OLIVE INTERNATIONAL SCHOL, QATAR (2022-23)

Revision Worksheet No.1

Grade: XI Subject: Chemistry (Code : 043)
Date of issue :07 .10.202 Date of submission : 10.10.2022
Lesson : 1 (Basic Concepts of organic Chemistry). Teacher’s Signature: ……………….
……………………………………………………………………………………………………..
Answer the following questions:-
1. Which of the following compounds will not give Lassign’s test for nitrogen?
a. C6H5NHNH2 b. C6H5NNC6H5 c. NH2---NH2 d. NH2CONH2
2. Which of the following ion is most resonance stabilized?
a. C2H5O- b. C6H5O- c. (CH3)3CO- d. (CH3)2CHO-
3. The reaction CH3CH2I +KOH(aq) CH3CH2OH + KI is classified as …………….
a. Electrophilic substitution c. nucleophilic substitution
b. Elimination d. Addition
4. Homolyte fission leads to the formation of …………………..
a. Nucleophile b. carbanion c. carbocation d. free radical
5. Sodium nitroprusside reacts with sodium sulphide formed in Lassaign’s test to detect the presence of
Sulphur gives violet colour due to ……………..
a. Na2[Fe(CN)5NO] b. Na4[Fe(CN)5NOS] c. Na2[Fe(CN)5COS] d. None of these

6. The structural formula for 1-chloro-4-methylbenzene is ………………..

7. Nucleophile is a species that should have …………..
a. A pair of electrons to donate c. positive charge
b. Electron deficient species d. none of these
8. Hyperconjugation involves the delocalization of …………………
a. Pi electrons of C-C bond
b. Electrons of C-H sigma bond of an alkyl group directly attached to an atom of an unsaturated
system
c. None of these d. lone pair of electrons
9. Match the following :-
Column I Column II
a. Two solids have different solubilities in a solvent (i). Steam distillation
And which do not undergo reaction when dissolved
In it
b. Liquid that decomposes at its boiling point (ii). Fractional Distillation
c. Steam volatile liquid (iii). Simple distillation
d. Two liquids which have boiling points close to each other (iv). Distillation under reduced P.
e. Two liquids with larger difference in boiling points. (v). Crystallisation
10. In the following questions, The Assertion and Reason have been put forward. Read the statements
carefully and choose the correct alternative from the following.
a. Both Assertion and Reason are true and Reason is the correct explanation for Assertion.
b. Both Assertion and Reason are true and Reason is not the correct explanation for Assertion.
c. Assertion is true Reason is false
d. Both Assertion and Reason are false.
[OIS- AL THUMAMA /XI CHEMISTRY/ Revision worksheet for HY Exam] Page 1
 (i).Assertion: Energy of resonance hybrid is equal to the average energies of all canonical forms.
Reason : Resonance hybrid cannot be presented by a single structure.
(ii).Assertion: Pent-1-ene and pent-2-ene are position isomers.
Reason: Position isomers differ in the position of functional group or a substituent.
(iii). Assertion: A mixture of o-nitrophenol and p-nitrophenol can be separated by steam
distillation
Reason: p-nitrophenool is steam volatile while o-nitrophenol is not steam volatile.
11. Aldehydes and ketones undergo nucleophilic addition reactions. [True / False]
12. Calculate the number of sigma and pi bonds in 1,3-butadiene.
13. Identify the most electronegative element in CH2FCl.
14. (CH3)3C+ is more sable than (CH3)2CH+. Explain why?
15. If we get blood red colouration on adding FeSO4 and dilute sulphuric acidto the sodium extract,
what do you infer about the elements present in the organic compound?
16. Complete the following (CH3COO)2 Pb + Na2 S ?
17. Identify the electrophilic centre in the following compounds. (i). CH3CHO (ii). CH3CN
18. Indicate the number of pi and sigma bonds in HCONHCH3.
19. Out of benzene, m-dinitrobenzene and toluene, which will undergo nitration more easily and why?
20. Write all the possible isomers Of the AROMATIC COMPOUND C8H10.
21. (i). Which of the following species acts a nucleophile.
NH3 , BF3 , NO2+ and C2H5O-
(ii). Identify the nucleophilic centre in CH3Br.
22. (i). Draw the structure of pent-4-ene-2-ol.
(ii). Name the electrophile/nucleophile generated by the following species:-
(i). HNO3 + H2SO4 (ii). CH3COCl (iii). Alcoholic KCN
23. Classify the reaction type as elimination, rearrangement, addition and substitution.
Heat/ Con.H2SO4
(i). C6H5-CH2-CH2-OH C6H5-CHCH2

(ii). CH3-CHBr-CH(CH3)2 CH3-CH2-COH(CH3)-CH3

Alcoholic KOH

25. Which is more stable and why:-

(i). C6H5-CH2+ or C6H11CH2+ (ii). (C6H5)CH* or C6H5-CH2*
26. Why is the staggered conformation of ethane more stable than eclipsed conformation?

27. (i). Draw the structure of 3-isopropyl-2-methylhexane.

(ii). Write the structure of a compound that contains both primary and secondary alcohol.
28. Name the reagent used to reduce alkynes to trans-alkenes.

…………………… Practise well …………………………………………………………………………….

[OIS- AL THUMAMA /XI CHEMISTRY/ Revision worksheet for HY Exam] Page 2