Printed Pages – 3

21113
B. Sc. (Final Year) Examination, 2021
(New Course)
CHEMISTRY
Paper : Third
(Organic Chemistry)
Time Allowed : Three hours
Maximum Marks : 28

ŸÊ≈U — ‚÷Ë ¬˝‡Ÿ ÁŸŒ¸‡ÊÊŸÈ‚Ê⁄U „U‹ ∑§ËÁ¡∞– •ÊãÃÁ⁄U∑§ Áfl∑§À¬ ‚Á„Uà (¬˝Áà ¬˝‡Ÿ Æw •¢∑§) ∑§ øÊ⁄U ‹ÉÊÈ ©UûÊ⁄UËÿ ¬˝‡ŸÊ¥
∑§Ê „U‹ ∑§⁄UŸÊ „ÒU– •ÊãÃÁ⁄U∑§ Áfl∑§À¬ ‚Á„Uà (¬˝Áà ¬˝‡Ÿ Æy •¢∑§) ∑§ ¬Ê°ø ŒËÉʸ ©UûÊ⁄UËÿ ¬˝‡ŸÊ¥ ∑§Ê „U‹ ∑§ËÁ¡∞–
Note: Attempt all questions as directed. Attempt short answer type 04 question of 02 marks each
with internal choice. Long Answer type five qustions of 04 marks each with internal choice.
πá«U-“•”
Section–‘A’

(‹ÉÊÈ ©UûÊ⁄UËÿ ¬˝‡Ÿ) y&w=}

(Short Answer Type Questions)

ŸÊ≈U — ‚÷Ë ¬˝‡ŸÊ¥ ∑§ ©UûÊ⁄U ŒËÁ¡∞– ¬˝àÿ∑§ ¬˝‡Ÿ w •¢∑§Ê¥ ∑§Ê „ÒU–
Note: Attempt all questions. Each question carries 2 marks.

1. ÁS¬Ÿ-ÁS¬Ÿ ÿÈÇ◊Ÿ ∑§Ê ©UŒÊ„U⁄UáÊ ‚Á„Uà ‚◊¤ÊÊß∞– w

Explain the SPIN-SPIN coupling with example.
•ÕflÊ
Or
•À≈˛UÊ flÊÿ‹≈U (¬⁄UÊ’Ò¥ªŸË) S¬Ä≈˛UÊÁ◊∑§Ë Ã∑§ŸË∑§ ∑§Ê ©U¬ÿÊª ∑§⁄UÃ „ÈU∞ ‚⁄U‹ ∑§Ê’¸ÁŸ∑§ ÿÊÒÁª∑§Ê¥ ∑§Ë ‚¢⁄UøŸÊ ∑§Ê ÁŸœÊ¸⁄UáÊ
∑§ËÁ¡∞–
Write down the application of ultra violet spectroscopy for simple organic compounds.

2. ÕÊÿÊ‹ (Thiol) ∑§Ê ŸÊ◊∑§⁄UáÊ ©UŒÊ„U⁄UáÊ ‚Á„Uà ‚◊¤ÊÊß∞– w

Explain the Nomenclature of Thiol with example.
•ÕflÊ
Or
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 Ä‹‚Ÿ ‚¢ÉÊŸŸ ∑§Ê ‚◊¤ÊÊß∞–
Explain the Claisen Condensation.

3. D (+) Ç‹Í∑§Ê‚ ∑§Ë fl‹ÿ ‚¢⁄UøŸÊ ∑§Ê ‚◊¤ÊÊß∞– w

Exlain the Ring structure of D (+) glucose.
•ÕflÊ
Or
•ÊÿÊ«UËŸ ◊ÊŸ •ÊÒ⁄U •ê‹ ◊ÊŸ ∑§Ê ÁflSÃÊ⁄U¬Ífl¸∑§ ‚◊¤ÊÊß∞–
Write down the Iodine Value and Acid Value.

4. ◊ÁÕ‹ •ÊÚ⁄Uã¡ ⁄¢U¡∑§ ∑§Ê flªË¸∑§⁄UáÊ ∑§⁄U∑§ ‚◊¤ÊÊß∞– w

Write down the classification of dyes-Methyl orange.
•ÕflÊ
Or
Á»§‡Ê⁄U-ßá«UÊ‹ ‚¢‡‹cÊáÊ ∑§Ê ‚◊¤ÊÊß∞–
Explain the Fischer-Indole synthesis.
πá«U-“’”
Section–‘B’

(ŒËÉʸ ©UûÊ⁄UËÿ ¬˝‡Ÿ) z&y=wÆ

(Long Answer Type Questions)

ŸÊ≈U — ‚÷Ë ¬˝‡ŸÊ¥ ∑§ ©UûÊ⁄U ŒËÁ¡∞– ¬˝àÿ∑§ ¬˝‡Ÿ y •¢∑§Ê¥ ∑§Ê „ÒU–
Note: Attempt all questions questions. Each question carries 4 marks.

