SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name Cleartron® ZB-628

1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use Water Clarifier

1.3 Details of the supplier of the safety data sheet

Company : Champion Technologies
Minto Avenue
Altens Industrial Estate
Aberdeen, UK AB12 3JZ
Telephone : 00 44 1224 879022 (Champion)
Telefax :
E-mail address : eh.productstewardship@champ-tech.com
Responsible/issuing person

1.4 Emergency telephone number

00 44 1224 879022

2. Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4 H302: Harmful if swallowed.
Specific target organ toxicity - repeated H373: May cause damage to organs through
exposure, Category 2 prolonged or repeated exposure.

Classification (67/548/EEC, 1999/45/EC)

Harmful. R22: Harmful if swallowed.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :

Signal word : Warning

Hazard statements : H302 Harmful if swallowed.

H373 May cause damage to organs through prolonged
or repeated exposure.

Precautionary statements : Prevention:

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/
spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this
product.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTER or

1 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

doctor/ physician if you feel unwell.

P314 Get medical advice/ attention if you feel unwell.
Disposal:
P501 Dispose of contents/ container to an approved
waste disposal plant.

Hazardous components which must be listed on the label:

ethanediol

2.3 Other hazards

Not Classified as PBT/vPvB by current EU criteria.

3. Composition/information on ingredients
3.2 Mixtures
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (REGULATION (67/548/EEC) [%]
REACH (EC) No
Registration 1272/2008)
Number
ethanediol 107-21-1 Acute Tox. 4; Xn; R22 >= 30 - < 60
203-473-3 H302
01- STOT RE 2; H373
2119456816-
28

For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.

4. First aid measures

4.1 Description of first aid measures
If inhaled : Remove to fresh air.
Oxygen or artificial respiration if needed.
If symptoms persist, call a physician.

In case of skin contact : In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes.

In case of eye contact : Immediately flush eyes for at least 15 minutes. Get medical
attention.
Remove contact lenses.

If swallowed : Never give anything by mouth to an unconscious person.

Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
Obtain medical attention.

4.2 Most important symptoms and effects, both acute and delayed
Risks : If you feel unwell, seek medical advice (show the label where
possible).

4.3 Indication of any immediate medical attention and special treatment needed

2 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

Treatment : No recommendation given, but first aid may still be required in

case of accidental exposure, inhalation or ingestion of this
chemical. If in doubt, GET MEDICAL ATTENTION
PROMPTLY!

5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Aqueous film forming foam (AFFF).

5.2 Special hazards arising from the substance or mixture

Hazardous decomposition : No hazardous decomposition products are known.
products

5.3 Advice for firefighters

Special protective equipment : Use personal protective equipment.
for firefighters In the event of fire, wear self-contained breathing apparatus.

Further information : In the event of fire and/or explosion do not breathe fumes.
Stay upwind/ keep distance from source. Use water spray to
cool unopened containers. Do not allow run-off from fire
fighting to enter drains or water courses.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions : Refer to protective measures listed in sections 7 and 8.
Ensure adequate ventilation.
Use the indicated respiratory protection if the occupational
exposure limit is exceeded and/or in case of product release
(dust).
Avoid inhalation, ingestion and contact with skin and eyes.

6.2 Environmental precautions

Environmental precautions : Do not allow contact with soil, surface or ground water.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up
: Stop leak if safe to do so.
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
Pick up and transfer to properly labelled containers.
Do not flush into surface water or sanitary sewer system.

6.4 Reference to other sections

For personal protection see section 8.
See section 13 for waste disposal information.

3 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

7. Handling and storage

7.1 Precautions for safe handling
Advice on safe handling
: Avoid inhalation, ingestion and contact with skin and eyes.
Use only with adequate ventilation/personal protection.
In case of insufficient ventilation, wear suitable respiratory
equipment.
Ensure that eyewash stations and safety showers are close to
the workstation location.
Smoking, eating and drinking should be prohibited in the
application area.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep container tightly closed in a dry and well-ventilated
areas and containers place.

7.3 Specific end use(s)

The identified uses of this product are detailed in section 1.2

8. Exposure controls/personal protection

8.1 Control parameters
Value Control
Components CAS-No. Update Basis
type parameters
ethanediol 107-21-1 TWA 20 ppm 2000-06-16 2000/39/EC

52 mg/m3

Further skin: Identifies the possibility of significant uptake through the skin Indicative
information:
STEL 40 ppm 2000-06-16 2000/39/EC

104 mg/m3

Further skin: Identifies the possibility of significant uptake through the skin Indicative
information:
TWA 20 ppm 2011-12-01 GB EH40

52 mg/m3

Further Sk: Can be absorbed through skin. The assigned substances are those for
information: which there are concerns that dermal absorption will lead to systemic toxicity.
TWA 2011-12-01 GB EH40

10 mg/m3

Further Sk: Can be absorbed through skin. The assigned substances are those for
information: which there are concerns that dermal absorption will lead to systemic toxicity.
STEL 40 ppm 2011-12-01 GB EH40

104 mg/m3

Further Sk: Can be absorbed through skin. The assigned substances are those for
information: which there are concerns that dermal absorption will lead to systemic toxicity.

