CHEMISTRY

CLASS XI ATOMIC STRUCTURE

Paper – 1

(One and a Half hours)

Answers to this Paper must be written on the paper provided separately.

Candidates are allowed additional 15 minutes for only reading the paper.

The time given at the head of this paper is the time allowed for writing the
answers.
ALL QUESTIONS ARE COMPULSORY

The intended marks for questions or parts of questions are given in brackets [ ].

[1*30=30]

Question 1:
If the Planck's constant, h = 6.6 x 10-34 J s, the de Broglie wavelength of a particle having momentum of 3.3 x 10 -24 kg m s-¹ will be:
(a) 0.02 Å (b) 0.5 Å (c) 2Å (d) 500 Å.
Question 2:
The wavelength associated with a ball of mass 100 g moving with a speed of 10 3 cm sec-1 (h = 6.6 x 10-34 Js )is:
(a) 6.6 X 1032cm (b) 6.6 X 10-27cm (c) 6.6 X 1027cm (d) 6.6 X 10-32cm
Question 3:
The de Broglie wavelength of an electron is 66 nm. The velocity of the electron is (h= 6.6 x 10 -34 kg m² s-1, m = 9.0 × 10-31 kg)
(a) 1.84 X 10-14 m s-1. (b) 1.1 X 104 m s-1. (c) 5.4 X 103 m s-1. (d) 1.1 X 103 m s-1.
Question 4:
The uncertainty in the momentum of an electron is 1.0 x 10-5 kg m s-1. The uncertainty in position will be (h= 6.6 x 10-34 kg m² s-1)
(a) 5.25 X 10-28m (b) 1.05 X 10-26 m (c) 5.25 X 10-30m (d) 1.05 X 10-28m
Question 5:
The momentum of a particle having a de-Broglie wavelength of 10 -17 m is (h= 6.625 x 10-34 J s)
(a) 6.625 X 10-17 kg m s-1. (b) 3.3125 X 10-7 kg m s-1. (c) 13.25 X 10-17 kg m s-1. (d) 26.5 X 10-7 kg m s-1.
Question 6:
The uncertainty in the position of an electron (mass = 9.1 x 10-28 g) moving with a velocity of 3.0 x 104 cm s-1 accurate upto 0.011% will be:
(a) 1.92 cm (b) 7.68 cm (c) 0.175 cm (d) 3.84 cm.
Question 7:
Given : Mass of electron 9.11 x 10-31 kg Planck's constant = 6.626 × 10-34 Js The uncertainty involved in the measurement of velocity with in a
distance of 0.1 Å is:
(a) 5.79 X 107 ms-1. (b) 5.79 X 108 ms-1. (c) 5.79 X 105 ms-1. (d) 5.79 X 106 ms-1.
Question 8:
A body of mass 'x' kg is moving with a velocity of 100 m/s. Its de Broglie wavelength is 6.62 x 10 -35 m. Hence x is [h= 6.62 × 10-34 Js)
(a) 0.25 kg (b) 0.15 kg (c) 0.2 kg (d) 0.1kg
Question 9:
P3- ion has the valence shell electronic configuration:
(a) 3s² 3p³ (b) 3s² 3p6 (c) 2s²2p³ (d) 4s² 4p³
Question 10:
The electronic configuration for Ca2+ ion is:
(a) [Ne] 3s² 3p6 (b) [Ne] 3s² 3p4 (c) [Ar] 4s² (d) [Ar] 3s²3p6
Question 11:
The number of unpaired electrons in chromium (Z = 24) is :
(a) 4 (b) 3 (c) 6 (d) 5
Question 12:
The number of d-electrons remained in Fe2+ (At. no. of Fe = 26) ion is:
(a) 4 (b) 5 (c) 6 (d) 3
Question 13:
According to Bohr's theory, the angular momentum of an electron in 5th orbit
is: (a) 1.0 h / π (b) 10 h / π (c) 2.5 h / π (d) 25 h / π
Question 14:
Uncertainty in the position of an electron (mass = 9.1 × 10 -31 kg) moving with a velocity 300 ms-1 accurate upto 0.001% will be:(h = 6.63 x 10-34
Js)
(a) 5.76 X 10-2m (b) 1.93 X 10-2m (c) 3.84 X 10-2m (d) 19.2 X 10-2m

