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BANGALORE SAHODAYASCHOOLS COMPLX

PRE-BOARD EXAMINATION 2021-22
CHEMISTRY-Code(043)
SET-1 Max. Marks: 35
Class: XI
Time: 90 Minutes
Date: 21/10/2021

General Instructions:

1. The Question Paper contains three sections.

2. Section A has 25 questions. Attempt any 20 questions.

3. Section B has 24 questions. Attempt any 20 questions.
4. Section C has 6 questions. Attempt any 5 questions.

5. All questions carry equal marks.

6. There is no negative marking.

SECTION A

In casee
This section consists of 25 multiple choice questions with overall choice to attempt any 20 questions.
considered for evaluation.
more than desirable numbers of questions are attempted,ONLY first 20 will be

substitution?
Which one of the following is most reactive towards nucleophilic
HC=CH-CCl2
S. CeHsC
CH-CH=CH-CI
D. CICH-CH=CH2
Which one among the following, reacts most readily with ethanol to form ethers?
2.
p-nitro benzyl bromide
P-chlorobenzyl bromide

C. p-methoxybenzyl bromide

D. p-methyl benzyl bromide

The unit cell structure of a compound is shown below. The formula of the compound is
3.

AB2Cs
AB,C3
C. ABCs
D. ABCs

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 closie

of these
electrical conductivity
shows Frenkel defects. The
and AgCl
Na shows Schottky defects
crystals is due to:
A. movement of ions and electrons
. movement of lons alone
movement of electrons alone
lower coordination number of NaCl.
side of the unit
.
Lithium metal crystallizes in a body- centered cubic crystal.
If the length of the
cell of lithium is 352pm, the atomic radius of the lithium will be
300.24 pm
B. 152.42 pm bet
C 158.2 pm
75.5 pm

6 The composition of a sample of Wustite is Fe0.930 and it shows metal deficiency defect.
What percentage of tho iron is present in the form of Fe (1) for the disappearance of 0.07 Fe ()
Ions?
5%
B
7.087
15.05 %
D. 23.60
What is the total volume of atoms in a face centred cubic unit cell of a metal? (ris atomic radius).
16/3 T
TTr
24/3 TT
D. 12/3 TT

8 Arrange the following halides in the decreasing order of Sw1 reactivity:

(0 CH,CH,CH,CI () CH, =CH-CH=CH-CH (CI) CH () CH;CH,CH(C) CHs
>Il> lll
ll>ll>

D. 1> I1>

9) The structures of 4 alkyl halides are given below; which of the following is the incorrect
statement regarding the alkyl halides given.

A. Tis more reactive for Sh2 reaction

B. IV is most reactive for Elimination reaction
Il is more reactive than ll in S1 reaction.
C.
None of the above.

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10 This reaction would follow which of the
following pathway predominantly?
Acetone
SNT
CH-CH-CH-CH,Br+CH,CH,0 7

. SN2
Nucleophilic addition
D. Elimination reaction
11. Predict the major product in the following reaction:
Bromobutane+ Phenol - EtOK/anhvdrous Ethanol

OEt
A. Et

oPh
C. OPh
D.
12 From amongst the following alcohols the one that would react fastest with conc HCl and
anhydrous ZnClh, is
2-butanol
.
2-methylpropan-2-ol
2-methylpropanol
D. 1-butanol
13. The best reagent to convert Hex-3-en-2-ol into Hex-3-en-2-one is

MnOz
Pyridinium chlorochromate
Acidified KMnO4
D. Acidified K,CrO
14. ldentify the set of reagents/reaction conditions X and Y in the following set of transformations:

CH-CHCH;Br Product
CH-CH-CHs
X= aqueous NaOH, Y = HBr Br
X = alcoholic KOH, Y = HBr
X= aqueous KOH, Y = Br:/CHCl

D. X= alcoholic KOH, Y = Bra / in CHCl

15) In the hydroboration-oxidation reaction of propene with diborane, H,02 and NaOH, the
organic compound formed is:
CH,CH,OH
B CH,CHOHCH
CH, CHCH,OH
D. (CH),COH

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 16. XeF is

Square pyramidal and acts a fluoride donor with CSF

Square planar and acts as a fluoride donor with
D.
Square planar and acts as a fluoride donor with SbFs
NaF
Octahedral and acts as
fluoride donor with AsFs
a

17. Consider the oxy acids HCIOn

regarding these oxy acids is: series, here value of n is 1 to 4. Then incorrect statement
A
B,
Acidic character increases with incroase in value of n.
Oxidizing power of
oxyacids increases with decrease
Thermal stability value of n.
of
oxyacids decreases with decreasing value
CHO bond order ofn
decreases with
decreasing value of n.
8. Which of the
following compounds don't undergo
TeFs i. SFe ii. NClh iv. NF3 hydrolysis?
i& i
ti & ii

&iv
i& Iv
9. Which of the
following is the
increasing order of
NH< PH,AsH enthalpy of
vaporization?
C
AsHa <PH<NH3
NH< AsHs PH <
D.
PH, AsHa< NH3
20 The total
Xa and Xa are thevapour pressure of a
binary
mole fractions of solution is
components A and B.given by: P
(75XA +360 Xa)=

