ESEO-CHEERE ACADERIW Chemistry Coacking for XI, XIl, lIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit 6. Why {s geometrical isomerism not possible in tetrahedral complexes having two different types of unidentate ligands coordinated with the central metal ion ? Ans. Tetrahedral complexes do not show geometrical isomerism because the relative positions of the unidentate ligands attached to the central metal atom are the same with respect to each other. Draw structures of geometrical isomers of [Fe(NH,),(CN),1- 7 - : Ans, NC. SNH nc. NHs oy aC Sic NC ‘CN Neale cn nus cls trans AQ 8. Out of the following two coordination entities, which is chiral. (optically active)? (@) cis{CrCl{ox),!* (b) trans-ICrCl,(ox),- = re Ans, The two entities are represented as @ eis {CrCl,ox) Nb 9, Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isome: Ww (a) K[cr(H,0),(C,0, Ay HLOLE.O0 C () [Cofen),ICl, (6) ICo(NHH,),(NO,)(NO,), \. (@ tH J07,0)C1,) Ans, (a) Both geometrical (cis-, trans) and optical isomers for cis can exist. (©) Two optical isomers'can exist. (©) There are 10 possible isomers, (Hint: There are geometrical, ionization and linkage isomers possible). (@) Geometrical (cis-,,trans-) isomers can exist. 10, Give eviderice that [Co(NH,),CIISO, and \u..-", © ICI are ionization isomers, ans. The ae dissolve in water to yield different ions and tinue rect differently to (Co(NH,),BrISO, + Ba? (Co(NH,),SO,JBr + Ba? (CotNH,),BriSO, + Agt [CofNH,),S0,IBr + Ag* — Bas0,(s) — No reaction — No reaction — AgBr(s) 11, The spin only magnetic moment of > Scepter iene of [MaBr,* is 5.9 BM. Predict the geometry of the Ans. ne‘ (n(n+2) BM =5.9BM, ..n=5 ADD- 54, HAN! c JUMAN NAGAR) CHANKYA PURI (NEAR RUSPANJALT BUILDING) AGRA, Pha = 9412425629ESEO-CEEENE AC ADEXVIWY Chemistry Coaching for XI, Xil, IIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr, Mohit Dixit 12. Explain on the basis of valence bond theory that [Ni(CN),] ion with square planar stmcture is diamagnetic and the (NiCl,] ion with tetrahedral geometry is paramag- netic. Ans, In INi(CN),}?-, CN- is a ‘strong ligand and as it approaches the metal ion, it causes the Pairing up of the two unpaired 3d electrons. It thus involves dsp? hybridization and has Square planar structure. Due to the absence of unpaired electrons, it is diamagnetic. In INICL?, Clr ts a weak ligand and is therefore unable to Pair up the two unpaired 34 electrons. It thus involves sp* hybridization and has tetrahedral geometry, Due to the pres- ence of unpaired electrons, it is Paramagnetic, ‘Ae 13, mol 4s paramagnetic while (Ni(CO),] is diamagnetic though both are tetrahedral, ay : Ans. In INi(CO),], Mi is in zero oxidation state whereas in (Nicl,*, it-is in-+2 oxidation state. In the presence of CO ligand, the unpaired a electrons of Ni pair up bitt CI being a weak ligand is unable topair up the unpaired electrons. at Cc 14, Irete,0} is strongly paramagnetic whereas [Fe(CN),|* is weakly paramagnetic. Explain. AVN) Ans.In presence of CN- (a strong ligand), the 3d electrons pair up leaving only one unpaired clectron. The hybridization is ¢sp* forming inner orbital complex. In the presence of H,0, (a weak ligand), 3d electrons do not pair up»The hybridization is spd? forming an outer orbital complex containing five unpaired electrons, it is strongly paramagnetic, 15. Explain [Co(NH,),J* is an inniér-érbital complex whereas INi(QNE,),]"* is an outer or- bital complex.] RAQ RY 3 Ans. In the presence of NH,, the 3d/electroris pair up leaving two d orbitals empty to be involved in @sp* hybridization forming inner orbital complex in case of [Co(NH,),*. In INIQVH,),)”*, NI is in™42axidalion state and has ° configuration, the hybridization in- Volved is spd? forming outer-orbital complex. 