1 Metanol - agua

F = 100 lb mol/h % recup B = 0.98

zF = 0.40 B = 61.25000 lb mol/h
xB = 0.04 D = 38.75000 lb mol/h
xD = 0.96903

q = 0.400

0.40 0.40000 xa = 0.1740 Rmin = 1.11164

0.30 0.46667 ya = 0.5505 R = 1.66746
0.10 0.60000

Zona de enriquecimiento
xD /( R + 1) = 0.36328 0.96903 0.96903
R / (R + 1) = 0.62511 0.00000 0.36328

Zona de empobrecimiento
L = R . D + F . q = 104.6140 lb mol/h L / V = 2.41246
V = D (R+1) + F (q-1) = 43.3640 lb mol/h B . xB / V = 0.05650

0.04 0.04000
0.20 0.42599
0.30 0.66724

Carga calórica en el condensador QC = D (HV - HD) xD = 0.96903

D = 38.75 lb mol/h

HV = 16103.60625299 BTU/lb mol QC = 1579260.22 BTU/h

HD = 824.9835681246 BTU/lb mol

Carga calórica en el recalentador QR = QC + D . HD + B . HB - F . HF

HB = 1582.3929 BTU/lb mol QR = 591864.792 BTU/h

HF = 11162.85113537 BTU/lb mol HLF = 861.998282 BTU/lb mol

HVF = 18030.0864 BTU/lb mol

0 0
1.00
1.00
1 1

0.90

0 0
0.80
1 1

0.70

0.60

0.50

0.40

0.30

0.20

0.10

0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
Metanol - agua PT = 1 atm

T °C x HL BTU/lbmol y HV BTU/lbmol

100.0 0.00 1870.5234 0.000 19422.7775

96.4 0.02 1713.2294 0.134 18954.5277
93.5 0.04 1582.3929 0.230 18618.5812
91.2 0.06 1475.8007 0.304 18360.9886
89.3 0.08 1386.6992 0.365 18150.0465
87.7 0.10 1311.5500 0.418 17968.3926
84.4 0.15 1162.4750 0.517 17628.6694
81.7 0.20 1051.7191 0.579 17411.8042
78.0 0.30 925.5907 0.665 17114.8387
75.3 0.40 861.9983 0.729 16896.9849
73.1 0.50 827.4494 0.779 16727.6349
71.2 0.60 809.1148 0.825 16574.1958
69.3 0.70 797.4236 0.870 16424.9728
67.6 0.80 803.0966 0.915 16278.5117
66.0 0.90 820.3835 0.958 16139.8069
65.0 0.95 819.8193 0.979 16070.8986
64.5 1.00 833.3864 1.000 16005.7771

xD = 0.96903 y1 = 0.96903

HD = 824.983568 HV = 16103.6063

zF = 0.40 zF = 0.40

HLF = 861.9983 HVF = 18030.0864

zF = 0.40 zF = 0.40

HLF = 820.3835 HVF = 18011.3076

 2
La relación ( K1 ) = Disolvente / Inerte es constante K1 = D / I K = (D +S) / I

S ( D + S )
D / I = ------- . -------- = yD . K = ( 1 - yS ) K K = (D/I) / ( 1 - yS )
(D + S ) I

K
xS = yS .
K + 1

K
xD = (1- yS) .
K + 1

2a K1 = 0.45
 yS K/(K+1) xS xD F = 100 xSo = 0.40 xDo = 0.00
0.0 0.3103 0.0000 0.3103 D = 50 ySo = 0.02 yDo = 0.98
0.1 0.3333 0.0333 0.3000
0.2 0.3600 0.0720 0.2880
0.3 0.3913 0.1174 0.2739 0 0
0.4 0.4286 0.1714 0.2571 xMS = 0.27333 xMD = 0.32667
0.5 0.4737 0.2368 0.2368 yS = 0.45556 yD= 0.54444
0.6 0.5294 0.3176 0.2118 xS = 0.20615 xD= 0.24637
0.7 0.6000 0.4200 0.1800
0.8 0.6923 0.5538 0.1385 y = 1.19512 x + I E
0.9 0.8182 0.7364 0.0818 y = -1.00000 x + 1.00000 S D
1.0 1.0000 1.0000 0.0000 y = -0.31034 x + 0.31034 Retención