The vapour This indicates: mm Hg where

pressure of the solution
is more than
Vapour pressure of
pure A is that of the
The vapour
pressure of pure A Hg and that of pure B is pure components.
T5mm
The and B are 360 mm 360mm Hg.
component evaporates more
A and 75 mm
Hg
Nitrogen gas is liberated by thermal
readily than B respectively.
Barium Azide decomposition of the following
compounds:
Ammonium nitrite
C.
Ammonium dichromate
D. All the above
22. An azeotropic mixture is
the one
A. Can be that
B.
separated
by
Shows either positive
simple distillation.
or
Behaves like negative deviations from Raoult's law.
D. mixture
a
Behaves Ike an ideal of components, as is mixea with it
solution. different
components.
23. Calculating the molar mass of a
compound using colligative
when:
properties will be accurate
CCur ate

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 The solute is volatile.
The solution is a supersaturated with solute.
The solution is dilute
D. Solution must be formed from similar substances.
24. Non-ideal solutions showing positive deviations from Raoul's law

A. Acetone+ CHC
B. CHClh+ CeHe
C. H0+ HC
D. H,0+ CaH,OH
25. The mole fraction of the solute ina1 molal aqueous solution is:

A. 1

B. 1.8
. 18
D. 0.018
SECTION B

to attempt any 20 questions. In case

This section consists of 24 multiple choice questions with overall choice
more than desirable number of questions is attempted, ONLY
first 20 will be considered for evaluation.

because of
26. DNA molecule is considered as a chiral molecule and shows optical activity
Nitrogenous bases
B. Deoxy ribose sugar
Ribose sugar
Phospho-ester bond.
The solubility of a gas in a liquid is directly proportional to the partial pressure of the gas present above
27.
the surface of liquid or solution.

Dalton's law of partial pressures.

Raoult's law
Henry's law.
D. Raoult's law & Henry's law

28. The depression in freezing point of equimolal aqueous soltion wll be highest for

Ca (NOs2
5.
CeH120s
Urea
D. La (NO3)

29.
length is:
Forthe compounds CH,Cl, CH,Br, CHl and CH,F, the correct order of increasing C-halogen bond
CH F < CH,Cl < CH,Br < CH
A.
B.
CH,F< CH,Br < CH,Cl< CHl

CH F< CHl CH Br < < CH,CI

. CH,CI < CH,Br < CH F < CH
D.

5|Page
 hemiacetal formation between
structure of glucose is due to
S0. Pyranose ring
A C1&C5
B C1&C4
& C3
c2 & C4 acid gives.
with concentrated nitric acid and sulphuric
Phenol, when reacts
S1
o-nitro phenol
p-ilrophenol
O-nitrophenol & p-nitrophenol
2,4, 6-trinitrophenol

2.
Amorphous solids are:

.
Anisotropic and super cooled liquids.
Isotropic and super cooled liquids.
5.

C. Isenthalpic and superheated liquids.

. Isotropic and super-heated liquids.
is
give two monochlorinated compounds,
S3. Of the four isomeric hexanes, the isomer which can

. 2-methyipentane
2, 2-dimethylbutane
2, 3-dimethyibutane
D. n-hexane
An example of an amino acid that has basic side chain:

Glycine
Gutamine
Lysine
D. Aspartic acid

5. HBr reacts fastest with:

2-methyl propan-2-ol
propan-1-ol
propan-2-ol
D. 2-methy! propan-1-ol
36. Ifthe dissolution process is endothermic (Asal H>0), the solubilty increases
With rise in temperature.
With decrease in temperature.
With the addition of more solute.
D. With the addition of more solvent.

37. In a Hexagonal crystal

g y 90, a=b=c
a= p= y# 90, a=b# C
.

a- py= 90, arbrFC

a B=90" Y= 120, a=b# c

In presence of NaOH, phenol reacts with CHC, to form o-hydroxy benzaldehyde. This reaction is
38.
called

6 1Page
 Riemer-Tiemann's reaction
Sandmeyer's reaction
Kolbe's reaction
0. Gattermann's Koch synthesis
39. The units of 1 ppm are:
1 pg
A.
. 1 mg/g
mg
1 pgl
1 mg/Kg

40. Phenol is less acidic than

Ethanol
B. Methano
O-nitrophenol
D. P-methyiphenol
ethyl ether will yield
41. On boiling with concentrated hydro bromicacid, phenyl
Phenol and ethyl bromide
Bromobenzene and ethanol
Phenol and ethane
. Bromobenzene and ethane
in the order of
2. The order of volatility of Hydrides of Group 16 show

HO> HS>HSe> HTe

HTe > H,Se > H;S > H,O
HS> H,Se> H,Te > H,0

H,Te < HS <HSe < H0

D.

INCORRECT about noble gases?

