
9 9
Clearly 2<k<4  k{x  R:| x – 3|< 1}
5. A spherical gas balloon of radius 16 meter subtends an angle 60º at the eye of the observer A while the
angle of elevation of its center from the eyes of A is 75º. Then the height (in meter) of the top most point
of the balloon from the level of the observer’s eye is:
,d xksykdkj xSl dk xqCckjk] ftldh f=kT;k 16 ehVj gS] ,d n’'kZd A dh vk¡[k ij 60º dk dks.k cukrk gS] tcfd
xqCckjs ds dsUnz dk A dh vk¡[k ls mUu;u dks.k 75º gSA rks n'kZd dh vk¡[k ds ry ls xqCckjs ds lcls Å¡ps fcUnw dh
ehVjksa esa Å¡pkbZ gS%

(1) 8 2  2  3  
(2) 8 6  2  2 
(3) 82  2 3 2  (4) 8 6  2  2
Ans. (2)
Sol. In triangle EOD

16
ED = = 16 3
tan 30
A
E
DF = 16 3 16
16
Now in  DFC O
16 3
B 45°
CF = 16 3. sin45 F
8 6 8 6
30° 30° 16 3
1
= 16 3. = 8 6
2 45°
D
CB= 8 6
c C
In le OBF
OB = 16cos45°
16
= 8 2
2

Height of top most point = 8 6  8 2  16 = 8 6  2  2 
6. The values of a and b, for which the system of equations
2x + 3y + 6z = 8
x + 2y + az = 5
3x + 5y + 9z = b
has no solution, are:
;fn lehdj.k fudk;

2x + 3y + 6z = 8
x + 2y + az = 5
3x + 5y + 9z = b
dk dksbZ gy ugha gS] rks a vkSj b dk eku gS%

(1) a = 3, b = 13 (2) a = 3, b  13
(3) a  3, b = 3 (4) a  3, b  13
Ans. (2)
Sol.  = 0 and any one of 1 , 2 and 3 should not be equal to zero
2 3 6
 1 2 a 0
3 5 9
 = 2[18 – 5a] – 3[9 – 3a] + 6[5– 6]
=3–a=0
a=3

8 3 6
1  5 2 3  8[18 – 15] – 3 [45 – 3b] + 6[25 – 2b] = 3(13 – b)
b 5 9
2 8 6 2 8 2
2  1 5 3  3 1 5 1  0
3 b 9 3 b 3
2 3 8
 3  1 2 5  2[2b – 25] – 3[b – 15] + 8[5– 6] = b – 13
3 5 b
If b = 13, then 1,2, and 3 all will be zero.
b 13
7. Let f : R  R be defined as
  x 2 – 5x  6
 , x2

  5x – x 2  6
 tan x  2 


f x    e x  x  , x2
  , x2




where [x] is the greatest integer less than or equal to x. If f is continuous at x = 2, then  +  is equal to :
ekuk f : R  R
  x 2 – 5x  6
 , x2

  5x – x 2  6
 tan x  2 


f x   e x  x 
  , x2
  , x2




}kjk ifjHkkf"kr gS] tcfd [x] egÙke iw.kkZd  x gSA ;fn x =2 ij f larr gS] rks  +  cjkcj gS%
(1) e(e–2) (2) 2e–1 (3) 1 (4) e(–e+1)
Ans. (4)
tan( x 2) tan( x 2)
Sol. RHL  lim e x  [ x]

 lim e ( x 2)
e
x2 x  2
 | x 2  5x  6 |
LHL  lim
x2  5x  6  x
2
For x < 2, |x2 – 5x + 6| = x2 – 5x + 6

 | x2  5x  6 |  
 LHL  lim 
x2  5x  6  x  
2
Also, f(2) = 

For f(x) to be continuous at x = 2,
RHL = LHL = f(2)

