% Cu Cusum Constant

29.452 -0.048 29.5 7.000

29.586 0.038 6.000
29.696 0.234
5.000

Cusum of Cu (%)
29.572 0.306
29.648 0.454 4.000
29.662 0.616
3.000
29.783 0.899
29.602 1.001 2.000
29.550 1.051 1.000
29.324 0.875
0.000
29.454 0.829
29.534 0.864 -1.000
29.831 1.195 0 10 20 30 40 50 60 70
29.386 1.081
Observation
29.380 0.961
29.584 1.045
29.546 1.091
29.604 1.194
29.110 0.804 30.2
29.332 0.637 30.0
29.311 0.448
29.8
29.570 0.518
Assay (% Cu)

29.427 0.445 29.6

29.433 0.378 29.4
29.287 0.164
29.436 0.100 29.2
29.664 0.264 29.0
29.457 0.222
28.8
29.759 0.481
29.705 0.686 28.6
29.394 0.580 0 10 20 30 40 50 60 70
29.535 0.615 Observation
29.429 0.544
29.776 0.820
29.494 0.815
29.387 0.702
29.527 0.729
29.778 1.007
29.513 1.021
29.689 1.210
29.331 1.041
29.487 1.028
29.688 1.216
29.346 1.062
29.573 1.135
29.659 1.294
29.478 1.272
29.565 1.336
29.621 1.457
29.421 1.378
29.844 1.722
29.826 2.048
29.967 2.515
29.365 2.379
29.707 2.586
29.626 2.712
29.361 2.573
29.563 2.636
29.742 2.879
29.833 3.212
29.625 3.337
29.855 3.692
29.321 3.513
29.571 3.584
29.750 3.834
29.840 4.174
29.652 4.325
29.753 4.578
29.333 4.411
29.599 4.510
29.910 4.921
29.611 5.031
29.655 5.186
29.514 5.200
29.451 5.150
29.562 5.212
29.712 5.424
29.699 5.623
29.838 5.961
29.531 5.992
30 40 50 60 70 80
Observation

30 40 50 60 70 80
Observation
All data Lab A Lab B Lab C Lab D Lab E Lab F Lab G
27.72 28.75 24.93 27.40 25.00 26.40 29.40
29.13 27.23 25.00 26.55 26.00 33.20 29.00
90% CIs 4.45 4.80 0.22 2.68 3.16 21.47 1.26

Anova: Single Factor

SUMMARY 32
Groups Count Sum Average Variance
A Lab A 2 56.85 28.425 0.99405 30 90% confidence interva

Mean A*b
B Lab B 2 55.98 27.99 1.1552 28
C Lab C 2 49.93 24.965 0.00245
D Lab D 2 53.95 26.975 0.36125 26
E Lab E 2 51 25.5 0.5
F Lab F 2 59.6 29.8 23.12 24
G Lab G 2 58.4 29.2 0.08 22
H Lab H 2 52.1 26.05 0.005 A B C D
I Lab I 2 51.9 25.95 2.205
Labo

ANOVA
Source of Variation SS df MS F P-value
Between Labs 47.41048 8 5.92631 1.876539 0.183675
Within Labs 28.42295 9 3.158106

Total 75.83343 17
 Lab H Lab I Without Lab F Lab A Lab B Lab C
26.00 24.90 27.72 28.75 24.93
26.10 27.00 29.13 27.23 25.00
0.32 6.63 90% CIs 4.45 4.80 0.22

Anova: Single Factor

32 SUMMARY
Groups Count Sum
30 90% confidence interval Lab A 2 56.85
28 Lab B 2 55.98
Lab C 2 49.93
26 Lab D 2 53.95
Lab E 2 51
24 Lab G 2 58.4
22 Lab H 2 52.1
A B C D E F G H I Lab I 2 51.9

Laboratory
ANOVA
Source of Variation SS df
Between Labs 32.27189 7
Within Labs 5.30295 8
SD
Total 37.57484 15
Lab D Lab E Lab G Lab H Lab I
27.40 25.00 29.40 26.00 24.90
26.55 26.00 29.00 26.10 27.00
2.68 3.16 1.26 0.32 6.63

