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The viscoelastic mechanical behavior of foam rubber-like materials under large deformation is studied using
thermodynamic methods. Because the strain energy function can be additively split into deformation
energy and volume energy, the deformation of materials is decomposed into volumetric deformation
Received 18th February 2015
Accepted 26th March 2015
and isochoric deformation. A nonlinear viscoelastic constitutive model for large deformation of foam
rubber-like materials is established in this paper. The nonlinear viscoelastic mechanical responses of
DOI: 10.1039/c5ra03116h
foam rubber-like materials under several common loading conditions are calculated by the new
www.rsc.org/advances proposed constitutive model.
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t t
v c Eðt sÞ; EðtÞ v c Eðt sÞ; EðtÞ
W_ ¼ _ þ _ sÞ
S¼0 S¼0
EðtÞ Eðt
vEðtÞ vEðt sÞ
t t t (13)
v c Eðt sÞ; EðtÞ c Eðt sÞ þ dEðt sÞ; EðtÞ c Eðt sÞ; EðtÞ
¼
S¼0 _ þ
EðtÞ lim S¼0 S¼0
vEðtÞ dEðt sÞ/0 dt
dt/0
33106 | RSC Adv., 2015, 5, 33105–33113 This journal is © The Royal Society of Chemistry 2015
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" #
t vW_ aðI1 3Þ þ bðI2 3Þ ð t t s
v c Eðt sÞ; EðtÞ where q1 is the relaxation factor of the materials at low strain
Sij uij r
S¼0 _
EðtÞ
vEðtÞ rate, and q2 is the relaxation factor of the materials at high
strain rate. Based on the deformation mechanism analysis of
t dEðt sÞ
rd c Eðt sÞ; EðtÞ $0 (15) the materials under load, it can be deduced that the squeezing
S¼0 dt
properties of foam rubber-like materials mainly depend on the
level of material porosity. The derivative form of the Helmholtz
The kinematic relation is given by the time differential of eqn free energy functional for volumetric deformation is given by
(4) and using eqn (10): the inuence law of the material porosity on the stress–strain
relationship.
_ ¼ uijF$FT
E(t) (16) _
vW h 1=2 i2
¼ d 1 þ 1 nf 1 nf ES ½JðtÞ 1ln½JðtÞ
Inserting eqn (16) into inequality (15) then yields _
vE KL vd
(21)
2 t 3
6 v c Eðt sÞ; EðtÞ 7 where nf is the material porosity, ES is Young's modulus of the
6Sij r S¼0
F $F T 7
4 vEðtÞ 5uij rubber matrix material, d is a constant that reects the pore
structure of foam rubber-like materials, and J(t) is the deter-
minant of the deformation gradient tensor F. The nonlinear
t dEðt sÞ
rd c Eðt sÞ; EðtÞ $0 (17) viscoelastic constitutive model independent of the coordinate
S¼0 dt
system of foam rubber-like materials under large deformation
can be obtained by inserting eqn (20) and (21) into eqn (19)
In order to satisfy inequality (17), the coefficient of uij is _ _
vW vW
equal to zero for a given material deformation history, and sij ¼ pdij þ rF ðtÞ þ F T ðtÞ (22)
vE_KL id vE_KL vd
using eqn (11) and (14), leads to
vW_ T
Sij ¼ rF ðtÞ F ðtÞ (18)
vE_
3. Numerical example
The hydrostatic pressure p is added to eqn (18). The To illustrate the application of the new model developed in the
nonlinear viscoelastic constitutive equation for large deforma- preceding section, a parametric study of sample cases is con-
tion of foam rubber-like materials is nally obtained as ducted here for three-dimensional rubber foams, whose
modeling motivated the present study. Under triaxial loading
vW_ T conditions, the elongation ratio of rubber foams in the loading
sij ¼ pdij þ rFðtÞ F ðtÞ (19) direction can be denoted as l1, l2, l3. The material is assumed
vE_
to be homogeneous and isotropic. The deformation of sample
cases under triaxial loading can be dened as the following
Because the strain energy function can be additively split form
into deformation energy and volume energy,22,23 the defor- 8
mation of materials is decomposed into volumetric deforma- < x1 ¼ l1 X1
x ¼ l2 X2 (23)
tion and isochoric deformation in this paper. Volumetric : 2
x3 ¼ l3 X3
deformation mainly depends on the microstructure
morphology of the foam; isochoric deformation is mainly
determined by the mechanical properties of the rubber.23,24 The deformation gradient F(t) is given by the differential of
The derivative form of the Helmholtz free energy functional eqn (23) and using eqn (2):
for the isochoric deformation part is given by the assumption 2 3
l1 0 0
of incompressibility of solid rubber-like materials.5,22 In this F ðtÞ ¼ 4 0 l2 05 (24)
case, I3 ¼ 1. 0 0 l3
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Green strain tensor E is given by inserting eqn (24) into The viscoelastic mechanical responses of foam rubber-like
eqn (4): materials in several common loading conditions can be calcu-
2 2 3 lated by the above stress expressions.