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Question 15:
A particle 'A' moving with a certain velocity has a de-Broglie wavelength of 1 Å. If the particle B has mass 25% of that of A and velocity 75% of
that of A, then de-Broglie wavelength of B will be approximately:
(a) 1.6 Å (b) 5.3 Å (c) 3.5 Å (d) 5.9 Å.
Question 16:
The velocity of particle A is 0.1 m/s and that of particle B is 0.05 m/s. If the mass of particle B is five times that of particle A, then the ratio of de
Broglie wavelength associated with particles A and B is :
(a) 2:5 (b) 6:4 (c) 3:4 (d) 5 : 2.
Question 17:
Time taken for an electron to complete one revolution in the Bohr orbits of hydrogen atom is:
(a) (b) (c) (d)
Question 18:
The proton and He2+ are accelerated by the same potential, then their de-Broglie wave lengths λ and λ are in the ratio of (𝑚 = 4𝑚 )
(a) (b) (c) 2√2 (d) ½
√ √
Question 19:
The wavelength of particles constituting a beam of helium atoms moving with a velocity of 2.0 x 104 ms-1 is:
(a) 4.99 pm (b) 49.9 pm (c) 499 nm (d) 499 pm
Question 20:
The mass of a photon moving with velocity of light having wavelength same as that of an ἀ-particle (mass = 6.6 x 10 -27 kg) moving with velocity
of 2.5 × 10² ms-¹ is:
(a) 7.92 X 10-21kg (b) 5.5 X 10-33kg (c) 5.65 X 10-31kg (d) 7.92 X 10-28kg
Question 21:
In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%. Certainty with which the position of an electron can be
located is (h = 6.6 × 10-34 kg m² s-¹;mass of electron, em=9.1 X 10-31 kg)
(a) 1.52 X 10-4m (b) 5.10 X 10-3m (c) 1.92 X 10-3m (d) 3.84 X 10-3m
Question 22:
Calculate the wavelength associated with a proton moving at 1.0 x 10³ m/s. (Mass of proton = 1.67 x 10 -27 kg and h = 6.63 x 10-34 Js)
(a) 0.032 nm (b) 0.40 nm (c) 2.5 nm (d) 14.0 nm.
Question 23:
If the speed of the electron in the Bohr's first orbit is x, then speed of the electron in the 3rd orbit would be:
(a) x/9 (b) x/3 (c) 3x (d) 9x
Question 24:
An ion has 18 electrons in the outermost shell, it is
(a) Cu+ (b) Th4+ (c) Cs+ (d) K+
Question 25:
The number of nodal planes in a px orbital is:
(a) 1 (b) 2 (c) 3 (d) 0
Question 26:
The speed of a 200 g golf ball is 5.0 metre per hour. The wavelength of this ball will be of the order of:
(a) 10-10m (c) 10-20m (c) 10-30m (d) 10-4m
Question 27:
Energy of H-atom in the ground state is -13.6 eV, hence energy in the second excited state is:
(a) -6.8 eV (b) - 3.4 eV (c) -1.51 eV (d) - 4.53 eV.
Question 28:
Uncertainty in position of a particle of 25 g in space is 10 -5 m. Hence, uncertainty in velocity (m s-¹) is (Planck's constant h = 6.6 x 10--34 J s)
(a) 2.1 X 10-28 (b) 2.1 X 10-34 (c) 0.5 X 10-34 (d) 5.0 X 10-24
Question 29:
In Balmer series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the following inner-orbit jumps of
the electron for Bohr orbits in an atom of hydrogen?
(a) 3→2 (b) 5→2 (c) 4→1 (d) 2→5
Question 30:
The de-Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 m/s is approximately (Planck's constant, h = 6.63 x 10 -34 Js)
(a) 10-33m (b) 10-31m (c) 10-16m (d) 10-25m

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