Average Variance
28.425 0.99405
27.99 1.1552
24.965 0.00245
26.975 0.36125
25.5 0.5
29.2 0.08
26.05 0.005
25.95 2.205

MS F P-value F crit
4.610271 6.955028 0.006907 3.500464
0.662869
0.814168
 Data for LAB A LAB B
Minitab example Day Method 1 Method 2 Method 1
1 0.240 0.280 0.235 0.195 0.214
2 0.210 0.390 0.160 0.145 0.222
3 0.180 0.230 0.155 0.170 0.203
4 0.170 0.110 0.100 0.130 0.220
5 0.070 0.170 0.120 0.145 0.163
6 0.130 0.170 0.085 0.130 0.179

Minitab Output

Analysis of Variance
Source DF SS MS F P(F)
Day 5 0.0516 0.01032 3.223 0.093
Lab 6 0.0192 0.00320 1.058 0.438
Method 12 0.0363 0.00303 2.079 0.061
Error (assay) 24 0.0349 0.00145 - -
Total 47 0.1421 - - -

Components of Variance
Source Variance % of total StdDev
Day 0.00089 28.05 0.0298
Lab 0.00004 1.38 0.0066
Method 0.00079 24.75 0.0280
Error (Assay) 0.00145 45.82 0.0381
Total 0.00317 100.00 0.0563
 LAB B
Method 1 Method 2
0.264 0.230 0.200
0.175 0.187 0.187
0.226 0.157 0.137
0.211 0.170 0.227
0.204 0.127 0.153
0.161 0.140 0.147

Anova: Two-Factor With Replication

LAB A
SUMMARY M1 M2 Total
1
Count 2 2 4
Sum 0.52 0.43 0.95
Average 0.26 0.215 0.2375
Variance 0.0008 0.0008 0.001208

2
Count 2 2 4
Sum 0.6 0.305 0.905
Average 0.3 0.1525 0.22625
Variance 0.0162 0.0001125 0.01269

3
Count 2 2 4
Sum 0.41 0.325 0.735
Average 0.205 0.1625 0.18375
Variance 0.00125 0.0001125 0.001056

4
Count 2 2 4
 Sum 0.28 0.23 0.51
Average 0.14 0.115 0.1275
Variance 0.0018 0.00045 0.000958

5
Count 2 2 4
Sum 0.24 0.265 0.505
Average 0.12 0.1325 0.12625
Variance 0.005 0.0003125 0.001823

6
Count 2 2 4
Sum 0.3 0.215 0.515
Average 0.15 0.1075 0.12875
Variance 0.0008 0.0010125 0.001206

Total
Count 12 12
Sum 2.35 1.77
Average 0.19583333 0.1475
Variance 0.00708106 0.0016523

ANOVA
Source of Variation SS df MS P-value
Sample 0.05325833 5 0.010652 0.007237
Columns 0.01401667 1 0.014017 0.005412
Interaction 0.01415833 5 0.002832 0.563178
Within 0.02865 12 0.002388

Total 0.11008333 23
Nested ANOVA Sample Batch 1 Batch 2
1 8.0 6.2
1 7.4 7.4 Analysis of
1 7.8 6.9 Source of variation
2 7.7 5.7 Batches
2 7.3 5.8 Samples
2 5.1 5.2 Analyses (error)
3 5.8 5.4 Total
3 5.6 6.1
3 5.7 4.6
Batch totals 60.4 53.3
N 18 Components of Varian
Source of variation
No. batches 2 Batches
No.samples per batch 3 Samples
No.analyses per sample 3 Analyses (error)
Total
Sample totals Sample Batch 1 Batch 2
1 23.2 20.5
2 20.1 16.7
3 17.1 16.1

Grand total 113.7

Grand mean 6.32
 Analysis of Variance
SS DF MS F P(F)
2.801 1 2.801 1.120 0.350
9.998 4 2.499 4.848 0.015
6.187 12 0.516 - -
18.985 17 - - -