1 4 l1 1 0 0
EðX ; sÞ ¼ 0 l2 2 1 0 5 (25)
2
0 0 l3 2 1
3.1. Viscoelastic mechanical responses with uniaxial loading
By substituting eqn (24) and (25) into eqn (19), the principal By substituting eqn (22) into eqn (27), the stress of foam rubber-
stress components of sample cases under triaxial loading is like materials under uniaxial compression deformation can be
nally obtained as expressed as
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vW_ vW_ s11 ðtÞ ¼ l2 r
aðI1 3Þ þ bðI2 3Þ
K1 ðtÞ
s11 ðtÞ ¼ p þ l1 2 r s22 ðtÞ ¼ p þ l2 2 r þcðI1 3ÞðI2 3Þ
_
vE 11 vE_22
(26)
vW_ l r2k aðI1 3Þ þ bðI2 3Þ
K2 ðtÞ
s33 ðtÞ ¼ p þ l3 r
2
þcðI1 3ÞðI2 3Þ
vE_33
h 1=2 i2
þ d l2 l2k r 1 þ 1 nf
The stress expressions in several common experiments can
be derived from eqn (26). 1 nf ES l2kþ1 1 ln l2kþ1 (31)
Based on the compressibility of rubber foams, the principal
where
stretches of the material under uniaxial compression and ðt t s
dl
tension can be expressed as l1 ¼ l, l2 ¼ l3 ¼ lk, where k is a K1 ðtÞ ¼ 2l exp ds
material constant. Considering the boundary conditions of 0 q ds
sample cases, the stress expressions under uniaxial compres- ðt t s
dl2k
sion and tension is given by eqn (27): K2 ðtÞ ¼ exp ds
0 q ds
vW_ vW_ and where a, b, c are material constants related to strain rate,
s11 ðtÞ ¼ l2 r l2k r (27)
vE_11 vE_22 and d is a constant that reects the pore structure of the
materials. Le Cauchy-Green tensor B is given by
2 2 3
The principal stretches of the material under pure shear l 0 0
deformation can be expressed as l1 ¼ lk, l2 ¼ 1, B ¼ F $F T ¼ 4 0 l2k 0 5 (32)
l3 ¼ lk. Considering the boundary conditions of sample 0 0 l2k
cases, the stress expressions under pure shear is given by
eqn (28):
The three principal invariants of B is given by
vW_ 1 vW_
s11 ðtÞ ¼ l r 2k
2k r I1 ¼ trðBÞ
¼ l2 þ 2l2k
vE_11 l vE_33 I2 ¼ 1=2 I1 trðB2 Þ ¼ 2l2kþ2 þ l4k
2
(33)
(28)
vW_ 1 vW_ I3 ¼ detðBÞ ¼ l4kþ2
s22 ðtÞ ¼ r 2k r
_
vE 22 l vE_33
Inserting eqn (33) into eqn (31) then yields
The principal stretches of the material under simple shear 2
a l þ 2l2k 3 þ b 2l2kþ2 þ l4k 3
deformation can be expressed as l1 ¼ lk, l2 ¼ lk, l3 ¼ 1. s11 ðtÞ ¼ l2 r 2 K1 ðtÞ
þc l þ 2l2k 3 2l2kþ2 þ l4k 3
Considering the boundary conditions of sample cases, the
stress expressions under simple shear is given by eqn (29): 2
a l þ 2l2k 3 þ b 2l2kþ2 þ l4k 3
l2k r 2 K2 ðtÞ
vW_ 1 vW_ vW_ þ c l þ 2l2k 3 2l2kþ2 þ l4k 3
s12 ðtÞ ¼ l2k r þ 2k r 2r (29)
_
vE 11 l _
vE 22 vE_33
h 1=2 i2
þ d l2 l2k r 1 þ 1 nf
The principal stretches of the material under equi-biaxial
tension deformation can be expressed as l1 ¼ l, l2 ¼ l, l3 ¼ 1 nf ES l2kþ1 1 ln l2kþ1 (34)
lk. Considering the boundary conditions of sample cases, the
stress expressions under equi-biaxial tension is given by eqn
