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5102 Ind. Eng. Chem. Res.

2010, 49, 5102–5109

Experimental and Computational Fluid Dynamics Study of Dense-Phase,


Transition Region, and Dilute-Phase Spouting
Marcos A. S. Barrozo,*,†,‡ Cláudio R. Duarte,‡ Norman Epstein,† John R. Grace,† and C. Jim Lim†
Department of Chemical and Biological Engineering, UniVersity of British Columbia, 2360 East Mall,
VancouVer, Canada V6T 1Z3, and School of Chemical Engineering, Federal UniVersity of Uberlândia,
Bloco K - Santa Mônica, 38400-902, Uberlândia, MG, Brazil

In this work, the transition between conventional dense-phase spouting and dilute-phase spouting is quantified
and characterized on the basis of experimental particle velocity and bed voidage data, obtained with an optical
fiber probe, as well as from the evolution of pressure with air velocity. The high gas velocities associated
with the dilute-phase spouted bed (DSB) flow regime result in voidages exceeding 0.9 over the entire bed,
with no discernible distinction between spout and annulus. The downward particle velocities for the DSB
regime differ in magnitude from those in the dense-phase spouting regime. Computational fluid dynamics
simulations using the Eulerian granular multiphase model show good agreement with experimental data for
the three reproducible flow regimes: dense-phase spouting, transition regime, and dilute-phase spouting.

1. Introduction In the case of sticky solids, a dilute-phase spouted bed (DSB),


Spouted beds have been studied for many processes such as compared with the CSB, has the advantages of higher particle
drying, coating, granulation, and pyrolysis.1-4 This technique velocity and higher bed voidage. The modification of the bed
is an alternative to fluidization for particulate solids too coarse geometry and the reduction of the static bed height result not
for good fluidization. In addition to their ability to handle coarse only in greater gas-solid dilution, but also in shorter particle
particles, spouted beds have structural and cyclic flow patterns cycle times in dilute-phase spouting.9 Higher gas velocities in
with effective fluid-solid contact. the DSB can also be an advantage for some drying process.
Gas-solids flow in a conventional spouted bed (CSB) can Olazar et al.5 observed a transition regime between conven-
be divided into three regions: a spout at the center, where the tional and dilute-phase spouting. Hence, three flow regimes are
gas and particles rise at high velocity and the particle concentra- of interest: (a) conventional spouting, (b) transition regime, and
tion is low; a fountain zone, where particles rise to their highest (c) dilute-phase spouting.
positions and then rain back onto the surface of the annulus; Operations in dilute-phase spouting and in the transition
and an annulus zone between the spout and the column wall regime are sensitive to the geometry of the equipment and to
where particles move slowly downward as a dense phase, with the particle diameter. The following ranges of the geometric
counter-current percolation of the fluid. Thus, a cyclic pattern parameters for stable operations in DSB and transition regimes
of solids movement is established. The gas enters the column have been suggested:
through an orifice and then flows upward quickly through the • Cone included angle (γ): the angle must be between 28
spout and more slowly through the interstices in the annulus and 45°.5 For smaller angles, mainly operating with small
zone. particles (ds < 2 mm), there is a mixing regime, without
Despite the versatility of conventional spouted beds, there the cyclic movement characteristic of the spouting regime.
are situations in which the fluid-solid contact is unsatisfactory. For angles greater than 45°, a rotation phenomenon is
Some applications need more vigorous contact; for example, produced in the gas circulation leading to bed instability.5
when the solids are sticky and tend to fuse (e.g., in catalytic • Inlet diameter/particle diameter (Do/ds): Do/ds should be
polymerization) or in fast reactions (e.g., ultrapyrolysis) with between 1 and 80. The lower limit corresponds to voidages
short residence time of the fluid phase.5 Some research on the of the order of 0.7, whereas the upper limit corresponds to
drying of suspensions also indicates limitations of the CSB. A voidages of 0.99 for DSB.5
low particle circulation rate and the required long residence time • Static bed height/inlet diameter (Ho/Do): Ho/Do can be
reduce the drying efficiency and have an adverse effect on between 2 and 5.10
material properties, particularly for heat-sensitive products. In In conical columns of low static bed depth, a small cone angle
many cases, excessive accumulation of the suspended material (28-45°), and with inlet diameter/cone bottom diameter ratio
causes bed blockage.6 (Do/Di) between 1/2 and 1, Olazar et al.11 proposed the following
Continued expansion of a shallow spouted bed can lead to a correlations for the minimum dense-phase spouting velocity
regime that has variously been dubbed as “jet spouted bed”5-7 (Uoms) and the minimum dilute-phase spouting velocity (Uomj):
or, more accurately, “dilute-phase spouting”,8 in contrast to
(Reo)ms ) 0.126Ar0.5(Db /Do)1.68[tan(γ/2)]-0.57 (1)
conventional dense-phase spouting. The high gas velocities
associated with this regime result in high voidages in the entire
column, with little distinction between the spout and the annulus. (Reo)mj ) 6.89Ar0.35(Db /Do)1.46[tan(γ/2)]-0.53 (2)
* To whom correspondence should be addressed. Fax: 55-34- The spatial distributions of voidage and particle velocity are
32394188. E-mail: masbarrozo@pesquisador.cnpq.br; masbarrozo@
ufu.br. of great importance in applications of spouted beds. He et al.12

