DandfBlockalements

yegg
4 S tiVEMNFEGNIM

Is Pt Ao
DA Re Hg
Ta 0s
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Platiniumbprubat
Heavymata

dBlo Transitianelement

dBlock Elements are not

Elements which
have unpaired e
transitionatements
in Giroud
T
state 453 d
or in any of q 34
thestable

O
 H
ay 3d

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t
I
Gs
s E
6

Sc ti v a ma ÉÉ co ni cu a
8
3d I 2 3 5 5 6 7
Ho to

US 2 2 2 BE 2 2 2 2 1 2

Rh Pd Ag Cd
Y U ND Mo

n s
RygRM
a t o n i

5s 2 2 1 1 1 2 1 I 2

p no ng
me w

is E i t's
 iP

tg M P
i
Zeff I ee mph E
egg
dominant
 Se Ti V U Mr Fe co Ni cu m
39
yd Rh Pd Ag Cd
Y a Nb Mo Ta

É_

to

DBlock act
5d

Pig

Density Density 00 22 578 43

If 22.61 81cm
 521am

3143 4I 6.07 7 19 7.4 78 8.7 89 8.9

71

Sc ti v or Mr Fe to Ni ru m

631 656 500623717762758736745 906 IED

a mm a m see
Mn Fe F

us
3d us
3ft Batts
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from
AA
DEMI has 540 lowest 7

Hgs 1007 highest I

Enactment MM
É M

3d Shill
Y

Mall d Block elements at é is removed

from no orbital

Hg has highest TEs

Ea has lowest TE in d Block

milkpoints

7
 l
scores

f 3o 7

Tie

u
metal Bonding depends on no ofimpaired é

Mt point Pt and M
sumento have high
Th
the middle and then des Bure up to
Mes up to
Tes which are
of cupaired
é
middle no

responsible for
metallic Banding

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D se ti v is nÉr
is
A way out point of E
less than
FE
Abnormal lattice
Mn has half filled d subonch
which is stableand does not
effectively its é to participate
all
in matalric Bonding
 lzrh.at E

M
Mfolid as Dhatomisation

Mfg MTG TE TIEL

mtYg Miley HE
African

Sc ti v or Mr Fe to Ni a
1.18 O 44 0.28 0.25 to 3y
MHM 1.63 1.18 0.9

o.z mt3ln
fo olif5oI7t93A
37 o.b

a.s.d miiiin
Hulk Hatten

F4 Hatha
q
 A is
I strongest o

at 1.23
mat
Fet
at

May medium that

cut cu 0.034 as will be more
stable which has
cut en 00.51 less RI

May medium at is more stable

cut will be more stable

Mrap Phase
d substrate d
due to fully filled

oxidain
Se Ti V U Mu Fa ro ni en m
O th th th th II th ta Fi ta

3 3 3 3 3 3 3 3 D
 4 y y y y

15 5
15

b tf tf

Os will be more stable for hd and Sd

higher
telling
b
or Oz is good 0 A
Reef

6 to
ate a table
MO 03 W Oz

fteoyJ
t
Fe shows maximum in Ferhat
which Exist in alkaline medium and is
unstable

Feroz Or
 Ru Oy

higher o s are stable with

OaudFI
while lower o S alee stable with 2

Feeds
e
tabes

Mn Mm Ots
ecenoid

with F Maxis y Mnf

Colored Compound of d Block are

generally
coloured
colour may be due to

d d transition vs
Shatin
charge tranter
Polarisation
 D D t a

oI
M t Hw T
Dodependson

and stigma
in strength of vijay

2 o s
of metal

Complementary 4 of absorbed wavelength

decides the colour
 Colour due to charge transfer

Mno I o s
of MN 7

Juturse Pink

In solid state Dark voi lets

7 2

Mate fuk

Y e comes to run from

oxygen

11
o charge transfer from

Af 0 ligand to metal
0 4
o Their is no electronic
3
transition rule valid
Fan Felon
273 for these transitions
KFeffefuls

U Tn

iI
 H

s
4

be Ti V Ch Mm Fo G Ni cu z

in
i

L
i p
i i

Vds is unstable and undergoes hydrolysis

1 form Vox's
 Mn forms MILF and Miro

Lotz is stable due to high lattice E

Fg is stable due to high Bond E

Beyond Mn
only CoardFe forms F exz

Cy Fu is Polymeric aedzio Polymeric

colourless
ME anhydrous form
cu Fr hydrated Blue

am solid cutt is touched with GF

4 are close and Zahearnayp

Halides of yd and 5d May be Polynuclear

 Oxide Afl transition aliments forms oxidI

Se Ti V Ch Mm Fe lo Ni cu m

pp
Ii i
p
p
p

spind sth
MnzoyJiIid
60304

Fezoy Juvets spinal s

Mnrot green oil

high Cov th it has low art.pk
Due to

Mmo 7 Acidic oxides

Gog

Mn 207 tho HMnoy

t new t t tha
 Vrosis amphoteric But more acidic

3
405 They have very high

nos maihem
acid roth
rog

Vo is Basic

Mmo and Miro Soild due to high lattice

Energy

Munoz

Choy resembles 3g
0203 is Polymeric in Native

exactness
Tr guments and their compounds acts as catalyst
In No of Rin's
 condition for Effective catalyst

variable o s

vacant sites must be their

so that it can form a transition state unity
Recatant and towels the activation

F
ZE so 3 so

loss

z t 2 Fat

HI
5 f son

is
Pd Hydrogenation
Nilptf
Ptoy Rxu pt Adam catalyst

Wacker Process
pddu

Rhd PhD Wilkinson's catalyst

cudu Deccan's Process

 Tidy Atty Natta catalysts
Ziegler

culzoo's dehydrogenation

M Kdoz Kd 0L

Pt
1 Oz No
Nfb Rh

contact Process
Yog
Fa hanger process

complexcompound formation

E EeHIEHh
Arterstitral Compounds
_0
Small atoms like C H N et are

trapped in voids of lattice

and forms interstitial confounded
voids are not uniformly filled
so compounds are non
stiochiometeeic
 Pd Hot Tic Fest

