MSDS

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SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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SUBSTANCE : Phenolic resin (powder)
Grade No : RD-9014
USAGE : Used for manufacture of friction materials
TRADE NAMES/SYNONYMS : Phenol polymer with formaldehyde novolacs,
Phenol-formaldehyde polymer
Phenol-formaldehyde resin
CHEMICAL FAMILY : polymers, hydroxyls, aromatic, aliphatic
MANUFACTURER
NAME
SHANDONG LAIWU RUNDA NEW MATERIAL CO.,LTD.
ADRESS
NO.9 WANGFUSHAN ROAD ,LAIWU ,SHANDONG ,CHINA
TELEPHONE / FAX
86-634-5639696 86-634-5639679
CREATION DATE : Sep1,2016

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SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS
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Chemical Name CAS No. Weight Percentage (%)
Phenolic Resin 9003-35-4 90.48~ 92.5
Phenol 108-95-2 0~1
Formaldehyde 50-00-0 0.02 max.
HMTA 100-97-0 7.5 ~ 8.5
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SECTION 3 HAZARDS IDENTIFICATION
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POTENTIAL HEALTH EFFECTS :

INHALATION :
Product dust may be irritating respiratory tract. Because of its low volatility and low concentration in the product,
phenol is not expected to present a significant vapor inhalation hazard at ambient temperature.
Phenol vapor may present a hazard during heat curing if ventilation is poor.
Over-exposure to phenol vapors can cause irritation to the respiratory system, central nervous system effects
(headaches, dizziness, unco-ordination and nausea) and damage to the lungs, kidneys and liver.

SKIN CONTACT :
Product dust may cause irritation (Skin Irritation-Rabbit on a series of phenolic resins similar to this product was
typically 0.0~3.0 on a scale of 8.0 ie. Practically Non-irritating to Slightly Irritating)
The product is unlikely to be harmful by skin contact (Dermal LD50-Rabbit on a series of phenolic resins

similar to this product was greater than 5000 mg/kg ie. Practically Non-Toxic)
Skin sensitisation is possible (due to formaldehyde based resin).

EYE CONTACT :
Product dust may cause irritation (Eye Irritation-Rabbit on a series of phenolic resins similar to this product was
typically 10~40 on a scale of 110.0 ie. Slightly Irritating to Moderate Irritating)
Vapors emitted during heat curing may be irritating to the eyes (See "INHALATION" above)

SWALLOWED :
Considered to be practically non harmful (Oral LD50-Rat on a series of phenolic resins
similar to this product was in the range of greater than 2500 mg/kg to greater than 5000 mg/kg ie.
Practically Non-Toxic to Slightly Toxic)

CHRONIC :
Repeated excessive exposure to phenol may cause central nervous system effects (including
breathing and movement difficulties and paralysis), digestive disturbances and liver and
kidney effects. Prolonged or repeated skin contact with the powder may cause sensitisation
resulting in allergic contact dermatitis in susceptible people (due to formaldehyde based resin)

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SECTION 4 FIRST AID MEASURES
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INHALATION :
When safe to enter area, remove from exposure. Use a bag valve mask or similar device to perform artificial
respiration (rescue breathing) if needed. Keep warm and at rest. Get medical attention immediately.

SKIN CONTACT :
Remove contaminated clothing, jewelry, and shoes immediately. Wash with soap or mild
detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes).
Get medical attention if irritation persists.

EYE CONTACT :
Wash eyes immediately with large amounts of water, occasionally lifting upper and lower lids,
until no evidence of chemical remains. Continue irrigating with normal saline until ready to transport to hospital.
Cover with sterile bandages. Get medical attention immediately.

INGESTION :
Contact local poison control center or physician immediately. Never make an unconscious
person vomit or drink fluids. When vomiting occurs, keep head lower than hips to help prevent aspiration.
If person is unconscious, turn head to side. Get medical attention immediately.
NOTE TO PHYSICIAN :
For inhalation, consider oxygen. For ingestion, consider gastric lavage and activated charcoal slurry.