University of British Columbia. used a fiber-optic probe to measure the vertical particle velocity

Federal University of Uberlândia. profiles in the spout, annulus, and fountain regions of a full-
10.1021/ie9004892 CCC: $40.75  2010 American Chemical Society
Published on Web 07/02/2009
Ind. Eng. Chem. Res., Vol. 49, No. 11, 2010 5103

Figure 2. Schematic diagram of the optical fiber probe.30

2. Experimental Setup
The particles in this study were glass beads of 1.16, 1.55,
Figure 1. Schematic diagram of a spouted bed column and its main and 2.12 mm Sauter mean diameter, 2500 kg/m3 particle density,
dimensions.
and sphericity of 1.0. For these particles, the loosely packed
voidage was found to be 0.39.
column conventional spouted bed. Benkrid and Caram13 adopted
The experimental apparatus was similar to that used by
a fiber-optic technique to determine particle velocities in the
Wang,29 with air from a compressor as the spouting gas. The
annulus of a full column and concluded that there is plug flow
air flow rate was determined by an orifice flow meter, and two
in the upper part of the annulus, where particles in the annulus pressure transducers measured the operating pressure upstream
move vertically downward and radially inward. On the basis of the orifice and the pressure drop across the orifice. To
of optical fiber probes, Olazar’s group studied the particle investigate the axial variation of pressure drop, static pressure
velocity distribution14 and local voidage distribution15,16 of probes were installed in ports along the wall of the column.
conical spouted beds of different geometries (cone angle and All signals from pressure transducers were logged into a
gas inlet diameter), for operation close to minimum conventional computer via a data acquisition system.
spouting. A schematic representation of the Plexiglas spouted bed
Most previous studies on the distribution of local voidage column is shown in Figure 1. Its main dimensions were: cone
and particle velocity in spouted beds were carried out in included angle (γ) 45°, gas inlet orifice diameter (Do) 0.019 m,
conventional spouted beds (dense-phase spouting regime).12-16 basal diameter (Di) 0.038 m, height of cone section (Hc) 0.50 m,
Knowledge of particle velocity and voidage is also key to and diameter of cylindrical section (Dc) 0.45 m.
understanding the transition between the CSB and DSB. The pressure drop across the bed for each superficial air
In addition to experimental work, computational fluid dynam- velocity was estimated by subtracting the grid pressure drop in
ics (CFD) studies have become popular recently. The two the absence of a bed.5 Minimum spouting was determined by
approaches used in simulating multiphase flows are the plotting spout pressure drop as a function of decreasing inlet
Eulerian-Lagrangian and the Eulerian-Eulerian. The first, air velocity. The point at which the spout collapses defined the
which involves the balance of forces at work upon individual minimum spouting air velocity. Once the dilute-phase regime
particles, requires considerable computational effort and is was reached, it was found to remain stable with further increases
suitable for particle volume fractions less than 0.1. The in air velocity, with a constant pressure drop. Therefore, the
Eulerian-Eulerian approach considers the dispersed particles minimum dilute-phase spouting velocity was determined from
as a continuous phase and is based on the equations of motion the same plot of pressure drop vs superficial air velocity, as the
applied to each phase. intersection between the constant pressure drop line (dilute
phase) and the descending line (transition), as well as by visual
Many recent studies of spouted bed hydrodynamics are based observation.
on CFD.17-28 These were carried out in conventional spouted
Particle velocity and local voidage were measured by an
beds (dense-phase regime). However, the CFD technique can
optical fiber probe. The optical fiber probe measurement system
also be important for understanding the transition between in the present work (particle velocity meter PV-4A) was
conventional and dilute-phase spouted beds and behavior in the obtained from the Institute of Process Engineering of the Chinese
higher-velocity flow regimes. Academy of Sciences. It consists of a probe, a light source,
In this work, particle velocity, bed voidage, and pressure drop two photomultipliers, and a high-speed data acquisition card
evolution with increasing air velocity were determined experi- connected to a computer. The probe contains three vertically
mentally in conventional dense-phase spouting and dilute-phase aligned optical fiber bundles with the one in the middle as the
spouting, as well as in the transition regime between them. The light projector and the other two as light receivers. When a
Eulerian multiphase CFD model is used to simulate spouted particle passes near the head of the probe, it reflects light emitted
bed fluid dynamics in these three flow regimes. The simulated by the central bundle of fibers. The reflected light was collected
results are then compared with the experimental data. in succession by the two fiber bundles located above and below,
5104 Ind. Eng. Chem. Res., Vol. 49, No. 11, 2010