43. Which of the following statement is
They belong 18
to group of periodic table.
forces.
B. They have weak dispersion
Noble gases have high melting and boiling points.
enthalpies.
D. They have positive electron gain
The boiling point of CoH, CH,OH, CHNH; and CjHNO; are 800, 650, 1840 and 212 respectively.
44.
at room temperature?
Which will show highest vapour pressure

CHs
CH,OH
CoHNH
CHNO2
wo statements labelled as Assertion (A) and Reason (R)
45. Given beloW ar
and dilute NaOH.
Assertion (A): Chlorine forms hypochlorite with cold
it disproportionate to form Chlorate and
Reason (R): Hypochlorite is unstable at high temperature,
chloride.
the options given below:
Select the most appropriate answer from

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 otA
A Both A and R are true and R is the correct explanation ofA.
B.
Both Aand Rare true but R is not the correct explanation
A is true but R is false.
D. A is false but R is true.
Given below are two statements labelled as Assertion (A) and Reason (R)
46
Assertion (A) The geometry of XeOaFa is seesaw shaped.
with three Oxygen atoms at equatorial position and
Reason (R): Xe undergoes SP d hybridization,
F-atoms at axial positions.
Select the most appropriate answer from the options given below
R are true and R is the correct explanation of A
A Both Aand
B. Both A and R are true but R is not the correct explanation of A.
A is true but R is false.
D. Als false but Ris true.

47 Given below are two statements labelled as Assertion (A) and Reason (R)
Assertion (A): Despite having an aldehydic group, Glucose does not react with NaHSOs
Reason (R): This reaction occurs in the presence of a free aldehyde group.

Select the most appropriate answer from the options given below

Both AA
and Rare true andbut
Risis not
R
the correct explanation of A
Both andRare true
A is true but R is false.
the correct explanation of A.

D. Ais false but Ris true.

48. Given below are two statements labelled as Assertion (A) and Reason (R)
Assertion (A): Metal excess defects are responsible for the colour of the crystal in LiCi.
Reason (R): The grealer the number of F-centers, the more Intense the color of the
compound
Select the most appropriate answer from the options given below:
A Both A and R are Irue and R is the correct explanation of A
A but R is not the correct explanation of A.
C.
Both andR are true
A is true but R is false.
D. A is false but Ris true.

49 Given below are two statements labelled as Assertion (A) and Reason (R)
Assertion (A) : XeFs +3H,0- Xe0,+6HF is a redox reaction.
Reason (R): In the hydrolysis reaction given the hybridization of Xe does not change.

Select the most appropriate from the options given

answer
below
A Both A and R are true and R is the correct explanation of A
B. Both A and R are true but R is not the correct explanation of A.
A is true but R is false.
. A is false but R is true
SECTION C

This section consists of 6 multiple choice questions with an overalchoice to allempt any 5. In case
more than desirable numbers of questions are attempted, ONLY first 5 will be considered for
evaluation.

8Page
50. Match the
following
A.HF
B. Covalency of
i. React with glass
N
C.XeF ii. Square pyramidal
D.BrFs iv. Distorted
E.HIL Octahedral
Which of the
following is the best matched option?
A-il, B-1, C-v, E-ii
B. A-v, B-1, C-i, D-il
C. A-ii, B-1, C-iv, D-ii
D. A-i, E-iv, D-ii, B-i

51. Which of the following analogies is correct?

A. XeOs: Tetrahedral:: NaN: inert
B. XeFz: Linear:: CIF;: Trigonal pyramidal
C. HNO: Disproportionate to HNO,& NO:: HNO: Ostwald's process
Pb (NOsh: Decomposes to NO:: SO, is an oxidizing agent.

2. Which of the following analogies is correct?

A. Ch Highly electronegative: Fa: High electron gain enthalpy

B. NH: Pyramidal:: 03: Thermodynamically unstable
C. XeFa: Square pyramidal: XeOs : An explosive liquid
Noble gases: Stronger intermolecular forces of attraction.
D. Pa: Allotropy:
Case 1: Read the passage given below and answer the following questions:

of this
For a molecule to taste sweet, it must bind to a receptor on a taste bud cell on the tongue. The binding
molecule causes a nenve impulse to pass from the taste bud to the brain, where the molecule is interpreted as
with the sweetness of glucose, the
being sweet. Sugars differ in their degree ot sweetness. Compared
Sweetness of sucrose is high, and that of fructose, the sweetest of all sugars. Developers of artificial sweetenet
must evaluatepotential products in terms of several factors-such as toxicily, stability and cost-in addition to
taste. Glucose, fructose and mannose are interconvertible carbohydrates through their keto enol isomerism.

The following questions are multiple cholice questions. Choose the most appropriate answer:

53. Look at the molecule given, which atom in the given molecule is anomeric carbon?

CHO

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 Atom B
B. Atom C
C. Atom D
D. Atom E
E. Atom F

54. Which name completely describes the above cyclic structure of compound?
A. a-D-Glucofuranose
B, B-D-Glucopyranose
C. a-D-Glucopyranose
D. B-D-Glucofuranose

55. Fructose gives positive test with Fehling's solution because

of
A. Presence of Carbonyl groupP
B. Presence of asymmetric carbon.
C. Fructose will tautomerise forming Glucose
D. Presence of primary alcoholic group.

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