Material Safety Data Sheet

Crude Oil
NFPA: HMIS III:

HEALTH 2
4 FLAMMABILITY 4
2 0 PHYSICAL 0
0 = Insignificant, 1 = Slight, 2 =
Moderate,3 = High, 4 = Extreme

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

Product name : Petroleum Crude Oil – Sweet
Synonyms : Sweet Crude Oil, Light Crude Oil, Crude Oil
Product Use Description : Refinery Feedstock
CAIRN INDIA LIMITED
Company : Survey No. 232 I Surat - Hazira Road I Village Suvali I Surat 394510
Gujarat, India
Contact Number : (0261) 671-1478, (0261) 671-1476
Emergency Contact : (0261) 671-1500

SECTION 2: HAZARDS IDENTIFICATION

This material is considered hazardous by the Occupational Safety and Health

Regulatory status :
Administration (OSHA) Hazard Communication Standard (29 CFR 1910.1200).

Physical State : Liquid

Emergency Overview : DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
HARMFUL IF INHALED.
HARMFUL IF ABSORBED THROUGH SKIN.
INHALATION CAUSES HEADACHES, DIZZINESS, DROWSINESS AND
NAUSEA AND MAY
LEAD TO UNCONSCIOUSNESS.
CAUSES EYE AND SKIN IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE
IRRITATION.
ASPIRATION HAZARD.
HARMFUL OR FATAL IF SWALLOWED.
CAN ENTER LUNGS AND CAUSE DAMAGE.
CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Target Organs: skin, Respiratory system, central nervous system (CNS),
peripheral nervous system, cardiovascular system, blood, liver, kidneys.
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 Extremely flammable liquid. Harmful by inhalation. Harmful in contact with skin.
Prolonged orrepeated contact can defeat the skin and lead to irritation and/or
dermatitis. Aspiration hazard ifswallowed. Can enter lungs and cause damage.
Keep away from heat, sparks and flame. Avoidexposure - obtain special
instructions before use. Do not breathe vapor or mist. Do not ingest. Ifingested, do
not induce vomiting. Do not get in eyes or on skin or clothing. Contains
materialwhich can cause cancer. Risk of cancer depends on duration and level of
exposure. Use onlywith adequate ventilation. Keep container tightly closed and
sealed until ready for use. Washthoroughly after handling.
Routes of Entry : Dermal contact, Eye contact, Inhalation and Ingestion.
Potential health effects
Eyes : Causes eye irritation.
Harmful if absorbed through the skin. Causes skin irritation. Prolonged or
Skin :
repeated contact can defeat the skin and lead to irritation and/or dermatitis.
Harmful if inhaled. Vapors may cause drowsiness and dizziness. Can cause
Inhalation :
central nervous system (CNS) depression. May cause respiratory tract irritation.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Causes
Ingestion :
gastrointestinal irritation and diarrhea.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Weight %
Petroleum; Crude oil 8002-05-9 100%
Butane 106-97-8 0 – 5%
Pentane 109-66-0 0 – 5%
N-hexane 110-54-3 0 – 1.5%
Benzene 71-43-2 0.1 – 3%
Cumene 98-82-8 Variable Trace < 1%
Naphthalene 91-20-3 Variable Trace < 1%
Xylene 1330-20-7 Variable Trace < 1%
Ethylbenzene 100-41-4 Variable Trace < 1%
Polycyclic Aromatic Compounds Variable
Toluene 108-88-3 Variable Trace < 1%

SECTION 4: FIRST AID MEASURES

In case of contact, immediately flush eyes with plenty of water for at least 15
Eye Contact :
minutes. Get medical attention.
Immediately wash exposed skin with soap and water. Remove contaminated
Skin Contact : clothing and shoes. Clean shoes thoroughly before reuse. Wash contaminated
clothing before reuse. Get medical attention.
If inhaled, remove to fresh air. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing apparatus.
Inhalation :
If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not
Ingestion : induce vomiting. Never give anything by mouth to an unconscious person. Get
medical attention immediately.
The severity of the symptoms described will vary dependent of the concentration and the length of exposure.
If adverse symptoms develop, the casualty should be transferred to hospital as soon as possible.

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SECTION 5: FIRE FIGHTING MEASURES

Flammability : Extremely flammable liquid.

Auto-ignition temperature : 240°C (464°F)
Flash point : Closed cup: < -5 °C (23°F)
Explosion limits : Lower: 1.1% Upper: 5.9%
In a fire or if heated, a pressure increase will occur and the container may burst,
with the risk of subsequent explosion. The vapor/gas is heavier than air and will
Fire/explosion hazards : spread along the ground. Vapors may accumulate in low or confined areas or
travel a considerable distance to a source of ignition and flash back. Runoff to
sewer may create fire or explosion hazard.

Highly explosive in the presence of the following materials or conditions: open

Unusual fire/explosion
: flames, sparks and static discharge and heat. Eliminate all ignition sources. Hot
hazards
containers may explode.
Extinguishing Media
Suitable : Use dry chemical, CO2, water spray (fog) or foam.
Not suitable : Do not use water jet.
Promptly isolate the scene by removing all persons from the vicinity of the incident
if there is a fire. No action shall be taken involving any personal risk or without
Fire - fighting procedures :
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire -exposed containers cool.

