Professional Documents
Culture Documents
a r t i c l e i n f o a b s t r a c t
Article history: The northern border of the Variscan Moroccan Meseta is characterized by the presence of Cambrian rocks
Received 14 July 2008 affected by pre-Variscan deformation (the Sehoul block) thrust to the south onto Ordovician, Silurian and
Received in revised form 26 June 2009 Devonian sediments and volcanics of the Bou Regreg corridor. A correct appraisal of the significance of
Accepted 5 July 2009
this tectonic contact in the framework of the Variscan orogen needs new data on the age, geochemical
Available online 16 July 2009
features and field relationships of granitoids cropping out in the Sehoul block (Rabat granitoids) and
the Bou Regreg corridor (Tiflet granitoids). Accordingly, we provide here with new geochemical data
Keywords:
and accurate U–Pb geochronology of these granitoids, which lead us to conclude that: (i) the Rabat grani-
U–Pb geochronology
Granitoids
toids are Late Devonian in age (367 Ma); (ii) the Tiflet granitoids are Late Proterozoic in age (605–609 Ma)
Caledonian and display Andean-arc features, thus being genetically linked to the Cadomian/Pan-African subduction
Neoproterozoic and forming part of the Variscan basement during the Palaeozoic; (iii) the previously accepted 430 Ma
Moroccan Variscides Rb–Sr age, common for the Rabat and Tiflet granitoids, which would imply a trivial Carboniferous dis-
placement of the Sehoul thrust, must be rejected; and (iv) the Sehoul thrust might be a major Variscan
boundary, perhaps hiding the Rheic Ocean suture.
Ó 2009 Elsevier Ltd. All rights reserved.
1464-343X/$ - see front matter Ó 2009 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jafrearsci.2009.07.005
2 A. Tahiri et al. / Journal of African Earth Sciences 57 (2010) 1–13
Fig. 1. 1A: Geological sketch of the Moroccan Variscides. 1B: Geological map of the investigated area showing, from north to south, the Sehoul block, the Sehoul thrust, the
Bou Regreg corridor and the Sidi Bettache Carboniferous basin (from El Hassani (1991), simplified).
is thrust onto the Bou Regreg corridor, which is made up of non- metamorphism has been found in the Ordovician to Lower Devo-
metamorphic rocks of Ordovician, Silurian and Devonian age, only nian sedimentary rocks of the Bou Regreg corridor around the Tiflet
affected by Variscan deformation. The Ordovician rocks of the Bou plutons. The Tiflet granitoids are quartz-diorites and granodiorites,
Regreg corridor show two distinctive features with respect to the with biotite as the main mafic mineral and amphibole present only
Ordovician of other regions in Morocco: (i) presence of volcanic ba- in minor amounts in the Taïcha outcrop; they contain some
sic rocks embedded in a clastic Lower Ordovician sequence, and (ii) metasedimentary enclaves, with mafic microgranular enclaves
lack of Upper Ordovician deposits (El Hassani, 1991). The rocks of only in Taïcha.
the Bou Regreg corridor are thrust onto an olistostromic/conglom- Hydrothermal alteration promoted by the tectonic deformation
eratic chaotic unit, which gradually passes southwards to the affects the Rabat and Tiflet granitoids, being responsible for car-
Upper Devonian/Lower Carboniferous clastic sediments and vol- bonate–chlorite veins locally found within the granitoids.
canics of the Sidi Bettache basin (Fig. 1B).
The granitoids of the Rabat area, cropping out a few kilometres
southeast of Rabat city, appear as decametre/hectometre-size tec- 3. Regional scenario
tonic lenses and dykes included in the Sehoul block (Fig. 1B and 2).
The granitoids are cut at different scales by faults which are con- The Rabat–Tiflet granitoids have yielded a 430 Ma Rb–Sr ‘‘iso-
gruent with the thrust of the Sehoul block over the Bou Regreg cor- chron” (Charlot et al., 1973), and have been related to the Caledo-
ridor. Because of this tectonic overprint, the association of the nian orogenic evolution (Piqué, 1989; El Hassani, 1991). In the
plutonic outcrops with their thermal aureole is not obvious, phyllites of the Sehoul block near Rabat (Fig. 1), biotite, andalusite
though adjacent andalusite/cordierite/biotite-bearing schists are and cordierite porphyroblasts attributed to contact metamorphism
considered to result from the contact metamorphism caused by are observed to have grown sealing the main foliation, thus indi-
the granitoids. The Rabat granitoids display some petrographic cating that granitoids intrusion occurred later than the main defor-
variety, having been described as syenites (Lecointre, 1931; García, mation event recorded in the phyllites. Accordingly, the age of that
1961), quartz-diorites, granodiorites and monzogranites (El Has- deformational event has been bracketed between the Cambrian
sani, 1991). (age of the sediments) and the 430 Ma attributed to the granitoids,
To the east, SW of Tiflet village, the granitoids of Taïcha and Bou i.e. it has been considered as a Caledonian event. This interpreta-
Jemaa crop out included in the Bou Regreg corridor (Fig. 1B and 2). tion is also supported by the K/Ar age of micas from the Sehoul
The boundaries of these granitoids are sometimes Variscan faults, phyllites (El Hassani, 1991): from six analysed samples, five of
but when non-faulted boundaries are observed they display sedi- them gave K/Ar ages between 327 and 359 Ma, with one of them
mentary rather than intrusive features. Thus, no trace of thermal yielding 453 Ma. These results were interpreted as Variscan
A. Tahiri et al. / Journal of African Earth Sciences 57 (2010) 1–13 3
Fig. 2. Location of the analysed samples (compare with Fig. 1B). Geographical coordinates are given for the samples studied for geochronology. 1: outcrops of the Sehoul
schists; 2: granitoids; 3 and 4: upper and lower tectonic boundaries of the Bou Regreg corridor.
