JAPANESE

INDUSTRIAL
STANDARD
Translated and Published by
Japanese Standards Association

JIS G 1314-1 :2011

(JFA/JSA)
Method for chemical analysis of
silicomanganese - Part 1: Determination
of manganese content

ICS 77.100
Reference number: JIS G 1314-1 : 2011 (E)

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G 1314-1 : 2011

Date of Establishment: 2011-10-20

Date of Public Notice in Official Gazette: 2011-10-20
Investigated by: Japanese Industrial Standards Committee
Standards Board
Technical Committee on Iron and Steel

JIS G 1314-1 : 2011, First English edition published in 2013-06

Translated and published by: Japanese Standards Association

4-1-24, Akasaka, Minato-ku, Tokyo, 107-8440 JAPAN

In the event of any doubts arising as to the contents,

the original JIS is to be the final authority.

© J5A 2013
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized
in any form or by any means, electronic or mechanical, including photocopying and microfilm, without
permission in writing from the publisher.

Printed in Japan HN

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 G 1314-1 : 2011

Contents

Page

Introduction································································································· 1
1 Scope ...................................................... ···········································1

2 Normative references············································································ 1
3 General ...................................................... ········································1
4 Classification of determination method ....................................... ·············1

5 Potassium permanganate visual titration method ·····································2

5.1 Summary···························································································· 2
5.2 Reagents ...................................................... ······································2
5.3 Amount of test portion·········································································· 2
5.4 Procedure ...................................................... ·····································2
5.5 Blank test················ ...................................................... ·····················3
5.6 Calculation ........................................................................ ·················3
5.7 Tolerances ...................................................... ····································4

6 Potassium permanganate potentiometric method······································ 4

6.1 Summary···························································································· 4
6.2 Reagents···························································································· 4
6.3 Apparatus and implements···································································· 5
6.4 Amount of test portion·········································································· 5
6.5 Procedure ...................................................... ·····································5
6.6 Blank test··························································································· 6
6.7 Calculation ........................................................................ ·················6
6.8 Tolerances·························································································· 6
7 Disodium ethylenediaminetetraacetate dihydrate titration method·············· 7
7.1 Summary····························································································7
7.2 Reagents ...................................................... ······································7
7.3 Amount of test portion ...................................................... ····················7
7.4 Procedure ...................................................... ·····································7
7.5 Blank test················ ...................................................... ·····················8
7.6 Calculation ........................................................................ ·················8
7.7 Tolerances· ......................................................................................... 9

Annex JA (informative) Comparison table between JIS and corresponding

International Standard .......................................... ··10

(i)

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Foreword

This translation has been made based on the original Japanese Indus-
trial Standard established by the Minister of Economy, Trade and In-
dustry through deliberations at the Japanese Industrial Standards
Committee according to the proposal for establishment of Japanese In-
dustrial Standard submitted by the Japan Ferroalloy Association (JFA)I
Japanese Standards Association (JSA) with the draft being attached,
based on the provision of Article 12 Clause 1 of the Industrial Stan-
dardization Law.
Consequently JIS G 1314:1998 has been withdrawn and partially replaced
with this Standard.
This JIS document is protected by the Copyright Law.
Attention is drawn to the possibility that some parts of this Standard
may conflict with a patent right, application for a patent after opening to
the public or utility model right. The relevant Minister and the Japanese
Industrial Standards Committee are not responsible for identifying the
patent right, application for a patent after opening to the public or utility
model right.
JIS G 1314 series consists of the following 6 parts under the general title
"Method for chemical analysis ofsilicomanganese":
Part 1: Determina tion ofmanganese con ten t
Part 2: Determination ofsilicon content
Part 3: Determination of carbon content
Part 4: Determina tion ofphosphorus con ten t
Part 5: Determination ofsulfur content
Part 6: Determina tion of boron con ten t

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JAPANESE INDUSTRIAL STANDARD JIS G 1314-1 : 2011

Method for chemical analysis of silicomanganese -

Part 1 : Determination of manganese content

Introduction
This Japanese Industrial Standard has been prepared based on the first edition of
ISO 4159 published in 1978 with some modifications of the technical contents to corre-
spond to the progress in analysis technology.
The portions given sidelines or dotted underlines are the matters in which the con-
tents of the corresponding International Standard have been modified. A list of modifi-
cations with the explanations is given in Annex JA.

