n 10. Common reagents (organic, inorganic and organometallic) in organic synthesis 11 Selective organic transformations ~ chemoselectivity, regioselectivity,steroseletvity, natioselectvity. Protecting groups 12. Physical characterization of organic compounds by IR, UV-, MS and NMR. 13. Principles related to Practical Chemistry. MATHEMATICS unr Analysis: Elementary set theory, Sets: Sets and their representations. Empty st, Firite & Infinite sets, Equal sets. Subsets, Subsets of the set of real numbers especially intervals (with notations). Power set. Universal set. Venn tiagrams Union and Intersection of sets Difference of sets. Complement ofa set, Properties of complement set. Finite, countable and uncountable sets, Real rumber system as a complete ordered field, Archimedean property, supremum, infimum Sequence and series: Sequence and Series, Arithmetic Progression (AP), Arithmetic Mean (A.M), Geometric Progresson (G.P), general term of @ G.P, sum of n terms of a GP . Arithmetic and Geometric series, infinite G.P, and its sum, Geometric mean (6 .M), relation between AM and GM, Sum to n term of the special series gr5n2 and 503 . Convergence. Sequences and series of functions, uniform convergence. ‘Binomial Theorem: History, statement and proof of the binomial theorem for positive integral indices. Pasca’s franc, general and middle term in binomial expansion, simple applications. Bolzano \Woverstrass theorem, Heine Borel theorem. Continuity and Differentiabiity: Continuity, uniform continuity. Continuity an Differentabilty, derivative of composite ‘inctons, chain rule, derivative of inverse trigonometric functions, derivative of impict asConcepts of exponential and logarithmic functions. Dervaives of loge® and eX. Logarithmic ifferetition. ervative of functions expressed in parametric forms, Second order derivatives, Rolle's and Lagrange's Mean Value Theorems (without proof) and thei geometric interpretations. Applications of Derivatives: Applications of derivatives: rate of change, increasing/decreasing functions, tangents and rarmal, approximation, maxima and minima. Simple problems (that illustrate basic principles and understanding of the subject as wel as real if situations). Limits and Derivatives Derivative introduced a rate of change both as that of distance function and geometrically, intuitive ea of tit, sup, limint. Oetantion of derivative, relate it to slope of tangent of the cure, derivative of sum, difference, product and quotient of functions, Derivatives of ‘polynomial and trigenometric functions. Mean value theorem. Integrals: integration as inverse process of cifferetiaion, Integration of a variety of functions by substitution, by partial fractions and by parts. Definite integrals as a limit of a sum, Fundamental Theorem of Calculus, 635° properties of definite integrals and evaluation of define integral Applications ofthe Integrals: Applications in finding the area under simple curves, especially lines, areas of ‘ves/parabolssfelipses, atea between the twa above said curves. Riemann sume and fiemann integral, Improper Integral. Monotonic functions, types of discontinuity, funetions of bounded variation, Lebesgue ‘measure, Lebesgue Integral. Functions of several variables, directional derivative, partial derivative, derivative asa linea transformation, inverse and implicit function theorems. Metric spaces, compactness, connectedness. Normed linear Spaces. Spaces of continuous functions as amples. Linear Algebra: Vector spaces: Vectors and scalars, magnitude and direction of a vector. Direction cosinosatios of vectors. Types of vectors (equal, unt, zero, parallel and collinear vectors) postion veetor of a point, negative of a vector, components ofa vector, adaition of vectors, ‘multighcatin ofa vector by a scalar, postion vector of a point dividing ane segment in a given ‘tio Salar (dot) praguct of vectors, projection of 2 vector on a line. Vector (ross) product of vectors, scalar triple product. Linear Inequalities: 16Linear inequalities, Algebraic solutions of linear inequalities in one variable and their representation on the number line. Graphical solution of linear inequalities in two variables. Solution of system of linear inequalities in two variables - graphically. Subspaces linear dependence, basis, dimension algebra of linear transformations. Matrices & Determinant: Concept, notation, order, equality, types of matrices, zero matrix, transpose of a matrin symmetric and skew symmetric matrices. Addition, multiplication and scalar multiplication of mateces, simple properties of addition, multiplication and scalar multiplication, Non- commutativity of multiplication of matrices and existence of non-zero matrices whose product is the rer0 matrix (restrict to square matrices of order 2). Concept of elementary row and Ccolume operations. Invertible matrices and proof of the uniqueness of inverse, iit exists Determinant of a square matrix (up to 323matrces), properties of determinants, minors, cofactors and applications of determinants in finding the area ofa triangle. -Agjoint and inverse ofa square matrix. Consistency, inconsistency