e = 

= e and = –e2
+ = e–e2
8. Let a parabola P be such that its vertex and focus lie on the positive x-axis at a distance 2 and 4 units
from the origin, respectively. If tangents are drawn from O(0,0) to the parabola P which meet P at S and
R, then the area (in sq. units ) of SOR is equal to:
ekuk P ,d ijoy; gS ftldk 'kh"kZ rFkk ukfHk /kukRed x-v{k ij gS vkSj mudh ewyfcUnw ls nwjh Øe'k% 2 rFkk 4 bdkbZ
gSA ;fn O(0,0) ls ijoy; P ij nks Li'kZ js[kk,sa [khaph tkrh gS tks P dks S rFkk R ij feyrh gS] rks SOR dk
{ks=kQy ¼oxZ bdkb;ksa esa½ cjkcj gS%
(1) 8 2 (2) 32 (3)16 (4) 16 2
Ans. (3)
Sol.
S
•
/2 Q(4,0)
• (2,0) •
O
(0,0)
•
R
x=0
Equation of parabola
(y – 0)2 = 4(2) (x – 2)
origin lies on the directrix x = 0
so SOR is right angle triangle.
Equation of chord of contact SR is
T=0
x=4
It is latus rectum of parabola
1
so area of SOR =  4  8  16 square units
2

9. The sum of all values of x in [0, 2], for which sinx + sin2x + sin3x + sin4x = 0, is equal to :
[0, 2] esa x, ds lHkh ekuksa] ftuds fy, sinx + sin2x + sin3x + sin4x = 0 gS] dks ;ksx gS%
(1) 12  (2) 8  (3) 11  (4) 9 
Ans. (4)
Sol. (sinx + sin4x) + (sin2x + sin3x) = 0
5x 3x 5x x
 2sin cos  2sin  cos  0
2 2 2 2
5x  3x x
 2sin  cos  cos   0
2  2 2
5x x
 4 sin cos x cos  0
2 2
5x x
 sin 0 or cosx = 0 or cos =0
2 2
5x  3 x 
  0 , , 2, 3, 4, 5 or x = , or 
2 2 2 2 2
2 4 6 8 10  3
 x = 0, , , , , or x = , or x = 
5 5 5 5 5 2 2
2 4 6 8  3
  x = 0, , , , , 2, , ,
5 5 5 5 2 2
 Hence sum of all solutions = 9
5 / 24
dx
10. The value of the definite integral 
 / 24
1  tan2x
3
is :
5 / 24
dx
fuf'pr lekdyu 
 / 24
1  tan2x
3
cjkcj gS %
   
(1) (2) (3) (4)
12 6 3 18
Ans. (1)
b b
Sol.  f(x)dx   f(a  b – x)dx
a a
5
24
dx
=
 1

3
tan2x
......(1)
24
By property

5
24
dx
=
 1

3
cot 2x
24
5
24 3
tan 2x dx
=
 1

3
tan 2x
......(2)
24
By adding (1) & (2)

5
24
(1  3 tan2x ) dx
2 =

 1  3 tan2x
24
5
24

2 =
 dx  6

24

=
12
11. Let the vectors

2  a  bî  a  2b  c ˆj  b  c kˆ , 1  bî  2b ˆj  b k̂ and 2  bî  2b ĵ  1 bk̂ , a, b, c  R
be co-planar, Then which of the following is true ?
ekuk
2  a  bî  a  2b  c ĵ  b  c k̂ , 1 bî  2b ĵ  b k̂ rFkk 2  bî  2b ĵ  1 bk̂ , a, b, c  R
lgryh; lfn'k gSA rks fuEu esa ls dkSulk dFku lgh gS \
(1) 3c = a+ b (2) 2b = a + c (3) a =b + 2c (4) 2a = b + c
Ans. (2)
Sol. Three vectors are coplanar
2  a  b a  2b  c  b  c 
 1 b 2b b  0
2b 2b 1 b
Apply C2  C2 + C3
2  a  b a  b  b  c 
 1 b b b 0
2b 1 b 1 b
Apply C1  C1 – C2
2 a  b  b  c 
 1 b b 0
1 1 b 1 b
 2[b – + b + b2] – (a + b) (1 – b + b) – (b + c) (1 + b – b) = 0
b2
 2b = a + c Ans.

