CLASS–XII TERM-1 TEST SERIES-2021

2 TOPIC/UNIT : HALOALKANES & HALOARENES

QN TIME : 1.00 Hr MM : 25

1. Answer strictly in the serial order (01 to 25).

2. In answers, write only the option number like A, B, C etc

01 CH3CH=CHC(Br)(CH3)2 is an example of :
A Allyl halide B Aryl halide C Vinyl halide D Alkyl halide
02 Ethylidene chloride is a/an :
A vic-Dihalide B gem-Dihalide C Allylic halide D Vinylic halide
03 Which of the following reactions follows Markovnikov’s rule ?
A C2H4 + HBr B C3H6 + Cl6 C C3H6 + HBr D C3H6 + Br2
04 Choose the correct order of boiling points of following compounds : 1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
A Butane<1-Chlorobutane<1-Bromobutane<1-Iodobutane B 1-Iodobutane<1-Bromobutane<1-Chlorobutane<Butane
C Butane<1-Iodobutane<1-Bromobutane<1-Chlorobutane D Butane<1-Chlorobutane<1-Iodobutane<1-Bromobutane
05 Which of the following is the most reactive towards nucleophilic substitution reaction ?
A ClCH2 – CH = CH2 B CH2 = CH-Cl C CH3CH = CH-Cl D C6H6Cl
1
06 Which of the following alkyl halides will undergo SN reaction most readily ?
A (CH3)3C-F B CH3CH2CH2CH2-I C CH3CH2CH(Br)CH3 D (CH3)3C-I
07 Correct IUPAC name for CH3CH(C2H5)CH2CH2Br is :
A 1-Bromo-3-ethylpropane B 1-Bromo-3-methylpentane
C 3-Methyl-1-bromobutane D 1-Bromo-2-ethyl-2-methylethane
08 Finkelstein’s reaction is used to prepare :
A RCl from RBr & RI B RBr from ROH C RI from RCl & RBr D RF from RBr & RI
09 To prepare 2,2-Dibromopentane by anti Markownikoff’s addition, HBr should be reacted with :
A 1-Pentyne B 2-Pentyne C 1-Pentene D 2-Pentene
10 Which reagent will you use for the following reaction : CH3CH2CH=CH2 CH3CH(Cl)CH=CH2 + HCl
A Cl2/UV light B NaCl + H2SO4 C Cl2 gas in dark D Cl2 in the presence of iron
11 Which of the following compounds will have highest melting point ?
A Chlorobenzene B o-Dichlorobenzene C m-Dichlorobenzene D p-Dichlorobenzene
2
12 Which of the following statements is correct about intermediate of S N reaction ?
A Intermediate is unstable ∵ C is attached to 5 atoms B Intermediate is unstable because C-atom is sp² hybridised
C Intermediate is stable because C-atom is sp² hybridised D Intermediate is more stable than the product
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13 Which of the following statements are correct about SN mechanism ?
A Nucleophile attacks RX from one side and X– simultaneously leaves from the other side
B An unstable intermediate will be formed in which nucleophile and halogen will be attached by weak bonds
C A carbocation is formed as an intermediate D A carbanion is formed as an intermediate
14 Correct reactivity order of following compounds in SN2 reaction is : (i) CH3Cl (ii) (CH3)3C-Cl (iii) (CH3)2CH-Cl (iv) CH3CH2-Cl
A (i) > (ii) > (iii) > (iv) B (iv) > (iii) > (ii) > (i) C (i) > (iv) > (iii) > (ii) D (iv) > (i) > (ii) > (iii)
15 A primary alkyl halide would prefer to undergo :
A SN1 reaction B SN2 reaction C α–Elimination D Racemisation
16 How many chiral C-atoms are there in 2,3-Dihydroxy butanedioic acid ?
A 1 B 2 C 3 D 4
alc KOH
17 In the reaction : CH3CH2CH(Br)CH3 CH3CH=CHCH3 (A) + CH3CH2CH=CH2 (B)
A (B) is major and (A) is minor product B (A) is major and (B) is minor product
C Only (A) is formed D Only (B) is formed
18 Alkyl halides are prepared from alcohols by treating with :
A Cl2 + Red P B Cl2/Sunlight C H2SO4 + KI D All the above
Contd….
 CLASS–XII TERM-1 TEST SERIES-2021
2 TOPIC/UNIT : HALOALKANES & HALOARENES

19 Which is the correct IUPAC name of Pentamethylene dichloride ?

A 1,2-Dichloro pentane B 1,1-Dichloro pentane C 1,5-Dichloro pentane D 2,2-Dichloro pentane
alc KOH Cl2/CCl4 alc KOH HCl (ex) aq KOH
20 2-Bromobutane A B C D E Compound E is :
A Butanoic acid B Butanal C Butanone D 2-Butyne
21 An organic dihalide A reacts with aq NaOH to give a carbonyl compound B. Compound B does not respond to Iodoform test.
Compound A is :
A 1, 3-Dichloropropane B 1, 2-Dichloropropane C 2, 2-Dichloropropane D 1, 1-Dichloropropane
22 Alkyl halides react with nucleophiles because :
A They have an electrophilic carbon & a bad leaving group B They have a nucleophilic carbon & a good leaving group
C They have an electrophilic carbon D They have an electrophilic carbon & a good leaving group
Amongst assertions and reasons given below (Q : 23-25), choose the correct answer out of the following choices :
(A) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(B) Assertion and reason both are correct statements but reason is not correct explanation for assertion.
(C) Assertion is correct statement but reason is wrong statement.
(D) Assertion is wrong statement but reason is correct statement.
23 Assertion : In monohaloarenes, further electrophilic substitution occurs at ortho and para positions.
Reason : Halogen atom is a ring deactivator.
24 Assertion : SN2 reaction proceeds with inversion of configuration.
Reason : SN2 reaction occurs in one step.
25 Assertion : Aryl iodides cannot be prepared by reaction of arenes with iodine in the presence of an oxidising agent.
Reason : Oxidising agent oxidises HI into I2.
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