1 Scope
This Standard specifies the determination method of manganese content in silico-
manganese.
NOTE: The International Standard corresponding to this Standard and the sym-
bol of degree of correspondence are as follows.
ISO 4159 : 1978 Ferromanganese and ferrosilicomanganese - Deter-
mination ofmanganese content - Potentiometric method (MOD)
In addition, symbols which denote the degree of correspondence in the
contents between the relevant International Standard and JIS are IDT
(identical), MOD (modified), and NEQ (not equivalent) according to
ISOIIEC Guide 21-1.

2 Normative references
The following standards contain provisions which, through reference in this text,
constitute provisions of this Standard. The most recent editions of the standards (in-
cluding amendments) indicated below shall be applied.
JJS_J!__19J)l ___ }i}!!:J;:Q!!JlQy§_~_G?lJ.?XEJIXl!}?§fQ~[lh~!!!jf;!!l/!-lJ.!Jlx~i~
J1SJ(_8_QQl ____ G~IJ.?XEJIXlJl~fQJ;:j;~~t!!!_f!_~.hQd$._Qfr..?_EJgf!!Jt~

3 General
.G-_~_1l~x~1_m_~_tt~x~ __GQm}:p.9}~~_JQ_Jh~ __ ~h~mj._G~1_~n~J.Y~5o~__ m_~thQd __ ~J~~ll_b~ __ in_~~~_Qxd~nG~
wj,th .JJS_ -'1 _l3-')t~

4 Classification of determination method

The determination method of manganese content shall be according to any of the fol-
lowing .
.~2 ___ P9_t~~~i~m__ p~;a:m~JJ.g~:n~t_~__ yj.J!~~Jd __tjJ:r~--tiQ~t _m~~hQ~t ___ Thi~__ }IlgtbQ~l_ j._~ __ ~p-p-h~_~_l)l~___tQ

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G 1314-1 : 2011

th~_~~mp-l~ __QfJY-hi~h_th~_m~ng~rr~~_~__<;gnt~rrt_x~_t~_i~_~J? __%__ (m_~_~~_f:t;~~tj9ll)_Qr__9Y~X_1lP_

t9__~_rrd_in<;1lJ.din.g_f?_Q__%__(mg~~_fr~<;_tiQn.)_._
b) Potassium permanganate potentiometric method This method is applicable to the
sample of which the manganese content rate is 55 % (mass fraction) or over up to
and including 95 % (mass fraction).
~2 ___ J)j~J;>JlhH~_~~hyl!iH).~di~mi"-~w_t~~~~_~_t~t~_d_~hyd~~t~_titx~t~9..n_m~thQd ____Tb5:~_))Jgtbgg__i~
~ppli~_~hl~_t9__ tlw__ ~_~_mp-l~ __Qf_whi~b__tb~ __m~n.g~n~_~~_~Qn.t~)Jtx_~_t~__ i~_JjJ?__ %__(m~~~__ fr~~_~
ti9.rr}_Qr_9.Y~x_J-JP__ tQ_~nJljrr~1!!gilJg_aQ_%_(m~~_~_fr~~ti9_lJ2!

5 Potassium permanganate visual titration method

5.1 Summary
Decompose the sample with nitric acid and hydrofluoric acid, add sulfuric acid, gen-
erate white fume of sulfuric acid by heating, and remove nitric acid. Neutralize with
zinc oxide, remove iron, etc., and titrate it with potassium permanganate solution.
5.2 Reagents
Reagents shall be as follows.
5.2.1 Hydrochloric acid (1 + 1)
5.2.2 Nitric acid
5.2.3 Hydrofluoric acid
5.2.4 Sulfuric acid (1 + 1)
5.2.5 Sodium disulfate
5.2.6 Zinc oxide milk Add about 100 ml of water to about 20 g of zinc oxide and stir
to make them milky.
5.2.7 0.02 mollL potassium permanganate solution The preparation, storage and
standardization method shall be in accordance with g) in JA.5.2 of JIS K 800l.
5.3 Amount of test portion
The test portion shall be 0.10 g weighed out to the digit of 0.1 mg.
5.4 Procedure
5.4.1 Preparation of sample solution
The preparation of sample solution shall be carried out according to the following
procedure.
a) Weigh out the sample, transfer it to a platinum dish (No. 100) or a polytetrafluoro-
ethylene (hereafter referred to as "PTFE") beaker (100 m!), and place a platinum or
PTFE cover.
b) Slide the cover a little, add 15 ml of nitric acid, and decompose it by dripping sev-
eral drops of hydrofluoric acid step by step. When the reaction becomes vigorous,
cool the outside of the container with water.