12. Let g : N  N defined as

g(3n + 1) = 3n + 2,
g(3n + 2) = 3n + 3,
g(3n + 3) = 3n +1, for all n  0.
Then which of the following statements is ture ?
(1) gogog = g
(2) There exists a function f : N  N such that gof = f
(3) There exists a one-one function f : N  N such that fog = f
(4) There exists an onto function f : N  N such that fog = f
ekuk g : N  N
g(3n + 1) = 3n + 2,
g(3n + 2) = 3n + 3,
g(3n + 3) = 3n +1, lHkh n  0 ds fy,
}kjk ifjHkkf"kr gSA rks fuEu esa ls dkSu&lk dFku lR; gS \
(1) gogog = g
(2) ,d ,dSdh Qyu f : N  N dk vfLrRo gS ftlds fy, gof = f gSA
(3) There exists a one-one function f : N  N such that fog = f
(4) ,d Qyu f : N  N dk vfLrRo gS ftlds fy, fog = f gS
Ans. (4)
Sol. g(3n + 1) = 3n + 2
g(3n + 2) = 3n + 3
g(3n + 3) = 3n +1, n  0
For x = 3n + 1
(1) gogog (3n + 1) = gog(3n + 2) = g(3n + 3) = 3n + 1
Similarly
gogog (3n + 2) = 3n + 2
gogog (3n + 3) = 3n + 3
So gogog (x) = x  x  N
(2) As f : N  N, f = 3n + 1
= 3n + 2
= 3n + 3
So, g(3n + 1) = 3n + 2, g(3n + 2) = 3n + 3, g(3n + 3) = 3n + 1
So g(f(x))  f(x)
(3) If f : N  N and f is a one-one function such that f(g(x)) = f(x) then
g(x) = x
but g(x)  x
(4) If f : N  N and f is an onto function such that f(g(x)) = f(x) then
One of its possibilities is by taking f(x) as onto function
a x  3n  1

f(x) = a x  3n  2 , aN
a x  3n  3

 f(g(x)) = f(x)  x  N

x2 y2  3 
13. Let ellipse E :   1 , a2 > b2 passes through  ,1 and the has eccentricity 1 . If a circle.
a 2
b 2  2 
  3
2
centered at focus F( ,0),  > 0 of E and radius , intersects E at two points P and Q, then PQ 2 is
3
equal to :
x2 y2  3 
,d nh?kZo`r E :   1 , a2 > b2] fcUnq  ,1 ls gksdj tkrk gS rFkk mldh mRdsUnzrk 1 gSA ;fn ,d o`r
a 2
b2  2 
  3
2
ftldk dsUnz E dh ukfHk F(,0),  > 0 ij vkSj f=kT;k gS, nh?kZo`r E dks nks fcUnwvksa P rFkk Q, ij dkVrk gS]
3
rks PQ2 cjkcj gS %

16 8 4
(1) 3 (2) (2) (3)
3 3 3
Ans. (2)
x2 y2
Sol. Let equation of ellipse is  = 1 (a > b)
a2 b2
 3  3 1
it passes through  , 1   2 = 1 ....(1)
 2  2a 2
b
 
1 2
Given e =  b2 = a2 (1 – e2) = a 2 .......(2)
3 3
Solve (1) & (2) we get a2 = 3, b2 = 2
x 2 y2
Ellipse is  = 1 ....... (3)
3 2
 1 
Focus (±ae, 0)    3. ,0  (± 1, 0)
 3 
2
 2  4
Hence circle is (x – 1)2 + y2 =    .......(4)
 3 3
Solve (3) & (4) 
 4 
2x2 + 3 – (x – 1)2 = 6
3 
2x2 + 4 – 3 (x2 + 1 – 2x) = 6
–x2 + 6x – 5 = 0
x = 1, 5
1 y2 4 2
When x = 1   = 1  y2 = y=±
3 2 3 3
2 2 16
Hence P( (1, ) , Q( 1, – )  PQ2 =
3 3 3
y2 25 22
When x = 5  =1 – =–  not possible
2 3 3
16
PQ2 =
3