reworking related to the Sehoul thrust, with some preservation (ICPMS) after HNO3 + HF digestion of 0.1 g of sample powder in a
(the 453 Ma sample) of the Caledonian low-grade metamorphism. Teflon-lined vessel at 180 °C and 200 psi during 30 min, evapo-
In the Bou Regreg corridor, near Tiflet (Fig. 1B), field relation- ration to dryness and subsequent dissolution in 100 ml of 4 vol.%
ships between granitoids and surrounding rocks are different with HNO3; the precision was better than ±5% for analyte concentrations
respect to those in the Rabat area, with the granitoids being cov- of 10 ppm. The concentration of Hf was calculated from the ICPMS-
ered here by a non-metamorphic sequence, dated at its base as determined Zr/Hf and the XRF-determined Zr concentration. Sam-
Upper Silurian. These Upper Silurian sediments also overlie a vol- ples for Sr and Nd isotope analysis were digested with HNO3 + HF
cano-sedimentary sequence of Early Ordovician age, but Upper Or- in the same way as before using ultra-clean reagents and analysed
dovician and Lower Silurian sediments are absent (El Hassani, by thermal ionization mass spectrometry (TIMS) in a Finnigan Mat
1991). The relationships between the granitoids and the Lower Or- 262 spectrometer after chromatographic separation with ion-ex-
dovician rocks are not observed in the field. change resins. Normalization values were 86Sr/88Sr = 0.1194 and
146
If the Rabat and Tiflet granitoids were 430 Ma old, the Sehoul Nd/144Nd = 0.7219. Blanks were 0.6 and 0.09 ng for Sr and Nd
block and the Variscan Meseta would be together at that pre-Vari- respectively. The external precision (2r), estimated by analysing
scan time because granitoids crop out in the two geological 10 replicates of the standard WS-E (Govindaraju et al., 1994), was
domains, at both sides of the Sehoul thrust (Fig. 2). However, the better than ±0.003% for 86Sr/88Sr (mean = 0.706596) and ±0.0015%
deformational structures in the thrust zone, as well as the develop- for 146Nd/144Nd (mean = 0.512462). The internal precision and accu-
ment to the south of a syn-sedimentary olistostromic Lower racy can be estimated on the averages of the standards NBS987,
87
Carboniferous unit strongly suggest that the Sehoul thrust is a Sr/86Sr = 0.710247 ± 0.000005, and La Jolla 143Nd/144Nd =
first-order Variscan structure bringing together two pre-Variscan 0.511844 ± 0.000007. 87Sr/86Rb and 143Sm/144Nd were directly
geological domains. determined by ICPMS following the method developed by Montero
and Bea (1998), with a precision better than ± 1.2% and ± 0.9% (2r),
respectively.
4. Samples and methods Laser Ablation-ICPMS analyses of U, Th and Pb isotopes were
carried out with an Nd-YAG 213 lm Mer-cantek laser and a
We collected twelve samples of the Rabat granitoids and six sam- torch-shielded quadrupolar Agilent 7500 ICPMS spectrometer.
