All India Test Series: Fiitjee

FIITJEE
ALL INDIA TEST SERIES

FULL TEST – III
JEE (Main)-2022
TEST DATE: 04-01-2022
Time Allotted: 3 Hours Maximum Marks: 300
General Instructions:
 The test consists of total 90 questions.
 Each subject (PCM) has 30 questions.
 This question paper contains Three Parts.
 Part-A is Physics, Part-B is Chemistry and Part-C is Mathematics.
 Each part has only two sections: Section-A and Section-B.
 Section – A : Attempt all questions.
 Section – B : Do any five questions out of 10 Questions.
Section-A (01 – 20, 31 – 50, 61 – 80) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
Section-B (21 – 30, 51 – 60, 81 – 90) contains 30 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer. There is no negative marking.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-III-PCM-JEE(Main)/2022 2
Physics PART – A
SECTION – A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. What are the dimensions of electrical permittivity?

–2 –2 –2
(A) ML T Q
–1 2 –3 –1
(B) M LT Q
(C) M–1 L–3T2Q2

–1 3 –2 –2
(D) M LT Q
Ans. C
Sol. Permittivity  
ch arg e2 
Q2
 M 1L3 T 2 Q 2
2
force  dis tan ce 
2 2
MLT  L
2. Two particles A and B are projected simultaneously in the directions vB= 10 3 m/s
shown in figure with velocities v A  25m/s and v B  10 3 m/s. If they vA=25m/s
collide in air after 2s, the angle  is
 60°
x
(A) 30°
(B) 45°
(C) 53°
(D) 37°
Ans. D
Sol. For collision, vB= 10 3 m/s

vA sin  = vB sin 60°
vA=25m/s
3
25 sin  = 10 3   60°
2
x
3
sin  =
5
or = 37°
3 AITS-FT-III-PCM-JEE(Main)/2022
3. A uniform chain of length L has one of its end attached to the wall at
A
3L
point A, while of the length of the chain is lying on table as shown 37°
4
in figure. The minimum co-efficient of friction between table and chain
so that chain remains in equilibrium is
(A) 1/3
(B) 1/4
(C) 3/4
(D) 1/5
Ans. B
L F
Sol. F cos 37  g N
4 T f
T
(where  is the mass/length of the chain). L
g 3L
F sin 37  T  f  N 4 g
4
1 1
    min 
4 4
4. A block of mass m is released from rest when the extension in the k
spring is x0. The maximum downward displacement of the block is
Mg
(A)  x0
2k
Mg
(B)  x0
2k
2Mg
(C)  x0
k
2Mg
(D)  x0
k
Ans. A
Sol. If block M moves a distance of x the extension in spring increases by 2x.

By work energy theorem,
1
k[ x02  ( x 0  2 x ) 2 ]  Mgx  O
2
1
 k ( 4 x 2  4 xx0 )  Mgx  O
2
1
k ( 4 x  4 x 0 )  Mg
2
Mg
x  x0 
2k
Mg
x  x0
2k
5. A particle is projected with such a velocity that its range is R. The particle
undergoes elastic collision with a wall placed at a distance of x (> R/2). x
The horizontal distance of point of projection and point where particle
hits the ground is R
(A) R+x
(B) x–R
(C) 2x – R
(D) R + 2x
Ans. C
Sol. Since collision is elastic, the horizontal velocity reverses its direction.
6. A ball of mass m is attached to the end of a thread fastened to the top of a O

vertical rod which is fitted to a horizontally revolving round table as shown. If w
l
the thread forms an angle  with the vertical, the angular velocity  of table
is r
g
(A)
l cos 
r
(B)
g tan 
g tan 
(C)
r  l sin 
g tan 
(D)
r
Ans. C
Sol. T sin   m 2 R Tcos

T cos   mg T 
2 R Tsin
tan  
g
mg
g tan  g tan 
  R= r+lsin
R r  l sin 
7. An artificial satellite of mass m is moving in a circular orbit at a height equal to the radius R of the
earth. Suddenly due to internal explosion the satellite breaks into two parts of equal masses. One
part of the satellite stops just after the explosion. The increase in the mechanical energy of the
system (satellite + earth) due to explosion will be
(Given: acceleration due to gravity on the surface of earth is g)
(A) mgR
mgR
(B)
2
mgR
(C)
4
3mgR
(D)
4
Ans. C
m m
Sol. Conserving momentum during the explosion mv   0  v' or v' = 2v
2 2
1m 1 1
Increase in the mechanical energy = K + U = K + 0 = ( 2v) 2  mv 2  mv 2
2 2 2 2
GMm mgR  GM 
=  v  
4R 4  2R 
8. A container has two immiscible liquids of densities 1 and 2 (>

1). A capillary tube of radius r is inserted in the liquid so that
its bottom reaches upto the denser liquid. The denser liquid
rises in the capillary and attains a height h from the interface of h 1
the liquids, which is equal to the column length of the lighter
liquid. Assuming angle of contact to be zero, the surface
tension of heavier liquid is 2
(A) 2r 2 gh
 2 rgh
(B)
2
r
(C)  2  1 gh
2
(D) 2r  2  1 gh
Ans. C
2T r
Sol. P0  h1 g   2 gh   P0 , T   2  1 gh
r 2
9. A cylindrical vessel contains a liquid of density  upto a height h. The liquid

is closed by a piston of mass m and area of cross-section A. There is a m, A
small hole at the bottom of the vessel. The speed v with which the liquid
comes out of the hole is: (neglect presence of atmosphere)
h
v
(A) 2 gh
 mg 
(B) 2 gh  
 A 
 mg 
(C) 2 gh  
 A 
mg
(D) 2 gh 
A
Ans. B
Sol. Applying Bernoulli’s theorem at 1 and 2

mg 1 2 m, A
gh   v
A 2 h
1 2
v
 mg 
or v  2 gh  
 A 
10. Find the natural frequency of the system as shown in figure. The pulleys are
massless and frictionless. k
2 k
(A)
 m
1 k
(B)
2 m
4 k
(C)
 m
8 k
(D)
 m
Ans. A
Sol. Let m is displaced downward by x from its mean position then spring will stretched by x0  4 x .
x0 2 2 k
 x , m x  4 kx0  16 kx  f 
4  m
11. A stationary wave is set up on a string fixed at both ends. The distance between two consecutive
nodes is 18 cm at a particular mode of vibration and for the next higher mode of vibration in the
same string the distance between two consecutive nodes is 16 cm. The length of string is
(A) 144 cm
(B) 140 cm
(C) 36 cm
(D) 32 cm
Ans. A
1 
Sol. n  n  1 2 … (i)
2 2
(Given  1 = 36, 2 = 32)
n=8
n 1
 l  l = 144 cm
2
12. The give curve represents the variation of temperature as a function of T

volume for one mole of an ideal gas. Which of the following curves
represents the variation of pressure as a function of volume?
To 45°
(A) P (B) P
V V
(C) P (D) P
V V
Ans. A
Sol. T  V tan 45  T0