Combustion products may include the following:

Hazardous combustion Carbon Oxides (CO, CO2) (carbon monoxide, carbon dioxide)
:
products Sulfur Oxides (SO2, SO3 etc.)
Nitrogen Oxides (NO, NO2 etc.)

SECTION 6: ACCIDENTAL RELEASE MEASURES

Evacuate nonessential personnel and remove or secure all ignition sources.

Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction
of product travel, diking, sewers, etc. to contain spill areas. Chemical splash
goggles. Chemical-resistant protective suit. Boots. Chemical-resistant gloves. Self-
contained breathing apparatus (SCBA) should be used to avoid inhalation of the
Personal precautions :
product. Suggested protective clothing might not be adequate. Consult a specialist
before handling this product. CAUTION: The protection provided by air-purifying
respirators is limited. Use a positive pressure air-supplied respirator if there is any
potential for an uncontrolled release, if exposure levels are not known, or if
concentrations exceed the protection limits of air-purifying respirator.
Carefully contain and stop the source of the spill, if safe to do so. Protect bodies
of water by diking, absorbents, or absorbent boom, if possible. Do not flush down
Environmental precautions : sewer or drainage systems, unless system is designed and permitted to handle
such material. The use of firefighting foam may be useful in certain situations to
reduce vapors.

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Methods for cleaning up
Take up with sand or oil absorbing materials. Carefully shovel, scoop or sweep
up into a waste container for reclamation or disposal - caution, flammable
vapors may accumulate in closed containers. Response and clean-up crews
: must be properly trained and must utilize proper protective equipment. Use
spark-proof tools and explosion-proof equipment. Dispose of via a licensed
waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product.

SECTION 7: HANDLING AND STORAGE

Handle as a combustible liquid. Put on appropriate personal protective equipment.

Handling
Requirements for storage
areas and containers
Workers should wash hands and face before eating or drinking. Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
: ventilated. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use non-sparking tools. Take precautionary measures against
electrostatic discharges. To avoid fire or explosion, dissipate static electricity
during transfer by grounding and bonding containers and equipment before
transferring material.
Use approved vented containers. Keep containers closed and clearly labeled.
Store in accordance with local regulations. Store in a segregated and approved
area. Store away from direct sunlight in a dry, cool and well-ventilated area, away
from incompatible materials. Eliminate all ignition sources. Separate from
:
oxidizing materials. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

OSHA
Components CAS-No. Type: Value
TWA 1 ppm
Benzene 71-43-2 STEL 5 ppm
OSHA_AL 0.5 ppm
N-hexane 110-54-3 PEL 500 ppm (1,800 mg/m3)

Cumene 98-82-8 TWA 50 ppm

Ethylbenzene 100-4-4 TWA 100 ppm

Naphthalene 91-20-3 TWA 10 ppm

Toluene 108-88-3 TWA 200 ppm

Xylenes 1330-20-7 TWA 100 -300 ppm
Polycyclic Aromatic Compound TWA 0.2 mg/m3

ACGIH
Components CAS-No. Type: Value
N-hexane 110-54-3 TWA 50 ppm
TWA 0.5 ppm
Benzene 71-43-2
STEL 2.5 ppm
Cumene 98-82-8 TWA 50 ppm

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 Ethylbenzene TWA 50 ppm
100-4-4
STEL 125 ppm
TWA 10 ppm
Naphthalene 91-20-3
STEL 15 ppm
Toluene 108-88-3 TWA 20 ppm
TWA 100 ppm
Xylenes 1330-20-7 STEL 150 ppm
Polycyclic Aromatic Compound TWA 0.2 mg/m3

Use adequate ventilation to keep gas and vapor concentrations of this product
Engineering measures : below occupational exposure and flammability limits, particularly in confined
spaces.
Ensure that eyewash stations and safety showers are close to the workstation
Eye protection : location. Goggles, and face shield or full face piece pressure-demand supplied air
respirator as needed to prevent eye and face contact.
Gloves constructed of nitrile, neoprene, or PVC are recommended. The
Hand protection : resistance of specific material may vary from product to product as well as with
degree of exposure.

Skin and body protection : Chemical protective clothing recommended based on degree of exposure.

An approved air-purifying respirator with organic vapor cartridges or canister may

Respiratory protection : be permissible under certain circumstances where airborne concentrations are or
may be expected to exceed exposure limits or for odor or irritation.

Avoid repeated and/or prolonged skin exposure. Wash hands before eating,
drinking, smoking, or using toilet facilities. DO NOT use gasoline, kerosene,
solvents, or harsh abrasive skin cleaners to clean skin. Waterless hand cleaners
Hygiene measures :
are effective. Promptly remove contaminated clothing and launder before reuse.
Consider the need to discard contaminated leather shoes and gloves. Use good
personal hygiene practices.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquid
Variable depending on its source; typical is a dark yellow to brown or greenish
Appearance :
black liquid
Odor : Petroleum asphalt odor
Flash point - typical : Variable (depending on components)
Lower explosive limit : 1.1 %
Upper explosive limit : 5.9 %
pH : Not Applicable
Percent Volatiles : 100 %
Specific Gravity : 0.780 to 0.850
Melting/Freezing Point : 0 to -60 °C
Boiling Point (range) : Variable (depending on components)
Vapor Pressure : 5.50 kPa
Water Solubility : Insoluble in Water
Pour Point : 6 to 18 °C

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SECTION 10: STABILITY AND REACTIVITY

Reactivity : Flammable Liquid and Vapor.