ples of the Tiflet granitoids for geochemical and isotopic studies (Ta- The laser beam was set at a diameter of 60 lm, with a repetition
bles 1 and 2; see location in Fig. 2), as well as for a preliminary test rate of 10 Hz and output energy of 1 mJ per pulse. The ablation
of previous Rb/Sr dating; samples were collected from areas with no time was 60 s and the spot was pre-ablated during 45 s with laser
visible alteration. Since the Rb/Sr isotopic data did not yield an accept- output energy of 0.3 mJ per pulse. The ablation was done in a He
able isochron age, we separated zircons for U–Pb geochronology from atmosphere. 91Zr was used as an internal standard. The external
three granitoids, one sample (BARR-1) from the Rabat area and two standard was the NIST-610 glass, which contains 439.9 ppm Zr,
samples (TA and BJE) from the Tiflet area (see location in Fig. 2). All 417.7 ppm Hf, 409 ppm Pb, 457.1 ppm U and 450.6 ppm Th (Pearce
the analyses (X-ray fluorescence for major-elements and Zr, ICPMS et al., 1997). The following isotope ratios, determined by TIMS at
for trace elements, LA-ICPMS for U–Pb and TIMS for Sr–Nd isotopes the University of Granada, were also used: 204Pb/206Pb = 0.0611,
207
and Pb–Pb technique) have been performed at the Centro de Instru- Pb/206Pb = 0.9127, 208Pb/206Pb = 2.1898, 206Pb/238U = 0.2501,
208
mentación Científica (CIC) of the Granada University. Pb/232Th = 0.5402. The precision (1r) estimated on ten repli-
Whole-rock major-element and Zr determinations were done by cates of the NIST-610 analysed in the same run was better than
X-ray fluorescence after fusion with lithium tetraborate. Typical 2.5% for element ratios and 1.3% for isotope ratios. The U–Pb age
precision was better than ±1.5% for an analyte concentration of of each zircon population was estimated by averaging the 207-
10 wt.% and ±2.5% for 100 ppm Zr. Trace elements were determined corrected age of all LA-ICPMS determinations, and the errors are
in an Agilent-7500 inductively coupled plasma mass spectrometer reported at 95% of confidence level.
4
Table 1
U–Pb isotope data of the studied samples.
Table 2
Pb–Pb isotopic data of the studied samples.
204 207 207
Sample Analysis Pb/206 Pb/206 Pb/206 cor SE Age (ma) Error Ma
BARR-1 (1)-1 0.000689 0.063663 0.0537305 0.9 360 20
BARR-1 (1)-2 0.00026 0.057246 0.0535776 0.7 357 16
BARR-1 (1)-3 0.000263 0.057442 0.053731 0.5 360 11
BARR-1 (2)-1 0.002295 0.08728 0.0539009 0.26 367 6
BARR-1 (2)-2 0.0023318 0.0878965 0.053985 0.28 370 7
BARR-1 (5)-1 0.0016217 0.0773278 0.0537753 0.6 362 13
BARR-1 (5)-2 0.001864 0.080876 0.0537855 0.4 362 9
BARR-1 (5)-3 0.001956 0.082506 0.0540843 0.23 375 5
BARR-1 (5)-4 0.0020346 0.0833587 0.0537768 0.25 362 5
BARR-1 (5)-5 0.001005 0.068538 0.0539964 0.3 371 7
BARR-1 (5)-6 0.001054 0.069327 0.0540719 0.16 374 4
BARR-1 (10)-1 0.001171 0.070663 0.0536902 1.3 358 29
BARR-1 (11)-1 0.001603 0.117999 0.0960367 1 1548 19
BARR-1 (11)-2 0.000052 0.11926 0.1188514 0.27 1993 5
BARR-1 (11)-3 0.000037 0.12488 0.1246899 0.18 2024 3
BARR-1 (11)-4 0.000035 0.124615 0.1244507 0.21 2021 4
BARR-1 (11)-5 0.000037 0.123933 0.1237399 0.19 2011 3
BARR-1 (12)-1 0.000535 0.061606 0.0539251 0.7 368 16
BARR-1 (12)-2 0.000066 0.054908 0.0540753 0.6 374 13
BJE (2)-1 0.000644 0.071446 0.0622935 0.5 684 11
BJE (2)-2 0.000926 0.07521 0.0619778 0.28 673 6
BJE (2)-3 0.000859 0.074414 0.0621532 0.39 679 9
BJE (2)-4 0.000703 0.072083 0.0620749 0.25 677 5
BJE (2)-5 0.000773 0.073413 0.0623987 688 688 4
BJE (2)-6 0.000815 0.073981 0.0623594 0.28 686 6
BJE (3)-1 0.000017 0.060046 0.0599032 0.5 600 11
BJE (3)-2 0.000018 0.060536 0.0604215 0.6 619 13
BJE (3)-3 0.000015 0.060202 0.0601301 0.4 608 9
BJE (5)-1 0.0001795 0.0623773 0.0599221 0.2 601 4
BJE (5)-2 0.000163 0.062148 0.0599314 0.12 601 3
BJE (5)-3 0.000172 0.062254 0.0599069 0.11 600 2
BJE (5)-4 0.000172 0.06231 0.0599632 0.14 602 2
BJE (5)-5 0.000182 0.062594 0.0601031 0.16 607 4
BJE (5)-6 0.000117 0.061482 0.0599318 0.2 601 4
BJE (5)-7 0.000121 0.061752 0.0601449 0.16 609 4
