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B) Chipping
This is a glancing blow which chips a corner off an irregular shaped
particle. The result is a large particle almost the same size as the original and a
very much smaller "chip". This mechanism rounds irregular rock into roughly
spherical shapes, for example the pebbles formed in autogenous grinding.
C) Abrasion
This is the wear of surfaces by rubbing. Again in autogenous grinding
this produces the smooth "beach" pebbles. The products are once more the main
particle, with little change in size, and very minute particles.
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A: Ball Mill Fundamentals
These last two mechanisms are what are commonly referred to as attrition
and the first we observe as crushing. In any mill these mechanisms overlap to
produce particle size distribution. However by studying the particle size
distributions produced, researchers have concluded that the last two
1
mechanisms of attrition account for the majority of size reduction which occurs
in a ball mill. Some fracture occurs in the first compartment.
Cataracting
As the mill speed is increased (or lifters installed) the balls are lifted
higher and more are ejected from the surface at the top of the mill and a cataract
is formed. These balls fall freely and impact at the toe with great force, some of
which is recovered as they strike the "downhill" side of the mill. The fraction of
critical speed at which cataracting onsets is a function of the filling ratio and lifter
design.
At the 75% of critical speed, at which most of our mills run, cascading is
the primary movement as this is optimum for the chipping and abrasion
mechanisms which are the most efficient for normal particle sizes. Lifters in the
first compartment assist in the cataracting to increase the fracture mechanism
necessary for large particles.
3A.1.3 Factors Influencing Size Reduction
1
L. G. Austin, R. R. Klimpel, P. T. Luckie, Process Engineering of Size Reduction: Ball Milling,
Society of Mining Engineers, New York, 1984.
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In Feet: Vc = or In Meters: Vc =
For Example: if the useful diameter of a mill was found to be 12 feet then:
Vc = = 22.1 RPM
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For the mill speed of 16.6 RPM, means that this ball is running at (16.6 ÷ 22.1) X
100 = 75 % of its critical speed. Bear in mind that feed material type, ball volume
loading, ball charge gradation and liner types can also affect the grinding
conditions as well. (Note: there are, arguably, more precise equations than the
one used here, but they all take a similar form.)
In general balls will cascade (or cataract) within a rotating mill; even with
a perfectly smooth interior surface provided that the RPM is close enough to
critical and the right volume loading exists. Recognize that the cascading action
also depends somewhat on the grinding media sizes used and the nature of the
material being ground as well.
The purpose of mill liners is not only to protect the mill shell but they
must also "grip" the grinding balls and release them at the right height to obtain
the tumbling action that maximizes the grinding rate. If the balls are carried too
high they will get thrown against the mill liners on the opposite side where the
balls or liners may break. If the grinding action is limited to the toe of the mill
load, we'll get good crushing but it won't generate enough fines. This is OK for a
first compartment grinding very coarse feed, but inappropriate for any other
scenario. If the balls are not carried high enough then the impact energies while
tumbling are greatly reduced, thus retarding the grinding action. In addition,
that some sliding contact will occur which will increases liner wear.
Liner design is critical to good grinding action and wear life. Careful
consideration must be given to ball charge design, material load and the grinding
action required in that compartment in order to design the appropriate liner.
Good installation is just as important. Occasionally the liners get installed
backwards and then the plant wonders why production went down or worse,
every single ball is broken. Usually this results from the lack of good training.
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material in the mill is shortened. Increasing the mill air sweep in the finish ball
mills will provide for the removal of fines from the mills as they are created.
This serves to unload the mill and prevents the fines from being overground.
Moreover, the removal of fine particles from the mill as they are created
and enter the mill air sweep has a positive influence on the size reduction
function of the mill. It has been shown that as a mill material load becomes finer,
it becomes more difficult to accomplish additional grinding work. Therefore,
removing fines promotes additional grinding work. Also, fine particle removal
inhibits ball coating. Therefore, for several reasons, high ventilation provides for
a more efficient size reduction. In fact, in very high sweep conditions such as
those found in Demopolis the better grinding allows for a finer ball charge,
(according to Slegten).
