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Original article
a r t i c l e i n f o a b s t r a c t
Article history: Fibre Optics Reflectance Spectroscopy (FORS) is a well-established technique, widely used in the conser-
Received 15 June 2012 vation field for in situ investigations and non-invasive diagnostics on traditional artworks. Nevertheless,
Accepted 22 August 2012 there is little knowledge on the use of this technique for investigating modern artists materials used in
Available online 29 September 2012
contemporary artworks. The present study, carried out within the wider framework of the EC funded
Project “POPART” (Preservation of Plastic ARTefacts in museum collections”), was aimed at investigating
Keywords: the possibility of extending the applications of FORS to synthetic polymers, and proposing this technique
Expanded polystyrene (EPS)
as new non-invasive analytical tool for diagnostics on plastic artworks in museum collections. Thus, a
Fibre Optic Reflectance Spectroscopy
(FORS)
real case was selected from the permanent collection of the Conteporary Art Centre “Luigi Pecci” (Prato,
Non-invasive diagnostics Italy). The artwork, created in 1990 by the artist Stefano Arienti, was entirely constituted of expanded
UV-Vis-NIR spectroscopy polystyrene (EPS) and it showed diffused signs of degradation. The need of singling out the main causes of
Contemporary art deterioration in order to prevent further damages was evident. An in situ FORS measurements campaign
Artist interview was performed with the aim of gaining in-depth information about its conservation state and identifying
the main agents responsible for the observed degradation. Thanks to the non-invasivity of the technique
an extensive spectroscopic characterisation of different areas of the EPS surface could be performed and
the spectral data were exploited to build a map of the degraded areas of the artwork. Data acquired in
field were compared with those obtained from laboratory test performed on artificially aged EPS samples.
These results helped in ascertaining the detrimental actions of the light sources used to back illuminate
the artwork. In particular, in this case FORS proved to be effective in detecting EPS alterations before the
chromatic effects became visually evident. These results suggested that FORS may be considered as a good
candidate to be used for non-invasive investigations also on some modern materials and contemporary
artworks. The research was completed with an interview to the artist Stefano Arienti, whose point of
view was constructively integrated with the scientific results obtained. This emphasized the importance
of an interdisciplinary approach to the solution of conservative problem in the field of contemporary art.
© 2012 Elsevier Masson SAS. All rights reserved.
1. Introduction and research aim number of new interweaved issues, not only related to the scientific
and technical aspects, but also to ethical and philosophical ques-
Over the last two decades, along with the growth of relevance of tions, continue to liven up a vivacious debate about conservation
the contemporary art sector in the cultural, economical and social of contemporary assets.
context, increased attention has been devoted to the themes of Some of the most difficult and still unresolved questions raised
preservation and maintenance of both modern and contemporary are related to the unexpectedly rapid degradation of many modern
artworks. Thus, a new research area, focussed on topics related to materials used to create contemporary artworks, which, despite
contemporary art, has progressively taken shape in the field of con- their short age, are starting to show dramatic deteriorations and
servation science, and it is documented by the growing literature changes in appearance. Among these modern materials erro-
and the increasing number of projects and events launched in the neously considered durable, a foremost place is occupied by the
last few years [1–5]. Because this is a dawning research field, a huge class of synthetic polymers, more commonly known as “plas-
tics”. Plastics occur in a number of often-quoted artworks and
museum objects of historical and artistic value. Nevertheless, the
∗ Corresponding author. Tel.: +39 0555226405. complex conservation problems related to preservation of plastic
E-mail addresses: c.cucci@ifac.cnr.it (C. Cucci), leo.bigazzi@hotmail.it (L. Bigazzi), objects have been mostly overlooked until quite recently. There
m.picollo@ifac.cnr.it (M. Picollo). are two explanations for this fact. The first is that, as commonly
1296-2074/$ – see front matter © 2012 Elsevier Masson SAS. All rights reserved.
http://dx.doi.org/10.1016/j.culher.2012.08.003
C. Cucci et al. / Journal of Cultural Heritage 14 (2013) 290–296 291
Fig. 3. In situ measurement campaign at the Contemporary Art Centre “Luigi Pecci”: Fig. 5. A laboratory test aimed at simulating the real conditions of the artwork
a detail of the 8◦ /8◦ probe-head connected to the optical fibre bundle used to acquire illuminated with fluorescent tubes.
the reflectance spectra on the Panel n.1 of the artwork Cartoline.