TA (2)-1 0.000022 0.060455 0.0602822 0.3 614 6
TA (2)-2 0.000033 0.060634 0.0603019 0.42 614 9
TA (2)-3 0.000023 0.060622 0.0604351 0.29 619 6
TA (2)-4 0.000024 0.06028 0.0600776 0.4 606 8
TA (2)-5 0.000017 0.060064 0.0599627 0.5 606 11
TA (3)-1 9.00E06 0.060063 0.0600779 0.3 606 6
TA (3)-2 0.000011 0.06019 0.0601762 0.7 610 15
TA (3)-3 5.00E06 0.059888 0.0599606 0.2 602 4
TA (3)-4 4.00E06 0.059839 0.059926 0.29 601 6
TA (3)-5 6.00E06 0.0601 0.0601586 0.5 609 11
TA (5)-1 6.00E06 0.060092 0.0601506 0.27 609 6
TA (5)-2 6.00E06 0.060031 0.0600894 0.29 607 7
TA (4)-1 8.00E06 0.059929 0.059981 0.22 602 5
TA (4)-2 9.00E06 0.059975 0.0599897 0.18 603 4
TA (4)-3 1.00E05 0.06018 0.0601807 0.28 610 6
TA (4)-4 0.000011 0.060202 0.0601882 0.21 610 5
TA (4)-5 0.000011 0.060084 0.0600699 0.31 606 7
TA (6)-1 0.000012 0.06033 0.0603021 0.25 614 5
TA (6)-2 0.000013 0.060408 0.0603657 0.3 617 7
Single-zircon evaporation analyses (Kober, 1986, 1987) were hopping), using a secondary electron multiplier as detector with
performed using a SEM-RPQ multi-collector Finnigan Mat 262 the 206–204–206–207–208 mass sequence. The mass-ratio 204/
thermal ionization mass spectrometer with a double filament 206 was monitored to detect and, if necessary, correct for common
ion-source arrangement, operated with the RunIt262 SpectromatTM lead. Factors for common lead correction were calculated by itera-
software. The zircon grain was mounted on a canoe-shaped Re tion from the 204Pb/206Pb and 204Pb/207Pb ratios provided by the
evaporation filament and heated until the lead beam was intense model of Stacey and Kramers (1975) at the calculated age, until
enough (200–400 206Pb ions per second). The lead was collected convergence to a constant value. For 207/206 mass fractionation
on the ionization filament for 20–30 min, and then analyzed in five in the detector was corrected by multiplying the measure value
p
blocks with seven scans per block. Once the analysis was finished, a by (207/206). Standard errors for each step were calculated
p
new step was started by heating the zircon on the evaporation fil- according to the formula: SE = 2 r / n. The age is calculated at
ament at a higher temperature than in the previous step (usually the 95% confidence level for the mean of all steps.
increasing the current by 50–100 mA) and analyzing, as before,
the Pb deposited anew on the ionization filament. The procedure 5. Geochronology
was repeated until all the lead was exhausted from the zircon.
The number of steps depended on the size and lead content of each Three granitoid samples have been dated by U–Pb Laser Abla-
zircon. Data acquisition was performed in dynamic mode (peak tion-ICPMS and 207Pb–206Pb stepwise evaporation.
6 A. Tahiri et al. / Journal of African Earth Sciences 57 (2010) 1–13
The sample BARR-1 corresponds to a granite of the Rabat group, Wasserburg concordia diagram, these analyses are concordant or
collected southeast of Rabat (Fig. 1B and 2). Twenty three zircon subconcordant [(238U/206Pb age)/(235U/207Pb age) > 0.97] and yield
grains analyzed by U–Pb LA-ICPMS (Table 1) yielded a discordia a mean U–Pb age of 606 ± 6 Ma (Fig. 5A, Table 1). Another five zir-
clearly caused by common lead, with a lower intercept at cons were analyzed by the 207Pb–206Pb stepwise evaporation
367 ± 9 Ma. Plotted in a Tera–Wasserburg concordia diagram, method, thus obtaining 19 evaporation steps. All zircons yield a
these analysis yield an average 207-corrected age of 368.7 ± 8 Ma uniform age, with no inherited cores or restitic grains. The mean
(Fig. 3A). No other populations were detected by this method. Fur- of the 19 performed steps depict a precise plateau age of
thermore, six zircons were analyzed by the 207Pb–206Pb stepwise 609 ± 3 Ma (Fig. 5B, Table 2), identical within error margins to
evaporation method, yielding 19 evaporation steps. Fourteen of the U–Pb LA-ICPMS age, and therefore representing the crystalliza-
these steps, corresponding to five grains, define a very uniform pla- tion age of the TA granitoid.