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c) Wash the lower surface of the cover with water, and remove it.
d) Add 10 ml of sulfuric acid (1 + 1), vaporize it by heating to generate vigorously
white fume of sulfuric acid for about 10 min, then, allow the solution as it is to cool.
When coloured insoluble residue exists at that time, add about 5 ml of hydro-
chloric acid (1 + 1), and generate again white fume of sulfuric acid by heating.
e) Add about 30 ml of water, and dissolve soluble salts by heating.
f) Filter the solution with filter paper (Class 5A), and wash it several times with
warm water. Receive the filtrate and washings in a beaker (300 m!), and store it as
the principal solution. Transfer the residue together with filter paper into a plati-
num crucible (No. 30), and ash the filter paper by ignition. After allowing it to cool,
add about 2 g of sodium disulfate, and fuse it by heating. After allowing it to cool,
put the melt together with the platinum crucible into the previously stored princi-
pal solution, and dissolve it by heating. Wash the platinum crucible with a small
amount of water, and take it out.
When insoluble residue is not observed, the operation of:tj is not carried out and
transfer the solution of e) to a beaker (300 m!) by using water.
5.4.2 Removal of iron, etc.
The removal of iron, etc. shall be carried out according to the following procedure.
a) Add water to the solution obtained in 5.4.1 :tj and make the liquid amount about
100 ml.
b) Add zinc oxide milk (5.2.6) gradually to neutralize, further add it a little exces-
sively, and heat to boiling.
c) Filter the precipitate together with excessive zinc oxide with filter paper (Class 5A),
wash it with warm water, and receive the filtrate and washings with an Erlen-
meyer flask (500 m!) 1).
Note 1) At this time, the opaque in filtrate and washings is permissible.
d) Add hot water to make the liquid amount to about 200 ml, and further add one or
two drops of zinc oxide milk (5.2.6) to make the solution opaque.
5.4.3 Titration
For the titration, boil the solution obtained in 5.4.2 d) by heating, immediately ti-
trate it with 0.02 mollL potassium permanganate solution (5.2.7), and take the point at
which faint pink colour of supernatant liquid does not disappear even though the solu-
tion is boiled for about 1 min after it has coloured to faint pink as the end point, and
obtain the amount of 0.02 mollL potassium permanganate solution used.
5.5 Blank test
A blank test is not carried out.
5.6 Calculation
The manganese content rate in the sample shall be calculated from the used amount

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of 0.02 mollL potassium permanganate solution obtained in 5.4.3 according to the fol-
lowing formula.

VI X J, x 0.001648
Mn = x100
ml

where, Mn: manganese content rate in sample [% (mass fraction)]

VI: used amount of 0.02 mollL potassium permanganate so-
lution obtained in 5.4.3 (m!)
fi : factor of 0.02 mollL potassium permanganate solution
mI: amount of test portion (g)
5.7 Tolerances
The tolerances shall be in accordance with table 1.

Table 1 Tolerances
Unit: % (mass fraction)
Manganese content rate I Wi thin -labora tory-reprod ucibility limit I Reproducibility limit
62.49 I 0.269 I 0.319
NOTE: The manganese content rate given in this table is the manganese content rate in the
sample used in the cooperative experiment for determining the tolerances based on
JIS Z 8402 : 1991.

6 Potassium permanganate potentiometric method

6.1 Summary
Decompose the sample with hydrochloric acid, perchloric acid and hydrofluoric acid,
generate white fume of perchloric acid by heating and remove hydrochloric acid and
hydrofluoric acid. Make coexist sodium diphosphate, adjust pH of the solution with
hydrochloric acid, and titrate it with potassium permanganate using the potentiome-
ter.
6.2 Reagents
Reagents shall be as follows.
6.2.1 Hydrochloric acid
6.2.2 Hydrochloric acid (1 + 2, 1 + 4)
6.2.3 Perchloric acid
6.2.4 Hydrofluoric acid
6.2.5 Sodium diphosphate solution Take 145 g of sodium diphosphate decahydrate
into conical flask (2 L), add about 1 L of warm water, dissolve it by heating at the tem-
perature not exceeding 60°C, and allow it to cool. This solution shall be prepared at
every serVIce.