R1 = 109.592 % = 43.520
Cantidad = 17.408

1 0
1.0 0 1

0.9
1.0

0.9
0.8

0.8
0.7
0.7

0.6
0.6

0.5
0.5

0.4
0.4
0.3

0.3
0.2

0.1
0.2

0.0
0.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

2b K1 = 0.45
yS K/(K+1) xS xD F = 100 xSo = 0.40 xDo = 0.00
0.0 0.3103 0.0000 0.3103 D = 20 ySo = 0.02 yDo = 0.98
0.1 0.3333 0.0333 0.3000
0.2 0.3600 0.0720 0.2880 0 0
0.3 0.3913 0.1174 0.2739 xMS = 0.33667 xMD = 0.16333
0.4 0.4286 0.1714 0.2571
0.5 0.4737 0.2368 0.2368
0.6 0.5294 0.3176 0.2118
0.7 0.6000 0.4200 0.1800
0.8 0.6923 0.5538 0.1385
0.9 0.8182 0.7364 0.0818
1.0 1.0000 1.0000 0.0000

1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
3C
3D
 3
Humedad inicial = 75 % xinicial = 0.75 Xinicial = 3.00000 lb agua/lb sólido seco

Humedad final = 15 % xfinal = 0.15 Xfinal = 0.17647 lb agua/lb sólido seco

Humedad de equilibrio X* = 0.02 lb agua/lb sólido seco

1.23 lb agua/lb sólido seco

Humedad libre en el punto
crítico = XC - X* = XC = 1.25 lb agua/lb sólido seco

N
4.5
qSecado = qC + qPC
4

3.5
Secado del sólido abarca los dos
3
períodos

2.5

2
LS/A = rglobal . (1 - xinicial) * zs
1.5

1
rglobal = 50 lb/pie3
0.5

X zS = 1.5 pulgadas
0
0 1 2 3 4 5 6 7 8 9 10

LS/A = 1.5625 lb sólido seco/pie2

Tiempo de Secado en el período antecrítico

qC = ( Ls / A ) . ( 1 / Nc ) (X1 - X2 ) X1 = Xinicial
X2 = Xcrítica
Tiempo de Secado en el período post-crítico

qPC = ( Ls / A ) . ( XC - X*). (1/Nc) ln (X1 - X* ) / (X2 - X* ) X1 = Xcrítica

X2 = Xfinal

Cálculo de la Velocidad de Secado en el Período Ante-Crítico

Nc = qC / ls = hc (tG - ts) / ls
De tablas a 86 ºF

tG = 170 ºF ls = 1045.2 BTU/lb

ts = 86 86 ºF

G = 1.50 lb/pie2-s hc = 0.0128 G0.8

G = 5400.000 lb/pie2-h
 hc = 12.39153 BTU/pie2-h-ºF

Nc = 0.99588 lb sólido seco/pie2-h

qC = 2.75 horas qSecado = 6.72 horas

qPC = 3.98 horas

Condiciones II : GII = GI GII = 5400.000 lb/pie2-h

hc = 12.39153 BTU/pie2-h-ºF

tG = 170 ºF De las cartas psicrométricas:

Y= 0.01 lb agua/lb aire seco ts = 88.2 ºF

De tablas a 88.2 ºF ls = 1044.22 BTU/lb

Nc = 0.97070 lb sólido seco/pie2-h

qC = 2.82 horas qSecado = 6.90 horas

qPC = 4.08 horas

qII / qI = 1.02593

% variación = ( qII - qI ) / qI

% variación = 2.5932%