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    14 views26 pages

    Practice Question GOC & Isomerism

    Uploaded by

    비Keerthu
    NEET

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    of 26
    10. {In which Of the j absent SHowing compound ap tybrisaion i ©) CHec-cH acy, (MP PET 2006) (9) CHec-cH, cH, © CHy~cH ecu, {@) CH, = cH -cH, cH, ach carbon atom in beaene inthe sae of ybdaton ICPMT 1989; MP PMT 1993; 2 KCET (Med, 1999; BHU 1999; DCE 2001), (a) sp’ (b) sp? (0 (a) sp Basic strength of @ Hen, WW) Hyc=eH (i) H-cn8 isin the order of re (cBse () >is ay 0) w>(>4ai) (9) i> >(a (2) (i> (iy >(i, ‘The stability of carbanions in PMT 2008} ‘the following ) Rew ) oF ii) RC =A (iw) RyC-Chi ICBSE PMT 2¢ la) iv) >(i)> (a> () {b) (i> (il) > (ai) > (iy) ont {e) (i> Gi) > Ga) > (ay) Wh (@) > (a)>Gy)>Q ‘at hybrid orbitals will f , (4) Only sp® increasing bond length of Cis (CBSEPMT re) 2011) =C B>A () C>A>B Toluene has {CPMT 1994; MP PMT 2000; Kerala CET 2005] (a) 6aand3 bond ——(b) 9 Gand 3x bond () 9aand6xbond ———(d) 15@and 3x bond Which carbon-atom has tetrahedral geometry 203 4 ¢H-CHz- COOH [Bihar CECE 2006] (o) B>C>A (@) A>B>C 1 CH: fa) 1 (b) 2 ( 3 (d) 4 Which of the following hybridization is known as trigonal hybridization (MH CET 2000) (a) sp* ( 9” (b) sp (d)_ dsp? 42. The Wes oT ybrdaang “ent in 1,2. butadiene are (MH CET 2000) and sp? 43, InZ-butene, which one of tye eh % a0 8? (2) sP.5p* and sp? (2 sp and sp ©) following statements is tre 1) C.-C, bond ina gp? {WB Jee 2012 (9) Ce~Cy bond isa ap ne 7 OM ©) Cr-Cr bondisa ap ye bam ot 18 C=C bondisa tne 7 oom 44. Cone ate ange te (2) 1,2butadiene IRPMT 1995, (c) hearse a 1 45. In which ofthe folowing en ; —— carbon mee ies is the ur ved to) crrconetsston “tee 208 urcron w ad ot Son (b) CH, CH,OH IOC Is (@) CH, =CH-CH. 46. The H-C-H bond angle in CHe's pp Per 2000 (a) 109°28° (0) 107923 n (@) 180° ons of C-Csingle bond of 28 IT SEE 1991; MP PET 1995, EPMT 2002; Odishe JEE 2005; We JEE 2009) ed (b) sp-sp? (2) sp? -sp (4) sp? sp? 48. Hybridisation in CH, and Cy are (urcenrr a (a) sp and sp? respectively 006; MP PET 2011) (6) sp* and sp* respectively (6) sp® and sp* respectively (4) sp* and sp? respectively 49. Consider the following compounds A. Chloroethene B. Benzene C. 1,3-butadiene D. 1,3,5-hexatriene All the carbon atoms are sp* hybridised in Keel PET 2006 (a) A,C,Donly (b) A, Bonly (c) B,C, Donly (d) C,Donly {e) A,B,CandD 50. How many bonds are there in (DCE 2005) oe oy (a) 140,8% (b) 180, 82 (co) 190, 4x (d) 140,20 51. In graphite C-atom is in ... state (CPMT 2002) (a) sp* (b) sp (c) sp* (d) None of these 52. 53. 54, 56, 87, 59, 60. 61. 62. 63. 64. fl nic chemistry 1443 General Or lecule Flow many londs ave present 8 RABHINAIENE TET agp} 0) 4 & : Oo (RPMT 2002) Hybridisation sate of Cin diamond ae (bo) 9 © & (a) sd ‘The numberof gad x bonds present in pent-ene-} YT s TAIIMS 2002; CPMT 2002; RPMT 20051 (a) 10,3 (b) 3,10 0 49 @) 9.4 ‘Which one ofthe followings more acidic (DPMT 2002] (2) Butane {b) L-butene {e) L-butyne (d) 2-butyne Graphite i soft while diamond is hard because (BHU 2003} (2) Graphite isin powder form (b) Diamond has sp? hybridization