Professional Documents
Culture Documents
CONTENTS
CONTENTS PAGE 1
PREFACE PAGE 3
LESSON PLAN
English competence is important to master. By having English competence, one can take many
advantages in this global era because English is regarded as a means of international communication.
Also for students of Diploma three program in rubber and plastic manufacture., English competence
needs to be mastered to support their academic and future career. English competence may help
students access information and survive in an English-speaking environment later. This module is created
for students of Diploma III program in rubber and plastic manufacture. It aims to assist them in
developing their English competence.
The module provides students the four English language skills including listening, speaking,
reading and writing. It comprises of 13 sessions. In each session, there are various activities that the
students can do individually or with other students. These activities aim to explore the students’
creativity in using the language. The students are expected to be skillful at doing the exercises, acting out
the dialogues, constructing sentences or texts and the other activities that facilitate them in using English
in communication both in the forms of oral and written.
Last but not least, the writers are very grateful to all people who have helped and given their
input, support and encouragement. Hopefully, this module will help the students of Diploma III program
in rubber and plastic manufacture learn English and achieve good English competence.
The writer
Working with a partner, make a list of five types of arrangement you would make on the phone.
Example: Dinner plans
1.
2.
3.
4.
5.
PRESENT TENSE
Use the Simple Present to express the idea that an action is repeated or usual. The action can be a habit, a hobby,
a daily event, a scheduled event or something that often happens. It can also be something a person often forgets
or usually does not do.
Positive Negative
S+V1 (s/es) /TOBE +Complement (Adj./Adv./N) S+ do/does/TOBE not + V1 +Complement
(Adj./Adv./N)
Example:
1. You speak English. Example:
2. The train leaves every morning at 8 AM. 1. You do not speak English.
3. Jakarta is the capital of Indonesia. 2. The train does not leave every morning at 8
AM.
3. Jakarta is not the capital of Indonesia.
Interrogatives WH-Question and Interrogatives
Do/does/TOBE +S+ V1 WH+ do/does/TOBE +S+ V1
+Complement (Adj./Adv./N) +Complement (Adj./Adv./N)
Example: Example:
1. Do you speak English? 1. What language do you speak?
2. Does the train leave every morning at 8 AM? 2. What time does the train leave every
3. Is Jakarta the capital of Indonesia? morning?
3. What is the capital of Indonesia?
Hi everyone! My full name ……… (1. To be) Rahmat Hermawan and this ……. (2. Be) about my family
activity. At 4.30 a.m., my mother always …….. (3. Wake) me up to pray. Then, I...........(4. Clean) myself to pray and
after that, I …… (5. Go) to bathroom for taking a shower. At 5.00 a.m., I.............(6. Wearing) my uniform and my
mother ………. (7. Cook) for my breakfast. My mother does not...........(8. Cook) noodles for my breakfast. Before I
leave my home, I ………. (9. Prepared) my book into my bag and my father................(10. Driven) a car to deliver me
to my school. At 6:30, my father and I ………… (11. Arriving) at my school and he..............(12. Go) to his office
directly after say goodbye with me. Every Monday, i ………. (13. Follow) the flag ceremony at school yard until 7.15
a.m. On Monday, class start at 7.30 a.m. but, on the others day, the class...........(14. Does) not start at 7:15 a.m. At
12:00 a.m., I.............(15. Has) lunch and I always eat together with my friends. At 15.00 p.m., my friends and i
……….. (16. Go) home by bus. After school on Friday, my friends and I always..........(17. Playing) football in soccer
field and we ……….. (18. Goes) home at 17.00 p.m. My mother always ask me about my homework and she ………
(19. Do not) ……… (20. Tolerates) if I postpone my homework. After i ……… (21. Took) a shower, I always............(22.
Doing) my homework. At 7 p.m., my family and I ……. (23. Has) dinner and sometimes we...........(24. Watched)
movies in our home. I usually ………. (25. Studied) from 10.00 p.m. until 11.00 p.m. After that, I always...........(26.
Sleeps) at 11:00 p.m. Do you ………. (27. Sleeping) before midnight everyday? My mother’s and father’s name …….