Other effects could be summarized as follows:
a) Higher mill sweeps will cool the mill requiring less water spray (less
chance of hydration), but depending on spray configuration it may suck the
spray onto the discharge grates and plugging them.
b) Higher mill sweeps will reduce the quantity of superfines and may lead to
longer setting times and lower 1 and 3 day strengths.
c) Increased sweep on mills will also vent moisture and lowers humidity.
This is an important consideration on raw mills and for plants grinding masonry
cements.
d) For mill circuits not equipped with grit separators, a higher sweep will
increase circulating loads by coarsening the dynamic separator feed. Production
may decrease as a result, if the mill circuit is already over loaded. In many mill
systems featuring highly air swept mills, the sweep air and material goes from
the mill to a static separator. The rejects from the static separator is transported
by the mill system bucket elevator to the separator where further classification
takes place. The fines are swept to the mill baghouse which discharges to the
finished product stream and, thus, to the pump. With a grit separator, the
dynamic separator feed will be coarser, corrective action, such as adding more
blades to a Sturtevant will be required. If the circuit has a conventional
separator, then adding a grit separator will globally improve the 325 mesh.
Production will rise.
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In a extreme case. Demopolis added very large mill sweep fans and grit
separators. Production rose about 12%, from 66 stph to 74 stph. The static grit
separator accounted for up to 60% of the circuit's total production.
In Exshaw, they went economical by installing an extremely large dropout
box, (a poor man's static separator). Production rose by an estimated 5%.
Generally speaking increasing the air sweep on a mill equipped with a
static separator will cause higher fan power consumption but due to the higher
net tonnage the overall kWh / ton should drop. To avoid excessively large fans,
one should consider larger center screens on the partition and discharge (e.g..
Slegten design) and modifying the feed chute and trunnions to allow more air
through. Unfortunately most mills in Lafarge, North America have trunnions
which were not designed for high sweeps and therefore are limited, (except
Aerofall mills).
Mill sweeps are generally quoted as velocity above the charge which is the
measured mill sweep duct flow (Nm3/s) divided by the cross sectional area
above the charge. The general rule of thumb is that mill sweep must be above 0.5
m/s. The target every tries (or designs) for is 1 m/s. Here are examples of what
we would consider as well swept finish mills:
As of 1993 the following Lafarge Corp. finish mills have static grit separators on
the mill sweep:
Alpena FM 19, 20, 21
Balcones FM 1, 2
Exshaw FM2 (dropout box only)
Fredonia (Nordberg)
The schematic below shows how static separators on mill sweep are typically
installed.
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What the graph says is that no matter what kind of volume loading of
grinding media you use, the void spaces must be filled between 60% and 110% to
maximize grinding. (The peak looks about 80 to 85%.)
At low material filling ratios there is a reduced number of ball-to-material
contacts, due simply to an absence of material in the nip points, therefore
breakage rates are reduced. Also the dynamics of breakage are modified as the
breakage occurring is preferential on the fine material, resulting in overgrinding
of the fines. At the same time, the coarser particles may migrate into the emptier
voids. This explains the tendency observed by some plants of low 325 mesh
coupled with high blaines when a mill is under fed severely.
Figure 3A.5.2a
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Steel to clinker ratio of 8 roughly corresponds to material filling ratios of 1.1 and
a steel to clinker ratio of 12 corresponds to a filling ratio of 0.6. Bypass occurs
when the steel to clinker ratio is less than 7 and the mill is badly underfed with
steel to clinker ratios greater than 12. The problems with using the steel to
clinker ratio are:
a) poor accuracy - test is subject to big errors.
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b) it's an average - it can't tell you if you've got a problem in one or the other
compartment, or both.
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Item [2] relates to raw mix chemistry. Items [1] & [3] relates to overburning.
Large alites means over burnt clinker thus it's harder to grind. Clinker with a lot
of pores are easier to crush. Some (not all) plants can monitor their grindability
by watch the clinker literweights. As it rises, the clinker becomes over burnt;
sometimes balls up into bigger pieces; and sometimes it gets very dense (no
pores). Good literweights are usually between 1250 and 1350. Watch out if gets
above 1400. Note that some plants make a very fine yet seemingly hard to grind
clinker. The researchers have observed that a high proportion of big alite crystals
can be found in the fine sizes, in these cases.