These compounds are hard and have high M.pt

than matey

Those compounds fictains their electrical conductance

These are Chemically inert

Alloying
For Alloy formn metal should lie in the haze
of 1st deviation of Radii of othel natal

are homogenous mix

Alley of 20h More they
metals These are Hard and have more

strength
Genchaky trust resistant
Bronze cut Sm

Brass he m
 Potassium Permapmate
Km

wiouiodnetoz.at
Y
qD
qmgy
Team dhomstcmtdhpendwmagmct.io

remind

fsocig.at D
Minor Koh t D
Kz Mnoy
Green

N
grin t2mn

ch
Kaninoy
Kinion
03

slectrohitic
CHKaline
 Mn Ah Bard larythsaea guy
0 11 yo M

D
Kumnoy t ou
Kmnoy t KOH

Mnoutt Mno52 44 Ninoy Mna

Mn out Mnt Eo 4 52W

mn.in mn
ygas o L

5
Yow
153
Mnon Mnoj EEO56 v
Basic

A
Kmnoy Kamnoy Mnon
 Naaidi cdm

Fe Fa

Sn SE

j z

y H L
505 soy

COL
Goy

Fe Croy FEB Cos

UB cuz on Az In
Bei Bsa

Jn Neutral medium

Has s
z
2 6
g Nazswy Naz soy

YE
01 tbh man minor
O
 Basic medium

j 25
Kmnaulai L
UB Cheech uz MB th
cold I ay uz
mon
Lmdn

t
m
1mn05
Baya's
Regent

Mz Eon

Kyung Potassiumdicomate

O O
5M 41 longer 11
u e

g motion
6 Bond lengths are sane

others are
and safe
 coloured due to change transfer

Ph from FeU ck

Fe O U wz t M t NazHoy
ohio
01 mi
Cf 0
fetow canal

Marlroy t though
naaazoz nai.su

Both compounds are

worth soluble
so they are separated
by fractional
crystallisation at
an Appropriate
lamp
marmot 2 tho

ABGYEgiuffofwa.sn

NAzlhr07tKU

LNAH KeUz
Goodo
Agent

Chop ht Cft Eo L 33 V

I z

GOI Coz

Fett FED

Kubu 07 sore Che Sou

Estey

chromylchlorideaest
Kilroy H_ cr
A
Hee

aoztH broach Nag

Rednabours

Aga Plock Hgch Hapur do not give

chromyl chloride test
 Pbthoyffchoof
A 024 5 croy
2

Fts Affront Red

k
5 s

Bt Bse

Kitkat Kd t Ucb Eh tho

n

b l 3 0
Ikuko't 6 HU Rkd 120lb Hk
n Igbo

Kurz 07 t 14114 Heel t 2 cry t 3lb 1 Hey

Woof e tsarroteeceved In theRay

nf Stiochrometric coefficient
 O O
K2 of f thou Clog Blue Colone

stable inatnd
0h Pyridine

Hiei
EI
kaU207 t Hgoog I k3A n

O 0
I
lo
I
 lanthanide
57 4ft 6s
ygq5d
ooeIi
pr Phaasodymim 65483
gg 182101
fo Nd 18199
61 Pm 75 181 goo

SM f 180 96
Gz
fit Igg 95

i if

62 110 hf ht
i
89
68 Fr 47775 88
69 Tm 4713 174 87
To Yb hf 173 86

Hw Ff

Ayhave MMM lies im 2 yto 2 LV

JEy is close to books 1mg

HE is close to 1200 KTfuot Chesemblemity G
All Gives the one thru with

Cath Good 0

Ev't Good RI

These are soft silvery metals

Due to Presence of unpaired e these are

paramagnetic Bmt train magnetic moment is

complex
µ Thirty teeth
have maximum Paramagnetism

Their compounds are coloured

may be due to

f f transition

change transfer

f f7g colourless

c Lmao
 her Lan
K

k web

My lnnS3

ln6H z
BaiJ
belomb
looking
Basic characters
wHe
In 1C Is Luca ne

this
neeiofnbltia
D
slnClz.b tho broch t Ha tho

Order of Fez is abnormal due to association

In Exchange
Enchff
 Actinoid

891 7 L
i
Pipe
i
nzn.is
Bk

g9qo Cfsf
m
Fm5f

Lh5f 6d17

actinoids show more valuable 0

techy

Sf orbitals isouts.cat
So easily take Part in Bard formetras
Larger size than Lm
less Tt 1ham Lm

Recats with Hu th
with HNos
passive Keto Peotechireolqques
Forms oxo cations µ out
colour is due to f f transition
more complex magnetic properties
than
Feed
Feroz 1 Hd Fe Uz
Feldt HU Feds

Feds 6hr0 Halloo

untyd mores facts D olid

dy Fa
th Fa
M
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or
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