16. Predict the number of,unpaired electrons in the square planar [Pt(CN),]* ion. Ans. For-square planar shape, the hybridization is dsp®. Hence the unpaired electrons in 5d orbital pair up,tomake one d orbital empty for dsp? hybridization Thus there is no unpaired electron; \\’) 17. The hexaaquo manganese(I1) ion contains five unpaired electrons, while the hexacyanido-ion contains only one unpaired electron. Explain using Crystal Field Theory. Ans, Hexaquomanganese(ll) ion is a tetrahedral complex. HO is a weak field ligand and causes only small splitting of d orbitals. Consequently, the orbital splitting energy is not suff ciently large to force pairing of electrons in Mnill) which has e,2t,,° configuration and thus hexaaquomanganese(il) Jon contains five unpaired electrons, On the other hand, hexacyanidomanganese(ll) fon is an octahedral complex with CN- ligand which is a strong field ligand. In this case, Mn) has &,5e,° configuration and thus contains only one unpaired electron. 18. Calculate the overall complex dissociation equilibrium constant for the Cu(NH,),2* ion, given that’, for this complex is 2.1 x,1013, Ans, The overall dissociation constant 1s the reciprocal of overall stability constant, te, 1/B, = 4.7 x 1074, ADD- 54, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANJAL/ BUILDING) AGRA. Ph : - 9412425629EE EQ-CEEDE ACA DEYIYV Chemistry Coaching for XI, Xl, IIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit NCERT Exercises 19 _ Explain the bonding in coordination compounds in terms of Wemer’s postulates. Sol. See Copy 20. FeSO solution mixcid with (NH)2SO, solution in 1:1 molarratio gives the test of Fe"* ion but CuSO, solution mixed with aqueous ammonia in 1:4 molar ratia does not give the test of Cu2* ion. Explain why? Sol. FeSO, solution mixed with (NH,),S0, solution in 1:1 molar ratio forms a double salt, FeSO, (NH,),S0,.6H,0 (Mohe's salt) which ionizes in the solution to give Fe ions. Hence, it gives the tests of Fe?* ions. “> CuSO, solution mixed with aqueous ammonia in 1:4 molat ratio forms a complex with formula [Cu(NH,),]SO,. The complexion, [Cu(NH,),}* does not ionize further to give Cu?*ions. Hence, it does not give the tests of Cu* ion, BS 21 Explain with two examples each of the following: coordination entity, ligand, coordination number, coordination polyhedron, homolepticand heteroleptic. Sol. See Copy AK 22 Whatis meant by unidentate, didentate and ambidentate ligands? Give two examples foreach. Sol. See Copy So 23 Specify the oxidation numbers of the metil (2) [Co(CN)(H,0)(en),P* orc (@ICrC1(NH,),] (@)[CoBr,(en),)") ()K,lFe(CN)J. Sol. (@)+3, (©) +2,(6) +3, (4) 43 (€) 43 NS 24 Using TUPAC norms write the formiilaé for the following: (a) Tetrahydroxozincate (I). ~». )>_ &) Hexaammine cobalt (II) sulphate (© Potassiumtetrachloridopalladate (1) (4 Potassium tri(oxalato)cheorrne aD (©) Diamminedichloridoplatinuim (1) (9 Hexaammineplatinum (IV) @ Potassium tetracyanidonickelate(I1) _(h) Tetrabromidocuprate (I) () Pentaamminenitrito-O-cobalt (II) () Pentaamniinenitrito-N-cobalt(II). Sol. (a) [Zn(OH),F> ) [CoWH),L(50), (© KyfPac,] @ KICKC,O),] © [PtCL(NH,),} © [PtNH,),J* @ KINICN),] (ht) [CuBr,)- @ ICo(NH,)(ONO)P* ~ G) {Co(NH,),(ONO)P* 25 Using TUPAC norms write the systematic names of the following the following coordination entities: } ” @ ICoNH,JCL,/ ©) [CoCUNO,)INE,) ICI (0) INiENEL),JC1 @trcuneeertave scr () IMn(ti,o),"* ** © [Colen),}* * @ (riGi,0))" y INCL ® INiCO},) Sol. (a) Hexaamminecobalt(l) chloride (b) Tetraamminechloridonitrito-N-cobal, (I) chloride (©) Hexaamminenickel(II) chloride (d) Diamminechlorido(methylamine)platinum (ID) chloride (© Hexaaquamanganese(II)ion () Tris(ethylenediamine) cobalt (111) ion (@)Hexaaquatitanium (I) ion _(h) Tetrachloridonickelate (1) ion ) Tetracarbonylnickel (0) 26 _Listvarious types of isomerism possible for coordination compounds, aL See Copy How many geometrical isomers are possiblein the following coordination entities? (@) [Cr(C,0,) (b) [Co(NH,)3Cls] @) Nil (&) Two (fac and mer) giving an example of each. ADD= 54, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANJALI BUILDING) AGRA, Ph i - 9012425629iz 7 IBEO-CHEEYE ACADENIY Chemistry Coaching for XI, Xil, IIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit 27 Draw the structures of optical isomers of : (a) [Cr(ox),}* (b) [PtCl,(en),¥* (c) [CrCl(en)(NH,),]* ° : ° Ny 3+ 3. ot os a 1% Ne=0 | CSc" s J i ' 9 oe anon ea | oO] oF Sol. < i oe a 7e—07 |, ! oJ ro—e, 2 Nee i pe fi 0 i \ es HC ' Hoc ciel 2 | A © Pecaee | oe tee | Hae, | 28 Sol. en 4a) NS? or, c a 4 “Ofte omar eis ata Trans -{CoClo(en) 1 [ } a + NHs|* } [i 4 i pray in i en Si i i Jou ae i HN cl ni Hg en ae 7 Ce \ ‘NH, , 3 as tsomer ‘Trans -isomer ADD: St, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANJALT BUILDING) AGRA. Ph : - 9412425629 RENNIE T EE renee———aS 1O-CHERE ACADERIY Chemistry Coaching for XI, XM, NT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mobit Dixit 29 30 Sol. 31 Sol 32 Sol. 33 Sol NH t CHg en t Hs | HgN- 1 Cl \ ! KF ~ i : 6 iY i S 4] } ‘C1 HyNG] Nis én lean ts tsomner d (+). Cts -fsomer t-) Trans -isomer Write all the geometrical isomers of [Pt(NH,)(B:\(CD\py)] and how many of these will exhibit optical isomers? Three isomers are possible as follows : HN: Isomers of this type do not show optical isomerism. Optical isomerism rarely occurs in square planar or tetrahedral complexes and that too: ‘when they contain unsymmetrical: chelating ligand. Aqueous copper sulphate solution (blue in cole Potassium fluoride, and (b) a bright green solition with aqueous potassium chloride. Explain these experimental resillts. VW AS CuSO, +4KCI—> K, [CuCl]. ¢K}S0} (green solution) Itis due to formation of complex compound that we get green solution. ‘Whatis the coordination entity Forined when excess of aqueous KCN is added to an aqueous solution of copper suilphate 2. Why is it that no precipitate of copper sulphide is obtained when H,S(g) is passed through this solution ? Potassium tetracyaniddcuparate (I) is formed when excess of aqueous KCN is added to an aqueous solution of cooper sulphate. CuSO} £4KCN —> [cuCN,] + Ko, sulphlte, Gyanide™ tetsRyanidocuparate ay POSSE, When H,S(g)\is passed through this solution, no precipitate of copper sulphide is obtained since potassium tetracyanidocuparate() on dissociation gives K* ions and [Cu(CN),F* ions Which donot react with S* ions to form copper sulphide. Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory: (a) [Fe(CN),]* (b) [FeF J (@)[Co(C,0,),F* (d) {CoF,-. Ton/ Central. Configura ion Hybridization Geometyof No.of Mi lex _Metal ion _of metal ma i n__ofmetalion _ thecomplex electrons behaviour “"TRe(CN) IF Fe ds sp octahedral." 0 —_Diammagnetic [Fer J Fe a sp'd® octahedral = 5 ~—_Paramagnetic [Co(C,0,),}*' Co as @sp> octahedral 0 Diamagnetic (CoF,}* Co a spd? octahedral 4 __Paramagnetic Draw figure to show splitting of degenerated orbitals in an octahedral crystal field. See Copy . ‘ADD- 54, HANUMAN NAGAR, CHANKYA PURI'(NEAR PUSPANJALI BUILDING) AGRA. Ph : - 9412425629ail ESEQ-CEREEWE ACAD EZYEW Chemistry ching for II, IIT/ AIEEE/ CBSE/ Medical Entrance Exam '. Mohit Dixit 34 What is spectrochemical series? Explain the difference between aweak field ligand and ‘strong field ligand, sinter ias Sol. The