On the other hand for fine grinding (> 3,000 blaine), the main factors
become:
1) alite size, as before
2) C2S content , as before
3) grinding aid
As the cement particle gets smaller the pores disappear and no longer become a
factor. Increasing the amount of grinding aid will make the cement easier to
grind.
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3B: Grinding Media
3B.1 Ball Types and Wear Rates
There are two major types of grinding media (balls) used in North
America. Generically they are called "forged steel" and "high chrome". To clarify
some metallurgical terms you should know about:
Steel: Iron based with alloying elements, but has a carbon content of less
than 1% (usually)
Cast Iron: The difference between steel and cast iron is that the carbon content
is greater than 2%
Rc Hardness: One of many hardness tests, this is very common in North
America. Stands for Rockwell C test. The hardest know steel
reaches 65 Rc.
Martensite: It a name for a steel's microstructure. It's the hardest (and most
brittle) form of steel and is made by rapid quenching (with the right
alloys present).
Austenite: Another steel microstructure. It means that all of the alloying
elements exist homogeneously (stays mixed). None of them have
precipitated out in another form. Common in 300 series stainless
steels.
Grain Size: For abrasion resistance the best kind is a fine grain size metal. The
larger grains almost always do not perform as well. Fine grains can
be achieved by heat treating then rapid cooling.
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The mill liners are usually slightly softer than the grinding media, so they
do not crack from constant impact, Rc of 50 - 58. As a rule of thumb, the center
hardness should be greater than your liner hardness.
WARNING: suppliers make forged steel balls for SAG mills in mining which are
very large diameter. In this case, they make a soft center ball on purpose, to
make the ball less brittle so it doesn't split. This type is not recommended, unless
you have a large diameter mill. If you're not sure then consult with the supplier -
they can tell you (almost all of our mills are not in what they consider to be the
large diameter class). If you don't specify the type of forged balls, the supplier
may send you some "high impact" media with soft centers since they're more
likely to stock this grade.
Forged steel media is generally economical in wet slurry mills, or where the
material is extremely hard such as pure quartz sand or soft coals.
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higher chrome content, which makes more carbide, but softens the surrounding
steel. Average hardness is about 60 Rc. This grade is sold for first compartment
balls where there's more cataracting taking place. The slightly softer metal,
keeps it from splitting but the extra carbide makes up for the wear. The latter has
less chrome, but average hardness is 64 Rc, which is ideal for second
compartment attrition effects.
However recent studies and plant experiences suggest that for very
abrasive materials (more commonly experienced in the mining industry) there
will be a smaller to no difference in wear rates between the two types. Wear
rates will vary from plant to plant and given the traditionally higher cost of
chrome media, some experimenting is recommended before switching from one
type to another.
In general, it is not good practice to mix forged and cast balls, or to mix
balls of differing metallurgy. Harder balls will cause softer balls to wear more
rapidly than is usually expected and causes the overall charge gradation to
deteriorate.
Ball destruction, that is, deformation, splitting, or spalling, can occur as a
result of a number of factors. Most ball problems occur as a result of metallurgy
and/or heat treating problems. If you suspect this there are numerous
independent labs that can test ball samples.
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5. Mill Overloading.
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breakage rate is optimized at a certain size particle depending on the ball size,
material characteristics, mill diameter, mill RPM and lining design. As we as
plant operators don't change mill geometry, speed or material characteristics, we
are left with ball size selection and lining types.
Researchers, like J. P. Bombled, have performed testing on a specific
clinker to find the optimum ball size based on the size of the clinker particles
present to be ground at a particular spot in the mill. His laboratory results are
summarized as follows:
What this data says is that for a given size of material to be ground there is
an optimum ball size for a given material and mill characteristics. This ball size
decreases with the particle sizes to be ground.
The reasons for the optimum are as follows. If the balls are too small then
they don't have the inertia to properly nip the material and break it. For
example; grits (or spitzers) in the second compartment, the cascading small balls
don't hit with enough force to fracture the grains so they are worn smooth at a
slow rate and retained in the mill, causing material transport problems.
If the balls are bigger than the optimum for the feed size then the lower
number of contact (nip) points reduces the specific breakage rate. Note that if a
particle size is smaller than either the optimum for both the smaller or larger ball
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the specific breakage rate of the smaller ball is superior, this is why finer balls in
the second compartment work well.