(28. Be) Sheryl and Dodo. My mother ……. (29. Be) a dentist and my father.........(30. Be) a petroleum engineer at
Pertamina. They ………. (31. Be) 50 years old and they.................(32. Does not) smoke at all. My mother and my
father ………… (33. Do not) work on Sunday and on holiday, sometimes, they always..............(34. Brings) me to
travel around Indonesia by plane. My mother hobby is cooking and she............(35. Does not) like watch a movie
while my father..............(36. Watch) a movie twice a week in our home. Although their hobby and their job is
different, but they always support each other. I..............(37. Loves) them very much
1. Is
2. Is
3. Wakes
4. Clean
5. Go
6. Wear
7. Cooks
8. Cook
9. Prepare
10. Drives
11. Arrive
12. Goes
13. Follow
14. Does
15. Have
16. Go
17. Play
18. Go
19. Does not
20. Tolerate
21. Take
22. Do
23. Have
24. Watch
25. Study
26. Sleep
27. Sleep
28. Are
29. Is
30. Is
31. Are
32. Do not
33. Do not
34. Bring
35. Does not
36. Watches
37. Love
Example :
Nia went to Jogjakarta with my friends last week
Negative
S + did + not + Verb 1 + C
or
S + To Be (Was / Were) + not + C
Example :
Rio did not come to school yesterday because he was sick
Interrogarives
Did + S + Verb 1 + C
or
Was / Were + S + C
Example :
Did they do the Math exam two days ago?
1. 6. Name :
Name :
Place : Place :
2. Name : 7. Name :
Place : Place :
3. 8. Name :
Name :
Place : Place :
4. Name : 9. Name :
Place : Place :
For example: We cannot go to Julia’s party because we are going away that weekend.
So..........that........
For example: The meteor storm was so beautiful that we watched it all night.
Such........that........
For example: It was such a beautiful meteor storm that we watched it all night.
Read at the following telephone conversation between two friends. Fill in the missing blanks with be + going
to or will/won’t. Then practice the dialogue with a partner. There may be more than one correct answer.
A: Hey, you finally answered your phone! What are you (1) do tonight?
B: I’m sorry. I was studying before. I have a test tomorrow, so I (2) probably stay home and
study.
A: Are you kidding? It’s Friday. A group of us (3) go out for dinner and drinks. Everyone (4)
be there. You should come!
B: What time are you going to meet everyone?
A: We (5) meet at the station at 9 p.m.
B: Hmm, OK. Maybe I (6) study until
8:30, and then (7) come to meet you.
A: Great! We (8) wait for you in the bookstore beside the station. The
station (9) be busy!
B: OK. I (10) see you in the bookstore at 9 p.m.
Write and practice making and declining invitation in dialogue, see example above!
Reading Articles
Read and study the following article.
WHAT IS RUBBER?
Rubber is a polymer with the property of elasticity. There are two categories of rubber: natural rubber currently
obtained from the rubber trees, or Hevea brasiliensis; and synthetic rubber derived from petrochemicals. The tire
industry consumes about two-thirds of natural rubber produced globally. Natural rubber is also used to make
gloves, condoms and thousands of other products for industries such as transport, construction, health, mining
and weapons. The Russian dandelion, or Taraxacum kok-saghyz (TKS), is a type of dandelion native to Kazakhstan
that can grow on marginal soil in temperate world regions. Its taproot produces a milky fluid, which is similar to
the fluid taken from the bark of the rubber tree.Guayule, a desert shrub native to the southwest United States and
Mexico, is also being explored as an alternative source in dry regions of the world
The rubber industry in Europe really started with Charles Macintosh in 1818. Many had sought suitable solvents
for rubber since its arrival in Europe as a raw material in the late 1700s, but none had been successful. Charles
Macintosh was an industrial chemist in Glasgow, then a major centre of the chemical industry, and was eager to
exploit the waste products of the new coal gasification process. James Syme, a medical student, found that coal
tar naphtha was a good solvent for rubber and so Macintosh’s specific skill came in exploiting the naphtha-based
rubber solution as a waterproofing layer between 2 fabrics. Hence the ‘macintosh’ was born. Only 2 years later, in
1820, Thomas Hancock discovered mastication. Hancock was using rubber in elastic fastenings for gloves, shoes
and stockings. These ‘garters’ were made by cutting strips from ‘bottles’ of pure rubber, and led to much waste.