T  V  T0
PV
For one mole of an ideal gas T 
R
PV
  V  T0  ( P  R ) V  RT0
R
Hence graph is rectangular hyperbola given in option (a).
13. A solid conducting sphere having a charge Q is surrounded by an uncharged concentric

conducting hollow spherical shell. The potential difference between the surface of solid sphere
and the outer surface of the hollow shell is V. If the shell is now given a charge of –3Q, the new
potential difference between the same two surfaces is
(A) V
(B) 2V
(C) 4V
(D) –2 V
Ans. A
Sol. In the given situation potential difference is independent of charge on outer shell.
14. A potentiometer wire AB is 100cm long and has total 10V

resistance of 10. Find the value of unknown resistance R so
that null point is obtained at a distance 40 cm from A.
40cm
C B
A
E = 5V G
r = 1
(A) 1
(B) 2
(C) 3
(D) 4
Ans. D
10 5
Sol.  40  5   1  R = 4
100 R 1
15. A conducting wire bent in the form of a parabola y  2 x carries a

2 y i A
current i = 2A as shown in figure. This wire is placed in a uniform
 2.0
magnetic field B  4kˆ tesla. The magnetic force on the wire is O x(m)
(A) –16 iˆ
(B) 32 iˆ
(C) –32 iˆ
(D) 16 iˆ
Ans. B
 
Sol.     
Fm  2 4  ˆj  4  kˆ = Fm  32iˆ
16. A very long uniformly charged rod falls with a constant velocity V through the +
center of a circular loop. Then the magnitude of induced emf in loop is (charge +
+
per unit length of rod = ) +
+
+
+
+
0
(A) V 2
2
0
(B) V 2
2
0
(C) V
2
(D) zero
Ans. D
Sol. Magnetic flux linked with the loop is always zero.

So induced emf is also zero
17. A capacitor of capacity 2 F is charged to a potential difference of 12V. It is then connected

across an inductor of inductance 0.6 mH. The current in the circuit at a time when the P.D. across
the capacitor is 6.0 V is
(A) 0.6 A
(B) 1.2 A
(C) 2.4 A
(D) 3.6 A
Ans. A
1 10 5
Sol.  
LC 12
q  q 0 cos t
2  10 6  6  2  10 6  12 cos t
1 
cos t   t 
2 3
dq
i   q0  sin t
dt
i=6A
18. A thin converging lens of refractive index 1.5 has power of +5D. When this lens is immersed in a
liquid, it acts as a diverging lens of focal length 100 cm. The refractive index of the liquid is
(A) 2
15
(B)
11
4
(C)
3
5
(D)
3
Ans. D
1 2 =1.5
Sol. P  (  1)
f R 
2
P  (1.5  1)  5
R
R = 20 cm
Focal length of this lens in medium (  ' )
1    2  1.5  2
   1    1
f '  '  R  '  20
 1  1. 5  1 1.5 1 9
   1   1 
10  ' 1 ' 10 10
15 5
'  
9 3
19. Unpolarized light of intensity 32Wm–2 passes through three polarizers such that transmission
axes of the first and second polarizer makes and angle 30° with each other and the transmission
axis of the last polarizer is crossed with that of the first. The intensity of final emerging light will be
–2
(A) 32 Wm
(B) 3 Wm–2
(C) 8 Wm–2
(D) 4 Wm–2
Ans. B
Sol. I 0  32 Wm -2
I0
After passing through first polarizer, I 1  = 16 W/m2
2
2
After passing through second polarizer, I 2  I1 cos 30  12 W/m2
2
After passing through third polarizer, I 3  I 2 cos 60  3 W/m2
20. When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have
maximum kinetic energy TA eV and de Broglie wavelength A. The maximum kinetic energy of
photoelectrons liberated from another metal B by photons of energy 4.70 eV is
TB  (T A  1.50) eV. If the de Broglie wavelength of these photoelectrons is B = 2A, then
choose the incorrect statement.
(A) the work function of A is 1.25 eV
(B) the work function of B is 4.20 eV
(C) TA = 2.00 eV
(D) TB = 0.5 eV
Ans. A
Sol.  B  2 A  4TB  TA
TB  TA  1.5
TB  0.5 eV
T A  2 eV
 A = 2.25 eV and B = 4.2 eV
SECTION – B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
21. A binary star consists of two starts A (mass 2.2 MS) and B (mass 11 MS), where MS is the mass of
the sun. They are separated by distance d and are rotating about their centre of mass, which is
stationary. The ratio of the total angular momentum of the binary star to the angular momentum of
star B about the centre of mass is
Ans. 00006.00
L total (IA  IB )w m A rA2 11

Sol.   2
 1  1 6
LB IB .w mBrB 2.2
22. Degree of freedom for a gas is 6. This gas does 25 J of piston work at constant pressure. Net
heat absorbed by the gas during this process is ……… .
Ans. 00075.00
Sol. Work done at constant pressure is

 1
W   1    Q total
 r
 1
 25   1   Qtotal
 r
2 2
But, r  1  1
f 6
4
or r
3
 3
So, 25   1    Q total
 4
or Q total  100 J
So, net heat absorbed by the gas = 100 – 25 = 75 J
23. A thin plano-convex lens of focal length f is split into two halves. One of
the halves is shifted along the optical axis. The separation between
object and image planes is 1.8 m. The magnification of the image formed
by one of the half lens is 2. Find the separation between the halves.
Ans. 00000.60
v
Sol.  2 or u  2 u
u
When u = –x, then v = + 2x and x  v  1.8m
 3x  1.8m or x  0.60 m
24. A uniformly charged thin spherical shell of radius R carries uniform

surface charge density 6 per unit area. It is made of two hemispherical
shells, held together by pressing them with force F. The value of F will
2 2
be (Take,  R = 40)
Ans. 00002.00
Sol. For the given area total force will be u dA