and number of solutions of system of linear equation by examples, solving system of linear equations in two or three variables. using inverse of a matrix. Rank and determinant of matrices, near equations. Eigen values and eigen vectors, Cayley-Hamilton theorem. Matix representation of linear transformations. Change of basi, canonical forms, agonal forms, triangular forms, Jordan forms. Inner product spaces, orthonormal basis. Quadratic ‘forms. reduction and clasifiation of quadratic Forms Straight tines Brief recall of 2D from earlier classes, Shifting of origin. Slope of a line and angle between two ines Various forms of equations ofa line: parallel to axes, point-slope form, slop-intercept form, two-point form, intercept form and normal form, General equation of a line. Equation of ‘amily of lines passing through the point of intersection of two lines. Distance of a point from a Conic Sections: Sections ofa cone; circles , elipse, parabola, hyperbola ,2 point, a straight line and a par of intersecting lines as a degenerated case of a conic section. Standard equations and simple properties of parabola, elipse and hyperbola. Standard equations ofa circle Introduction to Three-dimensional Geometry Coordinate a4es and coordinate planes in three dimensions. Coordinates of a point. Distance between nwo points and section form “Throe-dimensional Geometry: Direction cosines/ratos ofa line joining two points. Cartesian and vector equation of a line, coplanar and skew lines, shortest distance between two lines. Cartesian and vector equation of 2 plane. Angle between (i) two lines, (i) two planes, (il) ne anda plane. Distance ofa point from a plane vvuwir-2 {Complex Numbers and Quadratic Equations: Need for complex numbers, specially ¥-1,to be motivated by inability to solve every quadratic Iisavon frit desertion oflgebralc properties of complex numbers. Argand plane and polar seyresentation of complex numbers, Statement of Fundamental Theorem of Algebra, solution Feuer atic equations inthe complex number system. Square-roat ofa Complex numba ‘Algebra of complex numbers, the complex plane, polynomials, power series, transcendental funetions such as exponential trigonometric and hyperbolic functions. ‘Trigenometre Functions: Positive and negative angles. Measuring angles in radians and in degrees and conversion from spe measure to another, Definition of tigenometsc Functions withthe help of unit ice. Truth ofthe identity sin2x + cos2x = 1, forall x. Sins of trigonometric functions and sketch oftheir raphe. Expressing sin(xty) and coslxty) In terms of sin, siny,c05x & c05y Identities related to sin 2x, cos 2s, tn 2, sin 3x, cos 3x and tan 3x. General solution of trigonometric equations ofthe type sin = sna, cos® = cosa and tan = tana. [Anaytic functions, Cauchy: Riemann equations. Contour integral, Cauchy's theorem, Cauchy's integral formula, Uouvlle’s theorem, Maximum modulus principle, Schware lemma, Open mapping theorem, Taylor series, Laurent series, caleulus of residues. Conformal mappings, Mobius transformations Algebra Permutations & Combinations: Fundamental principle of counting, Factorial (nl) Permutations and combinations, derivation cf formulse and their connections, simple applications. Pigeon-hole principle, incusion- ‘exclusion principle. Fundamental theorem of arithmetic civility in, congruences, Chinese Remainder Theorem, Euler's 9 function, primitive roots, Groups, subgroups, normal subgroups, quotient groups, homomorphisms, cycle groups, permutation groups, Cayley’s theorem, clars equations, Sylow theorems, Ring, ideals, prime and maximal ideals, quotient rings, unique factorization domain, principal ideal domain, Euclidean domain, Polynomial rings and iteducbility crite, elds, finite feds field extensions, Galois Theory Dense sets, subspace and product topology, separation axioms, connectedness andunit-3 Ordinary Differential Equations (ODES): Differential Equations: Definition, oeder and degree, general and particular solutions of a differentia! equation. Formation of iferential equation wnese general solution is given. Solution of aliferentiat equations by method of separation of variables, homogeneous Giferetiol equations of frst erder and frst degree. Solutions of linear differential equation of, the type: oy +o rn where P and Q are futons of xo constant. it pea a where P and Q are funetions of y oF constant Eaistence and uniqueness of solutions of intial value problems for frst order ordinary differential equations, singular solutions of fist order ODEs, system of ist order ODEs. General theory of homogenous and non homogeneous linear ODEs, variation of parameters, ‘Sturm Louvile Boundary value problem, Green's function Parts Differential Equations (PDEs) Lagrange and Charpit methods for solving frst order POES, Cauchy problem for ist order PDES. Classfication of second order PDEs, General solution of higher order PDES with constant coefficients, Method of separation of variables for Laplace, Heat and Wave equations. ‘Numerical Analysis: ‘Numerical solutions of algebraic equations, Method of iteration and