separated by an effective distance (De). The probe was 4 mm


(Dprobe) in outside diameter. To eliminate the influence of the
blind zone,29,30 a glass window was added in front of the probe
tip.
A schematic representation of the optical fiber probe is shown
in Figure 2.
By off-line cross-correlation of sampled signals from the two
light receivers (A and B), the time delay (τ) can be obtained,
and the particle velocity (Vs) can be calculated for a known De
between the two light receivers (i.e., Vs ) De/τ). The effective
distance between the light-projection and light-receiving fibers
of the optical velocity probe was determined using a disk
rotating at known angular velocity with particles glued to it.29
By off-line averaging of sampled signals from the two light
receivers, the local voidage was also measured on the basis of
pre-established calibration between the voidage and the ampli-
tude of the signal.

3. CFD Simulations
3.1. Model. The granular Eulerian model is a complex
multiphase model predicting granular flows, such as those in
fluidized beds, spouted beds, risers, and other suspension
systems.17,21-28,31-35 In this approach, the gas and solid particles
are treated as interpenetrating continua and the concept of phase
volume fractions representing the space occupied by each phase
is adopted, so that the laws of conservation of mass and
momentum are satisfied by both phases.
Interphase momentum transfer between the gas and solid
phases is one of the dominant terms in the gas-phase and solid-
phase momentum balances. Several correlations for calculating Figure 3. Grid adopted in the CFD simulations.
the momentum exchange coefficient for gas-solid systems are
ensure that the correct maximum packing limit of the settled
available in the literature. In the present work, the momentum
layer is upheld. In the present work, the equation of Ogawa et
exchange coefficient was based on the drag model of Giadspow
al.41 was used to calculate the radial distribution function in
et al.,36 which combines the Wen and Yu37 model for dilute
the solid-pressure equation.
conditions (ε > 0.8) and the Ergun38 equation for dense
3.2. Simulation Conditions. The simulation strategy used
conditions (ε e 0.8).
by Duarte et al.17 was adopted in this work. The set of
The constitutive equations for shear and bulk viscosities conservation and constitutive equations was solved by finite
estimation are defined by the granular kinetic theory derived volume elements using Fluent 12.0.7 software.
by Lun et al.,39 analogous to the kinetic theory of gases. The The following conditions were adopted in the simulations:
concepts of granular temperature and solids pressure are also • Axial symmetry was assumed.
utilized in this model. For this approach39 in the dilute part of • The computational domain was discretized by 96 000
the flow, grains fluctuate randomly; this form of viscous structured grid cells (as shown in Figure 3).
dissipation and stress is called kinetic stress. At higher • The SIMPLE algorithm was adopted for the pressure-
concentrations, in addition to the previous dissipation form, velocity coupling.
grains can collide briefly, giving rise to further dissipation and • The first-order upwind algorithm was adopted in the spatial
stress, called collisional stress. At very high concentrations discretization for momentum and volume fraction.
(>50% by volume), grains undergo long sliding and rubbing • The inlet velocity was assumed to be uniform as the inlet
contacts, leading to a totally different form of dissipation and boundary condition.
stress, called frictional stress. In the present work, the solids • Atmospheric pressure was adopted as the outlet boundary
shear viscosity was calculated as proposed by Giadspow et al.36 condition.
The equation for solids bulk viscosity, which accounts for the • The no-slip boundary condition was assumed on the wall
resistance of the granular particles to compression and expan- for both gas and solids.
sion, was calculated as defined by Lun et al.39 • The particle-particle coefficient of restitution was taken
The basic idea underlying granular kinetic theory is that as 0.9.
particles are in a state of continuous and chaotic restlessness • The solution was considered to have converged when the
within the fluid. On the basis of an analogy with a gas, a scaled residuals were less than 1 × 10-3 with a time step
“granular temperature”, θs, of the solid phase is defined, of 1 × 10-4 s.
proportional to the kinetic energy of the random motion of the
particles.
4. Results and Discussion
In the granular model, the pressure exerted on the containing
wall by the particles and the transfer of momentum caused by 4.1. Experimental Results. Pressure-Drop Evolution. Fig-
particle streaming is calculated by a solids pressure. The solid- ure 4 shows the experimental pressure drop across the bed as a
pressure model40 is used to represent the interparticle forces function of the superficial air velocity for four static bed heights:
produced by the particles settling on top of each other and to 22, 32, 52, and 82 mm for particles of 1.55-mm diameter. The
Ind. Eng. Chem. Res., Vol. 49, No. 11, 2010 5105