Hancock noticed that fresh cut edges of rubber would unite perfectly and it occurred to him that if such pieces
were minced up very small, the amount of fresh cut edges would be greatly increased and with heat and pressure
might unite sufficiently for some purposes. So was developed Hancock’s famous ‘Pickle’ or wooden masticator. He
found that the effort to shred the rubber did not decrease with time, but increased, and when opened a
homogeneous roll of rubber was found. He used his ‘pickle’ to supply the Macintosh factory, and kept his
mastication process secret until he was forced to patent in 1837.
Adapted from:
http://inventors.about.com/cs/inventorsalphabet/a/rubber_2.htm
http://www.thestar.com.my/Business/Business-News/2014/08/21/What-is-rubber-and-what-is-it-used- for/?
style=biz
After reading the articles above, write down ten questions accordingly!
USING CONDITIONAL IF
The Second Conditional
Complete the sentences below by matching the if clauses to the correct main clauses.
If Clause Main Clause
If I had more money, a. we’ll catch the first train.
If the weather was better, b. my friends will be very happy for me.
If you worked harder, c. I wouldn’t need my coat.
If he is on time, d. I would lose weight.
If Kate goes out with me, e. I would buy a house in London.
If I ate less, f. you would get better grades.
Complete the following sentences with your own ideas. Then compare your answers with a partner.
Example: If I were rich, I would live in a huge house on top of a mountain.
1. If I saw somebody cheating on a test, _ .
2. If my parents asked me to stop eating chocolate, .
3. If my friend gave me a puppy for my birthday, .
4. If I didn’t like your friend’s new boyfriend/girlfriend, .
5. If my friend invited me to dinner, .
6. If a store gave me too much change, .
7. If your parents asked you move to another country, .
8. Your own idea: .
Now choose the 3 most interesting things you learned about your partner, and present them to the class.
Example: If my partner were rich, he/she would live in a huge house on top of a mountain.
1. If my partner ,
he/she .
2. If my partner ,
he/she .
3. If my partner ,
he/she .
Now take turns asking your partner what he or she would do.
Example: A: What would you do if your company asked you to work in Mexico?
B: I would buy a house there.
What would you do if .
He/she would .
What would you do if .
He/she would .
A Simple C.V.
When applying for a job, it is important that you have a good C.V. (curriculum vitae) or résumé. Place the
following information into the correct places on the C.V. below.
Where will you be? Use the following phrases to make questions to ask your partner. Then write down
their answers to complete the table.
Example: Q: Where will you be at 10 tonight?
A: I’ll probably be at home watching TV.
JOB INTERVIEW
Working with a partner, list three things you should do and three things you should never do in an interview.
With your partner, discuss one item from each column above. Why is it important to do or not to do that
thing? Write your answers in the space provided blow.
Example: You should not
You should
because
You should not
because
Job Skills
Match the following job skills to the pictures of jobs below.
Skills
a. Running meetings and organizing a team
b. Drawing diagrams of buildings and structures
c. Caring for people and making sure they are healthy
d. Speaking in public and solving legal problems
e. Answering calls and welcoming guests
f. Listening to people and taking their orders
Listen to the dialogue, and then answer the following questions. (U4-T15)
1. Where are the speakers going?
Job Interviews
In small groups, make a list of the job skills required to do the following jobs.
Secretary take messages, change appointments
Computer technician
Fashion designer
English teacher
Chef
CEO
Study the column above and then choose the BEST ending to the following statements.