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SECTION 5 FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT:
Not known
FLAMMABLE LIMITS
LFL: Not applicable
UFL: Not applicable
EXTINGUISHING MEDIA:
Water, foam, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS:
Can decompose in a fire emitting toxic fumes and gases, carbon dioxide, carbon monoxide,
hydrogen cyanide, oxides of nitrogen and other toxic and irritation gases can be produced .
depending on condition of combustion
FIRE FIGHTING EQUIPMENT:
Wear full bunker gear including a positive pressure self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
HEPA vacuum or wet wipe dusts and place in a disposal container. Avoid excess dust generation.
Keep separated from incompatible substances.
Use methods to minimize dust.
7. HANDLING AND STORAGE
Avoid contact with eyes. Avoid breathing dust. Minimize dust generation and accumulation.
Store indoors in dry area to protect material.
SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION
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EXPOSURE LIMITS :
PHENOLIC RESIN : No occupational exposure limits established.
VENTILATION : Provide local exhaust or process enclosure ventilation system.
Provide local exhaust or process enclosure ventilation system. Ensure compliance with
applicable exposure limits.
EYE PROTECTION : Wear splash resistant safety goggles with a face shield.
Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
CLOTHING : Wear appropriate chemical resistant clothing.
GLOVES : Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant gloves.

RESPIRATOR : Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use. Any supplied-airrespirator with a full facepiece that is
operated in a pressure-demand orother positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand
 or other positive-pressure mode.
For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator
with full facepiece and operated in a pressure-demand or other positive-pressure mode in
combination with a separate escape supply.
Any self-contained breathing apparatus with a full facepiece.
Any chemical cartridge respirator with organic vapor cartridge(s) and dust and mist filter(s).
Any chemical cartridge respirator with organic vapor cartridge(s) and dust and mist filter(s).
Any air-purifying respirator with a full facepiece, an organic vapor canister and a dust, mist, and fume filter.
Any powered, air-purifying respirator with a full facepiece and a high-efficiency particulate filter.

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SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL STATE : POWDER
COLOR : White to Yellowish
PHYSICAL FORM : Powder
ODOR : Almond Odor
BOILING POINT : Not Applicable
melting point: 80-90℃
VAPOR PRESSURE : Not Applicable
VAPOR DENSITY : Not Applicable
WATER SOLUBILITY : Insoluble
PH : Not Applicable
VOLATILITY : Not Applicable
ODOR THRESHOLD : Not Available
EVAPORATION RATE : Not Applicable
COEFFICIENT OF WATER/OIL DISTRIBUTION : Not available
SOLVENT SOLUBILITY:
Soluble: alcohols and ketones
10. STABILITY AND REACTIVITY
STABILITY:
Stable
MATERIALS TO AVOID:
Strong oxidizing agents, strong acids and bases,
especially oxalic and hydrofluoric acid, halogens, and acyl halides.
HAZARDOUS DECOMPOSITION PRODUCTS:
Toxic fumes and gases, carbon dioxide, carbon monoxide,
hydrogen cyanide, oxides of nitrogen and other toxic and
irritation gases can be produced depending on condition of combustion.
HAZARDOUS POLYMERIZATION:
Will not occur
SECTION 11 TOXICOLOGICAL INFORMATION
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PHENOLIC RESIN:
LOCAL EFFECTS:
Irritant: inhalation, skin, eye.
TARGET ORGANS: immune system (sensitizer), nervous system

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SECTION 12 ECOLOGICAL INFORMATION
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Not available.

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SECTION 13 DISPOSAL CONSIDERATIONS
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Dispose in accordance with all applicable regulations.

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SECTION 14 TRANSPORT INFORMATION
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No classification assigned.

SECTION 15 ADDITIONAL INFORMATION

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HAZARDOUS SUBSTANCE CLASSIFICATION
Health hazard classification and labelling according to the criteria of NOHSC
Overall health hazard classification : IRRITANT (Xi)
R43 May cause sensitisation by skin contact.
S24 Avoid contact with skin.
S37 Wear suitable gloves.

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SECTION 16 OTHER INFORMATION
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MSDS SUMMARY OF CHANGES : None