14. Let f: [0,)  [0,) be defined as
f x    ydy
x
where [x] is the greatest integer less than or equal to x. which of the following is true ?
(1) f is continuous at every point in [0,) and differentiable except at the integer points
(2) f is differentiable at every point in [0, ).
(3) f is continuous everywhere except at the integer points in [0,)
(4) f is both continuous and differentiable except at the integer points in[0,).
ekuk f; [0,)  [0,)
f x    ydy
x
}kjk ifjHkkf"kr gS] tcfd [x] egÙke iw.kkZd  x gSA rks fuEu esa ls dkSulk dFku lR; gS \
(1) iw.kkZd fcUnwvksa ds vfrfjDr [0,) ds lHkh fcUnwvksa ij f larr rFkk vodyuh; nksuksa gSA
(2) [0, ) ds izR;sd fcUnw ij f larr gS vkSj iw.kkZd fcUnwvksa ds vfrfjDr lHkh fcUnwvksa ij vodyuh; gSA
(3) [0,) ds izR;sd fcUnw ij f vodyuh; gSA
(4) iw.kkZd fcUnwvksa ds vfrfjDr] [0,) ds lHkh fcUnwvksa ij larr gSA
Ans. (1)
x
Sol. f(x) =  [y]dy
0
Let n  x < n + 1, n  
1 2 3 n x
= 
0
(0)dy + 
1
(1)dy + 
2
(2)dy + …… + 
n1
(n  1)dy +  (n)dy
n
= 0 + 1 + 2 + 3 + ……. + (n – 1) + n(x – n)
n(n  1)
=  n 2  nx
2
 n  n2 n(n  1)  n  1
 f(x) =  nx = nx –  f(x) = n x  
2 2 2 
 
 x  1
 x  ; x  n(Integer)
  2 
 f(x) = 

[x] 2x  [x]  1 
 ; x  Integer
 2 
 n(n  1)
Since lim f(x)   f(n)
xn 2
Hence f(x) is continuous at all integers.
But f'(x) = [x] is discontinuous at integers.
So, f(x) is non derivable at x integers.

15. Let f(x) = 3sin4x +10sin3x + 6sin2x – 3, x    ,   . Then, f is :

 6 2
 
     
(1) increasing in   ,  (2) decreasing in   ,0 
 6 2  6 
    
(3) increasing in   ,0  (4) decreasing in  0, 
 6   6
ekukf(x) = 3sin4x +10sin3x + 6sin2x – 3, x    ,   . gSA rks f :

 6 2
     
(1)   ,  esa o/kZeku gSa (2)   ,0  esa âkleku gSa
 6 2  6 
    
(3)   ,0  esa o/kZeku gSa (4)  0,  esa âkleku gSa
 6   6
Ans. (2)
Sol. f(x) = 3 sin4x + 10 sin3x + 6 sin2x – 3
f'(x) = 12 sin3x cosx + 30 sin2x cosx + 12 sinx cosx
f'(x) = 0
 6 sinx cosx (2 sin2x + 5 sinx + 2) = 0
Sin 2x = 0 or 2 sin2x + 5 sinx + 2 = 0
x=0 (2 sinx + 1) [(sinx + 2) = 0 is not possible]
1
sinx = , (sinx + 2) = 0
2
  