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6.2.6 0.02 mollL potassium permanganate solution The preparation shall be in ac-
cordance with 5.2.7.
6.3 Apparatus and implements
The following apparatus and implements shall be generally used.
6.3.1 Potentiometer That capable of measuring the potential difference between
electrodes by connecting electrodes of 6.3.2. pH meter having m V display may be used.
6.3.2 Electrodes For electrodes, any of the combination of platinum - saturated
calomel, platinum - tungsten or platinum - platinum shall be used.
6.4 Amount of test portion
The test portion shall be 1.0 g weighed out to the digit of 0.1 mg.
6.5 Procedure
Warning: The vapour of perchloric acid has a risk of explosion under presence of
ammonia, nitrite vapour or organic matters. The vapour shall be treated
at a place equipped with an exhaust equipment which ensures safety
under use of perchloric acid.
6.5.1 Preparation of sample solution
The preparation of sample solution shall be carried out according to the following
procedure.
a) Weigh out the sample, transfer it to a platinum dish (No. 200) or a PTFE beaker
(300 mn, and place a platinum or PTFE cover.
b) Add 10 ml of hydrochloric acid and 15 ml of perchloric acid, then decompose it by
adding about 20 ml of hydrofluoric acid gradually.
c) Heat gently at first, then increase the heat until dense white fume of perchloric
acid is generated. Continue heating until a syrupy consistency is obtained and
manganese dioxide begins to precipitate.
d) After allowing it to cool, add 20 ml of hydrochloric acid (1 + 4), and dissolve soluble
salts by heating. Heat the solution gently until it becomes transparent.
The case where insoluble residue exists shall be in accordance with 5.4.1 t).
e) Add 50 ml of hot water and allow it to cool to the room temperature.
6.5.2 Titration
The titration shall be carried out according to the following procedure.
a) Transfer the sample solution obtained in 6.5.1 e) into the volumetric flask (250 mn
using water, allow it to cool to the ordinary temperature, and add water up to the
marked line.
b) Take 50 ml of the solution using the pipette, transfer it to a beaker (500 mn, and
dilute it to 100 ml by adding water, and add 250 ml of sodium diphosphate solution
(6.2.5) 2).

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Note 2) When using the automatic titration apparatus having the potential dif-
ference meter on the market, a beaker (200 m!) used for titration may
be used. In this case, the aliquot shall be 25 ml, the amount after addi-
tion of water shall be 50 ml, and the addition amount of sodium di-
phosphate solution shall be 100 ml.
c) Place a beaker on the magnetic stirrer, put a rotator, and start to stir.
d) Adjust pH of this solution to 6.5 to 7.0 with hydrochloric acid (1 + 2) by using a pH
meter.
e) Titrate the solution with 0.02 mollL potassium permanganate solution (6.2.6) by
using the potentiometer and read the amount used by taking the point at which the
deflection of potentiometer becomes largest as the end point.
6.6 Blank test

6.7 Calculation
The manganese content rate in the sample shall be calculated from the used amount
of 0.02 mollL potassium permanganate solution obtained in 6.5.2 according to the fol-
lowing formula.
V, Xf2 xO.004395
Mn = ~ xiOO
m 2 xB /250

where, Mn: manganese content rate in sample [% (mass fraction)]

V2 : used amount of 0.02 mollL potassium permanganate so-
lution obtained in 6.5.2 (m!)
h __ = f~~t~:n:_9fQ:Q2_W_QlzL_r>Qt~~}:?j.JJJnJ?~rm~n.g_gJ}~t~_~9.11Jti9.n
m2: amount of test portion (g)
B : aliquot of sample solution (m!)
6.B Tolerances
The tolerances shall be in accordance with table 2.
~_QX_th~~_~_JQl~r~n~~_~~_J{Qt~_?!__QJ_~!Q!~ __~b_gU_~p-r>JY-.__AJ~Q_il}_tbg_<;~_~~_~h~r~_Jb._~ __glig1JQt_QJ
__
~~Hnr>l~__~Ql~_tiQn _i~ ~f)__mt RY_ ~_~il),g Jh~ __gJJ tQm_g_ti~ _
tj._tr~JiQn _~'p'pJn·_~_t~_~2 _th~y _~_h~ll ~P.PJy:~