5. (1H NMR) •ŸÈŸÊŒ S¬Ä≈˛UÊÁ◊∑§Ë ∑§Ê ‚◊¤ÊÊß∞– y

Describe the Resonance (1H NMR) spectroscopy.
•ÕflÊ
Or
ŸÊÁ÷∑§Ëÿ ¬Á⁄U⁄UˇÊáÊ ∞fl¢ Áfl¬Á⁄U⁄UˇÊáÊ ∑§Ê ÁflSÃÊ⁄U¬Ífl¸∑§ ‚◊¤ÊÊß∞–
Describe the Nuclear Shielding and dis-shielding.

6. ∑§Ê’¸◊ÒÇŸËÁ‡Êÿ◊ ÿÊÒÁª∑§Ê¥ ∑§Ë ‚¢⁄UøŸÊ •ÊÒ⁄U ’ŸÊŸ ∑§Ë ÁflÁœ ∑§Ê ÁflSÃÊ⁄U¬Ífl¸∑§ ‚◊¤ÊÊß∞– y
Discuss the Oranomagnesium compounds of structure and preparations.
•ÕflÊ
Or

[ 2 ] 21113
 ∞ÁÕ‹ ∞Á‚≈UÊ ∞Á‚≈U≈U ∑§Ë ∑§Ë≈UÊ-߸ŸÊ‹ ø‹ÊflÿflÃÊ ∑§Ê ‚◊¤ÊÊß∞–
Write down the Keto-enol tautomerism in Ethylaceto acetic.

7. ÁŸêŸÁ‹Áπà Á’ãŒÈ•Ê¥ ∑§Ê ‚◊¤ÊÊß∞ó y

(i) ‚Ê¢‡‹ÁcÊ∑§ •¬◊Ê¡¸∑§ ∑§Ê (ii) Ç‹Í∑§Ê‚ ‚ »˝§Ä≈UÊ Ê ◊¥ •ã×M§¬ÊãÃ⁄UáÊ ∑§Ê ‚◊¤ÊÊß∞
Write down the following topic :
(i) Synthetic Detergents (ii) Inter conversion of Glucose into Fructose
•ÕflÊ
Or
∞À«UÊ‚ ∑§ ‚÷Ë ‚¢⁄UøŸÊ •ÊÒ⁄U •Á÷ÁflãÿÊ‚ ∑§ •ÊœÊ⁄U ¬⁄U •Ê⁄UÊ„UáÊ fl •fl⁄UÊ„UŸ o΢π‹Ê ∑§Ê ÁflSÃÊ⁄U¬Ífl¸∑§ ‚◊¤ÊÊß∞–
Write down the Ascending and discending series in Aldose with all str. and configuration.

8. ÁŸêŸ Á’ãŒÈ•Ê¥ ∑§Ê ‚◊¤ÊÊß∞ó y

(i) ⁄UÊß’ÊãÿÈÁÄ‹ÿÊ‚Êß«U •ÊÒ⁄U ⁄UÊß’ÊãÿÍÁÄ‹ÿÊ≈UÊß«U (ii) DNA ∑§Ë Ám∑ȧá«UÁ‹ŸË ‚¢⁄UøŸÊ
Describe the following topic :
(i) Ribonucleoside and Ribonucleotide (ii) Double Helix Str. of DNA
•ÕflÊ
Or
Á¬Á⁄U«UËŸ, Á¬¬Á⁄U«UÊÚŸ ∞fl¢ Á¬⁄UÊ‹ ∑§Ë ÷ÊÁS◊∑§ÃÊ ∑§Ë ÃÈ‹ŸÊ ∑§ËÁ¡∞–
Comparison of Basicity between Pyridine Piperidine and Pyrrole.

9. ‚◊Áfl÷fl Á’ãŒÈ •ÊÒ⁄U flÒlÈà ∑§áÊ ‚¢ø‹Ÿ ∑§Ê ÁflSÃÊ⁄U¬Ífl¸∑§ ‚◊¤ÊÊß∞– y

Explain the Isoelectric point and Electrophoresis in details.
•ÕflÊ
Or
¬Ê°ø ∞fl¢ ¿U— ‚ŒSÿËÿ ‚¢ÉÊÁŸÃ ÁflcÊ◊ ø∑˝§Ëÿ ÿÊÒÁª∑§Ê¥ ∑§Ê ‚◊¤ÊÊß∞–
Describe the five and six membered condensed heterocyclic compounds.

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