Figure 7. Radial distributions of voidage at three levels for particles of ds


) 1.55 mm, Ho of 60 mm, and air velocity (Uo) of 7Uoms.

Figure 4. Pressure drop across bed as a function of superficial air velocity regime (c) was reached, the pressure drop remained constant
for different static bed depths (ds ) 1.55 mm). with further increases in velocity.5
When our experimental data for 1.55-mm glass beads are
three reproducible spouted bed flow regimes can be recognized. compared with predictions of Olazar et al.’s11 correlations, the
Beyond the conventional spouting regime (a), on increasing the mean deviations between calculated and experimental data for
superficial air velocity, there was a decrease in pressure drop, minimum dense-phase and minimum dilute-phase spouting
over an extended transition regime (b) between conventional velocities are, respectively, +20.8 and +9.1%. For this particle
and dilute solids spouting in which solid flow characteristics size, the minimum dense-phase spouting velocity is overpre-
were intermediate between those regimes, while maintaining dicted, and there is better agreement for the minimum dilute-
the cyclic particle movement characteristic of conventional phase spouting velocity. For the 2.12-mm particles, there was
spouted beds. The transition developed until the spout and better agreement in both cases, with the mean deviation between
annular zones were no longer distinguishable, and the bed calculated and experimental data for minimum dense-phase
voidage became almost uniform, leading to a new situation that spouting and minimum dilute-phase spouting velocities of +10.3
corresponds to a dilute-phase spouted bed (c). Once this flow and +7.7%, respectively. Better prediction for larger particles

Figure 5. Radial distribution of local voidage at z ) 37 mm for particles of ds ) 1.16 mm and Ho of 62 mm.

Figure 6. Radial distribution of voidage at z ) 37 mm for particles of ds ) 1.55 mm and Ho of 52 mm.


5106 Ind. Eng. Chem. Res., Vol. 49, No. 11, 2010

Figure 8. Radial distribution of particle velocity at z ) 37 mm for particles of ds ) 1.16 mm and Ho of 62 mm at four superficial air velocities.

Figure 9. Radial distribution of particle velocity at z ) 37 mm for particles of ds ) 1.55 mm and Ho of 52 mm at five superficial air velocities.