1. Before the interview, you should .
a. read about the company and its products b. read about your own company
c. read the newspaper d. read about the interviewer
2. To appear confident, you should .
a. arrive late for the interview
b. arrive on time for the interview
c. maintain eye contact with the interviewer
d. sit up straight
3. You should try to be .
a. negative about previous employers
b. positive about previous employers
c. relevant to the latest news
d. really loud
4. Employers expect you to be .
a. relaxed b. scared c. on time d. late
Read the dialogue with a partner and choose the BEST responses to Ms. Smith’s questions.
Interviewer: Good morning. I am Ms. Smith.
1. Interviewee:
a. Pleased to meet you, Ms. Smith. I am Marcus Anderson.
b. I am Marcus Anderson.
c. Are you interviewing me?
Interviewer: Nice to meet you, too. Now you are here to apply for a job on one of our sales teams, is that
correct?
2. Interviewee:
a. Yes, it is.
b. I want a job.
c. Yes, it is. When I saw the ad, I was very excited to work for your company.
Interviewer: Good, that means you know what you can expect if you come and work here. Have you
got any questions you’d like to ask me?
6. Interviewee:
a. Not really.
b. How much do you earn?
c. What is the standard dress code?
Culture Clash
Business is international, but people from different countries have different taboos. Before doing business with
someone from overseas, you should try to learn a little about their country. This can save you a lot of
embarrassment. Here are a few tips to help get you started.
In groups of 3–4 students, discuss the tips above. Now think of three customs in your local area.
1.
2.
3.
Introductions
Listen to the extract and answer the following questions.
(Listening U3-T13)
1. What should all introductions start with?
READING ARTICLES
Read the following article.
What is a Polymer?
Polymers are made up of many molecules all strung together to form really long chains (and sometimes more
complicated structures, too).
What makes polymers so fun is that how they act depends on what kinds of molecules they're made up of and
how they're put together. The properties of anything made out of polymers really reflect what's going on at the
ultra-tiny (molecular) level. So, things that are made of polymers look, feel, and act depending on how their
atoms and molecules are connected, as well as which ones we use to begin with! Some are rubbery, like a
bouncy ball, some are sticky and gooey, and some are hard and tough, like a skateboard.
Poly- means "many" and -mer means "part" or "segment". Mono means "one". So, monomers are those itty
bitty molecules that can join together to make a long polymer chain.
After reading the text above, now translate the sentences into Bahasa.
1. Polymers are made up of many molecules all strung together to form really long chains (and sometimes
more complicated structures, too).
............................................................................................................................. ..............................
..............................................................................................................................................................................
............................................................................................................................. ...........
2. What makes polymers so fun is that how they act depends on what kinds of molecules they're made up of
and how they're put together.
...........................................................................................................................................................
............................................................................................................................. ..............................
3. The properties of anything made out of polymers really reflect what's going on at the ultra-tiny (molecular)
level
...........................................................................................................................................................
...........................................................................................................................................................
...........................................................................................................................................................
4. So, things that are made of polymers look, feel, and act depending on how their atoms and molecules are
connected, as well as which ones we use to begin with!
...........................................................................................................................................................
............................................................................................................................. ...........................
5. Some are rubbery, like a bouncy ball, some are sticky and gooey, and some are hard and tough, like a
skateboard.
............................................................................................................................. ..............................
............................................................................................................................. ..............................
6. Poly- means "many" and -mer means "part" or "segment". Mono means "one". So, monomers are those itty
bitty molecules that can join together to make a long polymer chain.
............................................................................................................................. ..............................
...........................................................................................................................................................
...........................................................................................................................................................
4. Always use paraphrase when writing a summary. If you do copy a phrase from the
original be sure it is a very important phrase that is necessary and cannot be
paraphrased. In this case put "quotation marks" around the phrase.
5. Target your first draft for approximately 1/4 the length of the original.
1. Start your summary with a clear identification of the type of work, title,
author, and main point in the present tense.
Example: In the feature article "Four Kinds of Reading," the author, Donald Hall,
explains his opinion about different types of reading.
2. Check with your outline and your original to make sure you have covered
the important points.
3. Never put any of your own ideas, opinions, or interpretations into the summary.
This means you have to be very careful of your word choice.