x= x  , 
6  6 2
+ – +
 0
6
 
Decreasing in x   ,0 
 6 
16. The number of real roots of the equation

e6x – e4x – 2e3x – 12e2x + ex +1= 0 is
lehdj.k e6x – e4x – 2e3x – 12e2x + ex + 1= 0 ds okLrfod ewyksa dh la[;k gS%
(1) 2 (2) 1 (3) 6 (4) 4
Ans. (1)
Sol. e6x – e4x–2e3x–12e2x + ex + 1 = 0
 (e3x–1)2 – ex(e3x–1) –12e2x = 0

 m2 – mn – 12n2 = 0 where m = e3x–1, n = ex

 (m–4n) (m+3n) = 0
 m = 4n or m + 3n = 0
 e3x –1 = 4ex or (e3x–1) . ex = 0
Case-I e3x–1 = 4ex
y
y = e3x–1
y = 4ex
(0,4)
(0,0)
x
One solution
Case –II (e3x–1) ex = 0
 e3x = 1
 x = 0 (one solution)
 Total 2 roots
17. Let y=y(x) be the solution of the differential equation
 1 xe yx , 2  x  2,y 0   0
dy
dx

then, the minimum value of yx ,x   2, 2 is equal to 
ekuk vodyu lehdj.k
dy
dx

 1  xe yx , 2  x  2,y 0   0 dk gy y=y(x) gS rks x   2, 2 
y(x) dk U;wure eku cjkcj gS%
 
(1) 2  3  loge 2   
(2) 1  3  loge 3  1 
(3) 1  3   log  3  1
e (4) 2  3   log 2
e
Ans. (2)
dy
Sol.  1  xe y–x .........(1)
dx
dy
e –y  e –y  xe –x
dx
dy dt
Put e – y  t  e –y –
dx dx
dt –x
–  t  xe
dx
dt
 t  –xe – x ........(2)
dx
F. = e 
1. dx
 ex
Solution of equation (2) is


te x  (–xe –x ). ex dx  c
x2
te x  – c
2
x2
e x–y –  c ..........(3)
2
 2 – x2 
 y(0) = 0  1 = c  ex – y =  
 2 
 
 2 – x2 
x – y = n  
 2 
 
 2 – x2 
y = x – n  
 2 
 
dy  2 
Now,  1 x  
dx 2 – x2 
 2 – x 2  2x 
  = 0
 2 – x2 
 
 x 2 – 2x – 2 
–  = 0
 2 – x2 
 
x=1± 3
– + –
1– 3 1 3
ymin at x = 1 – 3 ymin = (1– 3) – n( 3 – 1)
b
18. If b is very small as compared to the value of a, so that the cube and other higher powers of can be
a
neglected in the identity
1 1 1 1
   .........   n  n 2  n3
a  b a  2b a  3b a  nb
then the value of  is :
;fn b, a ls cgqr NksVk gS] ftuds fy, fuEu loZlfedk
1 1 1 1
   .........   n  n 2  n3 b
a  b a  2b a  3b a  nb esa dh D;wc vkSj Å¡ph ?kkrksa dh mis{kk dh tk ldrh
a
gS] rks  cjkcj gS%
(1) a  b (2) a  b (4) a  b

2 2 2
(3) b
3a2 3a3 3a 3 3a3
Ans. (3)
1 1 1 1
Sol.    ........ 
a – b a – 2b a – 3b a – nb

1  b   nb  
–1 –1 –1 –1
 2b   3b 
= 1–   1–   1–   .......  1–  
a  a   a   a   a  
1   
  
 

2 2 2
 b b   2b   2b    nb   nb 
 1        ......   1        ........   1        ...... 
a   
  
 
       a   a    a   a  
a a
1 
n  1  2  ......  n  2 12  22  ......n2 
b b2
 
a a a 
1 n(n  1) b n(n  1)(2n  1) b 2 

 n 
a 2 a 6 a 2 
1 n 2 b n b 2n 3  3n 2  n  b 2 
 n     2 
a 2 a 2a 6  a 
1 b b2   b b2  b2
 n  2  3    2  3 n2  3 n3
 a 2a 6a   2a 2a  3a
by comparing this result to n + n2 + n3

b2
we get  
3a 3
19. The Boolean expression (p  q)  q ~ p  is equivalent to :
cwyh; O;atd (p  q)  q ~ p  fuEu esa ls fdlds rqY; gS \