Newton-Raphson method, fate of convergence, Solution of systems of linear alaebraie equations using Gauss elimination fn Gauss-Seidel methods, Finite differences, Lagrange, Hermite and spine interpolation, Numerical diferentiation and integration, Numerical solutions of ODES using Pieard, Euler, ‘modified Euler and Runge-Kutta methods. Calculus of Variations: Variation of a functional Euler-Lagrange equation, Necessary and sufficient conditions for trees. Varational methods for bouriory value prablems in ordinary and partial differential 19Linear integral Equations: LUnear integral equation of the frst and second kind of Fredholm and Volterra type, Solutions with separable kernels. Characteristic numbers and elgenfunctons, resolvent kernel Classical Mechani Generalized coordinates, Lagrange’s equations, Hamilton's canonical equations, Hamiton’s principle and principle of least action, Two-dimensional motion of rigid bodies, Euler's ‘dynamical equations forthe motion ofa rigid body about an axis, theory of smal oscilation. unas Descriptive statistics, exploratory data analysis. ‘Mathematical Reasoning: IMathemaucally acceptable statements. Connecting words/phrases-consolidating the Understanding of “if and only if (necessary and sufficient) condition”, " implies", “and/or, “implies by", "and, "or, there exits” and ther use through variety of examples related to real life and Mathematics , Validating the statements involving the connecting words-dfference bbetween contradiction, converse and contrapositve. Statistics [Measure of dispersion: mean deviation, variance and standard deviation of ungrouped/erouped data, Analysis of frequency distributions with equal means but afferent variances, Probability: Random experiments: outcomes, sample spacas| set representation). Events: Occurrence of events, ‘nt. ‘and’ & ‘or events, exhaustive events, mutually exclusive events, Axiomatic (set ‘heorete) probability, connections with the theories of earlier classes, Probabilty of an event, probability of ‘no, ‘and’ & ‘or’ events. Multiplication theorem on probability. Conditional probability, independent events, total probability, Baye's theorem, Random variable and its probability dstibuton, mean and variance of haphazard variable Repeated independent (Bernoull) trials and Binomial distribution. Sample space, discrete probabiity, independent events, Bayes theorem. Random variables and distribution functions {univariate and multivariate); expectation and moments. Independent random variables, marginal and conditional cistributions. Characteristic functions. Probabilty inequalities {chebyshe, Markov, Jensen). Modes of convergence, weak and strong laws of large numbers, Cental Limit theorems ‘Markov chains with finite and countable state space, classification of states, limiting behaviour ff nestep transition probabilities, stationary distribution, Poisson and birth-and-death processes. Standard discrete and continuous univariate dstibutions. sampling distributions, standard errors ané asymptotic distributions, distribution of order statistics and range, 20‘Methods of estimation, properties of estimators, confidence Intervals. Tests of hypotheses: ‘most powerful and uniformly mast powertul tests, liked ratio tests. Analysis of discrete data and chi-square test of goodness of it Large sample tests, Simple non-parametric tests for ‘one and two sample problems, rank correlation and test for independence. Elementary Bayesian inference. Gauss Markov models, estimabllty of parameters, best linear unbiased estimators, confidence intervals, tests for linear hypotheses. Analysis of variance and covariance. Fxed, random and ‘mixed effects models, Simple and multiple near regression Elementary regression dlagnostis. Logistic regression. ‘Mutivariate normal distrbution, Wishart distribution and their properties. Distribution of quadratic forms, Inference for parameters, partial and multiple correlation coeffkients and related tests. Data reduction techniques: Principle component analysis, Discriminant analysis, Cluster analyss, Canonical correlation Simple random sampling stratified sampling and systematic sampling. Probabllty proportional te size sampling Ratio and regression methods Completely randomized designs, randomized block designs and Latin-square designs. Connectedness and orthogonality of block design, BIBD. 2K factorial experiments: confounding and construction. Series and parallel systems, hazard function an fllue rates, censoring and life testing, LUnear Programming Problem: Introduction, definition of related terminology such as constraints, objectives function, ‘optimaation, eiferent types of linear programming (LP) problems, mathematical formulation of LP problems, graphical method of solution for problems in two variables, feasible and infoasblo region, feasible and infessble solutions, optimal feasible solutions (up to three non ‘rival constrains) Simplex methods, duality. Elementary queuing and inventory models. Steady state solutions of Markovian queuing models: M/M/2, M/MY/ with limited waiting space, M/M/C, M/M/C with limited waiting space, M/G/L. a