teau age of 367 ± 3 Ma, while the remaining zircon has a restitic Summing up, our geochronological data determine that grani-
older core with an age of around 2000 Ma (Fig. 3B, Table 2). U– toids in the Rabat–Tiflet region belong to two very different age-
Pb and Pb–Pb data are perfectly consistent, thus pointing to a pre- groups, as suspected from field relationships. The Rabat granitoids
cise crystallization age of 367 Ma for this rock. in the Sehoul block seem to be part of a magmatic event aged
The sample BJE was collected southwest of Tiflet (Sidi Bou Je- around 367 Ma, i.e. Late Devonian. The Tiflet granitoids are 605–
maa granitoid; see Fig. 1B and 2 for location). Fourteen zircons 609 Ma old, i.e. Late Neoproterozoic. A few inherited zircon cores
were analyzed by U–Pb LA-ICPMS. Plotted in a Tera–Wasserburg of Palaeoproterozoic and Neoproterozoic ages (around 2000 Ma
concordia diagram, these analysis are concordant or subconcor- and 680 Ma) have been found too, suggesting that the basement
dant [(238U/206Pb age)/(235U/207Pb age) > 0.98] and yield a mean of the Moroccan Western Meseta consisted of Palaeoproterozoic
U–Pb age of 605 ± 4 Ma (Fig. 4A, Table 1). No other population crust.
was detected by this method. Additionally, three zircons were ana-
lyzed by the 207Pb–206Pb stepwise evaporation method, and
6. Geochemistry
yielded 16 evaporation steps. Ten of these steps, performed in
two zircons, were very uniform and define a plateau age of
Table 3 displays the analytical data of the granitoids studied.
605 ± 4 Ma, exactly matching the U–Pb age. The third zircon ana-
They range from mild silicic in Tiflet to highly silicic in the Rabat
lyzed was entirely restitic and provided six evaporations steps,
group. All samples are markedly peraluminous, with mol. Al2O3/
whose mean are 681 Ma (Fig. 4B, Table 2). Therefore, the age of
(Na2O + K2O + CaO) between 1.05 and 1.40 (Fig. 6A), though this
605 ± 4 Ma seems to correspond to the crystallization age of this
can be a feature influenced by hydrothermal alteration. Samples
rock.
with SiO2 < 75 have K2O P Na2O (Fig. 6B), except the sample RB-
The sample TA is from the Taïcha outcrop (Fig. 1B and 2). Thir-
8 which is anomalous in many aspects; the most silicic samples
teen zircons were analyzed by U–Pb LA-ICPMS. Plotted in a Tera–
tend to be predominantly sodian. In the modified alkali/lime plot
Fig. 3. Geochronological dating of the sample BARR-1. A: Tera–Wasserburg concordia plot from Laser Ablation-ICPMS. 368.7 Ma is the average 207-corrected age for 23
points; observed discordia seems to be caused by common Pb. See Fig. 2 for sample location and text for additional comments.
A. Tahiri et al. / Journal of African Earth Sciences 57 (2010) 1–13 7
Fig. 4. Geochronological dating of the sample BJE. A: Tera–Wasserburg concordia plot from Laser Ablation-ICPMS. B: 207Pb–206Pb stepwise evaporation. See Fig. 2 for sample
location and text for additional comments.
Fig. 5. Geochronological dating of the sample TA. A: Tera–Wasserburg concordia plot from Laser Ablation-ICPMS. B: 207Pb–206Pb stepwise evaporation. See Fig. 2 for sample
location and text for additional comments.
(Frost et al., 2001) most samples plot in the boundary between the sian while the Rabat ones, with the only exception of RB-8, are fer-
alkali-calcic and calc-alkalic fields (Fig. 6C), with no differences be- roan (Fig. 6D).
tween the Rabat and Tiflet granitoids. By contrast, in the FeOt/ In general, the samples studied have moderate contents of most
(FeOt + MgO) plot (Frost et al., 2001) the Tiflet samples are magne- trace elements, lacking the elevated Cs and Li contents characteris-
8
Table 3
Major element (%) and trace (ppm) composition of analyzed samples.
