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IB DP Chemistry Topic 10.1 Fundamentals of organic chemistry SL Paper 1

IB DP Physics IB DP Maths IB DP Chemistry IB DP Biology

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Question

Which three compounds can be considered to be a homologous series?

A. CH3OH, CH3CH2OH, CH3CH2CH2OH

B. CH3CH2OH, CH3CHO, CH3COOH

C. CH3CH2CH(OH)CH3, CH3CH2CH2CH2OH, (CH3)3COH

D. CH3CH2CH2CH2OH, CH3CH2OCH2CH3, (CH3)2CH2CHO

Answer/Explanation

Question

What is the IUPAC name for CH3CH2CH(CH3)CH3?

A. 1,1-dimethylpropane

B. 2-ethylpropane

C. 2-methylbutane

D. 3-methylbutane

Answer/Explanation

Question

Which is a tertiary halogenoalkane?

A. CH3CH2CH2Br

B. CH3CH2CH(CH3)Cl

C. C(CH3)3Br

D. CH3CHClCH2CH3

Answer/Explanation

Question

What is the IUPAC name of the following compound?

A. 2-methylbutane

B. Ethylpropane

C. 3-methylbutane

D. Pentane

Answer/Explanation

Question

How many structural isomers exist with the formula C3H5Cl3?

A. 3

B. 4

C. 5

D. 6

Answer/Explanation

Question

What is the structural formula of 2,3-dibromo-3-methylhexane?

A. CH3CHBrCHBrCH(CH3)CH2CH3

B. CH3CHBrCBr(CH3)CH2CH2CH3

C. CH3CH2CHBrCBr(CH2CH3)2

D. CH3CHBrCHBrCH(CH2CH3)2

Answer/Explanation

Question

Which of the following substances are structural isomers of each other?

I. CH3(CH2)3CH3

II. (CH3)2CHCH3

III. CH3CH(CH3)CH2CH3

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Answer/Explanation

Question

Which order is correct when the following substances are arranged in order of increasing boiling point?

A. CH3CH3 < CH3CHO < CH3CH2OH

B. CH3CHO < CH3CH2OH < CH3CH3

C. CH3CH2OH < CH3CH3 < CH3CHO

D. CH3CH3 < CH3CH2OH < CH3CHO

Answer/Explanation

Question

Which of the following are isomers of pentane?

I. 2-methylpentane

II. methylbutane

III. dimethylpropane

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Answer/Explanation

Question

Which of the following pairs are members of the same homologous series?

A. CH3CH2CH2OH and CH3CH2CHO

B. CH3CH(OH)CH3 and CH3CH2CH(OH)CH3

C. CH3COCH3 and CH3CH2COOH

D. CH3COCH2CH3 and CH3CH2CHO

Answer/Explanation

Question

Which organic molecule is not a structural isomer of pentan-1-ol?

A. pentan-2-ol

B. 2-methylpentan-2-ol

C. 2-methylbutan-2-ol

D. pentan-3-ol

Answer/Explanation

Question

Which of the structures below is an aldehyde?

A. CH3CH2CH2CH2OH

B. CH3CH2COCH3

C. CH3CH2COOCH3

D. CH3CH2CH2CH O

Answer/Explanation

Question

Which molecule contains an ester group?

A. CH3CH2COOH

B. CH3COOCH3

C. CH3COCH2CH2OH

D. OHCCH2CHO

Answer/Explanation

Question

Consider the compound (CH3CH2)CH=CH(CH3). Which statements are correct?

I. A suitable name is pent-2-ene.

II. The empirical formula is CH2.

III. An isomer of the compound is pentane.

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Answer/Explanation

Question

Which statement about a homologous series is correct?

A. Members of the series differ by CH3.

B. Members of the series have the same physical properties.

C. Members of the series have the same empirical formula.

D. Members of the series have similar chemical properties.

Answer/Explanation

Question

Which compound is not an isomer of hexane?

A. CH3CH(CH3)CH2CH2CH3

B. CH3CHCHCH2CH2CH3

C. (CH3)3CCH2CH3

D. CH3CH2CH(CH3)CH2CH3

Answer/Explanation

Question

What is the name of the following molecule applying IUPAC rules?

A. 1,1-dimethylbutane

B. Hexane

C. 2-methylpentane

D. 4-methylpentane

Answer/Explanation

Question

How many non-cyclic structural isomers exist with the molecular formula C5H10?

A. 2

B. 3

C. 4

D. 5

Answer/Explanation

Question

Which three compounds can be considered to be a homologous series?

A. CH3NH2 CH3CH2NH2 CH3CH2CH2NH2

B. CH3CH2CH2NH2 CH3CH(NH2)CH3 CH3(NH)CH2CH3

C. C(CH3)4 CH3CH2CH2CH2CH3 (CH3)2CHCH2CH3

D. CH3CH2COOH CH3COOCH3 HCOOCH2CH3

Answer/Explanation

Question

What is the name of the following compound applying IUPAC rules?

A. 1,1,1-trimethylpropane

B. 2,2-dimethylbutane

C. 3,3-dimethylbutane

D. 2-methyl-2-ethylpropane

Answer/Explanation

Question

What is the name of (CH3)3CCOCH3, applying IUPAC rules?

A. 2,2-dimethylbutan-3-one

B. 3,3-dimethylbutan-2-one

C. 2,2-dimethylbutanal

D. 3,3-dimethylbutanal

Answer/Explanation

Question

Which statement is correct for members of the same homologous series?

A. They have the same empirical formula and a gradual change in chemical properties.

B. They have the same empirical formula and a gradual change in physical properties.

C. They have the same general formula and a gradual change in chemical properties.

D. They have the same general formula and a gradual change in physical properties.

Answer/Explanation

Question

Which properties are features of a homologous series?

I. Same general formula

II. Similar chemical properties

III. Gradation in physical properties

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Answer/Explanation

Question

Which compound is an isomer of octane, C8H18?

A. (CH3)2CH(CH2)2CH(CH3)2

B. (CH3)2CHCH2CHCHCH2CH3

C. CH3(CH2)5CH3

D. (CH3)2CH(CH2)2CHCHCH3

Answer/Explanation

Question

In which pair are both compounds secondary?

Answer/Explanation

Question

What is the name of the alkane shown in the diagram below, applying IUPAC rules?

A. Hexane

B. 1,1,1-trimethylpropane

C. Ethylmethylpropane

D. 2,2-dimethylbutane

Answer/Explanation

Question

Which structural formula represents a secondary halogenoalkane?

A. CH3CHBrCH2CH3

B. (CH3)3CBr

C. CH3(CH2)3Br

D. (CH3)2CHCH2Br

Answer/Explanation

Question

Applying IUPAC rules, what is the name of the compound?

A. 1-ethyl-1,3-dimethylbut-2-ene

B. 2-ethyl-4-methylpent-3-ene