4 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

DNEL
ethanediol : End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term exposure, Systemic effects
Value: 106 mg/kg bw/day

End Use: Workers

Exposure routes: Inhalation.
Potential health effects: Long-term exposure, Local effects
Value: 35 mg/m3

PNEC
ethanediol : Fresh water
Value: 10 mg/l

Marine water
Value: 1 mg/l

Intermittent use/release
Value: 10 mg/l

Sewage Treatment Plant

Value: 199.5 mg/l

Fresh water sediment

Value: 20.9 mg/kg

Soil
Value: 1.53 mg/kg

8.2 Exposure controls

Engineering measures
Effective exhaust ventilation system

Personal protective equipment

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
Respirator with filter for organic vapour

Hand protection : Wear protective gloves.

Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local
conditions under which the product is used, such as the
danger of cuts, abrasion, and the contact time.
Breakthrough time is not determined for the product. Change
gloves often!
Use a high fat protective cream after cleaning skin.

Eye protection : Safety glasses with side-shields.

Safety goggles.

Skin and body protection : Protective suit.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Wash hands before breaks and at the end of workday.

5 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

Wash hands before eating, drinking, or smoking.

Handle in accordance with good industrial hygiene and safety
practice.

Environmental exposure controls

General advice : Do not allow contact with soil, surface or ground water.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance : liquid

Colour
Odour
Odour Threshold
pH
Melting point
Boiling point
Flash point
Evapouration rate
Flammability (solid, gas)
Lower explosion limit
Upper explosion limit
Vapour pressure
Relative vapour density
Relative density
Solubility (qualitative)
Partition coefficient: n-
octanol/water
Auto-ignition temperature
Thermal decomposition
Viscosity, dynamic
Viscosity, kinematic
Explosive properties
Oxidizing properties
: white
: acrylic-like
: not determined
: 2.5 - 4.5, (1 - 10% in deionized water)
: Measured as pour point
: 100 °C, Based on solvent
: > 100 °C, Not applicable.
: < 0.01, n- butyl acetate = 1, Based on solvent
: not determined
: 3.2 %(V), Based on solvent
: 15.3 %(V), Based on solvent
: < 23 hPa, Based on solvent
: > 2.1, (Air = 1.0), Based on solvent
: 1.054 - 1.084, 20 °C
: Soluble in:, Water
: not determined
: not determined
: not determined
: < 300 mPa.s, 20 °C
: ca. 189 mm2/s, 40 °C
: not determined
: not determined

9.2 Other information

Pour point : < -15 °C

10. Stability and reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.

6 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

10.2 Chemical stability

Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Not relevant

10.4 Conditions to avoid

Conditions to avoid : Oxidizing agents

10.5 Incompatible materials

Materials to avoid : Strong acids.
Strong bases.
Strong oxidizing agents.

10.6 Hazardous decomposition products

Hazardous decomposition : No hazardous decomposition products are known.
products

11. Toxicological information

11.1 Information on toxicological effects
Product
Acute oral toxicity : Acute toxicity estimate: 1,572 mg/kg, Calculation method
Further information : no data available

Components:
ethanediol :
Acute oral toxicity : LD50: 4,700 mg/kg, rat
: LD50: 5,500 mg/kg, mouse
: LD50: 6,610 mg/kg, guinea pig
: Acute toxicity estimate: 500 mg/kg, Converted acute toxicity
point estimate

12. Ecological information

12.1 Toxicity
Product:
Toxicity to fish : no data available

12.2 Persistence and degradability

Product:
Biodegradability : no data available
Physico-chemical : no data available
removability

12.3 Bioaccumulative potential

Product:
Bioaccumulation : no data available

12.4 Mobility in soil

7 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

no data available

12.5 Results of PBT and vPvB assessment

Not Classified as PBT/vPvB by current EU criteria.
12.6 Other adverse effects
Product:
Additional ecological : not applicable
information

13. Disposal considerations

13.1 Waste treatment methods
Product
: Where possible recycling is preferred to disposal or
incineration.
If recycling is not practicable, dispose of in compliance with
local regulations.
Waste codes should be assigned by the user, preferably in
discussion with the waste disposal authorities.

14. Transport information

14.1 UN number
ADR
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
14.2 Proper shipping name
ADR
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
14.3 Transport hazard class
ADR
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
14.4 Packing group

8 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

ADR
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
14.5 Environmental hazards
ADR
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
14.6 Special precautions for user
Not relevant
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
This material may require an IBC code if carried according to the “International Code for the Construction
and Equipment of Ships Carrying Dangerous Chemicals in BuIk. Please contact Champion Technologies
Product Stewardship Team if you need further information.
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Notification status
DSL : All components of this product are on the Canadian DSL.
AICS : On the inventory, or in compliance with the inventory
NZIoC : On the inventory, or in compliance with the inventory

EU. REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT of 16 December 2008 on

classification, labelling and packaging of substances and mixtures

REGULATION (EC) No 1907/2006 of the European Parliament and of the Council concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). Annex IV: Exemptions
from the obligation to register

15.2 Chemical Safety Assessment

No chemical safety assessment has been carried out.

16. Other information

Full text of R-phrases referred to under sections 2 and 3
R22 Harmful if swallowed.

Full text of H-Statements referred to under sections 2 and 3.

H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportat ion, disposal and release and is not
9 / 10
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

Cleartron® ZB-628
Ver: 2.0 Revision Date: 24.12.2014 Print Date 01.04.2015

to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

10 / 10