Pengolahan Kalibrasi

Percobaan 2

Kalibrasi Bukaan Valve Pompa Umpan

Skala (%) Waktu (detik) Volume (mL)

20% 60 detik 55 mL
40% 60 detik 150 mL
60% 60 detik 260 mL
80% 60 detik 300 mL

Kalibrasi Rotameter Aliran Solvent

Skala (cm3/menit) Waktu(s) Volume (mL)

200 51,65 200
300 44,75 200
400 27,90 200
500 22,00 200
600 19,15 200

Komposisi Umpan

TCE = 2 Liter

Asam Propionat= 20 mL

Laju alur air = 0,2 liter/min

Laju alir organic = 0,2 liter/menit

Waktu (menit) Titer NaOH (mL)

Rafnat Ekstrak
1 6.6
3 7.6 9.9
5 7.9 11.5
7 8.2 13
9 8.6 14.5
 Penentuan Koefisien Distribusi Massa
Ekstrak Rafinat
Saat 1 menit
V1 x M1 = V2 x M2
6.6 x 0.1 = 5 x M2
0.66 = 5 M2
M2 = 0.132
Saat 3 menit
V1 x M1 = V2 x M2 V1 x M1 = V2 x M2
9.9 x 0.1 = 5 x M2 7.6 x 0.1 = 5 x M2
0.99 = 5 M2 0.76 = 5 M2
M2 = 0.198 M2 = 0.152
Saat 5 menit
V1 x M1 = V2 x M2 V1 x M1 = V2 x M2
11.5 x 0.1 = 5 x M2 7.9 x 0.1 = 5 x M2
1.15 = 5 M2 0.79 = 5 M2
M2 = 0.23 M2 = 0.158
Saat 7 menit
V1 x M1 = V2 x M2 V1 x M1 = V2 x M2
13 x 0.1 = 5 x M2 8.2 x 0.1 = 5 x M2
1.3 = 5 M2 0,82 = 5 M2
M2 = 0.26 M2 = 0.164
Saat 9 menit
V1 x M1 = V2 x M2 V1 x M1 = V2 x M2
14.5 x 0.1 = 5 x M2 8.6 x 0.1 = 5 x M2
1.45 = 5 M2 0.86 = 5 M2
M2 = 0.29 M2 = 0.172

Menentukan koefisien Perpindahan Massa

Pada waktu (menit) Konsentrasi (mol/L)

Ekstrak Rafinat
1 0.132
3 0.198 0.152
5 0.23 0.158
7 0.26 0.164
9 0.29 0.172
Neraca Massa

Rumus: Vo ( X1 -X2 ) = Vw (Y1 – 0)

Vw = Vo = 0.2 liter/menit = 12 L/s

Ekstrak Rafinat
Vw (Y1 – 0) = 0,2 L/m (0,132 – 0) mol/L Vp 1000
X1 = x
= 0.0264 mol/m x 74,08 gram/mol Mr V
= 1.955 gram/m 5 mL x 0,99 gram/mL 1000
X1 = x
74.08 gr /mol 5 mL
X1 = 13.364
Vw (Y1 – 0) = 0,2 L/m (0,198 – 0) mol/L Vo (X1 – X2) = 0.2 L/m (13.364 – 0.152) mol/L
= 0.0396 mol/m x 74,08 gram/mol = 2.64 mol/m x 74,08 gram/mol
= 2.933 gram/m = 195.75 gram/m
Vw (Y1 – 0) = 0,2 L/m (0,23 – 0) mol/L Vo (X1 – X2) = 0.2 L/m (13.364 – 0.158) mol/L
= 0.046 mol/m x 74,08 gram/mol = 2.69 mol/m x 74,08 gram/mol
= 3.407 gram/m = 199.66 gram/m
Vw (Y1 – 0) = 0,2 L/m (0,26 – 0) mol/L Vo (X1 – X2) = 0.2 L/m (13.364 – 0.164) mol/L
= 0.052 mol/m x 74,08 gram/mol = 2.64 mol/m x 74,08 gram/mol
= 3.852 gram/m = 195.571 gram/m
Vw (Y1 – 0) = 0,2 L/m (0,29 – 0) mol/L Vo (X1 – X2) = 0.2 L/m (13.364 – 0.172) mol/L
= 0.059 mol/m x 74,08 gram/mol = 2.638 mol/m x 74,08 gram/mol
= 4.296 gram/m = 195.452 gram/m

Rata-rata laju Perpindahan massa

Laju perpindahan massa di fasa Laju perpindaan massa di fasa

ekstrak (gram/s) rafinat (gram/s) Rata-rata (gram/s)
Vw (Y1 – 0) Vo (X1 – X2)
1.955
2.933 195.75 99.3415
3.407 199.66 101.5335
3.852 195.571 99.7115
4.296 195.452 99.874

Koefisien Perpindahan massa

(ΔX 1−ΔX 1)
Log rata-rata gaya dorong =
ln ¿ ¿
Waktu
Pengambilan Y1 K X* X1 X2
t3 0.198 0,5788 0.121 13.364 0.152
t5 0.23 0,5788 0.141 13.364 0.158
t7 0.26 0,5788 0.159 13.364 0.164
t9 0.29 0,5788 0.178 13.364 0.172
 Waktu
∆X1 ∆X2 Log Df Df
pengambilan
t3 0 13,243 4,467
t5 0,158 13,223 4,427  
t7 0,164 13,205 4,388  
t6 0,172 13,186 4,339  

Laju perpindahan massa

kYa =
volume packing x ( gaya dorong rata−rata ) logaritmik

Volume packing = π r 2 t

= (3,14)(9,15)2(130)

= 34.175,320 cm 2
= 34.175,320 mL

Pada t3
99.3415 gram/s
Ky A=
34.175,320mL x 4,467
= 6,507 x 10−4
Pada t5
101.5335 gram/ s
Ky A =
34.175,320mL x 4,467
= 6,651 x 10−4
Pada t7
99 ,7115 gram/s
Ky A =
34.175,320mL x 4,467
= 6,532 x 10−4
Pada t9
99.874 gram/s
Ky A =
34.175,320mL x 4,467
= 6,542 x 10−4