When dA is the area, then electrical force per unit area
2
1 1    2
  0E 2  0   
2 2  20  2ge0
Projection area  r 2
 2  2
 Net electrical force    ( R )
 2 0 
In equilibrium, this force should be equal to the applied force,
2R 2 40
F  2
2 0 20
25. Find charge supplied by the cell after the switch is closed (in C)
Ans. 00016.80
Sol. The potential difference across 1 F and 2 F (uppermost) capacitor

must sum up to
q q/2 24
 6q C
1 2 5
24
 Answer is 12   16.8C
5
26. Light of wavelength 1800 Å ejects photoelectrons from a plane of a metal whose work function is
2 eV. If a uniform magnetic field of 5  10–5 tesla is applied parallel to plate, what would be the
radius of the path (in metre) followed by electrons ejected normally from the plate with maximum
energy.
Ans. 00000.15
Sol. Energy of incident photons in eV is given as

12431
E eV
1800
As work function of metal is 2eV, the maximum kinetic energy of ejected electrons is
KEmax  E  
 KEmax  6.9  2eV
 KEmax  4.9eV
If max be the speed of fastest electrons then we have
1 2
m max  4.9  1.6  1019 joule
2
2  4.9  1.6  10 19
  max 
9.1 10 31
  max  1.31 10 6 m/s
When an electron with this speed enters a uniform magnetic field normally it follows a circular
path whose radius can be given by
mv mv 2
r [As qvB  ]
qB r
9.1 10 31  1.31 106
 r
1.6  10 19  5  105
 r  0.149 m
27. A U tube contains water and methylated spirit separated by mercury. The mercury columns in the
two arms are at the same level with 10.0 cm of water in one arm and 12.5 cm of spirit in the other.
What is the relative density of spirit?
Ans. 00000.80
Sol. For water column in one arm of U tube, h1 = 10.0 cm; 1 (density = 1 gcm–3)
For spirit column in other arm of U tube, h2 = 12.5 cm; 2 = ?
As the mercury columns in the two arms of U tube are in level, therefore pressure exerted by
each is equal.
h11 10  1
Hence h11 g  h2  2 g or  2    0.8 g cm–3
h2 12.5
Therefore, relative density of spirit = 2 /1 = 0.8 / 1 = 0.8
28. In an -decay the kinetic energy of -particle is 48 MeV and Q-value of the reaction is 50 MeV.
The mass number of the mother nucleus is X. Find the value of X/4. (Assume that daughter
nucleus is in ground state)
Ans. 00025.00
my
Sol. We have K   .Q
my  m
A4 A4
 K  .Q  48  .50  A  100
A A
29. Electrons in hydrogen like atom (Z = 3) make transitions from the fifth to the fourth orbit and from
the fourth to the third orbit. The resulting radiations are incident normally on a metal plate and
eject photoelectrons. The stopping potential for the photoelectrons ejected by the shorter
wavelength is 3.95 volts. Calculate the work function of the metal (in eV).
7 –1
(Rydberg constant = 1.094  10 m )
Ans. 00002.00
Sol. For hydrogen like atom energy of the nth orbit is

13.6 2
En   Z eV/atom
n2
For transition from n = 5 to n = 4,
1 1  13.6  9  9
hv  13.6  9     16  25  2.754 eV
 16 25 
For transition from n = 4 to n = 3,
 1 1  13.6  9  7
hv  13.6  9      5.95 eV
 9 16  9  16
For transition n = 4 to n = 3, the frequency is high and hence wavelength is short.
For photoelectric effect, hv - W = eV0, where W = work function
5.95  1.6  10–19 – W = 1.6  10–19  3.95
 W = 2  1.6  10–19 = 2 eV
30. The convex surface of a thin concavo-convex lens of glass of

refractive index 1.5 has a radius of curvature 20 cm. The concave
surface has a radius of curvature 60 cm. The convex side is silvered
and placed on a horizontal surface. At what distance should a pin be
placed on optical axis so that image is formed at same place.
Ans. 00015.00
Sol. This silvered concavo-convex lens behaves like a mirror whose focal length can be calculated by
the formula
1 2 1
 
f f1 f2
f 1 = focal length of concave surface.
f 2 = focal length of concave mirror.
1 2 1 4
   
f 30 10 30
 f = –7.5 cm
Using mirror formula
1 1 1 1 1 1
      x  15 cm
f v u 7.5  x  x
Chemistry PART – B
SECTION – A
31. When the letters shown have their usual meanings, the velocity of photoelectrons is:
1/2
 2hc  0   
(A)   
 m  0 
2
 2hc  0    
(B)   
 m  0  
2hc
(C)
m
2
 m 
(D)  
 2hc 
Ans. A
Sol. KE  h(v  v 0 )
1 1 1 
mv 2  hc   
2   0 
2hc  0   
v2   
m   0 
32. Which of the following properties is not shown by NO?
(A) It is a neutral oxide
(B) It combines with oxygen to form nitrogen dioxide
(C) Its bond order is 2.5
(D) It is diamagnetic in gaseous state
Ans. D
Sol. NO has total 15 electrons and one electron is unpaired.
33. AlCl3 and FeCl3 can be separated from their mixture by using:
(A) NH4OH
(B) NaOH
(C) H2O
(D) magnetic method
Ans. B
Sol. AlCl3 dissolves in aqueous NaOH while FeCl3 gives brown ppt. of Fe(OH)3 which on separation
can again be converted to respective chlorides.
NaOH
AlCl3  3NaOH 
3NaCl
 Al(OH)3 
 Na[Al(OH)4 ]
solution
FeCl3  3NaOH 
3NaCl
 Fe(OH)3
(brown ppt.)
34. OH
+
 ; Major product is ........

(A) OH (B) OH
(C) OH (D) OH
Ans. A
Sol. OH
OH
+
(for 1,4-addition)
35. What is R in the following set of reactions?