Materials to avoid : Strong Oxidizers
Hazardous decomposition
: Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).
products
Conditions to avoid : Avoid heat, flames and other sources of ignition.
Hazardous Reactions : Hazardous polymerization
Chemical stability : Stable under normal temperature conditions and recommended use.

SECTION 11: TOXICOLOGICAL INFORMATION

Classification
Name IARC NTP (USA) OSHA
Crude oil 3 - -
Toluene 3 - -
xylene 3 - -
Benzene 1 Proven. +
Naphthalene 2B Possible -
Ethylbenzene 2B - -
IARC :
1 - Carcinogenic to human.
2B - Possible carcinogen to human.
3 - Not classifiable as a human carcinogen.
NTP (USA) National Toxicity Program:
Proven - Known to be human carcinogens
Possible - Reasonably anticipated to be human carcinogens.

OSHA :
+ Potential occupational carcinogen

Inhalation : Vapors may irritate throat and respiratory system.

Eye Contact : May cause slight irritation.
Skin Contact : Prolonged contact may cause redness and irritation.
Ingestion : Irritant; may cause pain or discomfort to mouth, throat and stomach
Unknown acute toxicity : N/A
Sensitization : This product does not contain any components suspected to be sensitizing
Aspiration Hazard : No hazard from product as supplied

SECTION 12: ECOLOGICAL INFORMATION

Additional ecological
information
Persistence & degradability
Bio accumulative potential
Mobility in soil Mobility
Keep out of sewers, drainage areas, and waterways. Report spills and releases,
:
as applicable, under Govt. regulations.
: The product is expected to be slowly biodegradable.
: Has the potential to bio accumulate
Insoluble in water. The product contains volatile organic compounds (VOC) which
:
will evaporate easily from all surfaces

Toxicity to aquatic and fish : See component information below.

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 Component Toxicity to fish To daphnia & other aquatic invertebrates
36 mg/L (Daphnia magna) = 24 h
Petroleum distillates 258 mg/L (Salmo gairdneri) = 96 h
0.26 mg/L (Daphnia magna) = 48 h
1.59 mg/L (Pimephales promelas) = 96 h
PENTANE 9.87 mg/L (Oncorhynchus mykiss) = 96 h 9.74 mg/L (Daphnia magna) = 48 h
9.99 mg/L (Lepomismacrochirus) = 96 h
N-hexane NA Dose: 2.1 mg/l Exposure time: 48 h

SECTION 13: DISPOSAL CONSIDERATIONS

Waste residues/unused : Dispose of in accordance with local regulations
products
Contaminated packaging :
Empty containers should be transported/delivered using a registered waste carrier
for local recycling or waste disposal.
NOTE: The generator of waste has the responsibility for proper waste identification (based on characteristic(s) or
listing),transportation and disposal

SECTION 14: TRANSPORT INFORMATION

Proper Shipping Packing

Regulatory Info./UN Number Class Remarks
Name Group
DOT Classification UN1276 3 I Report if >=4.54 Kg 10 lbs.
TDG Classification UN1276 PETROLEUM 3 I -
CRUDE OIL
IMDG Classification UN1276 3 I -
IATA/ICAO Classification UN1276 3 I -
Special precautions
Hazard ID : 33

EmS (IMDG) : F-E [Non-Water Reactive Flammable Liquids]

S-E [Flammable Liquids (floating on water)]
Emergency action code : 3WE
Tunnel restriction code : Bulk or Tank carriage (D/E)

SECTION 15: REGULATORY INFORMATION

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008
Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the
European Parliament and of the Council on the Registration, Evaluation, Authorization and Restriction of
Chemicals (REACH). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals
(REACH), establishing a European Chemicals Agency, amending Directive 1999/EC and repealing Council
Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including
amendments.

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 International inventories
USA, Toxic Substances Control Act inventory (TSCA) : Complies
European Union - EINECS and ELINCS : Complies
Canada, Domestic Substance List (DSL) : Complies
Philippines (PICCS) : Complies
Inventory - Japan - Existing and New Chemicals list : Does not Comply
China (IECSC) : Complies
Korea (KECL) : Complies
Inventory - New Zealand - Inventory of Chemicals (NZIoC) : Complies
Australia (AICS) : Complies

SECTION 16: OTHER INFORMATION

Disclaimer:
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for
such material used in combination with any other materials or in any process, unless specified in the text.
Any express or implied warranty; or non-infringement of intellectual property rights; supplier assumes no
responsibility for any direct, special or consequential damages, results obtained, or the activities of others.
To the maximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as
stated in separate agreement between the parties.

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