Figure 10. Experimental results compared with CFD predictions of radial Figure 11. Experimental results compared with CFD predictions of radial
distribution of voidage at z ) 37 mm for particles of ds ) 1.55 mm, Ho of distribution of voidage at z ) 37 mm for particles of ds ) 1.16 mm, Ho of
52 mm, and Uo ) 1.6Uoms (CSB). 62 mm, and Uo ) 3.0Uoms (transition regime).

by Olazar et al.’s11 correlations was also observed by Wang26 spout zone and a sharp drop at the spout-annulus interface. In
for the minimum dense-phase spouting velocity. the annulus, where particles are in close contact with each other,
Particle Velocity and Voidage. Figure 5 shows experimental the voidage is uniform and almost equal to the initial packed
data for radial distribution of voidage 37 mm above the base of bed voidage.
the column, with particles of ds ) 1.16 mm and static bed height For the DSB regime conditions, it can be clearly seen in
(Ho) of 62 mm, for four superficial air velocities, corresponding Figures 5 and 6 that the bed voidage differs radically from that
to 1.5, 3.0, 6.0, and 8.0 times the minimum dense-phase spouting in the CSB regime. High expansion of the bed creates a very
velocity (Uoms). Figure 6 plots the distribution of voidage, at dilute system with high bed voidage. In this dilute flow regime,
the same height (z ) 37 mm), for 1.55-mm particles and Ho of the voidage in the annular region was similar to that in the spout
52 mm with Uo/Uoms ) 1.6, 2.8, 4.2, 5.4, and 6.9. zone (i.e., the boundaries between zones disappeared), and the
Figures 5 and 6 show radial distribution of voidage for the bed voidage was almost uniform across the whole bed. In the
conventional spouting regime, Uo ) 1.5 × Uoms and 1.6 × Uoms, transition flow regime, the voidages were higher than those for
qualitatively similar to those reported in the literature.12,15,16 In the conventional spouting regime, with the difference between
this dense-phase spouting regime, there is a clear distinction the spout and annular zones decreasing with increasing air
between the annular and spout zones, with high voidage in the velocity (Figure 6).
Ind. Eng. Chem. Res., Vol. 49, No. 11, 2010 5107

Figure 15. Experimental results compared with CFD predictions of radial


Figure 12. Experimental results compared with CFD predictions of radial distribution of particle velocity at z ) 37 mm for particles of dp ) 1.55
distribution of voidage at z ) 37 mm for particles of ds ) 1.55 mm, Ho of mm, Ho of 52 mm, and Uo ) 2.8Uoms (transition regime).
52 mm, and Uo ) 4.2Uoms (transition regime).

Figure 13. Experimental results compared with CFD predictions of radial Figure 16. Experimental results compared with CFD predictions of radial
distribution of voidage at z ) 37 mm for particles of ds ) 1.16 mm, Ho of distribution of particle velocity at z ) 37 mm for particles of dp ) 1.55
62 mm, and Uo ) 8.0Uoms (dilute-phase regime). mm, Ho of 52 mm, and Uo ) 5.4Uoms (transition regime; near minimum
dilute-phase condition).

increases significantly with increasing superficial gas velocity.


The upward particle velocities in the DSB regime were higher
than those for the other flow regimes, but of the same order of
magnitude. However, the downward particle velocities for the
DSB regime exceeded in magnitude those in the conventional
spouting regime. This must be due to nearly free-falling
movement of the particles along the containing wall of the
column, giving rise to much shorter particle cycle times in this
dilute flow regime.9
4.2. CFD Results. Voidage. The experimental data and CFD
results of radial distribution of voidage (at z ) 37 mm) for the
dense-phase spouting regime (Uo ) 1.6 × Uoms) are plotted in
Figure 14. Experimental results compared with CFD predictions of radial Figure 10, for particles of ds ) 1.55 mm and Ho of 52 mm. It
distribution of particle velocity at z ) 37 mm for particles of dp ) 1.55 can be observed that there is very good agreement between
mm, Ho of 52 mm, and Uo ) 1.6Uoms (conventional spouting regime).
simulated results and experimental data for the CSB.
The experimental data on radial distribution of voidage for Comparisons between CFD predictions and experimental
the DSB regime (Uo ) 7.0 × Uoms), at three different heights, voidage data for the transition regime at z ) 37 mm are shown
z ) 37, 88, and 139 mm for 1.55-mm particles and Ho of 60 in Figures 11 and 12. Figure 11 presents results for 1.16-mm
mm, are plotted in Figure 7. It was observed that for the DSB particles and a static bed height of 62 mm with Uo ) 3.0 ×
regime there was an increase in bed voidage with increasing Uoms, whereas Figure 12 is for 1.55-mm particles and a static
height, z, above the base. bed height of 52 mm with Uo ) 4.2 × Uoms. It can be observed
Figures 8 and 9 show the radial distributions of particle in Figure 11 that the voidage is underpredicted for the smaller
velocity at z ) 37 mm for different air velocities, respectively, particles (ds ) 1.16 mm) at the interface between the spouted
for 1.16-mm particles with Ho of 62 mm, and for 1.55-mm and annular zones. However, these results also show that for
particles with Ho of 52 mm. For the conventional spouting these two very distinct conditions of the transition regime, and
regime, the radial distribution of particle velocities was quali- hence with different annular and spout zone characteristics, the
tatively similar to those reported in the literature.9,12,14 In this CFD simulations were still able to predict the trends and the
dense-phase spouting regime, particles descend slowly in the radial voidage distribution in reasonably good agreement with
annulus zone, whereas much higher particle velocities are the experimental values.
obtained in the spout, with a maximum at the axis. Figure 13 shows the experimental voidage data and CFD
The experimental results of Figures 8 and 9 also indicate that, predictions for the dilute-phase regime, for particles of ds )
as expected, the upward particle velocity in the spout zone 1.16 mm, a static bed height of 62 mm, and Uo ) 8.0 × Uoms.
5108 Ind. Eng. Chem. Res., Vol. 49, No. 11, 2010

