Distinction between 10 2 30 Alcohol

1 Lucas Reagent
By
Conc HCl t Anny Znclz

ROH t 2nd R
I 2nd Raitt Enck H2O

PPT Turbidity
observation
Alcohol which can make Stable carbocation show
immediate PPT
Hence
30 Alcohol T Lucas Reagent Immediate PPT

20 Alcohol Lucas Reagent PPT after 5min

10 Alcohol Lucas Reagent pet after long time

PhazOH 0241 alcohol

CHECH ch oh Ally alcohol
produces immediate PPT

due to stable carbocation

 2 Victor mayer Test
RBC
RCHOH I RzCHOH 20 RzCOH 39
P Iz P Iz P Iz

RCHzI RICH I RzC I

AfMoz I Agnos ATHOL
RCHzMOZ RzCHHOz RzCMO
Learn HO M O HO M 0 I HMOz
R C Moz RLC Moz Morin
MOH IMO

mitotic acid Pseudo mitol

Moon Moon NAOH

Red color Blue color colorless

Soluble Insoluble

Test for Alcohol

CAN Test Certo Ammonium Nitrate Test

TCMHICE 0336

2 ROH MHIC 036 IC CMO ROH2 MHaMOg

Brick Red color
Mote
Phenol show brown black color in CAN Test


Glycol

Glycol is vie di ol CHIH Ethylene glycol I

CHIH

Preparation

17 from Alkene

i cold alkKMn04tBayerlsR
By
agent C

Hz CHz Bayer's reagent

CHz CHz

OH OH

It is syn hydroxylation

can also done 05041NAH503

by

1720

It is test for unsaturation

It follow Csm HSR

it By per acid OOOH

OH

D c

CHz CHz y CH CHz

ii thot DH

It is anti additton 4 follow CARITAM

iii

By Age

CHz CHz AT20 11304 CHz CHz

CHz CHz
o OH OH


27 from Gly oaal

CHO
HAI Hq CHIH

CHO CHIH

Properties

17 It is colorless liquid with Toxic nature

27 It is Anti freezing agent

Chemical Properties

It has two primary alcoholic groups

17 Reaction with Na

CHIH ma CHING

CHIH CHINA

2 Reaction with Pels

CHIM Pelt
CHEL

CHIH CHI I 1 POCK HCl

37 Reactors with PI

CHIH fyH2
Hkt

pI Iz

CHIH CHz CHz

vicinal di iodides are unstable

47 Reaction with 5042

CHIH SOCK CHI

CHIH CHI I

57 Reaction with HI 04

CHIH HEO t

CHIH z HCHO

67 Reaction with Acetoneldry Hd

Hz CH3 O
HO dryHel

c o C cyclic Ketal
HO CHz 0

Hz

of heat

77 Action

CHZOH soooo CH2

CHIH CHz

Intramolecular dehydration

conc o 0

204 dioxane Intermolecular

dehydration

Glycerol CHIH

HoH

KHIH

Preparation

from Triester

d R

GHz O CHIH

CH O F R NaOH 7 CHOH
R'COOMA

DP

Hz O R CHIH soap

Triester

Properties

17 It is colorless Hygroscopic 4 viscous Liquid

2 Non tonic in nature sweet in taste

37 used in

soap cosmetics to make dynamite

Chemical Properties

It has 2 alcohol group 4

primary
secondary alcohol group

I Reaction with Na

CHIH CHING

NA

CHOH CHO Ma t Hz 9

CHIH CHINA

2 Reaction with HI0

CHIH

HOH HIO4 HC OH 2 HCHO

CHIH

37 Reaction with RI

CHIH CHZI CHz

HOH PIs CHI CH

IZ

CHIH CHI CHZI Allyl iodide

4 Reactson with HI

CHIH CHZI CHz CHz

3 HI 1 HI

CHOY CHI Iz CH CHI

CHIH CHI CHI ctkI

Iz

CHz CH3

5 moles of HI consumed CHI CHI GH

Hz Ctf

Reaction with Pcb11913 5012

CHIH CHI't

10957093 5092

HOH CHC

CHIH CHUI

67 Reaction with

conc HMOs1172504

CHIH CHIN02

CONC HN03

HOH 2 CHONOz

concHIO4

CHIH CHzOMOz Nobel's oil

TMG CTrinitroglycerine

77 Reaction with Reocll COLO

CHIH CHICOR

HOH RCO CHOCOR

I 1

CHIH CHI R

87 Reaction with oxalic acid

9 At 110 C

0
CHzo d

CHIH MOOC CH20 COOH H

t COOH CO2

cmon
I 1
Holy HOH

CHIH CHIH CHIH

Glycerol mono Glycerol mono

oxalate formate

HIT

CHIH

HCOOH

HOH

it At 260 C CHIH

CHIH HOOG CHzOOC CHz

HOH MOOC 2600 CHOO E CH

I l 202 1

CHIH CHIH CHIH

Glycerol dionalate Ally Alcohol


97 Reaction with KHS04

CHIH CHz

HOH KHS04 CH

I I 1

CHIH CHO

Acrolein

Disagreeable Odor

For Information

Dynamite

Glycerol absorbed in wood pulp solid HH4140g

gun cotton

Blastinggelatin

Nitroglycerine

cellulose nitrate

cordite Nitroglycerine gun cotton 1 Vaseline

 Ether
Ether is R O R

Alkonyalkane
sntall

Types of Ether
9 Aliphatic ether

CHzocty symmetrical Ether

130 Et Un Symmetrical Ether
CHips unsymmetrical Ether
CHzochzph Unsymmetrical Ether

in Aromatic ether
Phone Anisole Unsymmetrical Ether
Phort Phenetole Unsymmetrical Ether

Methods
of Preparation
1 From Alkene
is By acid catalyzed add'n of alcohol

Ctb CH Cha
It CHIH Ctb
OR

Rearranged others obtained

Ii Demercuration
By Alleonymercuration
CAN DM
 CH
HAACK ROH
CH CH CATCH CH
MaBHa to GR
o MO carbocation formation
Markovnikov add'D

2 From Alcohol
9 By heating with Also

A203
2C KOH CACHOCHEH
2500C

it dehydration with conc thsoa

By

2 CBCHOH CON 2 4
CBC12042cg
14006

mechanism
ROH
YEH STI R t to
Ro n'path ROMI
pop pop

M OH I 10 alcohol on protonation can show say 2

Path However
20530 alcohol in similar condition go for sat
path by making possible stable carbocation
which
may rearrange
 At 1700C Alkene becomes major product

Iii By diazomethane
ROH CHM MBTI ROCK Mat

Mechanism
ÉEMEN IF CHz NIM
ROCH FROH
This method is use to make methyl ethers only

3 Williamson's method
Romat R'x ROR t Max

It follow saz path

For better yield R'x should be i primary halide
while R of ROMA may be 10 2 30

I 6 which route is better to me 0 Crag

Route I MET Brt Meong

or

Route I MECOMAT NEBO

Sol
 Route I Me C Cha Itis result of elimination
He E2

II rag come

HI If Possible Sire the best possible route to

prepare following others milliamson's synthesis
by
9 CHECKCHEONIC ii phoph
Iii Anisole in IproEt
v 1340ABu ri diving ether

Sol't
 properties of Ether
It is lewis base hence it co ordinate with
acidic species
It is less reactive hence a good solvent

Chemical Properties
1 Reaction with Pas
R OR t Pcl Rel t R'CI t POCY
used to detect metameric ethers

2 Reaction with sock

CBCtzocy kctgcltctgctz.CI 5029