The nonlinear viscoelastic mechanical behavior of the
(30):
materials under uniaxial loading is described by eqn (34). From
vW_ 1 vW_ eqn (34), using integration by parts leads to
s11 ðtÞ ¼ s22 ðtÞ ¼ l2 r 2 2k r (30)
_
vE 11 ll vE_33
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8 9
>
> l2 l4k2 ½1 expðt=qÞ >
>
> >
2 2 3>>
>
>
>
>
a l þ 2l 3
2k
>
> 1 t ð >
>
>
< >
=
6
2 6
7 l2
expð ðt sÞ=qÞds
s11 ðtÞ ¼ l r4 þ b 2l 2kþ2
þl 3
4k 7
5> q 0 >
>> >
>
þ c l2 þ 2l2k 3 2l2kþ2 þ l4k 3 > >
>
> 2k2 ðt >
>
>
>
>
> l >
:þ l expð ðt sÞ=qÞds >
2k
;
q 0
h 1=2 i2
þ d l2 l2k r 1 þ 1 nf 1 nf ES l2kþ1 1 ln l2kþ1
Published on 26 March 2015. Downloaded by University of Pittsburgh on 09/08/2015 16:22:24.
(35)
where l ¼ 1 + 311. Introducing the unit step function H(t) to The comparison of the theoretical prediction curve and the
represent constant strain as follows, experimental curve is shown in Fig. 4, and the error analysis is
shown in Fig. 5.
1 t.0
HðtÞ ¼ (36) As shown in Fig. 4, the theoretical prediction curve by the
0 t\0
compressible viscoelastic model is in good agreement with the
available experimental data under uniaxial compression. In
The constant strain is given by addition, it can be seen from the error analysis chart that the
residual stress error is approximately in the range of 0.02 MPa
311 ¼ 30H(t) (37) < D < 0.02 MPa and is approximately negligible compared with
the corresponding engineering stress amplitude.
Inserting eqn (36) and (37) into eqn (35) then yields
8 " # " #9
>
> ð1 þ 30 HðtÞÞ2 2ð1 þ 30 HðtÞÞ2kþ2 >
>
>
> a þb >
>
>
< þ 2ð1 þ 30 HðtÞÞ2k 3 4k >
=
2
þ ð1 þ 30 HðtÞÞ 3
s11 ðtÞ ¼ ½1 þ 30 HðtÞ r " #" #
>
> ð1 þ 30 HðtÞÞ2 2ð1 þ 30 HðtÞÞ2kþ2 >
>
>
> >
>
>
: þ c >
;
2k 4k
þ 2ð1 þ 30 HðtÞÞ 3 þ ð1 þ 30 HðtÞÞ 3
n
o
2 4k2
ð1 þ 30 HðtÞÞ ð1 þ 30 HðtÞÞ ½1 expðt=qÞ
n o h 1=2 i2
þ d ½1 þ 30 HðtÞ2 ½1 þ 30 HðtÞ2k r 1 þ 1 nf
n o
1 nf ES ½1 þ 30 HðtÞ2kþ1 1 lnð1 þ 30 HðtÞÞ2kþ1 (38)
The stress relaxation test of sample cases at low strain rate 3.2. Viscoelastic mechanical responses with two-
was carried out restricted to special purpose applications. The dimensional loading
specimens are porous silicon rubber thin sections; the size of
By substituting eqn (22) into eqn (30), the stress of foam rubber-
specimens is 60 mm 12 mm 0.65 mm. The experiments like materials under equi-biaxial tensile deformation can be
were conducted on a stress relaxation testing machine. The expressed as
density of the specimens is r ¼ 0.45 103 kg m3; the porosity ðt ðt
t s
dl2 t s
dl2k
is nf ¼ 60%; the SEM micrograph of the materials is shown in sðtÞ ¼ rLðtÞ l2 exp dsl2k2 exp ds
Fig. 1. The experimental data for eqn (38) is tted; the param- 0 q ds 0 q ds
eter values are given in Table 1, and the tting results are shown h i
1=2 2
þ dr 1þ 1nf 1nf ES l2 l2k2 lkþ2 1 ln lkþ2
in Fig. 2 and 3.