4. Write using "summarizing language." Periodically remind your reader that this
is a summary by using phrases such as the article claims, the author suggests, etc.
From: http://public.wsu.edu/~mejia/Summary.htm
Yoder, J. D., Hogue, M. Newman, R., Metz, L. & LaVigne, T. (2003). Exploring moderators of gender differences:
Contextual differences in door-holding behavior. Journal of Applied Social Psychology, 32, 1682-1686.
The social roles theory suggests that social contexts have different gender role expectations and those gender
role expectations can maximize or minimize gender differences. For instance, there are three competing
hypotheses as to why and in what situations certain people hold doors for others. The gender neutral stance
hypothesizes an equal amount of door holding would consistently be done by both sexes for both sexes. Chivalry is
associated with male roles and is another hypothesis that predicts that men hold doors open for women as an act
of helpfulness. Yet another stance looks at male dominance and how it is expressed in door holding behavior. This
stance adds to the social role theory hypothesizing that door holding behaviors will be different depending on the
emphasis on gender roles in the social context. The research done by Yoder, Hogue, Newman, Metz and LaVigne
(2003) looks at door holding behavior in a dating situation as opposed to everyday life situations, predicting that
males will hold open doors more often during a dating situation than in an everyday life situation. Seven hundred
and sixty-nine mixed-gender, college-age, male-female pairs were unobtrusively observed in 16 different
locations. The locations selected were places where either dating or non-dating couples were most likely to be
found. These locations included shopping malls, universities and fast-good restaurants, for non-dating couples,
and sit down restaurants and skate rinks, for dating couples. The amount of door holding for the other, either
male of female, was measured. In an everyday context 55.2% more women, in the couples observed, held the
door open for men than men did for women. In a dating context the reverse was found, 66.8% more men, in the
couples observed, held the door open for women than women held the door open for men. This study contradicts
studies done about 20 years ago, which suggests that door holding practices and gender roles have changed
somewhat over the years in everyday life scenarios but remain similar in dating scenarios. Applying these results
to the social role theory also suggests that door holding behavior may be different in dating versus everyday life
scenarios because gender roles are more prominent in dating scenarios.
From: http://courses.washington.edu/psy209/2003Door1.html
When giving a presentation, it is important that you engage your audience. You need them to pay attention to
you, or you are just wasting time.
With a partner, discuss three effective ways to ensure you successfully engage your audience.
Example: Giving a good introduction
1.
2.
3.
Now list three ways to ensure that your audience doesn’t pay attention to you.
Example: Arriving late
1.
2.
3.
What tools are commonly available to help make your presentations more engaging? Write a few of your ideas
below and then share them with another pair.
Example: Music
1.
2.
3.
As well as guiding your audience through your presentation, you need to make sure that they don’t knock you
off course. Study these phrases that you can use to prevent interruptions.
At the end of the presentation, you should include a very brief summary of the topics covered. To introduce this
part of your presentation, use the phrases below.
After your conclusion, you should ask the audience for questions. You will need to be prepared to respond to
these questions. Your response will depend on the type of question you were asked. Separate these responses
below into the three groups in the table.
Listen to the dialogue again, and then answer the following questions (U7-T27)
1. Who does Kelly work for?
a. Mr. Preston b. Not mentioned c. TechPro Consulting
2. Why has Kelly gone to see Mr. Preston and his colleagues?
a. To apply for a job b. To seek investment c. She works for them.
3. How long was kelly’s presentation supposed to last?
a. Ten minutes b. Two minutes c. Not mentioned
4. What was on Kelly’s first slide?
a. A list of services b. A model of a new office
c. A model of how companies can work together
5. What can TechPro do as it gets bigger?
a. Offer more services
b. Pay money to Mr. Preston c. Reduce costs
6. What is TechPro’s biggest running cost?
a. Salaries b. Investment c. Unknown
Altenberg, E.P. and Vago, R.M. 2010. English Grammar: Understanding the Basics. New York: Cambridge University
Press.
Azar, B.S. 1999. Understanding and Using English Grammar (3rd edition). New York: Pearson Education.