but graphite has sp° hybridization (0) Graphite is in planar form while diamond is in tetrahedral form (2) Graphite i covalent and diamond is ionic Hybridization of 1 and 2 carbon atoms in {HU 2003) (a) spp (b) sp*.sp? © sep (a) sp sp" iydrogen bonding is maximum in {UPSEAT 2003) (2) CoH,OH (b) CH; -0-CH, ©) (CH),C=0 (@) CHyCHO How many methyl group are present in 2, 5-dimethyl4- ethylheptane TEAMCET 2003} a2 3 4 (a5 Which one of the following does not have sp hybridised carbon IAIEEE 2008) (2) Acetontile {b) Acetic acid (€) Acetone (@) Acotamide Allyl cyanide contain o: and zebonds (MP PET 2004; UPCPMT 2006) (@) 90,32 (b) 90,92 (0 30,4" (@) 50,7 Strongest acid is MP PMT 2004, 09; BCECE 2005} (@) HC=CH (b) CoH (0) Coty (a) CHOH ~C=C- bond is found in (BHU 1982; MP PMT 1994) (2) Ethene (b) Butene (0) Ethyne (8) Gigcerine ‘The shapes of methane, ethene and ethyne molecules ar respectively (MNR 1988; MP PET 1997, 99, 200 ‘AFMC 2002; CPMT 200 (a) Tetrahedral, planar and linear (b) Tetrahedral, linear and planar (c)_ Pyramidal, planar and linear (@) Tetrahedral, pyramidal and planar 1444 General Organic Chemistry 65. Number of bonds in benzene [MP PMT 1997; DPMT 2005), (a) 60 and 3 (0) 120 and 3x (@) Sr and 128 (4) 66 and 6x 66. The number of double bonds in gammexane is{RPMT 20081 (a) 0 (1 2 (a 3 67. The enolic form of acetone contains ur Jee 1990; Bihar MEE 1997; Pb. PMT 2002; AMU (Engs.) 2012) (2) 80-bonds, 2x -bonds and I lone pars (b) 9.<7-bonds, Le-bond and 2lone pairs (0 9a-bonds, 2r -bonds and 1 lone pairs (4) 100 -bonds, 1 -bonds and 1 lone pairs 68. The hybridisation in methane, ethene and Ethyne respectively is [CBSE PMT 1991; EAMCET 1993: Bihar MEE 1996; JIPMER 1997: DPMT 2001; [MP PMT 2002; Kerala PET 2002; CPMT 2003; RPMT 2006] (2) sp, spt and sp (0) sp sp, sp (6) ssp? and sp (6) sp.se' so 69. Considering the state of hybridization of carbon atoms, find ‘ut the molecule among the following whichis linear [CBSE PMT (Pre) 2011], (@) CH, ~CH~CH,-CH, (0) CH; -CH=CH-CH, (0. CHy-C=C-cH, (@) CH, =CH-CH,-C=CH 70. In hexa-1,3-diene-5-yne the number of C-Co, C-Cx ‘and C-He bonds respectively are (Kerala PMT 2011] (a) 5,4and6 (b) 6,3.and5 (0) 5,3and6 (@) 6,4and5 (e) 5,5and5 71. In allene (CjHg), the type(s) of hybridisation of the carbon atoms is (are) {IT JEE 2012; Kerala PMT 2012) (2) spand sp* (b)_spand sp* (0) Only sp* (a) spand sp* 72. The C-H bond and C-C bond in ethane are formed by Which ofthe following types of overlap [KCET (Med. 2012} (a) sp°—sand sp*-sp? (b)_sp*-sand sp*—sp* (0. sp-sand ssp (d)._p-s and p-p 73. The number of sigma (¢) and pi (x) bonds present in 1,3,5,7-octatetraene respectively are {Kerala PET 2012] (a) 14and3 (0) 17and4 (o) W6and 5 (4) 15and4 (e) 16and3 74, Whats the hybridisation state of benay carbonium ion Oe {NET (Kamataka) 2013} (a) sp* (b) spd? (ce) sp’d (d) sp* “sp! hybrid re number of th (WBEE Dong 3 (8 (a) 2 ‘electrons in the fo ie bord electron loving " structure 15 (CH; is GH, He {AIPM (Cancelled) 2015) ® ia 8 iy 6 16 sey ecetoacette a lw as “The enolic form © Hy Hiev,-C\.20 — Yo 0 OCH, AIPMT (Cancelled) 2015) bond (a) 16.igma bond an oo (G) 9 sigma bonds and 2 Pe (o) 9 sigma b (d)_ 