Sample ID BARR-1 BARR-2 BJE RB-1 RB-2 RB-3 RB-5 RB-6 RB-7 RB-8 RB-9 RB-11 R-12 TA TF-1 TF-2 TF-3 TF-4
SiO2 72.75 76.95 71.3 70.53 71.3 75.31 70.09 72.05 72.59 65.19 77.92 57.54 57.89 64.63 72.25 69.86 65.8 71.62
TiO2 0.44 0.05 0.26 0.45 0.5 0.12 0.62 0.14 0.13 0.52 0.03 0.89 0.68 0.66 0.37 0.26 0.61 0.32
Al2O3 12.87 14.04 14.57 13.84 14.22 13.64 14.07 14.25 14.26 17.37 12.94 17.71 18.02 16.39 13.98 15.21 16.24 15.22
Fe2O3 3.24 0.71 1.94 3.44 3.83 1.28 4.55 1.37 1.77 3.5 0.75 6.15 4.4 4.47 2.14 2.43 4.56 2.77
MnO 0.08 0.04 0.03 0.08 0.08 0.03 0.09 0.04 0.05 0.09 0.03 0.13 0.08 0.06 0.03 0.04 0.06 0.04
MgO 0.66 0.05 0.72 0.67 0.78 0.15 1.01 0.24 0.22 1.25 0.1 3.33 2.25 1.9 0.7 0.86 2.06 1.09
CaO 1.43 0.22 1.04 1.37 0.81 0.22 1.01 1.23 0.93 2.2 0.16 5.38 4.22 2.45 0.98 1.22 3.23 0.52
Na2O 2.67 3.77 3.59 3.29 3.41 4.53 2.13 3.49 3.2 6.44 3.07 5.01 8.09 3.37 3.43 4.17 2.61 3
K2O 3.72 3.13 4.49 3.97 3.91 3.32 4.66 5.23 4.86 1.33 3.91 0.9 0.17 3.3 4.04 3.69 2.74 4.63
P2O5 0.16 0.02 0.1 0.16 0.18 0.04 0.21 0.06 0.04 0.18 0.02 0.24 0.13 0.17 0.1 0.14 0.16 0.1
LOI 1.8 0.86 1.31 1.65 1.22 0.62 1.78 1.63 1.26 2.28 0.72 1.83 4.2 2.3 1.4 1.39 1.95 1.17
Li 31.2 7.4 21 28.2 28.2 6 43 7.4 7.6 17.7 4.8 25.5 16.2 48.5 22.1 25.9 51.8 21.9
Rb 106 94 133 117 146 64 213 107 108 37 96 12 2 89 134 130 82 141
Fig. 6. Plots displaying the main geochemical features of the Tiflet (squares: TA; crosses: TF) and Rabat (filled circles: RB) granitoids. Fig. 6B: line indicates Na2O = K2O. Fig. 6C:
A, alkalic field; A-C, alkali-calcic field; C-A, calc-alkalic field. Raw chemical data are tabulated in Table 1. See text for further explanations.
tic of S-type granites, as well as the enrichments in Ga and Nb con- Chondrite-normalized REE patterns of the Tiflet samples display
tents of typical A-type granites. The Rabat samples have Nb/Ta ra- an elevated LREE/HREE fractionation, with no (or very little) Eu
tios around the typical crustal value of 11 (Green, 1995), while the anomaly and almost flat patterns from Er to Lu (Fig. 7A). These fea-
Tiflet ones, especially those from Taicha, tend to higher values with tures are almost exclusive of subduction-related granites (Bea
an average of 16.3 (Fig. 6E), close to what Green (1995) considered et al., 1997), though melts from a crust formed itself at subduction
characteristic of mantle-derived magmas. The marked decrease in would have also such characteristics. By contrast, the chondrite-
Zr/Hf as Zr diminishes in the Rabat samples indicates that these normalized patterns of the Rabat granitoids are much more varied
samples likely crystallized from progressively differentiated mag- (Fig. 7B). Most of them have the negative Eu anomaly and moder-
mas (Fig. 6F). ate LREE/HREE fractionation, which is very common in crustal
10 A. Tahiri et al. / Journal of African Earth Sciences 57 (2010) 1–13
Fig. 8. Sr and Nd isotope correlations of the Tiflet (squares: TA; crosses: TF) and
Rabat (filled circles: RB) granitoids. See Table 2 for analytical data and text for
explanation. eNd(t) have been calculated for t = 367 Ma for RB samples and
t = 605 Ma for TA and TF samples.
Model Age
(DM). Ga
was a period of marine regression, likely the eustatic regression re-
lated to the well known Late Ordovician glaciation, whose effects
1.7
1.9
1.8
1.8
1.9
1.7
1.3
1.5
1.5
1.4
2
are observed in many other areas of the Variscan orogen. This time
might correspond to the formation of the erosional surface on top
Model Age
(Chur). Ga
1.3
1.2
1.4
1.2
1.2
1.1
1.3
0.5
0.7
0.8
0.7
the Upper Silurian to the Middle Devonian, overlies both the Lower
Ordovician rocks and the Neoproterozoic basement (Fig. 9C). This
e Nd(t)
11.5
7.6
9.1
5.8
7.6
1.5
7.8
3.3
8.3
3.6
2.6
7.6
9
9
rise subsequent to the Late Ordovician cooling, though the inclu-
sion of the Early Silurian in the stratigraphic hiatus suggests some
Nd/144Nd init
0.511396
0.511577
0.511391
0.511561
0.511399
0.511776
0.511769
0.511775
0.511992
0.511979
0.511778
0.512088
0.512033
0.51174
tic Caledonian Sehoul block and the Variscan Meseta took place,
initiating the deformation, uplift and coarse-grained syn-tectonic
143
155.1
61.8
47.1
78.7
113.6
115.6
160.2
96.7
103.3
99.6
197
69
60
100
0.714986
0.715349
0.717936
0.711342
0.708135
0.708642
0.709327
0.708294
0.710878
0.712066
0.712206
0.711108
0.711082
0.707101
Variscides
Nd Inst.