Table 2 Tolerances
Unit: % (mass fraction)
Manganese content rate I Within-laboratory-reproducibility limit I Reproducibility limit
62.49 I 0.277 I 0.342
NOrE _: ___l:lw_ );lJ~l))g~p~~E?_ ~9nt~)~~t _r_~_tE?_ gj:Y~n _in _tb:i_~ _t~bl~ j~__tpg _W_~_I)g~rr~~_E? _~9ntE?nt _:r~t.E? _:in t.pg
~_~_wI>1E?_~~E?Jl:iD_fh~__GQ9I>_E?r_~_tiY:E?__E?~R~xjm~ntfQr_JJgt_E?rmining_th~_tQl~x~rr~_E?J~_9.~~~rl_9)),.
~:US_ Z_ ~~Q~ _: _l~J)J-,

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7 Disodium ethylenediaminetetraacetate dihydrate titration method

7.1 Summary
After decomposing the sample with nitric acid and hydrofluoric acid, make it the hy-
drochloric acid solution, and add hydroxyl ammonium chloride and 2,2',2"-nitrotrietha-
nol. Adjust pH at about 10, add potassium cyanide, and titrate with disodium ethyl-
enediaminetetraacetate dihydrate (hereafter, referred to as "EDTA2Na") solution by
using thymolphthalein complexion as the indicator.
7.2 Reagents
Reagents shall be as follows.
7.2.1 Hydrochloric acid (1 + 1)
7.2.2 Nitric acid
7.2.3 Hydrofluoric acid
7.2.4 Sulfuric acid (1 + 1)
7.2.5 Potassium cyanide solution (10 gIL)
7.2.6 Sodium disulfate
7.2.7 Ammonium buffer solution After dissolving 54 g of ammonium chloride in wa-
ter' add 600 ml of aqueous ammonia, and add water to make the liquid amount 1 000
ml.
7.2.8 Hydroxyl ammonium chloride solution (50 gIL)
7.2.9 2,2',2"-nitrotriethanol (alternative name: triethanolamine) solution (250 mllL)
7.2.10 0.05 mollL EDTA2Na solution The preparation, storage and standardization
method shall be in accordance with c) in JA.5.2 of JIS K 8001.
7.2.11 Thymolphthalein complexion indicator Put 0.1 g of thymolphthalein com-
plexion and 10 g of potassium nitrate in the agate mortar, and grind them thoroughly.
Warning: Since potassium cyanide is fatally poisonous, special care shall be taken
for handling this reagent and the solution containing this reagent solu-
tion.
7.3 Amount of test portion
The test portion shall be 0.10 g weighed out to the digit of 0.1 mg.
7.4 Procedure
7.4.1 Preparation of sample solution
The preparation of sample solution shall be carried out according to the following
procedure.
a) Weigh out the sample, transfer it to a platinum dish (No. 100) or a PTFE beaker
(100 mn, and place a platinum or PTFE cover.

