@ilbTions XERCISES = Multiple Choice Questions & When 1 mole of benzene is mixed with 1 mole of toluene, the vapour will contain: (Given : vapour pressure of benzene = 12.8 kPa and vapour pressure of toluene = 3.85 kPa). (a) equal amount of benzene and toluene as it forms an ideal solution (6) unequal amount of benzene and toluene as it forms a non ideal solution (c) higher percentage of benzene (d) higher percentage of toluene When 0.6 g of urea is dissolved in 100 g water, the water will boil at (K, for water = 0.52 K m™ and normal boiling point of water = 100°C): (a) 372.48K (6) 273.52 K (c) 373.052K (d) 273.052 K. - A solution of solute X in benzene boils at 0.126°C higher than benzene. What is the molality of the solution ? (K, for benzene = 2.52 K/m) ? (a) 0.05 (6) 2 (ce) 1 (d) 20. - A pressure cooker reduces cooking time because : (a) heat is more evenly distributed (6) the high pressure tenderises the food (c) the boiling point of water inside the cooker is elevated (d) the boiling point of water inside the cooker is depressed. The vapour pressure of a pure liquid ‘A’ is 70 torr at 27°C. It forms an ideal solution with another liquid B. The mole fraction of B in the solution is 0.2 and total vapour pressure of solution is 84 torr at 27°C. The vapour pressure of pure liquid B at 27°C is : Answers on page-44 [iITTER 10. il. 12, (a) 14 torr (6) 56 torr (ec) 140 torr (d) 70 torr. . When a sugar solution is slowly frozen, the first solid which separate out is (a) ice (6) sugar (c)_ solid solution of sugar ice (d) a compound formed from sugar and water (hydrated sugar) An aqueous solution containing 1 g of urea boils at 100.25°C. The aqueous solution containing 3 g of glucose in the same volume will boil at : (a) 100.75°C (6) 100.5°C (c). 100°C (d) 100.25°C. A solution of solute X in benzene boils at 0.126°C higher than benzene. What is the molality of the solution ? (K, for benzene = 2,52 K/m) (a) 0.05 (6) 2 © 1 (d) 20. . Mole fraction of a solute in 2.5 molal aqueous solution is (@) 0.43 (6) 0.043 © 43 (d) 43. Vapour pressure of dilute aqueous solution of glucose is 750 mm of Hg at 373 K. The mole fraction of solute is (a) V76 (6) V7.6 (©) 1/38 @ vio. Two liquids. P and Q have vapour Pressures 450 and 200 torr respectively at certain temperature. In an ideal solution of the two, the mole fraction of P at which two liquids have equal Partial pressures is (@) 0.80 (6) 0.308 (©) 0.444 (@) 0.154 When a non-volatile solute (A) is added to solvent (B), its vapour pressure isis. la as 16. 17. retuced by 10%, If molar mass of B is SU% of molar mass of A, the mass ratio of Band Ais ta) O88 ) 60 w) 30 @) 0.66 The mass of a non-volatile solute of molar mass 40 g mol! that should be ahssolved itt 114 g of octane to lower its vapour pressure by 20% is (a) 8g 0) 4g ©) 98¢ @) 1288 $1 gofethytene gtyool (CJH,O,) is mixed wath 500 g of solvent (KL of the solvent is. 2 Rg mol '). What is the freezing point of the solution in K° (freezing point of solvent = 278 KD. (a) ty a) 27. At S00 K, the vapour pressure of an. ideal solution containing 1 mole of Liquid A and 2 moles of liquid B is 500 mm of Hg. The vapour pressure of the solution increases by 25 mm of Hg if one more mole of B is added to the above ideal solution at 300 K. Then vapour pressure of A in its pure state is (a) 300 mm of Hg (6) 40 mm of Hg (©) 500 mm of Hg (@) 600 mm of Hg Henry's law constant of oxygen is 1.4 10° mol L™ atm™ at 298 K. How much of oxygen is dissolved in 100 mL at 298 K when the partial pressure of oxygen is 0.5 atm ? (a) 148 () 32¢ () 224mg d)_-:2.24 mg (e) 32mg A solution of sucrose (molar mass = 342 g mol) has been prepared by dissolving 6.85 g of sucrose in 100 g of water. The freezing point of the solution obtained will be (Ky for water = 1.86 K kg mol *) (a) +0.372°C (b) - 0. 