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Dense ceramics of BaTiO 3 produced from powders

prepared by a chemical process Download full-text PDF

December 1995 · Journal of the European Ceramic Society 15(12):1163-1170

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DOI:10.1016/0955-2219(95)00090-9

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C. Miot Chantal Proust E. Husson Why you can bank on Candidate Search — now and in
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Citations (32) References (28)

Abstract

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A sintering optimization of barium titanate ceramics from ne-grained and homogeneous
reproducible powders obtained by the citric process is presented. Different sintering
research
parameters are studied: heating rates, nal temperature, dwelling times at this nal
20+ million members
temperature, and in uence of the powder deagglomeration step. The sintering is followed by
dilatometric measurements. The ceramics obtained by sintering at 1230 or 1300 °C are free of 135+ million publications
barium carbonate, the residual carbon content being estimated at about 400 ppm in the
surface layer. They exhibit a grain size close to 1 μm, a structure in which the cubic and
700k+ research projects
tetragonal phases coexist, and a density of about 96% of the theoretical density. Their
permittivity and loss factor are respectively about 5000 and 2.5 × 10−2 at 25 °C. Join for free

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Citations (32) References (28)

... The dielectric and other properties of BaTiO 3 powders and ceramics depend strongly on the method and conditions of their synthesis [5]
[6][7] [8] [9][10][11][12][13][14][15][16][17][18][19][20][21][22][23][24]. This in uence is due to several factors: an increase in the ceramics
density and, therefore, reduction of its porosity with an increase in the sintering temperature; dependence of the ceramics grain size on the
sintering temperature and time (which, in turn, affects the sizes of ferroelectric domains in grains and the fraction of low-permittivity
intergranular interlayers in the ceramics); and the BaO volatility at high temperatures, which leads to a change in the [Ba]/[Ti] stoichiometry
in barium titanate samples. ...

... At room temperature, the core has a tetragonal symmetry and exhibit ferroelectric properties [7-9, 19, 25-30], whereas the shell structure
is not tetragonal and is characterized by low permittivity. According to the X-ray diffraction (XRD) data, the grain-shell structure contains
defects and is characterized by cubic symmetry [7, 8, 19,25,26]. There are other data on this subject. ...

... The re nement was carried out for speci c ranges of the sample diffraction patterns rather than for the complete diffraction patterns. A
similar approach was applied in [8, 35]. In this case, the number of re ned parameters decreases signi cantly. ...

Cubic and Tetragonal Modi cations in BaTiO3 Ceramic Samples: X-Ray Diffraction Analysis by the Rietveld Method

Article Nov 2020 · CRYSTALLOGR REP+

Alexandr Bush · V. P. Sirotinkin · S. A. Ivanov

View

... Barium titanate, revealing both ferroelectric and piezoelectric properties, is a very desirable perovskite-type ceramic material in the eld
of electroceramics and microelectronics (Biglar et al., 2015;Vijatović et al., 2008). BaTiO3 is destined for many applications in different
industries, such as energy storage devices and multilayer actuators (MLAs) (Miot et al., 1995; Kao and Yang, 1999). These applications
require materials with a good density, a high dielectric constant and a low loss factor. ...

... At Curie temperature the barium titanate transforms from paraelectric to ferroelectric phase (Ertuğ, 2013). Synthesis of materials with
these properties needs highly pure, ne grained ceramics, which may be obtained from homogeneous reproducible powders of spherical
particles (Miot et al., 1995; Kholodkova et al., 2012). Choi et al. (2008) underline that MLCs have been investigated because their
advantages are high precision, little noise and low power consumption, compared with conventional multilayer actuators (MLAs). ...

... The values of relative density evaluated as the ratio of apparent density to the theoretical density are very similar (Table 1). Duran et al.
(2002) and Miot et al. (1995) found that density of BaTiO3 sintered pellets based on the value of lattice constant is equal to 6.02 g/cm 3 .
So, the obtained relative density is in agreement with the results of other authors. ...