COOH
CH2
SOCl AlCl
Zn/Hg/HCl

2
 P 

3
Q  R
(A) (B)
CH2
OH
(C) (D)
Ans. C
Sol. CH2 CH2
SOCl AlCl

2
 2

HO C C
Cl
O O
(P)
ZnHgHCl
 
O
(Q)
(R)
36. Which of the following species has the shortest bond length?
(A) NO2-
(B) NO+
(C) NO
(D) NO-
Ans. B
Sol. MOT of NO,

* *
1s2  1s 2  
2s2
 2s 2  
2px 2
 2py 2  2pz 2  px1  2py
10  5
B.O   2.5
2
For NO 
10  4
B.O.  3
2
For NO2 
10  7
B.O.   1.5
2
10  6
For NO  ,B.O.  2
2
1
Bond length 
Bond order
37. Consider the standard reduction potentials (in volts) as shown below. Find Eo.
0.936 0.576 1
SO24   SO32   S2O32
2
Eo  ?
(A) 0.326 V
(B) 0.425 V
(C) 0.756 V
(D) 0.512
Ans. C
Sol. Go  G1o  Go2

nFEo  nFE1o  nFEo2
4FEo  2F  (0.936)  2F(0.576)
4Eo  2  0.936  2  0.576
1.872  1.152
Eo   0.756
4
38. 100 mL of 0.2 M CH3COOH, 50 mL of 0.1 M HCl and 50 mL of 0.5 M NaOH are mixed together at
25°C If Ka (CH3COOH) = 10-5, then pH of the resulting solution will be;
(A) pH = 8
(B) pH = 9
(C) pH = 8.5
(D) pH = 9.5
Ans. B
Sol. (1) HCl + NaOH  NaCl+H2

5 25 0
0 20 5
(2) CH3 COOH + NaOH  CH3 COONa+H2 O

20 20 0
0 0 20
20
C  0.1M
200
1
pH  7  {5  log(0.1)}  9
2
39. Which of the following does not exist?
(A) PF5
(B) SF4
(C) BiI5
(D) BiI3
Ans. C
Sol. BiI5 doesn’t exist due to the inert pair effect of Bi and reducing property of I--.
40. For equilibrium process S8(g)  4S2 (g) reaction starts with S8(g), at equilibrium V.D. of mixture
is found to be 64. Calculate degree of dissociation of S8.
(A) 2/3
(B) 1/3
(C) 4/3
(D) 5/3
Ans. B
Sol. S8  4S2
1 
32  8
1  3  2
32  4
1
 
3
41. What is the free energy change for the process:
H2 O(l, 10o C,0.28Pa,1 mole)  H2O
(s, -10o C,0.26 Pa, 1 mole)
Given that vapour pressure of water and ice at
-10°C is 0.28 and 0.26 Pa respectively.
14
(A) R  263  ln
13
13
(B) R  263  ln
14
13
(C) R  10  ln
14
(D) Zero
Ans. B
Sol. dG  VdP  SdT

dG  VdP (T=constant)
P   0.26 
G  nRT ln  2   263R ln  
 P1   0.28 
 13 
 263Rln  
 14 
42. Beryllium shows diagonal relationship with aluminium, which of the following is incorrect?
(A) Be2C like Al4C3 yields methane on hydrolysis
(B) Be, like Al is not rendered passive by HNO3
(C) Be(OH)2 like Al(OH)3 is basic
(D) Be forms beryllates and Al forms aluminates
Ans. C
Sol. Factual
43. Select the incorrect statement.
(A) In alkaline solution XeO3 forms xenate ions
(B) Perxenate ions can be formed by disproportionation of xenates in alkaline conditions
(C) In perxenates Xe is in +6 oxidation state
(D) Perxenates can act as oxidizing agents
Ans. C
Sol. Xenates (+6), Persenates (+8)

XeO3  NaOH  Na  [HXeO 4 ]
2[HXeO 4 ]  2OH  [XeO6 ]4   Xe  O2  2H2 O
44. Which one of the following pairs of isomers and types of isomerism are correctly matched-
(P) [Co(NH3 )5 (NO2 )]Cl2 and [Co(NH3 )5 (ONO)]Cl2 ... linkage
(Q) [Cu(NH3 )4 ](PtCl4 ) and [Pt(NH3 )4 ][CuCl4 ].... co-ordination
(R) [Pt(NH3 )4 Cl2 )] Br2 and [Pt (NH3 )4 Br2 ]Cl2 .....ionization
Select the correct answer using the codes given below:
(A) Q and R
(B) P, Q and R
(C) P and R
(D) P and Q
Ans. B
Sol. Factual
45. IUPAC name of the complex compound Na3 [Cr(O)2 (O2 )(O2 )2 (NH3 )] where half of the
coordination number are occupied by neutral ligands with magnetic moment   15 must be:
(A) Sodium amminedioxodioxygensuperoxochromate (III)
(B) Sodium amminedioxygendioxodisuperoxochromate (III)
(C) Sodium amminebisdioxygendioxoperoxochromate (III)
(D) Sodium amminebisdioxygendioxoperoxochromium (III)
Ans. C
Sol. Factual
46. An aqueous solution of colourless metal sulphate M, gives a white ppt., with NH4OH. This was
soluble in excess of NH4OH. On passing H2S through this solution a white ppt. Is formed. The
metal M in the salt is:
(A) Ca
(B) Ba
(C) Al
(D) Zn
Ans. D
Sol. Zn2   2NH3  2H2O  Zn(OH)2  2NH4

2
Zn(OH)2  4NH3  [Zn(NH3 )4 ](soluble)  2OH
Zn2  H2S  ZnS   2H

(white ppt)
47. A pale green crystalline metal salt of M dissolves freely in water. On standing it gives a brown ppt.
On addition of aqueous NaOH. The metal salt solution also gives a black ppt. On bubbling H2S in
basic medium. An aqueous solution of the metal salt decolourizes the pink colour of the
permanganate solution. The metal in the metal salt solution is:
(A) copper
(B) aluminium
(C) lead
(D) iron
Ans. D
Sol. The salt could be iron (II) sulphate, in the presence of NaOH and air is oxidised to ferric
hydroxide. On passing H2S forms FeS which is black in colour, potassium permanganate oxidises
Fe+2 to Fe3+ and itself get reduced to Mn+2 due to which the pink colour disappears.
48. In which of the following cases the compound written on right shows the mentioned phenomenon
more than the compound written on left?
(p)
(acidity)
(q) O O
Br
(acidity)
H H
(r) O
H3C
OEtH3C . (Nucleophilic attack)
O
. .
(A) p, q
(B) q, r
(C) p, r
(D) in all
Ans. B
Sol. Factual.
49. A mixture of organic compound responded positively for following reagents (X, Y, Z):
(i) PhSO 2Cl (i) Zn/NH4Cl
(X) (ii) KOH
;(Y) = 
(ii) Tollen's reagent
;
(Z) = Na metal.
The mixture has:
(A) OH NH2 NO 2
+ +
(B) NH2 COOH