Components of Variance
Variance % of total Std.Dev.
0.033 2.76 0.183
0.661 54.64 0.813
0.516 42.60 0.718
1.210 100.00 1.100
Data from
Ex. 12.4. Sample variance 0.661 k n Variance
Assay variance 0.516 1 1 1.177
Sample cost 1 2 1 0.588
Analysis cost 5 3 1 0.392
4 1 0.294
n for minimum cost 0.39 5 1 0.235
6 1 0.196
V 0.4 1 3 0.833
k 2.9421296 2 3 0.417
3 3 0.278
4 3 0.208
5 3 0.167
6 3 0.139
Cost (relative) D
6 -
12 4.67
18 1.89
24 1.49
30 1.28
36 1.14
16 2.59
32 1.55
48 1.22
64 1.04
80 0.92
96 0.84
STD-Fe INT-Fe
19.64 45.4833 140
20.49 44.1259
120

Intensity (kcps)
34.85 69.88537
100
8.231 18.93013
80
8.59 21.43317
5.9033 15.14897 60
5.236 13.80816 40
61.85 131.1507 20
33.21 73.94191 0
8.04 17.58589 0 10 20 30 40 50 60 70
7.06 15.62905 STD % Fe
5.12 11.83972
17.5 33.26305
18.6 41.48443
8.1 17.91446
5.2 11.69447
9.2 20.31671
8.2 18.73318
21.5 43.74022
15.5 33.81401
6.21 15.21087
SUMMARY OUTPUT
New observations
Regression Statistics
Multiple R 0.9976114898
R Square 0.9952286846
Adjusted R Square0.9949775628
Standard Error 2.0345061518
Observations 21
Mean new readin
ANOVA
df SS MS F Significance F
Regression 1 16404.249997 16404 3963.13 1.602703E-23
Residual 19 78.645090353 4.13922
Total 20 16482.895087

Coefficients Standard Error t Stat P-value Lower 95% Upper 95%

Intercept 1.5812912417 0.680571039 2.32348 0.0314 0.1568396895 3.00574279
STD Fe % 2.0775856888 0.0330019622 62.9534 1.6E-23 2.0085117882 2.14665959
New observations Confidence % 95
t = 2.09302405441
m (no.repeats) = 2
Mean y = 34.0539852381
Mean x = 15.6300142857
SS x = 3800.48033

Mean new readings Predicted % Fe CI (± % Fe) Lower CI Upper CI

15.5 6.70 1.55 5.15 8.25
53.6 25.04 1.55 23.49 26.59
103.2 48.91 1.88 47.03 50.79

D = 0.001105376
 Particle Mean Wt. distn. of Cum. distn. No. 95% CI
N0 N1
composition (%) Comp. (%) mineral (%) (%) particles (±)
0 0 0.00 100.00 10350 - - -
0-10 5 7.15 100.00 133 10350 268 0.00
10-20 15 9.51 92.85 33 10483 135 1.26
20-30 25 4.93 83.34 20 10516 102 3.03
30-40 35 4.90 78.41 10 10536 82 4.11
40-50 45 6.72 73.51 9 10546 72 5.05
50-60 55 3.34 66.80 4 10555 63 6.14
60-70 65 12.21 63.46 13 10559 59 6.63
70-80 75 6.13 51.25 6 10572 46 8.09
80-90 85 14.41 45.13 13 10578 40 8.60
90-100 95 21.92 30.71 11 10591 27 8.99
100 100 8.79 8.79 16 10602 16 4.40

100
90
Cum. wt. distribution (%)

80
70
60
50
40
30
95% confidence limits
20
10
0
0 10 20 30 40 50 60 70 80 90 100
Mean composition (% chalcocite)
 LCL UCL

- -
100.00 100.00
91.59 94.11
80.31 86.37
74.30 82.52
68.46 78.56
60.65 72.94
56.83 70.09
43.16 59.34
36.53 53.72
21.73 39.70
4.40 13.19

90 100
 Before After t-Test: Two-Sample Assuming Equal Variances
2.34 0.87
1.68 0.35 Before After
1.30 0.91 Mean % Chalcocite 1.775 0.79
1.71 0.91 Variance 0.11887 0.04784
1.68 0.81 Observations 6 6
1.94 0.89 Pooled Variance 0.083355
Hypothesized Mean Diff. 0
95% CI 0.148 0.094 df 10
t Stat 5.909232
P(T<=t) one-tail 7.46E-05
t Critical one-tail 1.812461
P(T<=t) two-tail 0.000149
t Critical two-tail 2.228139
al Variances

Diff
0.985