EXAMINATION QUESTION PAPER

DEPT. OF ACADEMICS

Details
Campus Ahmedabad Date 11/8/21
Name of student Class XII

Name of examination Cyclic Test II Student Roll No.

Mail ID of subject lata.punjabi@globalindianschool.org

teacher

Subject Chemistry
Session 2021-2022
Duration 2 Hours
Maximum marks 50

GENERAL INSTRUCTIONS
1. Please log in to Eklavya portal for writing exam.
Q.1
2. Students are requested to use minimum A4 size paper.
3. Use back pen for writing.
4. On completion of paper, please take a clear photograph of answer sheet and save in pdf then upload in
Eklavya.
5. Please write your name, section and class in first page.
6. All questions are compulsory.

Answer the following questions:

Q.1.The curve Y is for KCl or CH3COOH?

Q.2. What is intercept on ˄m axis for ‘X’ equal to?

Q.3. Give mathematical equation representing

straight line.

Q.4. What is slope equal to?

Q.5. When concentration approaches zero molar

conductivity is called as _______

 EXAMINATION QUESTION PAPER
DEPT. OF ACADEMICS

Table 2

Table 1

Table 3

Q.6. Which ion has maximum coagulation power for As2S3 ion?

Q.7. Which ion is best to coagulate Fe (OH)3 Fe3+ sol?

Q.8. Which is the best protective colloid?

Q.9. What is protective colloid?

Q.10. What is least effective protective colloid?

(a) Both assertion and reason are correct statements, and reason is the correct explanation of the assertion.

(b) Both assertion and reason are correct statements, but reason is not the correct explanation of the assertion.

(c) Assertion is correct, but reason is wrong statement.

(d) Assertion is wrong, but reason is correct statement.

Q.11. Assertion: Coating iron with zinc prevents rusting.

Reason: The coating of zinc prevents moist air to come in contact with the metal.

Q.12. Assertion: When aqueous sodium chloride solution is electrolyzed, Oxygen gas is produced at the anode.
 EXAMINATION QUESTION PAPER
DEPT. OF ACADEMICS

Reason: It is due to the overpotential for oxidation of water to oxygen.

Q.13. Assertion: Reduction of 1 mole of Cu2+ ions require 2 Faraday of charge.

Reason: 1 Faraday is equal to the charge of 1 mole of electrons.

Q.14. Assertion: The half-life of a reaction is independent of initial concentration for a first order reaction.

Reason: The integrated rate law for a first order reaction is independent of initial concentration.

Q.15. Assertion: The slowest elementary step in a complex reaction decides the rate of the reaction.

Reason: The slowest elementary step always has the smallest molecularity.

Q.16. Assertion: Increase in temperature increases rate of reaction.

Reason: More colliding molecules will have energy greater than threshold energy.

Q.17. Assertion: Adsorption is a surface phenomenon.

Reason: The intermolecular forces at the surface of the adsorbent is unequal in different directions.

Q.18.Assertion: Shape selective catalysis is possible for zeolitic catalyst.

Reason: Zeolites are sodium alumino silicates with definite crystal structure.

Q.19. Assertion: Keeping an electric field during dialysis enhances the process.

Reason: The dialysis process involves removing old solvent for new pure solvent.

Q.20. Assertion: Hydrolysis of methyl ethanoate is a pseudo first order reaction.

Reason: Water is present in large excess and therefore its concentration remained constant throughout the

reaction.

Choose the correct option/s (Note : some questions may have two correct answers and each will carry half a
mark) :

Q.21. The role of a catalyst is to change ______________.

(i) Gibbs energy of reaction.

(ii) enthalpy of reaction.

(iii) activation energy of reaction.

(iv) equilibrium constant.

 EXAMINATION QUESTION PAPER
DEPT. OF ACADEMICS

Q.22.

Consider Fig and mark the correct option.

(i) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
(ii) Activation energy of forward reaction is E1 +E2 and product is more stable than reactant.
(iii) Activation energy of both forward and backward reaction is E1 +E2 and reactant is more stable than
product.
(iv) Activation energy of backward reaction is E1 and product is more stable than reactant.