+
(C) H3C CH2 CH CH 2 N CH3
NO 2 C2H5
C CH
+
(D) H C C CH2 CH2 N CH3
CH3
N O
OH
Ans. A
Sol. A primary amine gives positive test with Hinsberg reagent (PhSO2Cl), a –NO2 group gives
positive test with mulliken’s reagent (Zn/NH4Cl, Tollen’s reagent and an acidic functional group
gives positive test with sodium metal.
50. In Fishcher-Killiani synthesis, the anomeric carbon of the reactant:
(A) remains as carbonyl
(B) is lost as CO2
(C) becomes the new epimeric centre
(D) becomes a nitrile carbon.
Ans. C
Sol. Fischer-Killiani synthesis produces C-2 epimers.
SECTION – B
51. On the basis of the information available from the reaction;

4 2
Al  O2  Al2O3 ; G  827 kJ mol 1 of O2
3 3
The minimum EMF required to carry out electrolysis of Al2O3 is:
(1 F = 96500) C mol-1 of electrons)
Ans. 00002.14
Sol. 1 mol Al, n = 3 (electron exchanged)

4 4
mol Al,n   3  4
3 3
Go  nFE0  E0  2.14V
52. Calculate  (ratio of Cp and Cv) for triatomic linear gas at high temperature. Assume that the
contribution of vibrational degree of freedom is 75%:
Ans. 00001.18
3 3 11
Sol. Cv  R  R  4R   R;
2 4 2
11 13
Cp  R  R  R
2 2
Cp 13
  1.18
Cv 11
53. In the presence of excess of anhydrous SrCl2, the amount of water taken up is governed by Kp =
1012 atm-4 for the following reaction at 273 K
SrCl2 .2H2O(s)  4H2O(g)  SrCl2 .6H2O(s)
What is equilibrium vapour pressure (in torr) of water in a closed vessel that contains
SrCl2.2H2O(g)?
Ans. 00000.76
1
Sol. Kp 
PH42O( g)
1/ 4
 1 
 PH2 O(g)  
 K 
 p
 (10 )  10 3 atm
12 1/ 4
 K p  10 3  760  0.76 torr
54. Consider the following first order competing reactions:

k1 k2
X  A  B and Y  CD
If 50% of the reaction of X was completed when 96% of the reaction of Y was completed, the ratio
of their rate constants (k2/k1) is:
Ans. 00004.65
1 100
Sol. K 2  ln ...(i)
t 4
1 100
K 1  ln ....(ii)
t 50
K 2 ln 25
  4.65
K2 ln 2
55. If 0.50 L of a 0.60 M SnSO4 solution is electrolysed for a period of 30.0 min using a current of
2+
4.60 A. If inert electrodes are used, what is the final concentration of Sn remaining in the
solution?
[At. Mass of Sn = 119]
Ans. 00000.51
W 4.6  30  60
Sol. 2 
M 96500
2+
Moles of Sn reduced = 0.043
Initial moles of Sn2+  0.5  0.6  0.30;
2+
Remaining moles of Sn = 0.30 – 0.043
0.257
 [Sn2+ ]=  0.514M
0.5
56. 9.2 grams of N2O4(g) is taken in a closed one litre vessel and heated till the following equilibrium
is reached N2O 4 (g)  2NO2 (g)
At equilibrium, 50% N2O4(g) is dissociated. What is the equilibrium constant (in mol litre-1)
(molecular mass of N2O4 = 92)
Ans. 00000.20
Sol. N2O 4 (g)  2NO2 (g)

t = 0 0.0(1-) 2(0.1)
   0.5
[NO2 ]2
Kc 
[N2 O 4 ]
57. 9 moles of “D” and 14 moles of E are allowed to react in qa closed vessel according to given
reactions. Calculate number of moles of B formed in the end of reaction, if 4 moles of G are
present in reaction vessel. (Percentage yield of reaction is mentioned in the reaction)
80%
Step-1 3D  4E   5C  A
50%
Step-2 3C  5G   6B  F
Ans. 00002.40
Sol. L.R.
80%
3D  4E   5C  A
5
9 mole 14 mole  9  0.8  12 mole
3
50%
3C  5G   6B  F
12 mole 4 mole
L.R. is G
6
Moles of B formed   4  0.5  2.4
5
58. A sample of 28 mL of H2O2 (aq) solution required 10 mL of 0.1m KMnO4 (aq) solution for
complete reaction in acidic medium. What is the volume strength of H2O2?
Ans. 00001.00
Sol. Eq. of H2O2 = Eq. of KMnO4

(25  M  2)  (10  0.1 5)
M  0.089
Volume strength = M  0.1 =1
59. Calculate the value of A.

E
A  1,2 where En,Z  Energy of electron in nth orbit, Z = atomic number of hydrogen like
2E2,1
species.
Ans. 00008.00
E1,2 13.6  22  22 16
Sol. A   8
2E2,1 2  12  ( 13.6)  12 2
60. 2 mole of zinc is dissolved in HCl at 25°C. the magnitude of work done in open vessel is (in kJ)
Ans. 00004.95
Sol. w  P.V  nH2

2  8.314  298
RT    4.955 kJ
1000
Mathematics PART – C
SECTION – A
 
61. The vectors a and b are non-zero and non-collinear. The value of x for which vector
     
c = (x –2) a + b and d = (2x +1) a – b are collinear.
(A) 1
(B) 1/2
(C) 1/3
(D) 2
Ans. C
 
Sol. Since c and d are collinear.
 