570°C (e) -0.372°C (d) -0 620°C Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene 19, a1. MBD Exam, Master Chemistry - Xt glycol which should be added to 4 kg of water to prevent it from freesing at ~ 6 °C will be (K for water = 1.86 K mol, and molar mass of ethylene glycol = 62g mol) (a) 400.00 ¢ (6) 904.60 g {e) 800.00 5 (d) 204.30 g What is the mole fraction of the solute in a 1.00 m aqueous solution? (a) 0.0354 (b) 0.0177 (©) 0.177 (a) 1.770 ‘The mixture which shows positive deviation from Raoult's law is (a) Acetone + Chloroform (b) Chloroethane + Bromoethane () Ethanol + Acetone (d) Benzene + Toluene A set of solutions is prepared using 180g of water as a solvent and 10g of different non-electrolyte and non-volatile solutes A.BandC. Therelative loweringof vapour pressure in the presence of these solutes are in the order (given, molar mass of ! A = 100 g mol, B = 200 g mol, | C = 10,000 ¢ mot”) : (6) B>C>A (a) A>B>c ©) C>B>A — @) A>C>B At 35°C, the vapour pressure of CS; is 512 mm Hg and that of acetone if 344 mm Hg. A solution of CS, in ace tone has a total vapour pressure of 600 mm Hg. The false statement | | amongst the following is : (a) heat must be absorbed in order t@ | ' produce the solution at 85°C Raoult’s law is not obeyed by this system a mixture of 100 mL CS, and 100 mL acetone has a volume < 200 mb CS, and acetone are less att to each other than to themselves ) tc (d) . The vapour pressure of acetone at 20°C is 185 torr. When 1.2 g of a non-volatil® substance was dissolved in 100 § acetone at 20°C, its vapour pressut® |\ was 183 torr. The molar m of the substance is 43s (gmt)(S@uTIONs (a) 128 (6) 488 (c) 32 (d) 64 How many grams of concentrated nitric acid solution should be used to Prepare 250 mL of 2.0 M HNO,? The concentrated acid is 70% HNO . (a) 90.0 g conc. HNO, (6) 70.0 g conc. HNO; (c) 54.0 g conc. HNO, (d) 45.0 g conc. HNO, |. A 6% solution of urea is isotonic with (a) 0.05 M solution of glucose (6) 6% solution of glucose (c) 25% solution of glucose (d) 1M solution of glucose An aqueous solution of a substance X boils at 100. 512°C. The freezing point of the solution is (K, = 1.86 Km™ and K, = 0.512 Km™) (a) 0.93°C (6) -0.93°C (©) 186°C (@) -1.86°C A solution containing 10 g per dm’ of urea (molecular mass = 60) is isotonic with a 5% solution of a non-volatile solute, The molecular mass of this non- volatile solute is (a) 300g mol? (6) 350g mol (c) 200g mol (d) 250g mol Density of 1M solution of a non electrolyte, CgHiz0¢ is 1.18 g mL“. If K, for water is 1.86 Km’, the freezing point of solution is (a) -158°C (6) -3.16°C (c) -1.86°C — (d)_‘1.86°C ‘The vapour pressures of two liquids A and B in their pure states are in ratio of 1:2, Abinary solution of A and B contains A and B in the mole proportion of 1: 2. The mole fraction of A in the vapour phase of the solution will be (a) 0.33 (b) 0.2 (c) 0.25 (d) 0.52 The density (in gml”') of a 3.60 M sulphuric acid solution that is 29% H,SO, (molar mass = 98 g mol) by mass will be : 81, 33. 34, 36. 37. 