0.0016
0.0017
well with the features of the Sehoul thrust, which appears in the
field and in regional maps as an important structure and might
Nd/144Nd
0.51179
0.51239
0.51229
0.51226
0.51229
0.51228
0.51234
0.51204
0.51204
0.51205
0.51209
0.121
0.112
0.125
0.219
0.125
0.123
0.128
0.131
0.106
0.098
0.203
0.09
8.79
35.85
7.25
10.08
34.04
Sr and Nd parameters calculated for t = 367 Ma for samples RB and t = 605 Ma for samples TF.
4.4
0.72729
0.72114
0.71947
0.71366
0.73242
0.73571
0.71748
0.72995
0.71762
0.72138
0.72388
0.71909
0.70935
0.7153
3.402
0.502
1.063
0.203
0.807
530.84
84.91
176.17
311.06
107.06
173.2
the main Rheic suture being located between this block and the
Moroccan Mesetas (Fig. 10A). In other words, the thrust at the
southern border of the Sehoul block might be a late expression of
Rb (ppm)
125.56
111.75
130.13
82.26
212.58
95.64
106.64
37.17
63.71
that main Variscan suture (Fig. 10B). The Ordovician volcanic basic
141.2
134.3
108.5
116.8
146.1
RB-11
RB-10
TF-4
TF-1
TF-2
TF-3
Ref.
Fig. 9. Evolutionary sketch envisaged for the Rabat–Tiflet region, from (A) an early stage of rifting affecting the northern Meseta at Cambrian–Ordovician times to (D)
continental collision between the Sehoul block and the northern Meseta at Late Devonian–Early Carboniferous times.
Sehoul block and those in the adjacent Bou Regreg corridor. There-
fore, one previous assumption of a common Caledonian plutonism
in the Rabat and Tiflet areas, which would imply a trivial Variscan
entity for the Sehoul thrust, can be ruled out.
9. Conclusions
conflict is now avoided with the new ages provided here. In Hermes, O.D., Murray, D.P., 1988. Middle Devonian to Permian plutonism and
volcanism in the N American Appalachians. Geol. Soc. London Spec. Publ. 38,
fact, we suggest that the Sehoul thrust may be a main Vari-
559–571.
scan tectonic boundary hiding the Rheic Ocean suture. Hoepffener, Ch., Soulaimani, A., Piqué, A., 2005. The Moroccan Hercynides. J. Afr.
Earth Sci. 43, 144–165.
Hoepffener, Ch., Houari, M.R., Bouabdelli, M., 2006. Tectonics of the North African
Variscides (Morocco, western Algeria): an outline. C. R. Geoscience 338, 25–40.
Kober, B., 1986. Whole-grain evaporation for 207Pb/206Pb-age investigations on
Acknowledgements single zircons using a double filament thermal ionization source. Contrib.
Mineral. Petrol. 93, 482–490.
We thank J.P. Liegeois, B. Thomas and an anonymous referee for Kober, B., 1987. Single-zircon evaporation combined with Pb+ emitter-bedding for
207Pb/206Pb age investigations using thermal ion mass spectrometry and
in-depth reviews of our paper, thus contributing to improve its sci- implications to zirconology. Contrib. Mineral. Petrol. 96, 63–71.
entific quality. This research has been supported by the Académie Lecointre, G., 1931. Les terrains paleozoïque de Sehoul et des Zemmour (Maroc
Hassan II des Sciences et Techniques, the Agencia Española de occidental). C. R. Somm. Soc. géol. France 3, 35–37.
Matte, Ph., 2001. The Variscan collage and orogeny (480–290 Ma) and the tectonic
Cooperación Internacional (A/4938/06) and the Spanish Ministry definition of the Armorica microplate: a review. Terra Nova 13, 122–128.
of Education and Science (CGL2007-63101/BTE, TOPO-IBERIA CON- Michard, A., Hoepffner, C., Soulaimani, A., Baidder, L., 2008. The Variscan belt. In:
SOLIDER-INGENIO 2010 CSD2006-00041). Michard, A., Saddiqui, O., Chalouan, A., Frizon de Lamotte, D. (Eds.), Continental
Evolution: The Geology of Morocco. Springer.
Montero, P., Bea, F., 1998. Accurate determination of 87Rb/86Sr and 143Sm/144Nd
ratios by inductively-coupled-plasma mass spectrometry in isotope geoscience.
References an alternative to isotope dilution analysis. Anal. Chim. Acta 358, 227–233.