We have pc  qd = 0 where p + q = 0 for some scalars p and q.
 
  
p { (x –2) a + b } + q{ (2 a +1) a – b } = 0
   
 p(x –2) = -q(2x +1) and p b =q b (since a, b are non-colinear)
 p(x –2) = - p(2x +1)
 x = 1/3.
62. If in ABC,  A = sin–1(x),  B = sin–1(y) and  C = sin–1(z), then

x 1  y 2 1  z 2  y 1  x 2 1  z2  z 1  x 2 1  y 2 is equal to
(A) xyz
(B) x+y+z
1 1 1
(C)  
x y z
(D) None of these
Ans. A
Sol. In a ABC
sin(A+ B+ C)= 0
= sinA cosB cosC + sinB cosC cosA + sinC cosA cosB – sinA sinB sinC
 xyz = x 1  y  2
1  z   y 1  x 1  z   z 1  x 1  x 
2 2 2 2 2
63. The value of a for which the equation 4cosec2( (a + x)) + a2 – 4a = 0 has a real solution, is
(A) a=1
(B) a=2
(C) a = 10
(D) None of these
Ans. B
Sol. 4 [1 + cot2 (a + x)] + a2 – 4a = 0

2 2
4cot  (a + x) + (a – 2) = 0
2
 a – 2 = 0 and cot  (a + x) = 0
 a = 2.
64. If a sinx + bcos(C + x) + bcos (C –x) = , then the minimum value of |cosC| is
 2  a2
(A)
b2
 2  a2
(B)
4b 2
 2  a2
(C)
16b 2
(D) None of these
Ans. B
Sol. We have asinx +2bcosCcosx = 

The maximum value of asinx + 2bcosCcosx is a 2  4b 2 cos 2 C
which increases as | cosC| increases. So the minimum value of |cosC| will correspond to the
situation when a 2  4b 2 cos 2 C is just equal to , so as to give a real solution of the
equation.
 a 2  4b 2 cos 2 C = 
2  a2  2  a2
cos2C = ; | cosC| = .
4b 2 4b 2
65. If 5a + 4b + 20c = t, then the value of t for which the line ax + by + c  1 = 0 always passes
through a fixed point is
(A) 0
(B) 20
(C) 30
(D) None of these
Ans. B
ax by
Sol. Equation of line   1  0 has two independent parameters. It can pass through a
c 1 c 1
fixed point if it contains only one independent parameter. Now there must be one relation
a b a
between and independent of a, b and c so that can be expressed in terms of
c 1 c 1 c 1
b
and straight line contains only one independent parameter. Now that given relation can be
c 1
5a 4b t  20c
expressed as   .
c 1 c 1 c 1
Now RHS be independent of c if t = 20.
66. Consider the equation x2 +x – n = 0, where n is an integer lying between 1 to 100. Total number
of different values of ‘n’ so that the equation has integral roots is
(A) 6
(B) 4
(C) 9
(D) None of these
Ans. C
Sol. x2 +x –n = 0, discriminent = 1+ 4n = odd number = D(say)

Now given equation would have a integral solution if D is a perfect square .
Let D = (2 +1)2  n =  +2 = ( +1) = even number
 n can be 2, 6, 12, 20, 30, 42, 56, 72, 90.
n
r2  r  1
67. r 1 r  1!
is equal to
n
(A)
(n  1)!
1
(B)
(n  1)(n  1)!
n
(C) 1
(n  1)!
(D) None of these
Ans. B
n n
r2  r  1 r 1 r  n
Sol. r 1 r  1!
  
r 1 r!
 
(r  1)!  (n  1)!
.
68. Two events A and B have probabilities 0.25 and 0.50 respectively. The probability that both A and
B occur simultaneously is 0.14. Then the probability that neither A nor B occurs is
(A) 0.39
(B) 0.25
(C) 0.11
(D) None of these
Ans. A
Sol. P(A) = .25, P (B) = .50, PA  B   .14

PA  B   P( A )  P(B )  P ( A  B)
= .25 + .50 – .14 = .61
   
P A  B  P A  B  1  PA  B  = 1 – .61 = .39
69. The number of positive integral solutions of the equation x1 x2 x3 = 60 is
(A) 54
(B) 27
(C) 81
(D) None of these.
Ans. A
Sol. Here x1x2 x3 = 22  3  5

Let number of two’s given to each of x 1 , x2 , x3 be a, b, c .
Then a + b + c = 2, a, b, c  0
The number of integral solutions of this equations is equal to coefficient of x 2 in (1 – x)-3 i.e. 4C2
i.e. the available 2 two’s can be distributed among x 1, x2 and x3 in 4C2= 6 ways.
Similarly, the available 1 three can be distributed among x 1, x2, x3 in 3C2 = 3 ways.
(= coefficient of x in (1 – x)-3)
4 3 3
 Total number of ways = C2  C2  C2 = 6  3  3 = 54 ways.
70. In a bag there are 15 red and 5 white balls. Two balls are chosen at random and one is found to
be red. The probability that the second one is also red is
12
(A)
19
13
(B)
19
14
(C)
19
15
(D)
19
Ans. C
14
C1 14
Sol. Probability that out of remaining balls the one that is red is =
19

C1 19
71. Let S be the set of 6-digit numbers a1a2a3a4a5a6 (all digits distinct)
where a1 > a2 > a3 > a4 < a5 < a6. Then n(S) is equal to
(A) 210
(B) 2100
(C) 4200
(D) 420
Ans. B
Sol. First, 6 distinct digits can be selected in 10C6 ways. Now the position of smallest digit in them is
fixed i.e. position 4. Of the remaining 5 digits, two digits can be selected in 5C2 ways. These two
digits can be placed to the right of 4th position in one way only. The remaining three digits to the
left of 4th position are in the required order automatically.
So n(S) = 10C6  5C2 = 210  10 = 2100.
72. If the normals at the end points of a variable chord PQ of the parabola y2 – 4y – 2x = 0 are
perpendicular, then the tangents at P and Q will intersect at
(A) x+y=3
(B) 3x – 7 = 0
(C) y+3 = 0
(D) 2x + 5 = 0
Ans. D
Sol. Since normals at P and Q are perpendicular, the tangents at P and Q will also be perpendicular
but any two perpendicular tangents of a parabola always intersect on its directrix.
The parabola is (y – 2)2 = 2( x +2). So its directrix is 2x + 5 = 0
4
73. If A is a skew–symmetric matrix of order 3, then matrix A is
(A) skew–symmetric
(B) symmetric
(C) diagonal
(D) None of these
Ans. B
Sol. We have A    A     A  A  A  A   A A A A 
and A 4
4
=   A   A   A   A    1 A 4  A 4
Hence (B) is the correct answer.
sin2 x, x rational
74. Let f(x) =  . Then set of points, where f (x) is continuous is
 sin2 x, x irrational
  