The tting curves from Fig. 2 to Fig. 3 show that the quality of (39)
the t is essentially comparable between the two cases. In order
where
to examine the validity of the constitutive model, the mechan-
ical properties of three porous silicon rubber thin sections with LðtÞ ¼ aðI
1 3Þ þ bðI2 3Þþ cðI1 3ÞðI2 3Þ
different densities (0.56 g cm3, 0.78 g cm3 and 0.90 g cm3) ¼ a 2l2 þ l2k 3 þ b 2l2kþ2 þ l4 3
under uniaxial compression are theoretically forecasted by þ c 2l2 þ l2k 3 2l2kþ2 þ l4 3
substitution of the parameter values in Table 1 into eqn (35).
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where l ¼ 1 + 3.
In the same way, by substituting eqn (22) into eqn (28), the
stress of foam rubber-like materials under pure shear defor-
mation can be expressed as
8 ð 9
> 4k 4k l2k t 2k >
>
> l l ½1expðt=qÞ l >
>
expððtsÞ=qÞds
>
< q 0 >
=
sðtÞ¼rMðtÞ Fig. 2 Comparison between stress relaxation fitting curve and
>
> 2k ð t >
> experimental results (t ¼ 100 s).
>
>þ l >
>
: l2k expð ðt sÞ=qÞds ;
q 0
h 1=2 i2
þ dr 1 þ 1 nf 1 nf ES l2k l2k lk 1 ln lk
a b c d k q1
95.722 7.443 0.0079 3.275 0.658 6.887 Fig. 4 Comparison between theoretical prediction curve and exper-
imental results of materials of various densities.
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The experimental data are tted by eqn (40) and (41), and the
material parameters are obtained as shown in Tables 2 and 3.
All the experimental data used here are derived from Treloar's
classic experiments and the experiments of James et al.25–27
These experimental data have been widely used to validate the
quantitative model of rubber-like materials under different
loading conditions.28–33 The experimental data from James
Published on 26 March 2015. Downloaded by University of Pittsburgh on 09/08/2015 16:22:24.
a b c d k q1
a b c d k q1
Fig. 8 Comparison between theoretical prediction curve and exper-
imental results (equi-biaxial extension).
41.627 6.554 1.558 3.457 0.770 7.106
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Acknowledgements
4. Conclusions The authors would like to thank J. S. Lei and J. L. Tao for fruitful
Based on the viscoelastic constitutive theory and mathematical discussions on developing the constitutive model framework
derivation methods, the nonlinear viscoelastic constitutive employed in this paper. The work was funded by the grant from
model for large deformation of foam rubber-like materials is the National Natural Science Foundation of China.
nally established as:
_ _ References
vW vW
sij ¼ pdij þ rFðtÞ þ F T ðtÞ
vE_KL id vE_KL vd 1 M. Hosseini, A. Aidy and B. B. Sahari, Am. J. Appl. Sci., 2010,
3, 232.