Brown, H. D. 2007. Teaching by principles: an interactive approach to language pedagogy. New York. USA. ISBN-
10: 0-13-612711-8
Davenport, M. and S. J. Hannahs. 2010. Introducing phonetics and phonology. London, Great Britain. ISBN: 978- 1
444 10988 7
H. Ismail, R. Nordin, A.M. Noor. Polymer Testing. Volume 21, Issue 5 2002, pages 565-569
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accessed September, 17 2020 at 7.05 pm
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Rost, M. 2002. Teaching and researching listening. Great Britain. ISBN: 978 – 0 – 582- 36930-6
Shearn, R., Ferris and G. Tacket. 2012. English at work 3. Taipei, 10349, Taiwan, R.O.C. Cengage Learning ASIA Pte.,
Ltd. ISBN-10: 986- 6121-63-1
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accessed September, 17 2020 at 3.35 pm
Abstract
The effect of recycled rubber powder (RRP) on cure characteristics, tensile properties and swelling
behaviour of natural rubber (NR) compounds was investigated in the concentration range of 0 to 50 phr.
Results indicate that the minimum torque and Mooney viscosity of the natural rubber compounds increase
with increasing RRP loading whereas the scorch time and cure time exhibit a decreasing trend. Increasing
RRP loading also gives natural rubber compounds better resistance towards swelling and reduces the
elongation at break but the tensile stress, M100 (stress at 100% elongation) and M300 (stress at 300%
elongation), increases slightly. However, the tensile strength increases up to 10 phr of RRP and then
decreases. 2002 Elsevier Science Ltd. All rights reserved.
Keywords: Cure characteristics; Tensile properties; Natural rubber; Recycled rubber powder; Swelling
behaviour
1. Introduction
Scrap rubbers are made up of rubber that does not meet processing and product specifications, leftover rub-
ber from manufacturing activities and also old and defec- tive rubber products. The scrap rubbers are waste
and usually discharged. The discarded scrap rubber does not degrade rapidly enough and this causes
environmental pollution. To reduce this pollution there is a need to recy- cle scrap rubber [1]. Reclamation of
scrap (vulcanized) rubber can be done by mechanical [2,3] and chemical processes [3,4]. Crane and Kay [5]
have shown that scrap rubber vulcanizates could be depolymerized to a product known as “depoly- merized
scrap rubber”, which should be useful as a rub- ber compounding ingredient and as a fuel-oil extender. The
purpose of this study is to investigate the cure characteristics, tensile properties and swelling behaviour of
recycled rubber powder (RRP)-filled natural rubber (NR) compounds. A morphological study of the tensile
fracture surfaces of the natural rubber compounds was also carried out.
2. Experimental
2.1. Material
Natural rubber (SMR L) was purchased from Kumpu- lan Guthrie Sdn Bhd, Seremban, Malaysia. The
recycled rubber waste (rubber powder) product from the sanding process (polishing) of rubber ball and
artificial eggs with particle size of 250–500 nm was obtained from Watas Holding (M) Sdn Bhd, Penang,
Malaysia. Table 1 shows the formulation used in this study. Other compounding ingredients such as zinc
oxide, stearic acid, sulfur, N- cyclohexyl-2-benzothiazole sulfenamide (CBS) and 2,2-methylene-bis(4-
methyl-6-tert-butylphenol were all pur- chased from Anchor Chemical Co. Compounding was done in
accordance with ASTM D 3184-89 using a two- roll mill at room temperature.
Table 1
where M1 is the initial mass of specimen (g) and M2 is the mass of specimen (g) after immersion.
2.5 Tensile properties
Dumb-bell-shaped samples were cut from the moulded sheets according to ASTM D 412. Tensile test were
per- formed at a cross-head speed of 500 mm/min. Tensile testing was carried out with a Monsanto
Tensometer M500.
2.6 Scanning electron microscopy
The fracture surfaces of the RRP-filled natural rubber compounds were investigated with a Leica
Cambridge S-360 scanning electron microscope. The aim was to obtain information regarding RRP
dispersion, bonding quality between RRP and natural rubber, and to detect the possible presence of
microdefects.