Synthesis of Barium Titanate Piezoelectric Ceramics for Multilayer Actuators (MLAs)

Article Full-text available Dec 2017

Mojtaba Biglar · Magdalena Gromada · Feliks Stachowicz · Tomasz Trzepieciński

View Show abstract

... BaTiO 3 (BT)-based materials are among the most used oxide systems in microelectronics, in particular for tunable elements,
pyroelectric, piezoelectric, electro-optic and charge storage applications [1][2] [3] [4][5][6][7]. BT and its solid solutions are lead-free
ferroelectrics with a wide range of permittivity varying from a few hundreds to thousands, depending mainly on the doping level,
microstructural characteristics, density and grain size, temperature range and applied eld [7][8][9][10][11]. ...

Study of the role of porosity on the functional properties of (Ba,Sr)TiO3 ceramics

Article Full-text available Sep 2015 · J ALLOY COMPD

Roxana-Elena Pătru · C.E. Ciomaga · Leontin Padurariu · L. Mitoseriu

View Show abstract

... These values denote the increase of BaTiO3 particles incorporation, being comparable with chitosan biopolymeric lms reported in the
literature (1.5 g/cm 3 ). [16,23] The highest density observed for S3 lms can be explained by the presence of the highest quantity of
BaTiO3 14 particles (the amounts of chitosan and particles in S3 lms are 1.5% and 3.0% w/v, respectively), with a theoretical density of
6.02 g/cm³ [30] . Table 1. ...

Flexible Piezoelectric Chitosan and Barium Titanate Biocomposite Films for Sensor Applications

Article Mar 2021 · EUR J INORG CHEM

Dayana Lizethe Guzmán Sierra · Igor Bdikin · Alexander Tkach · Paula Ferreira

View Show abstract

... [29] The peak of CO2, around 2300 cm -1 , was removed as it is related to the purge conditions of the spectrometer. particles (the
amounts of chitosan and particles in S3 lms are 1.5% and 3.0% w/v, respectively), with a theoretical density of 6.02 g/cm³ [30] . Table 1.
...

Flexible Piezoelectric Chitosan and Barium Titanate Biocomposite Films for Sensor Applications
Article Dec 2020

Dayana Lizethe Guzmán Sierra · Igor Bdikin · Alexander Tkach · Paula Ferreira

View Show abstract

... The nal results of the full-pattern re nement for the sample 1 are shown in Fig. 3, Tables 1 and 2. The cubic phase with the space group
Pm-3 m is present in a small amount.The tetragonal phase with the non-centrosymmetric space group P4mm is the main one. According to
[13] [14] [15] the cubic phase is defect-rich. It is present as a shell on the grains of the tetragonal phase. ...

Phase composition of ceramic samples of the BaTiO3–PbTiO3–BaZrO3 system near BaTiO3

Article Full-text available Jan 2021 · J Mater Sci

V. P. Sirotinkin · Alexandr Bush

View Show abstract

... However, this method produces relatively coarse and agglomerated particles, which is not suitable for most applications. In order to get
ne-grained powders, alternative processing methods have been developed with chemical routes using non-oxide precursors [49, 50]. [32].
...

Recent Progress on Core-Shell Structured BaTiO3@polymer/Fluorinated Polymers Nanocomposites for High Energy Storage:
Synthesis, Dielectric properties and Applications

Article Apr 2020 · PROG MATER SCI

Fatima ezzahra Bouharras · Mustapha Raihane · Bruno Ameduri

View Show abstract

... The relative and true densities as a function of milling time are given in gure 8. The theoretical density of sintered barium titanate
calculated based on the lattice constant is 6.02 g cm −3 [27, 28] . As the mechanical activation time increased, the grain size decreased,
and denser structures were formed as a result. ...

Low temperature formation of barium titanate in solid state reaction by mechanical activation of BaCO3 and TiO2

Article Jan 2020

Fatih Apaydin · Tuğba Tunç Parlak · Kenan Yildiz

View

Characterization of BaTiO3 piezoelectric perovskite material for multilayer actuators

Article Jul 2017 · B MATER SCI

Magdalena Gromada · Mojtaba Biglar · Tomasz Trzepieciński · Feliks Stachowicz

View Show abstract

Hydrothermal synthesis of barium titanate powders from a co-precipitated precursor

Article Jan 2003 · J CERAM PROCESS RES

B.W. Lee · G.S. Choi

View Show abstract

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