(1) ~p (2) p (3) ~q (4) q
Ans. (1)
Sol. = (p  q)  (p  ~ q)
= (~ p v q)  (~ p v ~ q)
= ~ p v (q  ~ q)
=~pvf
=~p
x y z
20. Let the foot of perpendicular from a point P(1, 2, –1) to the straight line L    be N. Let a line
1 0 1
be drawn from P parallel to the plane x + y + 2z = 0 which meets L at point Q. If  is the acute angle
between the lines PN and PQ, then cos is equal to ________
x y z
ekuk ljy js[kk L    ij fcUnw P(1, 2, –1) ls Mkys x, yEc dk ikn N gSA ekuk P ls lery] x + y +
1 0 1
2z = 0 ds lekUrj [khaph xbZ ,d js[kk L dks fcUnw Q ij feyrh gSA ;fn js[kkvksa PN rFkk PQ ds chp dk U;wudks.k 
gS] rks cos cjkcj gS%
3 1 1 1
(1) (2) (3) (4)
2 3 2 3 5
Ans. (2)

x y z
Sol. Let foot of  from P(1, 2, – 1) on line   is N (, 0, –)
1 0 1
 1( – 1) + 0 (0 –2) – 1 (–  + 1) = 0
 = 1
 N (1, 0, – 1)
Now equation of line passes through P(1, 2, –1) is
x 1 y  2 z 1
  …… (1)
a b c
This line is parallel to plane x + y + 2z = 0
 a + b + 2c = 0 …… (2)
x y z
Any point on the line L :   is
1 0 1
Q(r, 0 , – r) lies on line (1)
r  1   2 1 r
  
a b c
 c=–a
By (2) we have b = a
Hence a : b : c = a : a : – a
x 1 y  2 z 1
So, line PQ is  
a a a
And directions line PN is (0, 2, 0)
Acute angle between PQ and PN is '' then
0  2a  0 1
cos  = 
3a  2 3
INTEGER
1 1 1 
log 0.25    2  3 ........ upto  
 2 6 10  3 3 3 
1. If the value 1  3  2  3  ........upto 
 3 3 
is , then  2 is equal to _______________

1 1 1 
log 0.25    2  3 ........ upto  
 2 6 10  3 3 3 
;fn 1   2  3  ........upto 
 3 3 3 
dk eku , gS] rks 2 cjkcj gS _______________
Ans. (03.00)
  
  
1 1
log0.25    
 2 6 10   3 2 
Sol. 1   2  3
 ......    
  3 

 3 3 3 
1
log 1
 2 6 10  2
1  2  3  ......  
4
3 3 3 
2 6 10
Let 1     .....  x
3 32 33

2 6 10
(x – 1) =    .... …. (1)
3 32 33
1
x  1  22  63  ..... …. (2)
3 3 3
From (1) – (2), we get
2
x  1  2  42  43  .....
3 3 3 3
 
2 4  1 
2
x  1   2
3 3 3  1
 1 
 3
2
x  1  2  42 3 .
3 3 3 2
2
x  1  2  2
3 3 3
x–1=2 & x=3
1
log 1
2
So , 3 4

1
3
2
2 = 3
2. There are 5 students in class 10, 6 students in class 11 and 8 students in class 12. If the number of ways,
in which 10 students can be selected from them so as to include at least 2 students from each class and
at most 5 students from the total 11 students of class 10 and 11 is 100 k, then k is equal to ________d{kk
10 esa 5 Nk=k] d{kk 10 esa 6 Nk=k rFkk d{kk 12 esa 8 Nk=k gSA ;fn 10 Nk=kksa dks pquus ds rjhdksa dh la[;k] ftuesa ls
izR;sd d{kk esa ls de ls nks Nk=k gks rFkk d{kkvksa esa 10 vkSj 11 Nk=kksa esa ls vf/kd ls vf/kd 5 Nk=k gks] 100 k, gS rks
k cjkcj gS% ________
Ans. (238)
Sol. Total student (5) (6) (8)
Class 10th 11th 12th
2 2 6  5C  6 C  8 C
2 2 6
2 3 5  5C2  6C3  8C5