Table 2 shows that increasing the recycled rubber powder loading in natural rubber compounds reduces
the scorch time. This is because of the presence of cross- linked precursors and unreacted curative in the
rubber powder [7]. The existence of unreacted accelerator in rubber powder waste has been reported by
Mathew et al. [8]. The other reason is diffusion of sulfur from the rub- ber matrix phase to the rubber
powder phase, which low- ers the concentration of sulfur in the rubber matrix [8– 11]. Increasing the
recycled rubber powder loading in natu- ral rubber compound also reduces the cure time t90, as shown in
Table 2. Similar trends were also observed by Baharin et al. [1], Ishiaku et al. [12] and Phadke et al. [11]
using different types and sizes of rubber powder particles. The minimum torque, a measure of the stock
viscosity, shows a slight increase with increasing rubber powder loading. This indicates that the
processability of the com- pounds becomes a little more difficult (Table 2). The increase could be due to
the agglomeration of rubber powder particles in the natural rubber matrix. The other possibility is that
rubber powders are already cross- linked, and do not easily flow in the matrix, so an increase in recycled
rubber powder loading will reduce the flow and consequently increase the torque. A similar observation
can be seen in Fig. 1 for the Mooney vis- cosity of RRP-filled NR compounds at 120°
The tensile strength gradually increased to a maximum at 10 phr of rubber powder as shown in Fig. 2.
Further increases of rubber powder loading led to a decrease in tensile strength. It is thought that below
10 phr of rubber powder loading, smaller particle size and uniform disper- sion of recycled rubber powder
in natural rubber com- pounds contribute to a higher tensile strength. However, when more than 10 phr
was used, the weak interaction
and bonding between the rubber powder particles and the natural rubber matrix is responsible for the
deterio- ration in tensile strength. As the rubber powder concen- tration increases, agglomeration and
hence particle–par- ticle interaction of the rubber powder also increases.
The elongation at break of natural rubber compounds decreases with increasing recycled rubber powder
loading (Fig. 3). However, the decrease is small, particularly after 20 phr of recycled rubber powder
loading. A similar observation was reported by Baharin et al. [1]. This indi- cates that the addition of
recycled rubber powder does not adversely affect this property.
Variation in tensile modulus, M100 (stress at 100% elongation) and M300 (stress at 300% elongation),
which is a measure of stiffness, is shown in Fig. 4. It can be seen that M100 and M300 increase slightly with
increas- ing recycled rubber powder. This shows that the recycled rubber powder behaves like a rigid
particulate filler since it has a higher modulus then the natural rubber matrix.
Table 2
0 10 20 30 50
Minimum torque (dN 0.06 0.0 0.11 0.13 0.14
m)a 9
Scorch time (min) 6.69 4.52 3.11 2.56 2.37
Cure time (min) 12.76 9.38 7.54 6.83 6.49
a
desiNewton meter [NM (X 1/10)]
Fig. 2. The effect of RRP loading on the tensile strength of natural rubber compounds.
Fig. 4. The effect of RRP loading on the tensile modulus of natural rubber compounds.
Fig. 7. Tensile fracture surface of natural rubber gum com- pound (magnification 150X)
Fig. 8. Tensile fracture surface of natural rubber compound filled with 10 phr of RRP (magnification 150X)
Fig. 9. Tensile fracture surface of natural rubber compound filled with 30 phr of RRP (magnification 150X).
4. Conclusion
Cure characteristics such as scorch time and cure time of the natural rubber compounds decrease with
increas- ing recycled rubber powder loading but show slight increases in minimum torque. Swelling
resistance increases with increasing recycled rubber powder load- ing in natural rubber compounds.
Tensile properties such as tensile modulus slightly increase with increasing recycled rubber powder loading
whereas the elongation break shows a decreasing trend. However, for tensile strength, the maximum
value was observed at 10 phr of recycled rubber powder.
Acknowledgements
The authors gratefully acknowledge the support given by family and the research grant provided by
Universiti Sains Malaysia, Penang.
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