Q.23. Consider a first order gas phase decomposition reaction given below:
A(g) ⎯→ B(g) + C(g)
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure of the
system increased by x units and became ‘pt ’ The rate constant k for the reaction is given as _________.
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DEPT. OF ACADEMICS

Q.24. Which of the following graphs represents exothermic reaction?

(i) (a) only

(ii) (b) only
(iii) (c) only
(iv) (a) and (b)

Q.25. Compounds ‘A’ and ‘B’ react according to the following chemical equation. A (g) + 2 B (g) ⎯→ 2C (g)
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants constant and rates
were measured as a function of initial concentration. Following results were obtained. Choose the correct option for
the rate equations for this reaction.

(i) Rate = k [A]2 [B]

(ii) Rate = k [A] [B]2
(iii) Rate = k [A] [B]
(iv) Rate = k [A]2 [B]0

Q.26. Which of the statements about solutions of electrolytes is not correct?

(i) Conductivity of solution depends upon size of ions.

(ii) Conductivity depends upon viscosiy of solution.
(iii) Conductivity does not depend upon solvation of ions present in solution.
(iV) Conductivity of solution increases with temperature.
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DEPT. OF ACADEMICS

Q.27. Which of the following statement is correct?

(i) ECell and ΔrG of cell reaction both are extensive properties.
(ii) ECell and ΔrG of cell reaction both are intensive properties.
(iii) ECell is an intensive property while ΔrG of cell reaction is an extensive property.
(iv) ECell is an extensive property while ΔrG of cell reaction is an intensive property.

Q.28. Which one of the following is not applicable to the phenomenon of adsorption?

(i) ΔH > 0
(ii) ΔG < 0
(iii) ΔS < 0
(iv) ΔH < 0

Q.29. Which of the following options are correct?

(i) Micelle formation by soap in aqueous solution is possible at all temperatures.

(ii) Micelle formation by soap in aqueous solution occurs above a particular concentration.
(iii) On dilution of soap solution micelles may revert to individual ions.
(iv) Soap solution behaves as a normal strong electrolyte at all concentrations.

Q. 30. Which of the following phenomenon occurs when a chalk stick is dipped in ink?

(i) adsorption of coloured substance

(ii) adsorption of solvent
(iii) absorption and adsorption both of solvent
(iv) absoprtion of solvent.

Q.31. Consider the following diagram in which an electrochemical cell is coupled to an electrolytic cell. What will be
the polarity of electrodes ‘A’ and ‘B’ in the electrolytic cell?
 EXAMINATION QUESTION PAPER
DEPT. OF ACADEMICS

Q.32. Consider a cell given below:

Cu|Cu2+|| Cl—|Cl2,Pt

Write the reactions that occur at anode and cathode.

Match the items of Column I and Column II. (Q.33 to Q. 36)

For a general reaction A ⎯→ B, plot of concentration of A vs time is given in Fig.

Answer the following question on the basis of this graph.
Q.37. What is the order of the reaction?
Q.38. What is the slope of the curve?
Q.39. What are the units of rate constant?

Q.40. Write the rate equation for the reaction 2A + B ⎯→ C if the order of the reaction is zero.

Fill in the blanks:

Q.41. An electrochemical cell converts _____- energy into ______ energy.

Q.42. The molar conductance _________ with dilution and its specific conductance _______with dilution.

Q.43. Dispersion medium in the case of gel is _______.

Q.44. The number of collisions per second per unit volume of the reaction mixture is known as _______.

Q.45. For ac chemical reaction with rise in temperature by 10 degree C , the rate constant is nearly _____.
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DEPT. OF ACADEMICS

Q.46. Lithium has the lowest electrode potential indicating that lithium ion is the weakest _______agent while
lithium metal is the most powerful _______ agent in an aqueous solution.

Q.47. Colloids that once precipitated, do not give back the colloidal sol by the addition of the dispersion
medium are called ________ sols.

Q.48. The potential difference between the fixed layer and the diffused layer of opposite charges is called the
______ potential.

Q.49. For complex reaction, order is given by the _______ step and molecularity is same as the order of the
overall reaction.

Q.50. Identify the reaction order from each of the following rate constants.

(i) k= 2.3 x 10-5 Lmol/s

(ii) k= 3 x 10-4 s-1.