18 sigma bonds ‘Which of the following | He 0 Hiemgee# { by OCH ‘ediates is pyramidal in shape oom TAMU 2016, (o) HC (a) HC=C® cthyne molecules, carbon atoms are oe TAMU 2016) (a) HAC° fo He? In ethane, ethene present in hybrid states of fa) ap a9" spp PP ) sp? =19.90° 9B 80 as (2) sp —sp sp" 80" P (a). sp? —sp?,sp? -sp.80" ~ 5 80. The pair of electron in the given carbanion, CHC=C®,is present in which ofthe following orbitals INET (Phase-} 2016) (@) 2 (0) sp” (c) sp* (d) sp i ‘Which has zero dipole moment IT JEE 1994; CBSE PMT 1996; BHU 2001) (a) Cis-2-butene (b) Trans-2-butene (o) L-butene (d)_2-methyl-1-propene ‘The temporary effect in which there is complete transfer of a shared pair of pi-electrons to one of the atoms joined by multiple bond on the demand of an attacking reagent i called (Kerala PET 2011; KCET (Med.) 2012 (a) Inductive effect (b) Positive resonance effect (c)_ Negative resonance effect (a) Hyperconjugation (e} Electromeric effect 5 6. u. 12. 13, _ shows di (9) 1.4-dichoro berg (bY 1, 2c (©) Trons-t, 2d + 2ichlone (@) Trans-2.butene™” sthene Which of the fo (0) CH, “moment TPMT 2002) "6 58 poe () HeL o () cu, The dipole moment ig a (2) Trons-2-buteng. '® Bishest for (€) Acetophenone Reronance structure of mole 1) Meet’! aangemen of atoms (b) Neatly the (0 Thesame ae energy content (@) ential bonding PA eectrons ‘end in bezene areca ue mpound (MH CET 2003), cc, (©) 1, 3.dimety (4) Ethanot ‘ule does not have WT JEE 1984) {Roorkee 1990; KCET 1998) © tfect Aromatic properties of benzen Somer are proved by (a) Aromatic sextet 1 the (©) Molecular orbital thee (CBSE PMT 1998) (a) -NRp<-OR>-F —(b) _NR, > ORs () -NRp<-OR<-F (d) -NR, >-OR <-F Benzene is unreactive because (a) Ithas double bonds (b) Ithas carbon-carbon single bond (c) Carbon are sp? hybridised (d)_x electrons are delocalised IKCET 1998) Carboxylic acids are easily ionised. The main reason of this statement [UPSEAT 1999] (a) Absence of a-hydrogen (b) Resonance stabilisation of carboxylate ion (c)_ Reactivity of achydrogen (d) Hydrogen bond “C-C" bond length in benzene lies between single and double bond. The reason is IRPET 1999} (a) Resonance (b) Isomerism () Metamerism (@) Inductive eect in may be 15, Polarisation of electrons in acrolein may E—_ EE ———— chemistry 1445 es organic ~ General eer 7 eg aracre edit fo te ng Suc ay (a ate 1) Bone iten as wit 40001 (a) CHf =CH-CH® =O (o) CHf =CH-CH=0" (CHE «cH ~cH-0 (@) CH =cH-cH =o 16. Which of the following free radical is most stable (AMU 2016) een © An @ Aw 17. Which among following statements are true with respect to ‘electronic displacement in a covalent bond (1) Inductive effect operates through bond (2) Resonance effect operates through a'bond (3) Inductive effect operates through otbond (4) Resonance effect operate through bond (5) Resonance and Inductive effect operate through bond IKCET 2006; Kerala PMT 2008} (a) Sand 4 (b) Land2 () 2and4 (a) Land3 (©) 2and3 18. Arrangement of (CH3)s—C-(CHy)z-CH-CH,-CH,-CH, when attached to benayl or an unsaturated group in increasing order of inductive effect is TAIEEE 2002} (2) (CHs)3 -C-<(CH,), ~CH-< CH, ~CH, - (0) CHs ~CHy~< (CH), ~ CH~ <(CH,), -C- (0) (CH), ~CH-<(CH,), -C-ms, ©) 1>0>q ) t>n>1 @ ton ct > () > a (4) a> (im) > ay) > of stability (2) ct) > avy > «wy > @y (ay > ay > > ay ‘Which isthe decreasing order () CHy~Ch-cH, i) CH; -CH-o-cH, (ii) CH -CH-Co-cH, UIT JEE 1993; alms 2007) (2) (<(t)