3 2 5  5C3  6C2  8C5
Total number of ways = 5C  8C 6C  6C   5C  6C  8C
2 3 3 2 2 2 6
= 23800
3.  
If ,  are roots of the equation x 2  5 2 x  10  0 ,  >  and Pn = n–n and for each positive integer
 P P  5 2P17 P19 
n, then the value of  17 20  is equal to _____
 P P  5 2P2 
 18 19 18 
 
;fn lehdj.k x 2  5 2 x  10  0 , ds rFkk  nks ewy gS  >  rFkk Pn = n–n ¼izR;sd /ku iw.kkZd n ds fy,½
 P P  5 2P17 P19 
gS] rks  17 20  dk eku gS_____A
 P P  5 2P 2 
 18 19 18 
Ans. (01.00)
Sol. x2 + 5 2 x + 10 = 0 ;  > 

Pn = n – n
P17 = 17 – 17, P18 = 18 – 18
2 + 10 = 5 2 ... (1)
2 + 10 =  5 2 ... (2)

P17  20  20  5 2 19  19   =    
P17 18  2  5 2  18 5 2  2  ;

P18  15
19
 5 2  18

18
 P18  
17 2
5 2    5
17
2   
2
P17 · P18  10

using eq (1) & (2) = 1
P18 · P17  10
4. Let y = y(x) be solution of the following differential equation
dy 
ey  2e y sin x  sin x cos 2 x  0 , y   0
dx 2
If y(0) = loge(+ e–2), then 4( + ) is equal to _____
ekuk y = y(x) vody lehdj.k
dy 
ey  2e y sin x  sin x cos 2 x  0 , y   0
dx 2
dk gy gSA ;fn y(0) = loge(+ e ), rks 4( + ) cjkcj gS _____
–2
Ans. (04.00)
dy
Sol. ey  2e y sin x   sin x cos 2 x
dx
Put e y  t
dy dt
ey 
dx dx
dt
 2t sin x   sin x cos 2 x
dx
I.F = e 
 2 sin xdx
 e 2 cos x

e y  e2cos x  e2cos x ( sinx _ cos2 xdx
cos x = z
  p 2z z 2 dz
e2 z 2
z   e2z .zdz
2
e 2z 2  e 2z e 2z 
 z  .z  c
2  2 4 
e 2z
 e y e2cos x  (2z 2  2z  1)  c
4
e2cos x
 e y e2cos x  (2cos2 x  2cosx  1)  c
4
1
 e y  (2cos 2 x  2cos x  1)  c
4

At x = y = 0,
2

1 3
 1   c  c 
4 4
1
4
 3
 e y  2cos 2 x  2cos x  1  e 2 cos x
4

 1 3 2 
y(0) = n   e 
4 4 
 y(0) = n   e2  
1 3
= =
4 4
4(+) = 4
5.
  
 
Let p  2î  3 ĵ  k̂ and q  î  2 ĵ  k̂ be two vectors. If a vector r  î   ĵ  k̂ is perpendicular to each
    
