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Herbicide diuron removal from aqueous solution by bottom ash: Kinetics,

isotherm, and thermodynamic adsorption studies


T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Kl*MW*1000*55.5)
293 232.02 0.65 0.003413 11.9237959377369 15.9448229296838
303 339.94 7.89 0.0033 14.8021205452891 18.441201980634
313 349.52 90.63 0.003195 17.271101347692 20.8823911298429
25

20 f(x) = − 22635.5378138965 x + 93.1818562515966


R² = 0.999841276407923
f(x) = − 24531.5442062735 x + 95.6867191243677
15 R² = 0.999369315245195

10

0
0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.00345

Adsorption of bentazon on activated carbon prepared from Lawsonia inermis wood: Equilibrium, kinetic and thermodynam

T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Qe/Ce)


293 169.491 0.183 0.003413 10.3422859809071 6.83086467088287
303 104.166 0.51 0.0033 10.8803965062062 5.31887444217118
313 89.956 0.672 0.003195 11.0095790024194 4.89570307906676

31016.85 12

53124.66 f(x) = − 3079.34913034293 x + 20.9143433453771


60450.43 10 R² = 0.900442387806885

925.99 8
204.15
133.71 6 f(x) = 8925.2716611947 x − 23.7959409575111
R² = 0.915447741129791

0
0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0

Adsorption and Release Kinetics, Equilibrium, and Thermodynamic Studies of Hymexazol onto Diatomite

T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Cterserap/Ce)


298 18.25 0.0004 0.003356 1.98787434815435 6.7162528475459
308 18.18 0.0006 0.003247 2.38949646498334 5.23252907785022
318 20.07 0.0008 0.003145 2.77608261149404 4.81872661555942
7.3 825.7176 3
10.908 187.2658
f(x) = − 3734.14732068502 x + 14.5168685687639
16.056 123.8073 2.5 R² = 0.999940251770494

1.5

0.5

0
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335

Adsorption behavior of herbicide paraquat from aqueous solutions using starfish particles: kinetic, isotherm, and thermod

T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Kl)


288 10.235 0.163 0.003472 7.41956341992002 5.08137211664395
298 10.194 0.137 0.003356 7.24178023774598 4.9249830075574
308 10.152 0.116 0.003247 7.07126092151845 4.77835851903689
318 10.06 0.102 0.003145 6.93353997795586 4.64057746046299
328 9.93 0.093 0.003049 6.82815997121034 4.51193109477402
8

7 f(x) = 1412.7296516224 x + 2.50237129103544


R² = 0.995808219534401
6

5
f(x) = 1345.33142420021 x + 0.410243244493709
R² = 0.999999169788575
4

0
0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.

Assessment of the use of Moringa oleifera seed husks for removal of pesticide diuron from contaminated water

T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Kl)


298 5.198 0.828 0.003356 8.36728709060456 0.18873316295147
308 7.632 0.614 0.003247 8.45234486229313 0.487754968149483
318 15.989 0.451 0.003145 8.88336832530596 0.796300246761165

10

9
f(x) = − 2426.7025599117 x + 16.4521139999739
8 R² = 0.856842232595745
7

5
10

9
f(x) = − 2426.7025599117 x + 16.4521139999739
8 R² = 0.856842232595745
7

1
f(x) = − 2877.27498269058 x + 9.83930332776383
0 R² = 0.999227774229728
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335

Removal of secbumeton herbicide from water on composite nanoadsorbent

T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Kl)


293 11.24 4.94 0.003413 10.9245994546475 2.4178962086238
303 10.42 6.4 0.0033 11.107780305673 2.30634080968838
313 9.62 8.67 0.003195 11.3314683344522 2.19422798912647
12

f(x) = − 1862.9571318316 x + 17.2741255508227


10 R² = 0.994163881416327

2 f(x) = 1025.2190889918 x − 1.07986598331454


R² = 0.999580176903864

0
0.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.00345

Carbon nanotube-based magnetic and non-magnetic adsorbents for the high efficiency removal of diquat dibromide herbi

T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Cterserap/Ce)


298 20.9 0.378 0.003356 8.97464335459035 0.944473056686142
308 23 0.79 0.003247 9.80752716139022 2.31185701476777
318 25.5 1.13 0.003145 10.2686513638708 12.9356711343903

14

12
f(x) = − 56322.241684138 x + 188.390400279673
10 R²
f(x)==0.82011746447741
− 6148.17194637876 x + 29.6592475460208
R² = 0.978941610093779
8

0
R² = 0.978941610093779
8

0
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034
Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-29.04639 203.959 0.795542 -38.84162 188.1957 0.77471515
-37.28864 -46.45601
-44.94428 -54.34187

335 0.0034 0.00345

rium, kinetic and thermodynamic studies


Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-25.19 25.60 173.88 -16.64 -77.23 -207.00
-27.41 -13.40
-28.65 -12.74