38. (a) 1.88 (b) 1.22 () 1.45 (d) 1.64 Battery acid is 4.27M H,SO, (aq) and has the density of 1.25 g mL. The molality of HSO, in the solution is (a) 3416m —(b)_ 3.342 m (©) 5.135m = (d)_:2.135m Sea water is converted into fresh water based upon the phenomenon of (@) Diffusion (6) Osmosis (c) Plasmolysis (d) Reverse osmosis. When 0.1 mole of glucose is dissolved in 10 mole of water, the vapour pressure of water is (@) Increased by 1% (6) Increased by 10% (©) Decreased by 1% (@) Decreased by 10%. Ifa solution containing 5% ofa substance X is isotonic with a solution containing 10 g of urea per litre. The molar mass of substance X is : (@) 150 (©) 600 (6) 300 (d) 450. . The osmotic pressure of 5% aqueous solution of glucose (n,) is related to that of 5% aqueous solution of urea (,) as @ =m (0) mm @) m=ny2 Osmotic pressure is measured by (@) Ostwald’s method (6) Berkeley and Hartley method (©) Pfeffer’s method (d) Beckmann’s method. The osmotic pressure of a 0.2 m solution of non-electrolyte at 27°C (R = 0.082 L atm Kt mol") is: (@) 4.92 atm (®) Latm (©) 0.2 atm (@) 27 atm, ‘Two solutions A and B are separated by a semipermeable membrane. If the solvent flows from A to B, then (a) Ais more concentrated than B(6) Both A and B have the same concentration (c) Ais less concentrated than B (d) Both A and B get diluted 25 ml of a solution of barium hydroxide on titration with 0.1 molar solution of hydrochloric acid gave a titre value of 35 ml. The molarity of barium hydroxide solution was (a) 0.14 (6) 0.28 (©) 0.35 (d) 0.07 Which of the following statements is not correct? (a) Osmotic pressure is directly proportional to molar concentration (6) A hypertonic solution will be less concentrated with respect to other solution (c) Isotonic solutions have same molar concentrations (d) Osmotic pressure depends upon temperature. Which of the following units is useful in relating concentration of solution with its vapour pressure? (a) mole fraction (6) parts per million (c) mass percentage (d) molality On dissolving sugar in water at room solution feels cool to touch. Under which of the following cases dissolution of sugar will be most rapid? (a) Sugar crystals in cold water. (b) Sugar erystals in hot water. (c) Powdered sugar in cold water. (d) Powdered sugar in hot water. . At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent sat 7 (a) less than the rate of crystallisation (b) greater than the rate of crystallisation so (c) equal to the rate of crystallisation (d) zero 4. 47. & 49. . Low concentration of oxygen in the MBD Exam. Master Chemistry - iy Abeaker contains a solution of substanes ‘A’. Precipitation of substance ‘a takes place when small amount of ‘A’ is added to the solution. The solution is (a) saturated (b) supersaturated (c) unsaturated (d) concentrated Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon (a) Temperature (b) Nature of solute (c) Pressure (d) Nature of solvent blood and tissues of people living at high altitude is due to (a) low temperature (6) low atmospheric pressure (c) high atmospheric pressure (d) both low temperature and high atmospheric pressure Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law? (a) Methanol and acetone. (6) Chloroform and acetone. (c) Nitric acid and water. (d) Phenol and aniline. Colligative properties depend on (a) the nature of the solute particles dissolved in solution. (b) the number of solute particles ia solution. (c) the physical properties of the solute particles dissolved in solution. (d) the nature of solvent particles. The unit of ebullioscopic constant is (a) Kkg mol" or K (molality (6) mol kg K" or K(molality) (©) _kg mol K* or K\molalityy? (d) K mol kg” or K (molality) An unripe placed in a concentrated ipe mango salt solution to prepare Fe pickle, shrivels because@iuTIns @) it gains water due to osmosis. 