The nonlinear viscoelastic mechanical responses of foam 2 K. Cornish, Nat. Prod. Rep., 2001, 18, 182.
rubber-like materials under several common loading condi- 3 G. J. Moody and J. D. R. Thomas, Analyst, 1979, 104, 15.
tions are calculated by the above constitutive model. The 4 R. C. Picu, So Matter, 2011, 7, 6768.
theoretical values predicted by the current model are in good 5 H. Guo, W. J. Hu and J. L. Tao, Chin. J. Comput. Mech., 2013,
agreement with results based on the available experimental 30, 575.
data. 6 L. Wahba, M. D'Arienzo, R. Donetti, T. Hanel, R. Scotti,
L. Tadiello and F. Morazzoni, RSC Adv., 2013, 3, 5832.
7 S. Rooj, A. Das, K. Werner Stöckelhuber, De-Y. Wang,
5. Appendices V. Galiatsatos and G. Heinrich, So Matter, 2013, 9, 3798.
8 R. W. Ogden, Proc. R. Soc. London, 1972, 326, 565.
9 A. N. Gent, Rubber Chem. Technol., 1996, 69, 59.
x The coordinate of a typical particle in the current
10 O. H. Yeoh, Rubber Chem. Technol., 1997, 70, 175.
conguration
11 J. C. Simo, Comput. Meth. Appl. Mech. Eng., 1987, 60, 153.
X The coordinate of a typical particle in the reference
conguration 12 S. Govindjee and J. C. Simo, Int. J. Solids Struct., 1992, 29,
s Time variable 1737.
t Current time 13 A. Lion, J. Mech. Phys. Solids, 1997, 45, 1805.
F Deformation gradient 14 K. Hausler and M. B. Sayir, J. Mech. Solids, 1995, 43, 295.
B Le Cauchy-Green tensor 15 R. M. Christensen, J. Appl. Mech., 1980, 47, 762.
C Right Cauchy-Green tensor 16 K. N. Morman and T. Y. Pan, Rheol. Acta, 1988, 27, 13.
E Green strain tensor 17 L. J. Gibson and M. F. Ashby, Cellular Solids Structure and
I 1 I2 I3 Three principal invariants of B Properties, Cambridge University Press, 1999.
l1 l2 Three principal stretches of B 18 F. Irgens, Continuum Mechanics, Springer Press, 2008.
l3 19 E. H. Dill, Continuum Mechanics: Elasticity, Plasticity,
J(t) The determinant of the deformation gradient tensor F Viscoelasticity, CRC Press, Germany, 2006, ISBN 0849397790.
r Mass density 20 M. E. Gurtin, An Introduction to Continuum Mechanics,
r Heating function per unit mass Academic Press, 1981.
W Helmholtz potential per unit mass 21 R. M. Christensen, Theory of Viscoelasticity: An Introduction,
T Absolute temperature Academic Press, 1971.
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22 Y. Q. Yang, W. B. Luo, Y. T. Wei, P. Xu and Q. G. Gang, Theory 27 L. R. G. Treloar, Trans. Faraday Soc., 1944, 40, 59.
and Application of Viscoelastic, Science Press, 2004. 28 M. C. Boyce and E. M. Arruda, Rubber Chem. Technol., 2000,
23 Z. F. Liu, L. F. Li, W. J. Hu and R. F. Jiang, J. Chongqing Univ., 73, 504.
2001, 4, 12. 29 P. D. Wu and E. Giessen, J. Mech. Phys. Solids, 1993, 41, 427.
24 Z. F. Liu, L. F. Li and W. J. Hu, Acta Mech. Solida Sin., 2002, 3, 30 E. M. Arruda and M. C. Boyce, J. Mech. Phys. Solids, 1993, 41,
347. 389.
25 A. G. James, A. Green and G. M. Simpson, J. Appl. Polym. Sci., 31 T. Beda and Y. Chevalier, J. Appl. Phys., 2003, 94, 2701.
1975, 19, 2033. 32 A. Z. Elias and M. F. Beatty, Int. J. Eng. Sci., 2002, 40, 2265.
26 L. R. G. Treloar, The Physics of Rubber Elasticity, Clarendon 33 W. Kuhn and F. Grun, Kolloid-Z., 1942, 101, 248.
Press, Oxford, 1975.
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