(A) 2n  1 , n  I
 2 
(B) null set
(C) {n, n  I}
(D) set of all rational numbers
Ans. C
Sol. If a is any number for which sin a  0, then we don’t get any fix tendency of f (x) to approaches
where x  a
so lim f (x) does not exist
x a
but if sin a = 0, lim f (x) = 0
x a
x7 / 2
75.  dx equals to
x9  1
(A) sin–1 x 2  9  c
1  x 9  1 
(B) In c
2  x 9  1 
2  9/2
(C) In  x  x 9  1   c
9  
(D) None of these
Ans. C
9/2 9 7/2
Sol. Put x x dx  dt , So given integral reduces to
= t then
2
2 dt 2 2
  In  t  t 2  1  c  In  x 9 / 2  x 9  1   c
9 t 1 9 
2  9  
76. Four points are such that the line joining any two points is perpendicular to the line joining other
two points. If three points out of these lie on a rectangular hyperbola then the fourth point will lie
on
(A) the same hyperbola
(B) conjugate hyperbola
(C) one of the directrix
(D) one of the asymptotes
Ans. A
Sol. The points are such that one of the points is the orthocentre of the triangle formed by other three
points. When the vertices of a triangle lie on a rectangular hyperbola the orthocentre also lies on
the same hyperbola.
x2  
77. The value of ‘’ so that the range of the function y = is R, is
x 1
(A) ( ,  2]
(B) ( ,  1]
(C) ( , 0)
(D) None of these
Ans. B
x2  
Sol. Given that y =
x 1
 x2  yx +   y = 0
 y2  4(  y)  0  y2 + 4y + 4  4 + 4
4 + 4  0     1.
(3 x  4 y  7 ) 2
78. The length of the major axis of the ellipse (5 x  10) 2  (5 y  15) 2  is
4
(A) 10
20
(B)
3
20
(C)
7
(D) 4
Ans. B
2
 1 3x  4y  7 
Sol. ( x  2) 2  ( y  3) 2    is an ellipse, whose focus is (2, -3), directrix 3x – 4y + 7
2 5 
1
= 0 and eccentricity is .
2
3  2  4  ( 3)  7
Length of  from focus to directrix is 5
5
a a 10
 ae  5  2a   5  a 
e 2 3
20
So length of major axis is
3
/2
n 1
79. If I(n) =   . sin
n
d , n  N, n > 3, then the value of I(n) - In  2 is
0
n
1
(A)
n2
1
(B)
n 1
1
(C) 2
n 1
1
(D)
n 1
Ans. A
/2
n
Sol. I(n) =   . sin
0
 d
/2
 I(n) =   . sin
n 2
 
 1  cos2  d
0
/2
  . cos  . cos . sin

n 2
= I(n-2) –  d
0
/ 2
sinn 1   / 2 sin n 1

= I(n-2) - .cos .
n 1 0
  . sin   cos .
0
n 1
d
/ 2 /2
1 1
= I(n-2) -  . sinn  d  n 1
 cos . sin  d
n  1 0
n 1 0
1 1 /2
= I(n-2) - .In   . sinn 
n  1 n  1n 0
n 1 n 1 1
 In   In  2  ,  I(n) – I(n –2) .  2 .
n 1 n  1n n n
x1 y1 z1
80. Let x1y1z1, x2y2z2 and x3y3z3 be three 3–digit even numbers and  = x 2 y2 z 2 . Then  is
x3 y3 z3
(A) divisible by 2 but not necessarily by 4
(B) divisible by 4 but not necessarily by 8
(C) divisible by 8
(D) none of these
Ans. A
100 x1  10 y1  z1 y1 z1 2A y1 z1
Sol.  = 100 x 2  10 y 2  z2 y2 z2 = 2B y2 z 2 , where A, B, C  I
100 x 3  10 y 3  z3 y3 z3 2C y 3 z3
A y1 z1
= 2 B y2 z2 , which is divisible by 2 but not necessarily by 4 or 8.
C y3 z3
SECTION – B
81. If the line y = 3x cuts the curve x4 + ax2y + bxy + cx + dy + 6 = 0 at A, B, C and D, then
OA.OB.OC.OD (where O is the origin) is
Ans. 00096.00
r r 3
Sol. The line y = 3x can be written as x = , y= . If this line cuts the given curve, then
2 2
r 4 ar 3 3 br 2 3 cr dr 3
     6  0.
16 8 4 2 2
Therefore OA. OB.OC.OD = |r1| |r2| |r3| |r4| = |r1 r2 r3 r4| = 96
82. The value of ‘a’ for which the equation  a 2  4a  3  x 2   a 2  a  2  x   a  1 a  0 has more than
two roots is –k, then the value of k+2020? is
Ans. 02021.00
Sol. a 2
  
 4a  3 x 2  a 2  a  2 x   a  1 a  0   a  1 a  3  x 2   a  1a  2  x  a  1 a  0
 a  1  a  3  x 2   a  2  x  a   0
if a = 1, then quadratic have more than two roots.
83. Equation of the normal to the curve x2 = 4y which passes through the point (1, 2) is x + y = k-12,
then k =
Ans. 00015.00
Sol. Equation of the normal to the curve x 2 = 4y is x = my – 2m – m3, passes through the point
(1, 2)  m = –1.
84. If the value of the sum 29  30   28  30   27  30   ......  1 30   0  30    30  where  n   n Cr ,