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G 1314-1 : 2011

b) Slide the cover a little, add 15 ml of nitric acid, and decompose it by dripping sev-
eral drops of hydrofluoric acid step by step. When the reaction becomes vigorous in
this procedure, cool the outside of the container with water.
c) Evaporate the solution to dry up by heating, further heat for about 10 min, then,
allow it to cool.
d) Wash the lower surface of the cover with a small amount of water and remove it,
add 10 ml of hydrochloric acid (1 + 1), and dissolve soluble salts by heating 3).
Note 3) When insoluble residue is not observed, the operation of e) need not be
carried out.
e) Filter the solution with filter paper (Class 5A), and wash it several times with
warm water. Receive the filtrate and washings in a beaker (300 m!), and store it as
the principal solution. Transfer the residue together with filter paper into a plati-
num crucible (No. 30), and ash the filter paper by ignition. After allowing it to cool,
moisten with several drops of sulfuric acid (1 + 1), add about 1 ml of hydrofluoric
acid, and heat to dry up. After allowing it to cool, add about 2 g of sodium disulfate,
and fuse it by heating. After allowing it to cool, put the melt together with the
platinum crucible into the previously stored principal solution, and dissolve it by
heating. Wash the platinum crucible with a small amount of water, and take it out.
7.4.2 Titration
The titration shall be carried out according to the following procedure.
a) Transfer the solution obtained in d) or e) of 7.4.1 into an Erlenmeyer flask (500 m!)
with water, add water to make the liquid amount about 150 ml, and allow it to cool
to the room temperature.
b) Add 5 ml of hydroxyl ammonium chloride solution (50 giL) and 20 ml of 2,2',2"-ni-
trotriethanol solution (1 + 4) while shaking the solution, and further gradually add
50 ml of ammonium buffer solution (7.2.7). Thereafter, add about 1 mlofpotassium
cyanide solution (10 giL).
c) Add 0.05 g to 0.08 g of thymolphthalein complexion indicator (7.2.11). After shak-
ing, immediately titrate with 0.05 mollL EDTA2Na solution (7.2.10), take the point
at which the solution turns from blue to yellow or colourless as the end point, and
obtain the amount of 0.05 mollL EDTA2Na solution used.
7.5 Blank test
A blank test is not carried out.
7.6 Calculation
The manganese content rate in the sample shall be calculated from the used amount
of 0.05 mollL EDTA2Na solution obtained in 7.4.2 according to the following formula.

Mn =
~
-
xh- x 0.002747 x 100
m3

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G 1314-1 : 2011

where, Mn: manganese content rate in sample [% (mass fraction)]

V3: used amount of 0.05 mollL EDTA2Na solution obtained
in 7.4.2 (m!)
h : factor of 0.05 mollL EDTA2Na solution
m3: amount of test portion (g)
7.7 Tolerances
The tolerances shall be in accordance with table 3.

Table 3 Tolerances
Unit : % (mass fraction)
Manganese content rate I Within-laboratory-reproducibility limit I Reproducibility limit
62.59 I 0.314 I 0.546
NOTE: The manganese content rate given in this table is the manganese content rate in the
sample used in the cooperative experiment for determining the tolerances based on
JIS Z 8402 : 1991.

Bibliography
JIS Z 8402 : 1991 General rules for permissible tolerance of chemical analyses and
physical tests

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 o~
o
~
CJJ
~
~
Annex JA (informative) ~
I

Comparison table between JIS and corresponding International Standard

t-.:l
JIS G 1314-1 : 2011 Method for chemical analysis ofs11icomanganese - Part 1 : ISO 4159 : 1978 FeITomanganese and fen'osilicomanganese - Deter o
~
~
Determination ofmanganese content mination ofmanganese content - Potentiometric method
(1) Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) Justification for the
national International Standard deviation between JIS and the Interna- technical deviation and
Standard tional Standard by clause future measures
number
No. and Content No. of Content Classifica - Detail of technical deviation
title of clause tion by
"'d
~ clause clause
o 1 Scope Determination method 1 Scope Poten tiometric Addition In ISO Standard, only po- In JIS, two other methods
~
t:rj
o of manganese content method for determi- tentiometric method is widely used in Japan and
~
t:rj in silicomanganese is nation of manganese specified. In JIS, two other necessary as JIS are added.
U
specified. content of ferroman- determination methods are Proposal of addition of
to
~ ganese and ferrosili- added. these to ISO will be stud-
o
o comanganese. ied.

~ 2 Norma-
o
"""" tive refer-
~
~ ences

3 General In accordance with JIS 1 Scope In accordance with Alteration Practically identical. -
G 130l. ISO 3713.

4 Classifi- Potassium permanga- 1 Scope Only potentiometric Addition In ISO Standard, only po- For determination meth-
cation of nate visual titration method is specified. tentiometric method is ods other than potenti-
determina- method, potassium specified. In JIS, two other ometric method, proposal
tion permanganate potenti- determination methods are to ISO will be studied.
method ometric method, and specified.
disodium ethylenedia-
minetetraacetate di-
hydrate titration
method
 (n Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) Justification for the
national International Standard deviation between JIS and the Interna- technical deviation and
Standard tional Standard by clause future measures
number
No. and Content No. of Content Classifica - Detail of technical de via tion
title of clause tion by
clause clause
5 Potas- Potassium permanga- - - Addition Potassium permanganate Added because this method
sium per- nate visual titration visual titration method is widely used in Japan.
manganate method which utilizes faint pink col-
visual ti- our is added.
tration
method
"'d
~
o 6.1 Sum- Decompose sample 3 Prin- Identical with JIS. Identical - -
~
t:rj mary with acid, adjust pH ciple
o
~ and carry out potenti-
t:rj
U ometric method
to
~ 6.2 Re- 0.02 mollL potassium 4Re- 0.1 N potassium per- Alteration In JIS, mollL which is of SI Proposal to ISO will be
o
o agents permanganate solution agents manganate solution units is used. studied.