Fig. 6. Normalised absorbance spectra measured on the n.17, 25, 34 and 37 points, Fig. 7. Normalised absorbance spectra measured on the light-aged EPS samples
respectively, on the front and on the backside of the Panel n.1. The spectra may be exposed in controlled conditions under a halogen light with average Illuminance
grouped in two classes, corresponding to degraded and non-degraded areas of the I = 1040 lux and UV = 443 W/m2 . The overall exposure lasted 10 months (from June
panel. 2010 to May 2011), with periodic measurements made at T0 = un-aged; T1 = after
3 months; T2 = after 5 months; T3 = after 10 months.
Fig. 8. Scheme of the distribution of degraded areas on the Panel n.1 based on the spectral data measured by FORS.
the front side of the panel. Conversely, a slight tendency to yellow- The Stefano Arienti interview was conducted in his studio in
ing (b* > 0) was revealed on the back of the panels, as expected, Milan on 22 September 2010 [27]. The conversation was focused
within the areas closest to the fluorescent tubes. on the artwork Cartoline, with regard to its history, the artistic
Although the above outcomes could be considered only prelim- techniques and the reasons for the choice of the material. Also,
inary and qualitative, some important conclusions and indications more general issues were discussed, such as the artist’s opinions
can be drawn on the basis of these results. First of all, an indirect about the decay of artworks and conservation and restoration inter-
confirmation of the suspected detrimental action of the fluorescent ventions. In particular, the artist’s point of view on the mounting
tubes was obtained. Additionally, it was evident that the observed scheme and on the role of the retro-illumination in the artwork
colour unevenness of the front of the panels was not simply explain- Cartoline was one of complete openness to changes to the set-up
able with a photo-induced degradation because these areas were currently in use. Following the interview, an intervention program
not characterised by spectral behaviours similar to those typical of for Cartoline was initiated and it is now on-going. The program’s
aged material. Thus, other additional degradation external agents, goal is to select a different light sources and a new mounting
such as dust depositions and repeated handling, were supposed to scheme, both of which will minimise the impact on the EPS.
have a role in determining the present conditions of the panels.
The overall analysis performed made it possible to build a kind
of map of the degraded areas on the basis of the spectral charac- 6. Conclusions
teristics observed (Fig. 8). Thus, FORS spectra could be effectively
exploited to detect alterations of the EPS surface not observable by The study presented evidences the advantages of a multidisci-
the naked eye. plinary approach to the solution of conservative problem in the
field of contemporary art. In particular, this paper describes and
discusses the results of an interdisciplinary study performed on
the EPS artwork “Cartoline”.
5. The interview with the artist In situ FORS measurements were performed on selected pan-
els by means of non-invasive UV-Vis-NIR spectroscopy, in order
The results of the scientific analysis based on non-invasive UV- to gain in-depth information about their conservation state and
Vis-NIR spectroscopy, though non exhaustive, clearly indicated that to identify the main agents responsible for the observed degrada-
the prolonged exposure of the EPS to the fluorescent tubes could be tion. The spectroscopic analysis made it possible to build a map of
deleterious. Moreover, the mechanical damages and the friability the degraded areas and to ascertain the detrimental actions of the
of the edges of the panels could, likely, be attributed to repeated fluorescent tubes used to back illuminate the artwork. The mea-
handling and to the use of pins to fix the artwork to the wood surements evidenced a spectral alteration of the EPS in the areas
structure. close to the positions of the light sources.
Based on all these findings, it is recommended that other mount- As part of the wider Project POPART, this paper may also be
ing schemes, more compatible with safeguarding the artwork considered to be a pilot study to determine the applicability and
Cartoline, be adopted. On the other hand, because illumination the effectiveness of the FORS technique for the analysis of plas-
seemed to be important to the artist, Stefano Arienti, it was decided tics. In the specific case examined, FORS was able to detect EPS
to seek his opinion. alterations before the chromatic effects become visually evident.