9143433453771

9409575111

0.00335 0.0034 0.00345

to Diatomite
Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-4.925102 31.04448 0.120694 -16.64 14.44 253
-6.118812 -13.399
-7.339552 -12.74
x + 14.5168685687639

325 0.0033 0.00335 0.0034

kinetic, isotherm, and thermodynamic studies


Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-17.76564 -11.74519 0.020805 -12.167 -11.184 0.003413
-17.94203 -12.202
-18.10746 -12.236
-18.33125 -12.269
-18.62034 -12.304

237129103544

10243244493709

.00325 0.0033 0.00335 0.0034 0.00345 0.0035

contaminated water (kemungkinan salah ada)


Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-20.73056 20.17558 0.136782 -0.4676 23.9208 -8.18E-05
-21.64402 -1.249
-23.48631 -2.1053

16.4521139999739
16.4521139999739

9.83930332776383
325 0.0033 0.00335 0.0034

Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-26.61235 15.48898 0.143616 -5.89 -11.08 -0.0178
-27.98208 -5.81
-29.48768 -5.71

227

335 0.0034 0.00345

oval of diquat dibromide herbicide from water: OMWCNT, OMWCNTFe3O4 and OMWCNT-κ-carrageenan-Fe3O4 nanocomposites
Proposed Original
Gibbs Entalphy Entropy Gibbs Entalphy Entropy
-22.23533 51.11613 0.246585 -2.34 51.2 0.1799
-25.11425 -5.92
-27.14879 -34.2
O4 nanocomposites
Conversion of a renewable bio-resource to a functional composite material: Product design, comprehensive characterization a
Proposed
T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Qe/Ce) Gibbs Entalphy
298 263.16 3.71E-03 0.003356 6.88379408883714 0.16144838575832 -17.0551 55.41198
308 370.37 2.93E-03 0.003247 6.98950492900033 0.32022343785635 -17.89811
318 400 0.0101 0.003145 8.3039999709552 0.97963123503131 -21.95455

8
f(x) = − 6664.89208743566 x + 29.0469162
R² = 0.790444091185529
7

1
f(x) = − 3849.6892147122 x + 12.99488504
0 R² = 0.877002589214584
0.0031 0.00315 0.0032 0.00325 0.

High-performance removal of 2,4-dichlorophenoxyacetic acid herbicide in water using activated carbon derived from Queen p
(Syagrus romanzoffiana)
Proposed

Ln KD Ori
(Kl*BM*Activity
coefisien/unitary
T Qmax KL 1/T Ln KD (Qmax*Kl*1000) activity coef) Gibbs Entalphy
298 355.08 5.28E-02 0.003356 9.83885430691234 9.36804258362623 -24.37647 68.26792
308 358 1.07E-01 0.003247 10.5524268044317 10.075322800846 -27.02173
318 365.54 0.1864 0.003145 11.1292706145778 10.6284315460926 -29.42414
328 367.77 0.7021 0.003049 12.4615335867982 11.9545638564396 -33.9825
14

12
f(x) = − 8211.20428638378 x + 37.262943206484
f(x)==0.95373502997385
R² − 8082.06793341298 x + 36.3609083517761
R² = 0.951620705663561
10

0
0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034
2

0
0.003 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034

Application of graphene nanosheet oxide for atrazine adsorption in aqueous solution: synthesis, material characterization, and
Proposed
T Qmax KL 1/T Ln KD (Qmax*Kl*1000) Ln KD Ori (Qe/Ce) Gibbs Entalphy
298 18.233 0.228 0.003356 8.33257876801151 1.11641558751875 -20.64456 28.21439
308 21.114 0.317 0.003247 8.80883810144478 1.71983417112116 -22.5569
318 23.844 0.356 0.003145 9.04646334420971 1.8631905265499 -23.91751

10

9
f(x) = − 3393.57243492925 x + 19.7551369761033
8 R² = 0.970737907479612

2
f(x) = − 3560.70948580025 x + 13.1353581865011
1 R² = 0.89925634266152

0
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034
ehensive characterization and adsorption of 2,4-D herbicide
Proposed Original
Entropy Gibbs Entalphy Entropy
0.241497 -0.4 30.99 0.10476
-0.82
-2.59

64.89208743566 x + 29.0469162838282
444091185529

49.6892147122 x + 12.9948850419566
002589214584
0.0032 0.00325 0.0033 0.00335 0.0034

bon derived from Queen palm fruit endocarp

Proposed Original

Entropy Gibbs Entalphy Entropy


0.309805 -23.21 67.3 0.3025
-25.8
-28.1
-32.6

0.00335 0.0034
0.00335 0.0034

terial characterization, and comprehension of the adsorption mechanism


Proposed Original
Entropy Gibbs Entalphy Entropy
0.164243 -2.766 29.48 0.108415
-4.404
-4.926

0.00335 0.0034

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