    Gid> Gay (Gi) > Gi) > (4) > Gi >) The order of decreasing stability ofthe catbanions (1) (CHy),€ (2) (CH), CH (3) CH CH, (4) GHCH, is IKCET 1996) (@) 1>2>3>4 (b) 4>3>2>1 () 4>1>253 (d) 1>2>453 31. 32, 33, 34, 35. 36. ‘Choose the chain terminating step () Hy oH +h (2) Baw (3) Bre +HBr-»H" Br (4) H+ Br, “te, (5) Br* + Br’ + Bry TRY on (3 4 (5 Te compound, which ges he MOH SHE coy ‘on dehydrogenation (PSEA ay (a) CH, ~ CH~CH,OH " “Hy CH 0) cHy-€ oe CH; (@)_ CH, ~CH, -CH, ~CH,OH (8) ClHy ~ CH -CH, ~CHy CH, are lowit quires radical intermediate ‘Which of the following requ (Odlaha see, su (a) CH; ~CH =CH, + HBr > CH, “ge, cn (0) CHy ~CHO + HON + CH, -CH< (©) Chg -CH = CHly + HBr > CHy ~CHly~ Cp -g, (@)_CH,CHO + NH,OH—!»CH, ~CH = Noy The stabity of MeC=CH, i more than tha, MeCH,CH = CH, due to (WB JEE 20) (2) Inductive effect ofthe Me group (b) Resonance effect of the Me group (6). Hyperconjugatve effec ofthe Me group (@) Resonance aswell as inductive efecto the Me goup Jn hich of the folowing species the cent Caiem negatively charged (a) Carbanion (b) Carbonium ion {c) Carbocation (d) Free radical ‘Among the following carbocations (0. PhyC*CH,Me (ll) PRCH,CH,CH*Ph, (Ml) PhyCHCH* Me (IV) PhyCiMeycHs ‘The order of stability is (WB JEE 20 () W>u>i>m (o) 1>0>m>1 (@ U>I>wom (@) 1>1V>m>0 ‘Which ofthe following contain three pits of electrons (BHU 198 (2), Carbocation (b) Carbanion (6) Free radical (4) None of these The least stable free radical is (Kerala PET 20 (a) CH; CH, (b) CH.CH, CH, (2) (CH),0H (@) (CH) (e) CH, a 39. a. 43. 47. ——— ‘Among the sive cations. the mon wabio op he most stable carbon (UT ger 4: bynes MNR A co senate: CBSE aT isa, aos 9: 200: {e)_m-butyi (0) Ter-buy, Ine comPoAn Gren! Health HN: a Wnt a COOH Cy ea ‘order of the ‘acidity of the positions OX), (Y) and fa) (2) > (xX) > (NT JEE Screening 2004} ” © M>M>a M>|>y aw. CClond length in benzene g” > (MP Por 129A 1987, 2001; AIIMS 2001) (b) 154A (0 134A (@) Different in different bonds Heterolysis of carbon-chitine bond produces (a) Twoftee radicals “NN 1986: MP PEt 1956 (b) Two carbonium ions (0) Two carbanions (4) One cation and one anion In CHSCH2OH, the bond that undergoes heterlytic cleavage most readily is (IT JEE 1988; MP PMT 2005] fa) C-C (b) C-0 () C-H (6) 0-H ‘Which of the following intermediate have the complete octet around the carbon atom, (Oats SEE 2005) (a) Carbonium ion (b) Carbanion ion (0) Free radical (@) Carbene A solution of D (+) - 2-chloro-2-phenylethane in toluene racemises slowly in the presence of small amount of SbCIs, due to the formation of IIT JEE 1999; JEE (Mains) 2013; WB JEE 2013) {a) Carbanion (0) Carbene (c) Free radical (€) Carbocation ‘The reagent in Friedel Crafts reaction is ([DPMT 2005), (a) Pyridine (b) RCOCI (c) RCOOH (@) Her Which gives monosubstituted product (DPMT 2005), (a) 0 -dinitrobenzene (¢) _p-dinitrobenzene (b)_m -

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