to predict the hydrodynamic behavior of all three flow regimes


of spouting: CSB, transition regime, and DSB.

Acknowledgment
We are thankful for financial aid from CNPq, Brazil, and
from the Natural Sciences and Engineering Research Council
of Canada.

Nomenclature
Ar ) Archimedes number, Ar ) ds3F(Fs - F)/µ2 [-]
Db ) top diameter of static bed [m]
Dc ) diameter of cylindrical section [m]
Figure 17. Experimental results compared with CFD predictions of radial
De ) effective distance between two light receivers (optical fiber
distribution of particle velocity at z ) 37 mm for particles of dp ) 1.55
mm, Ho of 52 mm, and Uo ) 6.9Uoms (DSB). probe) [mm]
Di ) diameter of base [m]
Although there was slight overprediction (4.5%), the CFD Do ) diameter of gas inlet orifice diameter [m]
simulations were able to predict the characteristic trend of the ds ) particle diameter [mm]
radial distribution of voidage for the dilute-phase regime, with Hc ) height of cone section [m]
no clear boundary between spouted and annular zones, and the Ho ) static bed height [mm]
bed voidage nearly constant over the entire cross section.6 ∆P ) pressure drop [Pa]
(Reo)ms ) FdsUoms/µ, particle Reynolds numbers for minimum
Particle Velocity. The experimental data and CFD predictions dense-phase spouting
for the radial distribution of particle velocity (at z ) 37 mm) (Reo)mj ) FdsUomj/µ, particle Reynolds numbers for minimum dilute-
for the dense-phase spouting regime (Uo ) 1.6 × Uoms) are phase spouting
plotted in Figure 14 for 1.55-mm particles and a static bed height t ) time [s]
of 52 mm. As for the voidage, the CFD simulations were again Uo ) superficial gas velocity, referred to Do [m s-1]
able to give good predictions of the radial distribution of particle Uoms ) superficial gas velocity at minimum spouting based on Do
velocity for the CSB. [m s-1]
Figures 15 and 16 compare the CFD predictions and Uomj ) superficial gas velocity at minimum dilute-phase spouting
experimental particle velocities at z ) 37 mm in the transition based on Do [m s-1]
regime for particles of ds ) 1.55 mm and a static bed height of
52 mm. Figure 15 shows the CFD predictions for a transition Greek Letters
condition near the conventional spouting regime (Uo ) 2.8 ×
γ ) cone angle [degrees]
Uoms), whereas Figure 16 is for a condition near the dilute-phase
ε ) voidage [-]
regime (Uo ) 5.4 × Uoms). These figures again show good θs ) granular temperature [m2 s-2]
agreement between the CFD predictions and experimental data µ ) gas viscosity [Pa s]
for these two very distinct conditions in the transition-flow F ) gas density [kg m-3]
regime. The CFD results show more clearly the inflection point F ) particle density [kg m-3]
at the interface between the spouted and annular zone than the τ ) time delay [s]
experimental data.
Figure 17 demonstrates that the CFD simulation model was
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