 0 1  2  28   29   30  r 
32
is equal to k2 , then the value of k is equal to
Ans. 00003.50
 30   30   30   30   30   30 
Sol. S  29    28    27    ......  1   0     
 0 1   2  28   29   30 
 2S  28  C 0  C1  C 2  ....  C30   28  230 
30 30 30 30
7 32 7
Hence, S  14  230  2 .  k 
2 2
85. Let A  a ij  be a 3  3 invertible matrix. If determinant value of matrix A is 3, then the value of
det((adjAT)T) + det.((adjA–1)–1) (where det(B) denotes determinant value of matrix B)
Ans. 00018.00
Sol. det((adjA T )T )  (det A)2  9

det((adjA 1 )1 )  (det A)2  9
86. If z1, z2, z3 are complex number such that |z1| = 2, |z2| = 3, |z3| = 4 then maximum value of
| z1  z 2 |2  | z 2  z 3 |2  | z3  z1 |2 is
Ans. 00087.00
Sol. | z1  z 2 |2  | z 2  z 3 |2  | z3  z1 |2
= 2(|z1|2 + |z2|2 + |z3|2) – (z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1 )
= 58 – (z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1 ) ……(1)
2
Now |z1 + z2 + z3|  0
2 2 2
 |z1| + |z2| + |z3| + z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1  0
 – (z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1 )  29 ……(2)
from (1) and (2)
maximum value = 58 + 29 = 87.
87. A point P (x, y) is said to be integral point iff both x, y are integers. Then number of integer points
2 2
inside or on the circle x + y = 9 is
Ans. 00029.00
Sol. Let (n, m) be a integer point, then

n2 + m2  9
if n2 = 9, m2 = 0  2  1 = 2 points
if n2 = 4, m2 = 0, 1, 4  2  5 = 10 points
2 2
if n = 1, m = 0, 1, 4  2  5 = 10 points
if n = 0, m2 = 0, 1, 4, 9  1  7 = 7 points
2
so in total, we have 29 points, which are integral points.
8 80 240
88. Let (1 + x)n = 3 
  4  .... , x, n  R. Then the sum of the series
3 33 3
8 80 240
3   3  4  .... is
3 3 3
Ans. 00027.00
8 80 240 n(n  1)x 2

Sol. (1+ x)n = 3   3  4  .... = 1 + nx + +....
3 3 3 2
2
On comparison, n = -3 and x = .
3
ai
89. If ai, i = 1, 2, 3, 4 be four real numbers of the same sign, then the minimum value of a j
,
i, j  {1, 2, 3, 4}, i  j, is
Ans. 00012.00
ai
Sol. a j
, i, j  {1, 2, 3, 4}, i  j has a total of 4  4 – 4 = 12 terms i.e. 6 pairs, each pair of the
 ai a j 
type   .
 a j ai 
 
a aj  ai
Now  i   2 (as  0)
 a j ai  aj
 
ai ai
  aj
 26 a j
 12 .
N
90. Let N be any four digit number say x1 x2 x3 x4. Then maximum value of is
x1  x 2  x 3  x 4
equal to
Ans. 01000.00
N 1000 x1  100x 2  10 x 3  x 4
Sol. 
x1  x 2  x 3  x 4 x1  x 2  x 3  x 4
= 1000 −
900x 2  990x 3  999x 4   maximum value of N
= 1000
x1  x 2  x 3  x 4  x1  x 2  x 3  x 4

All India Test Series: Fiitjee

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

All India Test Series: Fiitjee

Uploaded by

Copyright:

Available Formats

FIITJEE

ALL INDIA TEST SERIES

 The test consists of total 90 questions.

 Each subject (PCM) has 30 questions.

 This question paper contains Three Parts.

 Part-A is Physics, Part-B is Chemistry and Part-C is Mathematics.

 Each part has only two sections: Section-A and Section-B.

 Section – A : Attempt all questions.

 Section – B : Do any five questions out of 10 Questions.

1. What are the dimensions of electrical permittivity?

(C) M–1 L–3T2Q2

Sol. For collision, vB= 10 3 m/s

Sol. If block M moves a distance of x the extension in spring increases by 2x.

6. A ball of mass m is attached to the end of a thread fastened to the top of a O

Sol. T sin   m 2 R Tcos

8. A container has two immiscible liquids of densities 1 and 2 (>

(D) 2r  2  1 gh

9. A cylindrical vessel contains a liquid of density  upto a height h. The liquid

Sol. Applying Bernoulli’s theorem at 1 and 2

12. The give curve represents the variation of temperature as a function of T

Sol. T  V tan 45  T0

13. A solid conducting sphere having a charge Q is surrounded by an uncharged concentric

14. A potentiometer wire AB is 100cm long and has total 10V

15. A conducting wire bent in the form of a parabola y  2 x carries a

Sol. Magnetic flux linked with the loop is always zero.

17. A capacitor of capacity 2 F is charged to a potential difference of 12V. It is then connected

(A) the work function of A is 1.25 eV

(B) the work function of B is 4.20 eV

L total (IA  IB )w m A rA2 11

Sol. Work done at constant pressure is

24. A uniformly charged thin spherical shell of radius R carries uniform

Sol. For the given area total force will be u dA

Sol. The potential difference across 1 F and 2 F (uppermost) capacitor

Sol. Energy of incident photons in eV is given as

Sol. For hydrogen like atom energy of the nth orbit is

30. The convex surface of a thin concavo-convex lens of glass of

32. Which of the following properties is not shown by NO?

(A) It is a neutral oxide

(B) It combines with oxygen to form nitrogen dioxide

(C) Its bond order is 2.5

(D) It is diamagnetic in gaseous state

Sol. NO has total 15 electrons and one electron is unpaired.

(D) magnetic method

35. What is R in the following set of reactions?

Sol. CH2 CH2

Sol. MOT of NO,

Sol. Go  G1o  Go2

Sol. (1) HCl + NaOH  NaCl+H2

(2) CH3 COOH + NaOH  CH3 COONa+H2 O

39. Which of the following does not exist?

Sol. dG  VdP  SdT

(A) Be2C like Al4C3 yields methane on hydrolysis

(B) Be, like Al is not rendered passive by HNO3

(C) Be(OH)2 like Al(OH)3 is basic

(D) Be forms beryllates and Al forms aluminates

43. Select the incorrect statement.

(A) In alkaline solution XeO3 forms xenate ions

(B) Perxenate ions can be formed by disproportionation of xenates in alkaline conditions

(C) In perxenates Xe is in +6 oxidation state

(D) Perxenates can act as oxidizing agents

Sol. Xenates (+6), Persenates (+8)

(A) Sodium amminedioxodioxygensuperoxochromate (III)

(B) Sodium amminedioxygendioxodisuperoxochromate (III)