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Exercise 2
NUCLEAR REACTIONS, BINDING ENERGY AND RATE OF DECAY
OBJECTIVES
Direction: Answer the following questions. Show complete solution, whenever applicable.
A. Nuclear Reactions
Balance the following nuclear reactions by filling out the missing species or predicting
the products.
1 3 4
1. H + 1¿ 1 H → 2 He ¿
239 4 235
2. 94 Pu → 2 He + 92U
3. U + 239 4 242 1
92 ¿ 2 He → 94 Pu + 0 n ¿
212 4 208
4. 83 Bi → 2 He + 81Tl
37 37 0
5. 19 K → 18 Ar + +1e
226 4 222
6. 88 Ra → 2 He + 86 Rn
7. Be+ 94¿ 11 H → 63 Li + 42 He ¿
254 4 256 1
8. Es+ 99 ¿ 2 He → 101 Md +2 0n ¿
222 0 222
9. 86 Rn + −1 e electron capture 85 At + X−ray
→
222
10. 86 Rn alpha emission 218 4
84 Po + 2 He
→
B. Binding energy
Given:
m Os=189.95863 amu
190
76
m n =1.008664 amu
0
m p =1.007276 amu ¿
+¿
Formula:
∆ m=mnucleus−mparticles
2
∆ mc 8 m
E= where c=3.0 × 10 ;
A s
A=number of nucleons=190
Solution:
+¿=76 ¿
p
n 0=m Os− p+¿=189.95863−76=113.95863 ≈114 ¿
( )=−2.627044023× 10
−27
1.66054 ×10 kg ( −27 )
∆ m=−1.582042amu kg
1 amu
2
∆mc
∆ E=
A
( )
2
(−2.627044023× 10(−27) kg ) 3.0 × 108 m
s
¿
190 nucleons
−2.464337884 ×10−10 J
¿
190 nucleons
−12 J −12 J
E=−1.24438836 ×10 ≈−1.24 ×10
nucleon nucleon
2. Calculate the amount of energy released (in kJ) 235U undergoes fission to form Te-137
and Zr-96 (Given: m(235U) = 235.043915 amu; m( 1n) = 1.008664 amu; m(137Te) =
136.925449 amu; m(96Zr) = 95.908286 amu)
Note: Fission occurred because of the collision of 235U with a neutron.
Given:
m U =235.043915 amu
235
92
m n=1.008664 amu
1
0
m Te=136.925449 amu
137
52
m Zr =95.908286 amu
96
40
Formula:
∆ m=mreactants−m products
235 1 137 96 1
92 U + 0n → 52 Te + 40Zr +3 0n
reactants products
8 m
E=∆ m c
2
where c=3.0 × 10
s
Solution:
∆ m=mproducts −m reactants
( )
−27
1.66054 × 10 kg
∆ m=−0.192852 amu
1 amu
∆ m=−3.202384601×10−28 kg
Calculate energy released:
CHM031L. Chemistry for Engineers Laboratory Page E2-3
No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay
2
E=∆ m c
( )
2
m
¿(−3.202384601×10−28) 3 ×10 8
s
−11
E=−2.882146141× 10 J
Convert Joules to kilojoules:
¿−2.882146141×10
−11
J ( 1000
1 kJ
J)
238 234
3. How much energy is released in the decay of 92 U into 90 Th and an alpha particle?
Given:
m U =238.0508 amu
238
92
m Th=234.0426 amu
234
90
m α =4.0026 amu
4
2
Formula:
∆ m=mproducts −m reactants
238
92 U → 234 4
90 Th+ 2α
reactants products
8 m
E=∆ m c 2 where c=3.0 × 10
s
Solution:
∆ m=mproducts −m reactants
2
E=∆ m c
( )
2
−30 m
8
E=(−9.299024 ×10 kg) 3 ×10
s
C. Rate of Decay
Given:
N 0=30.0 g
t 1 =5 years
2
t=15 years
Required:
Amount left in 30.0 g after 15 years, N
Formula:
ln
( ) N
N0
=−kt
−kt
A=A 0 e
ln (2)
k=
t1
2
Solution:
ln (2)
k=
t1
2
ln (2)
¿
5 years
k =0.1386294361/ year
CHM031L. Chemistry for Engineers Laboratory Page E2-5
No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay
N=N 0 e−kt
¿(30.0 g)(e [ (−0.1386294361 / year ) (15 years )] )
N=3.750000288 g ≈ 3.75 g
2. The half-life of plutonium-239 is 24,110 years. If an original sample is 100. grams, how
much plutonium-239 remains after 96,440 years?
Given:
N 0=100 g
t 1 =24 , 110 years
2
t=96 , 440 years
Required:
Plutonium-239 remains after 96,440 years, N
Formula:
ln
( NN )=−kt
0
−kt
N=N 0 e
ln (2)
k=
t1
2
Solution:
ln (2)
k=
t1
2
ln (2)
¿
24 , 110 years
k =2.874936 ×10−5 / year
−kt
N=N 0 e
¿(100 g)(e [(−2.874936 ×10 / year ) (96,440 years) ])
−5
N=6.250002774 g ≈ 6.25 g
CHM031L. Chemistry for Engineers Laboratory Page E2-6
No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay
3. Iodine-131 is used in the treatment of thyroid disease. What is the half-life of iodine-131
if a 160-mg sample became 5 mg after 40 days?
Given:
N 0=160mg
N=5 mg
t=40 days
Required:
Half-life of iodine-131, t 1
2
Formula:
ln (2)
k=
t1
2
ln (2)
t 1=
2
k
ln
( )
N
N0
=−kt
−ln ( NN ) =k
0
Solution:
k=
−ln ( ) A
A0
t
k=
−ln ( 1605 mgmg )
40 days
−2
k =8.664339757 ×10 /day
ln (2)
t 1=
2
k
ln ( 2 )
t 1=
2 8.664339757× 10−2 / day
t 1 =8 days
2
4. Carbon-14 has a half-life of 5715 years. It is used to determine the age of ancient
objects. If a sample today contains 0.060 mg of carbon-14, how much carbon-14 just
have been present in the sample 11,430 years ago?
Given:
t 1 =5 ,715 years
2
t=11,430 years
N=0.060 mg
Required:
Carbon-14 present in the sample 11,430 years ago, N 0
Formula:
ln ( )
N
N0
=−kt
N
N 0= −kt
e
ln (2)
k=
t1
2
Solution:
ln (2)
k=
5,715 years
−4
k =1.2128559× 10 / year
N
N 0= −kt
e
0.060 mg
N 0= [(−1.2128559 ×10 / year)(11,430 years )]
−4
e
CHM031L. Chemistry for Engineers Laboratory Page E2-8
No part of this laboratory manual may be reproduced without the written permission of the College of Arts and
Science, Malayan Colleges Laguna.
Exercise 2: Nuclear Reactions, Binding Energy and Rate of Decay