Tugas Kinetika

1. Laju suatu reaksi 40°C adalah 3x laju reaksinya pada 20°C. Tentukan Energi pengaktivan reaksi ini.
2. Suatu reaksi memiliki energi pegaktifan 40 kkal. Tentukan Perbandingan laju reaksi pada 0°C dan 10°C.
3. The decomposition of nitrogen pentoxide dissolved in carbon tetrachloride at 45°C takes place according
to the equation:
2 N2O5 = 4 NO2 + O2

Time / s [N2O5] / mol dm-3

0 2.33
319 1.91
867 1.36
1198 1.11
1877 0.72
2315 0.55

Show the reaction is first order and determine the first order rate constant
4. Equal concentration of triethylamine and methyl iodide were reacted in nitrobenzena solution to form the quartenary ammonium salt. If
the concentration of of methyl iodide varies with time as follows, show that the reaction is first order with respect to both reactants and
calculate the half life under this condition

[CH3I]/mol dm-3 0.01 0.0069 0.0044 0.0035 0.0031 0.0026

Time/s 0 650 2100 2600 3100 4000

5. Observation from the alkaline hydrolysis of ethyl 2-methylpropenoate in 84.7% ethanol at 40ºC: initial concentration both ester and
alkali was 0.0508 M. 10 cm3 of the reaction mixture were remove from the reaction vessel at the time stated, pipetted into 10 cm3 of
0.0668 M hydrochloric acid and the excess acid titrated with 0.0511 M sodium hydroxide:

Time/s 600 1500 2400 3600 4800 6600

NaOH titre/cm3 4.03 5.11 5.98 6.86 7.57 8.36

Calculate the mean value of the second order rate constant