All balls must be bigger than the optimum, (for example, according to
Bombled, a 1/4" ball would optimum for 45 µm particles. As these balls wouldn't
stay in the mill, this size is obviously impractical.) Generally, the inefficiency of a
small ball isn't as bad as a larger one on that size particle.
Therefore we design ball charges, trying to match size to size and taking
into account the good and bad aspects of the mill and circuit as it's designed.
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average ball weights be sure that you are using the same data otherwise you will
get misleading results. All average ball weights given in the handbook are
calculated using the following table:
In North America, average ball weights for the first compartment varies
considerably from 1.3 kg/ball to 1.7 kg/ball, (with a few exceptions) and averages
at about 1.5 kg/ball. In general, plants with soft clinkers use a smaller average
ball weight and plants with harder clinkers use a larger one. Ciment Lafarge
says that mills with adjustable partitions can use a coarser first compt. ball
charge and their average ball weights vary between 1.85 and 2.3 kg/ball.
Moreover recognize that reducing the average ball weight tightens the ball
charge and increases the mill's tendency to overfill and backspill. For example
one plant had a 1st compt. avg. ball weight of 1.31 kg/ball and increased it
progressively to 1.58 kg/ball to reduce backspillage.
However to be technically correct we had said earlier that flow resistance
in the mill is due to the total steel surface area, including the ball charge. The
concept of average ball weight is easy to understand appropriate in the first
compartment where we are more concerned with the ability to crush. In the fine
grinding second compartment, the surface area is more important to know.
Recognize that for the same average ball weight one can have slightly different
steel areas. Therefore, in terms of permeability and grinding rate in the second
compartment, it is better to use the avg. area per ton of ball mixture, (m2/mt mix
or ft2/st mix). No average Lafarge Corp. values will be shown since there's such
a wide range of different mill circuit designs used.
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In this case, the charge porosity is the only corrective action possible to
adjust the material level in the whole mill and the mill throughput. Therefore the
right porosity is critical in mills with this type of partition.
Maximum Production
The maximum production of a mill will occur at up to 40% volume loading,
depending on the given mill's drive power, trunnion design and partition design.
This is shown on the following graph from Austin's Process Engineering...Ball
Milling.
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Here this research indicates that for optimal specific grinding energy, a volume
loading of 26% should be used.
However, there are other considerations one must take into account.
Firstly, liner wear is accelerated at low volume loads. Secondly, the capital costs
are increased because for a given mill power a larger (longer) mill will be used to
produce the same output. To build mills running at 20-25% volume loads would
mean very large mills for the power they consume and the cement they produce.
In a given mill system the production will drop if the volume load is reduced.
Conclusions
Therefore if power is cheap, as it has been, up until recently in the North
America, then a small, low cost mill with high volume loads is traditionally used
to obtain maximum production, but at poor specific grinding energies. In
Europe, where power is expensive, the mills are larger, higher cost units running
with reduced volume loads and better specific power consumptions.
The conclusion is that a mill should be run with the minimum charge
(over 26%) that will allow production targets to be met, if power costs are a
factor. At reduced capacity due to market down turns, some plants have taken
advantage of this. If maximum production is the target, load the mill to the
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maximum allowable (below 40%) by power available and trunnion and partition
designs.
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b) The traditional design also has much more 2.5" diameter balls than the
Lafarge design. Therefore one can expect the traditional design to choke itself off
faster as the balls wear. This may be one of the reasons why the traditional
design is coarser to begin with.
c) The Lafarge design will likely give a longer useful charge life and a more
effective and uniform grinding performance over that life.
Here are some starting designs using the method preferred by Lafarge.
Table D: 1st Compt Starting Ball Charge Designs
(%'s are by weight)
Avg. Ball Wt. 3.5" 3.0" 2.5"
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These are rules of thumbs based on the collective experience of many plants.
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1.5" Ø = 8% by weight
1.25" Ø = 32%
1.0" Ø = 35%
0.75" Ø = 25%
Figure 3B.4
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Many references are made to these models when designing a ball charge. The
actual equations are tedious and laborious to calculate and therefore are not
discussed here, (see Volume 3). To recap, the sizing of the charge in the second
compartment is determined by:
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1.5" 7%
1.25" 8%
1.0" 21%
0.75" 49%
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