~ 6.3 Appara- Potentiometer, elec- 5 Appa- Conical flask, reflux Deletion General instruments such There is no deviation prac-
o
"""" tus and im- trodes ratus condenser, pH meter, as glass instruments quoted tically.
~
~ plements potentiometer, etc. in JIS G 1301 are deleted.
are specified.

6.4 Amount 1.0 g 7.1 1.0 g Identical - -

of test por- Test

tion portion

6.5 Proce- After decomposition by 7 Pro- Identical with JIS. Identical - -

0
dure acid, titrate by adjust- cedure I--'
CA:l
ing pH and using po- I--'
tentiometer *:'"
I--'

~
0
I--' I--'
I--' I--'
 o~
~
~
CJJ
~

(n Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) Justification for the ~
~
I

national International Standard deviation between JIS and the Interna- technical deviation and
~
Standard tional Standard by clause future measures o
~
number
No. and Content No. of Content Classifica - Detail of technical de via tion ~

title of clause tion by

clause clause
6.6 Blank Blank test is not car- 7.2 Blank test is carried Alteration With/without blank test. Blank test is not carried
test ried out. Blank out. ou t because manganese
test contained in reagents, etc.
"'d
are negligible and deter-
~ mination of end point of
o
~ blank test in which little
t:rj
o manganese exists is diffi-
~
t:rj
U
cult.
to Proposal to ISO will be
~
o studied.
o
SEx-
~
6.7 Calcu- Formula includes fac- Corresponding Alteration The formula does not con- In JIS K 8001, the conver-
lation tor of potassium per- pres- amount of manga- tain blank test value as sion method of correspond-
o
"""" manganate solution. sion of nese per millilitre of blank test is not carried out ing manganese amount is
~
~ results potassium perman- in JIS. Moreover, in ISO altered because the con-
ganate standard so- 4159, content rate of man- centration of potassium
lution. ganese is calculated from permanganate standard
corresponding manganese solution is corrected by
amount per millilitre of po- factor. Moreover, for the
tassium permanganate blank test, proposal to ISO
standard solution. On the will be studied.
other hand in JIS it is cal-
culated from transformation
constant and factor.
6.S Toler- Tolerances are speci- 9 Re- Reproducibility is Alteration In JIS, they are determined Proposal to ISO will be
ances fied. pro- specified. from cooperative experi- studied.
duci- ment.
bility
 (n Requirements in JIS (II) Inter- (III) Requirements in (IV) Classification and details of technical (V) Justification for the
national International Standard deviation between JIS and the Interna- technical deviation and
Standard tional Standard by clause future measures
number
No. and Content No. of Content Classifica - Detail of technical de via tion
title of clause tion by
clause clause
7 Disodium Disodium ethylenedia- - - Addition Disodium ethylenediamine- Added because this
ethyl- minetetraacetate di- tetraacetate dihydrate titra- method is used in Japan.
enedia- hydrate titration tion method is added.
mIne-
tetraace-
tate di-
"'d
~ hydrate ti-
o tration
~
t:rj
o method
~
t:rj
U
to
~
o Overall degree of correspondence between JIS and International Standard (ISO 4159 : 1978): MOD
o
~
NOTE 1 Symbols in sub-columns of classification by clause in the above table indicate as follows:

o
"""" - Identical: Identical in technical contents.
~
~ - Deletion: Deletes the specification item(s) or content(s) of International Standard.

- Addition: Adds the specification item(s) or content(s) which are not included in International Standard.

- Alteration: Alters the specification content(s) which are included in International Standard.

NOTE 2 Symbol in column of overall degree of correspondence between JIS and International Standard in the above table indicates as follows:

- MOD: Modifies International Standard.

o
I--'
CA:l
I--'
*:'"
I--'

~
o
I--' I--'
I--' CA:l
Errata for JIS (English edition) are printed in Standardization and Quality Control, published
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