5) it loses water due to reverse osmosis. it gains water due to reverse osmosis. d) it loses water due to osmosis. @. Ata given temperature, osmotic pressure of a concentrated solution of a substance c a) is higher than that of a dilute solution. (5) is lower than that of a dilute solution. c) is same as that of a dilute solution. (d) cannot be compared with osmotic pressure of dilute solution. @. Which of the following statements is false? (a) Units of atmospheric pressure and osmotic pressure are the same. In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower concentration of solute to a region of higher concentration. (c) The value of molal depression constant depends on nature of (b) solvent. (d) Relative lowering of vapour pressure, is a dimensionless quantity. .. Value of Henry’s constant Ky ; (a) increases with increase in temperature. (6) decreases with increase in temperature. (c) remains constant. (d) first increases then decreases. $. The value of Henry's constant Ky is greater for gases with higher solubility. greater for solubility. (a) (b gases with lower (c) constant for all gases. (d) not related to the solubility of gases. Consider the figure given below and mark the correct option. Piston (A\ Piston B) Ao eo Concentrated a sodium water (A) —— solution in water (B) 56. (A) (B) (Cc) water will move from side (A) to side (B) if a pressure lower than osmotic pressure is applied on piston (B). water will move from side (B) to side (A) if a pressure greater than osmotic pressure is applied on piston (B). (c)_ water will move from side (B) to side (A) if a pressure equal to osmotic pressure is applied on piston (B). water will move from side (A) to side (B) if pressure equal to osmotic pressure is applied on piston (A). On the basis of information given below mark the correct option. Information: In bromoethane and chloroethane mixture, intermolecular interactions of A-A and B-B type are nearly same as A-B type interactions. In ethanol and acetone mixture A—A or B_B type intermolecular interactions are stronger than A-B type interactions. In chloroform and acetone mixture A~A or B-B type intermolecular interactions are weaker than A-B type interactions. (a) Solution (B) and (C) will follow Raoult’s law. (6) Solution (A) will follow Raoult’s law. (a) ) @MBD Exam. Master Chemistry - XI Reason: When a volatile solute is added to a volatile solvent elevation in boiling point is observed 15, Assertion: When NaCl is added to water a depression in freezing point is observed. Reason: The lowering of vapour pressure of a solution causes depression in the freezing point. 16. Assertion: When a solution is separated from the pure solvent by a semipermeable membrane, the solvent molecules pass through it from pure solvent side to the solution side. Reason: Diffusion of solvent occurs from a region of high concentration solution to a region of low concentration solution. 3.) 4) 6.(c) (a) 7d) 8.(a) 9.(6) , 10.(a) 11.6) 12%.(c) 18.(@) 14.(6) 15. (a) 16.(d) 17.(c) 18.(c) 19.(6) 20. (6) 21.(a) 22.(c) 28.(d) 24.(d) 25.(d) 26.(d) 27.(a) 28.(c) 29.(6) 30.(0) B1.©) 82.(¢) 88.(c) 34.00) 85.06), 36.(6) 87(a) 98.(6) 89.(d) 40.(6) 41.(@) 42.(d) 48.(0) 44.(6) 45.(0) 46.(b) 47.(a) 48.(6) 49.(a) 50.(d) Bl.(a@) 52.(b) 58.(a) 54.(6) 55. (6) 56.(6) 57.(a) 58.(d) 59.(d) 60. (6) 61. (c) Assertion Reason Type Questions 1L@ 26) 86) 40) 5 @), 6@ 7@ 8) %© w6@) 1L.@ 12) 18.@) 14@ 15.4 16. (c) ee 1. (c) Higher percentage of benzene because its vapour pressure is high pibenzene) = 128 kPa x 0.5 = 6.4 kPa, 3.85 kPa x 05 = 1.925 kPa Pftoluene) = x1000xw, 1, XM, 2) aT, _ 0.52 x 1000 x 0.6 S 100 x 60 -. Boiling point of solution = 373.052 K = 0.052 = AT, 9:226 20.05 m 8 (a) m= Fh = SE = 006 4. (c) Inside the pressure cooker, the pressure becomes high so that the boiling point increases. 5. (c): Mole fraction of A = 1-0.2=0. PA’ XX, + Pp’ X Xp =P 70 x 0.8 + pg? x 0.2 Pp’ x 0.2 = 84 - 56 = 28 Pp’ = 28/0.2 = 140 tor 7. (@) Since Ky and wy solutions