The importance of the interaction with the artists in contempo- The scientific investigations, although limited to few panels, vali-
rary art conservation is, indeed, widely recognised, and the recourse dated the hypothesis that a preservation program for Cartoline had
to interviews as tool for problems solving is strongly recommended to include a modified mounting scheme and a different illumination
[1,2]. system. These results were presented to the artist Stefano Arienti,
296 C. Cucci et al. / Journal of Cultural Heritage 14 (2013) 290–296
whose openness to change was crucial to the proposal of alterative [8] B. Keneghan, Plastics preservation at the V&A, V&A Conservation Journal 50
solutions for the maintenance of the artwork. (2005) 15–17.
[9] S. Blank, An introduction to plastics and rubbers in collections, Studies in Con-
servation 38 (1990) 53–63.
Acknowledgements [10] Y. Shashoua, Conservation of plastics: it is possible today? in: B. Keneghan, L.
Egan (Eds.), Plastics: looking at the future and learning from the past, Archetype
Publications London, 2008, pp. 12–19.
The research leading to these results was partially funded [11] Y. Shashoua, Conservation of Plastics, first ed., Elsevier, Butterworth-
from the European Community’s Seventh Framework Programme Heinemann, 2008, Oxford.
FP7/2007-2013 within Research Project POPART (grant agreement [12] F. Waentig, Plastics in Art, Verlag, Ptersberg (Germany), 2009.
[13] http://popart.mnhn.fr/.
No. 212218). [14] B. Lavédrine, R. Rivenc, M. Schilling, POPART. An International Research Project
Authors wish to acknowledge the Direction of the Contempo- on the Conservation of Plastics. The GCI Newsletter, 24Getty Conservation Insti-
rary Art Center “Luigi Pecci” in Prato for offering the opportunity of tute, Los Angeles, 2009, pp. 10–12.
[15] C. Cucci, M. Bacci, M. Picollo, R. Olmi, Non invasive techniques for identification
performing in situ investigations on the artwork Cartoline, and in
and characterisation of polymers in contemporary artworks, in: T. Berchtold
particular Elena Pecci, Marco Bazzini, Stefano Pezzato and Raffaele (Ed.), Future Talks 009 The Conservation of modern materials in applied arts and
Di Vaia for their kindness and fruitful collaboration. A special thank design, Proceedings of the Conference Future Talks 009, Die Neue Sammlung
Munich, 22–23 October 2009, Munich, Germany, 2011, pp. 178–184.
is due to the artist Stefano Arienti, for his courtesy, helpfulness and
[16] T. Van Oosten, et al., Identification and characterization of plastics artefacts, in:
precious contribution to this research. The restorer Rachel Morellet B. Lavédrine, A. Fournier, G. Martin (Eds.), Preservation of Plastic Artefacts in
is also gratefully acknowledged for kindly providing the condition museum collections, CTHS Editions, France, 2012, pp. 29–105.
report on the artwork. [17] M. Bacci, F. Baldini, R. Carlà, R. Linari, Color Analysis of the Brancacci Chapel
Frescoes Applied Spectroscopy 45 (1) (1991) 26–31.
Part of the technical apparatus used for aboratory test was kindly [18] M. Bacci, A. Casini, C. Cucci, M. Picollo, B. Radicati, M. Vervat, Non-invasive
provided by the technical services section of the Uffizi Gallery in spectroscopic measurements on the Il ritratto della figliastra by Giovanni Fat-
Florence. tori: identification of pigments and colourimetric analysis, Journal of Cultural
Heritage 4 (4) (2003) 329–336.
Finally, authors are particularly grateful to Mauro Bacci and Mar- [19] M. Leona, J. Winter, Fiber optics reflectance spectroscopy: a unique tool for
vin Gore for useful discussions and suggestions. the investigation of Japanese paintings, Studies in Conservation 46 (3) (2001)
153–162.
[20] M. Bacci, R. Bellucci, C. Cucci, C. Frosinini, M. Picollo, S. Porcinai, B. Radicati,
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