New Light Classes

12B-Che Date-20/01/2022

a. carbinoamine CH3-N-CH3
1. Select the incorrect statement-
CH2OH
a. Methyl cyanide is reduced to methyl
b. imine CH3N=CH2
amine by LiAIH4
c. formyldimethylamine CH3-N-CH3
b. Methyl isocyanide is hydrolysed to
CHO
methyl amine
d. None of the above
c. Homologated 1o amine is obtained in
5. Select the correct statement(s)-
𝑁𝑎𝐶𝑁 𝐿𝑖𝐴𝐼𝐻₄
the process R-Br → → a. Primary and secondary amines are
d. Acetamide is reduced to ethyl amine hydrogen-bonding acceptors
by LiAIH4 b. All the three classes of amines are
2. RNH2 can be converted into R2NH (and no hydrogen-bonding donors
other amine) by- c. Tertiary amines cannot hydrogen-bond
a. its reaction with RX with other amine molecules because
b. its reaction with (CHCI3/KOH, ∆) of the absence of a hydrogen bonded
followed by reduction to nitrogen
c. its reaction with (CHCI3/KOH, ∆) d. All of the above are correct statements
followed by hydrolysis 6. Which has the highest value of pKb?
d. all of the above
3. Identify product of the following reaction a. NH2

Br + NH3 →

b. N-H

a. NH2
c. –NH2

H
b. N d. N

7. Which is the strongest conjugate acid?

c. NH2Br
a. –NH3
d.

b. (CH3)2NH
4. CH3NHCH3 by reduction amination using CH2O
changes to (CH3)3N through an intermediate- c. – NH3
 New Light Classes
12B-Che Date-20/01/2022

d. –CH2NH3 c. N-methylpiperidine
d. N, N-dimethylclohexylamine
13. Amides can be converted into amines by a
8. Which is the best leaving group? reaction named after-
a. N2 a. Perkin
b. OH⊝ b. Claisen
c. N𝐻2⊝ c. Hofmann
d. CH3COO⊝ d. Kekule
𝐻𝑁𝑂₂ 𝐻𝑁𝑂₂ 𝑃𝐶𝐼₅ 𝑁𝐻₃
9. CH3CH2CH2NH2 → A (mixture) Mixture can 14. C2H5NH2 → A → B → C. the compound
contain- “C” is identified as-
a. CH3CH2CH2OH a. acetamide
b. CH3CHCH3 b. ethylamine
OH c. ethyl cyanide
c. CH2-CH3 d. methyl amine
CH2 15. The source of nitrogen in Gabriel synthesis of
d. All of these amine of-
10. Dipole moment of a. NaN3
I. CH3CH2CH3 b. NaNO2
II. CH3CH2OH c. KCN
III. CH3CH2NH2 d. C6H4(CO2)2N-K+
Will be in order-
a. I<II<III Answer Key
b. III<II<I 1-a
c. I<III<II 2-c
d. II<III<I 3-d
11. Maximum pKb value is of- 4-a
5-d
a. –NHCH3 6-c
7-c
8-a
b. (CH3CH2)2NH 9-d
c. (CH3)2NH 10-c
11-d
d. –NH- 12-b
13-c
14-b
12. Which of the following is a secondary amine? 15-d
a. 2-butanamine
b. N-ethyl-2-penatanamine