Murphy, J.B., Keppie, J.D., 2005. The Acadian orogeny in the Northern Appalachians.
Bea, F., Fershtater, G., Montero, P., Smirnov, V., Zinkova, E.y., 1997. Generation and Int. Geol. Rev. 47, 663–687.
evolution of subduction-related batholiths from the central Urals: constraints Nysther, E., Torsvik, T.H., Feist, R., Walderhaug, H.J., Eide, E.A., 2002. Ordovician
on the P-T history of the Uralian orogen. Tectonophysics 276, 103–116. palaeogeography with new palaeomagnetic data from the Montagne Noire
Bouabdelli, M., Piqué, A., 1996. Du bassin sur décrochement au bassin d́avant pays: (Southern France). Earth Planet. Sci. Lett. 203, 329–341.
dynamique du bassin d́Azrou–Khénifra (Maroc hercynien central). J. Afr. Earth Pearce, N.J.G., Perkins, W.T., Westgate, J.A., Gorton, M.P., Jackson, S.E., Neal, C.R.,
Sci. 22, 213–224. et al., 1997. A compilation of new and published major and trace element data
Buchwaldt, R., Kröner, A., Feely, M., Toulkeridis, Th., 2001. Geochronology and Nd– for NIST SRM 610 and NIST SRM 612 glass reference materials. Geostandards
Sr systematics of Late Caledonian granites in Western Ireland: new implication Newslett. 21, 115–144.
for the Caledonian orogeny. Abstract at the GSA Northeastern Section – 36th Piqué, A., 1984. Faciès sédimentaire et évolution d́un bassin: le bassin dévono-
Annual Meeting, Burlington, Vermon. dinantien de Sidi Bettache (Maroc nord-occidental). Bull. Soc. géol. France 6,
Charlot, R., Rhalib, M., Tisserant, D., 1973. Etude géochronologique préliminaire des 1015–1024.
granites de la région de Rabat–Tiflet (Maroc occidental). Notes et Mém. Serv. Piqué, A., 1989. Variscan terranes in Morocco. Geol. Soc. Am. Spec. Paper 230, 115–
géol. Maroc 249, 55–58. 129.
El Hadi, H., Simancas, J.F., Tahiri, A., González Lodeiro, F., Azor, A., Martínez Poyatos, Piqué, A., 1994. Géologie du Maroc. Les domaines régionaux et leur évolution
D., 2006. Magmatic zonation of the Variscan orogen. A comparison between the structurale. Edition Pumag. Marrakech, 284 p.
granitoids of Morocco and Iberia. Geodin. Acta 19, 103–116. Piqué, A., Michard, A., 1989. Moroccan Hercynides: a synopsis. The Paleozoic
El Hassani, A., 1991. La zone de Rabat – Tiflet. Bordure Nord de la chaine calédono- sedimentary and tectonic evolution at the northern margin of West Africa. Am.
hercynienne du Maroc. Bull. Inst. Sci. Rabat 15, 1–134. J. Sci. 289, 286–330.
Frost, B.R., Barnes, C.G., Collins, W.J., Arculus, R.J., Ellis, D.J., Frost, C.D., 2001. A Simancas, J.F., Carbonell, R., González Lodeiro, F., Pérez Estaún, A., Juhlin, C., Ayarza,
geochemical classification for granitic rocks. J. Petrol. 42, 2033–2048. P., Kashubin, A., Azor, A., Martínez Poyatos, D., Almodóvar, G.R., Pascual, E., Sáez,
García, C., 1961. Roches éruptives et métamorphiques de la région de Rabat. R., Expósito, I., 2003. The crustal structure of the transpressional Variscan
Travaux Inst. Sci. Chérif, série Géol. et Géogr. Phys. 12, 42. orogen of SW Iberia: The IBERSEIS deep seismic reflection profile. Tectonics 22
Govindaraju, K., Potts, P.J., Webb, P.C., Watson, J.S., 1994. 1994 Report on Whin Sill (6), 1062. doi:10.1029/2002TC001479.
Dolerite WS-E from England and Pitscurrie Micrograbbro PM-S from Scotland: Simancas, J.F., Tahiri, A., Azor, A., González Lodeiro, F., Martínez Poyatos, D., El Hadi,
assessment by one hundred and four international laboratories. Geostandards H., 2005. The tectonic frame of the Variscan–Alleghanian orogen in Southern
Newslett. 2 (2), 211–300. Europe and Northern Africa. Tectonophysics 398, 181–198.
Green, T.H., 1995. Significance of Nb/Ta as an indicator of geochemical processes in Stacey, J.S., Kramers, J.D., 1975. Approximation of terrestrial lead isotope evolution
the crust-mantle system. Chem. Geol. 120, 347–359. by a two-stage model. Earth Planet. Sci. Lett. 26, 207–221.