of the vectors p  q and p  q , and r  3 , then      is equal to_______
 
ekuk p  2î  3 ĵ  k̂ rFkk q  î  2 ĵ  k̂ nks lfn'k gSA ;fn lfn'k


r  î   ĵ  k̂  nksuksa  
lfn'kksa p  q rFkk
  
p  q , ds yEcor~ gS rFkk r  3 gS, rks      cjkcj gS _______
Ans. (03.00)
î ĵ k̂
   
Sol. p  q  p – q  3 5 2  –2 î  2 ĵ – 2k̂
1 1 0
   
 p  q  p – q
r  3  
p  q p – q 

=  – î  ĵ – kˆ 
so   1,   1,   1
  =3
 n
0 i  a b a b 
 
6. Let S  n  N       a,b,c,d  R  , where i  1 . then the numbers of 2-digit number

  1 0   c d   c d  

in the set S is _________
 0 i 
n
a b a b 
;fn S  n  N      

a,b,c,d  R  , tgk¡ i  1 . gS] rks leqPp; S esa nks vadks okyh la[;kvksa

  1 0  c d   c d  

dh la[;k gS _________
Ans. (11.00)

n
0 i  a b
Sol. Let A =   and B =  
 1 0 c d
AB = 
(A – )B = 0
A=
n
0 i 
 1 0 = 
 
 1 0
A8 =  
0 1
n = multiple of 8
Number of two digit numbers is S = 11 (16, 24,......96)
7. The ratio of the coefficient of the middle term in the expansion of (1 + x) 20 and the sum of the coefficients
of two middle terms in expansion of (1 + x)19 is _____________
Ans. (01.00)
20 20
C10 C10
Sol.  1
19
C9 19 C10 20
C10
10
 x 1 x 1 
8. The term independent of 'x' in the expansion of  2 1
 1


, where x  0, 1 is equal to
 x 3  x 3 1 x  x 2 
______
Ans. (210)
10
  x  1 
Sol.  (x1/ 3  1) –  
  x  
 
(x1/3 – x–1/2)10
Tr+1 = 10cr (x1/3)10–r (– x–1/2)r
10 – r r
– =0  20 – 2r – 3r = 0
3 2
 r=4
10  9  8  7
T5 = 10C4 = = 210
4  3  2 1
  a b 
9. Let M   A    : a,b,c,d   3,  2,  1,0 . Define f : M  Z, as f(A) = det(A), for all A  M, where Z
  c d 
is set of all integers. Then the number of A  M such that f(A) = 15 is equal to _______

  a b 
ekuk M   A    : a,b,c,d   3,  2,  1,0 gSA f : M  Z, (Z= lHkh iw.kkZadks dk leqg½ f(A) = det(A), lHkh A
  c d 
 M, }kjk ifjHkkf"kr gSA rks mu A  M dh la[;k ftuds fy, f(A) = 15 gS] rks _______
Ans. (16.00)
Sol. |A| = (ad – bc) = 15
where a, b, c, d  {±1, ±2, ±3}
Case – I ad = 9 & bc = – 6
ad  (3,3) or (– 3, –3) bc  (2, – 3), (–2, 3), (–3,2), (3, –2)
Total = 2 × 4 = 8 matrix
Case – II ad = 6 and bc = – 9
Similarly, Total = 4 × 2 = 8 matrix
Total such matrix = 8 + 8 = 16 matrix

10. Consider the following frequency distribution

fuEu ckjackjrk caVu ij fopkj dhft,%
Class : 10-20 20-30 30-40 40-50 50-60

Frequency  110 54 30 
If the sum of all frequencies is 584 and median is 45, then |–| is equal to _______
;fn lHkh ckjackjrkvksa dk ;ksx 584 gS rFkk ekf/;dk 45, |–| cjkcj gS _______
Ans. (164)
Sol. Class Frequency C.F
10-20   
20-30 110  + 110
30-40 54  + 164
40-50 30  + 194
50-60   + 194 = 584
_________________
N= f = 584
+= 390
 N  
 2   c 
Median (m) =       h
 f 
 
 
584
N  292
2
 292    164
m = 45 = 40 +    10
 30 
 128   
45 = 40 +  
 3 
128  
5=
3
15 = 128 –
= 113
= 277
|–| = |113–277| = 164


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JEE Main_25-07-2021_Shift-01

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