arrangement of ligands in order of their increasing field strength creasing. ang ig field strengths, i,,.increasing crystal field splitting energy (CFSE) values is called spectrochemical series, a The ligands with small value of CFSE are called weak field ligands while those with large val Of CFSE are called strong field ligands, Ade 35. What is crystal field splitting energy? How does the magnitude of A, decide the actual Configuration of d orbitals ina coordination entity? Sol. When ligands. approach a transition metal ion, the d-orbitals ‘Split into two sets, one with lower crete the other with higher energy. The difference of energy between tre twa sels of orbitalsis called crystal field splitting energy (dy for octahectral field), , fAo

P, the 4th electron pairs up in one of the tog orbitals giving the configuration ff, e? thereby forming low spin complexes. oy) : 36 [CH(NH;)¢)* is paramagnetic while [Ni(CN),]-is diamagnetic. Explain why? Sol In [Ce(NH)<)*, central metal ion Cr>* with electronic configtiration [Ar] 342 undergoes d’sp3 Tn [Ni(CN),}, central metal ion Ni? hybridization. CN-being a strong field d ligand leads to pairing up of electrons in d-subshell. The four pairs of electrons from four CN“ ions.occupy the four dép? hybridized orbitals: Due va absence of unpaired electrons, [Ni(CN),|*is diamagnetic. 37 Asolution of [Ni(t1,0),]"*is green buta solution of [Ni(CN),]™is colourless. Explain. Sol. In [Ni(H,0),]**, Ni is in +2 state with the configuration 348, ie,, it has two unpaired electrons which do not pair up in the presence of the weak field H,O ligand. Hence, itis coloured. The d 4d transition absorbs red lightand the complementary light emitted is green. In IN(CN),I*, Ni is again'in 42 state with the configuration 3¢® but in presencé of the strong field CN" ligand, the two unpaired electrons in the 3d orbitals pair up. Due to absence of unpaired electrons, it is colourless. 38 UFe(CN)ql* anid [Fe(H1;0),I* are of different colours in dilute solutions. Why? Sol. Inboth the complexes, Feis in +2state with 3¢*configuration, ie, ithas four unpaired electrons. In presence of the weak H,O ligand, they don’t pair up. In presence of strong C's ligand, they Pair up leavirg-no unpaired electron. Because of the difference in the number of unpaired electrons, they have different colours. 39 Discuss the nature of bonding in metal carbonyls. Sol See Copy : ip 49 Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complexes: (2) KslCo(C200)3]_(b) (NHgxfCoF]__(©)_cis-{Cr(en)2Cl,IC1_ (4) IMn(3,0),150, Sol. Complex Cooidination No. ‘orbital occupation (a) Ks*ICo(C,0,)3)* 6 (as CO? is didentate) Co =3d5= HS, €? (b) (NH)3*CoF,. xe | 4 Cot = 3d =f, © cis-[Crlen)CL)* Cr x+0-2= 41,4243 6 (enis didentate) CH 230 = By AIMNHZO) PSO? x4+0=42, 2542 ‘ 6 Mn? =30= #3, ef ‘ADD: 54, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANJALI BUILDING) AGRA, Pk : - 9412425629= EEEO-CHERE ACADERIYV Chemistry Coaching for XI, XII, IIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit 41 Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration and coordination number. Also give stereochemistry and magnetic moment of the complex: (@) K[CrH,0),(C,0,)213H,0 (b) CrCly(pyly (© KMn(CN). @ [Co(NH))sCLICh (©) CsfFeChd @) Potassium diaquadioxalatochromate (Ill) hydrate. Coordination no. = 6. Shape : octahedral Oxidation state of Cr: x +0 +2 (-2) s-1x=43 BC. of Cr+ =30 = £3, €2 . Unpaired electrons (n) =3. ‘Magnetic moment (u) = /n(i+2) = V3x5 = V15 BM =3.87B @) Trichloridotripyridinechromium (IID) : - Coordination no. of Cr = 6. Shape : octahedral Oxidation state of Cr: x-3 +0=0,x=43 EC. of Cr = 30? = 8, 0, n=3,1=3.87BM (© Potassium hexacyanidomanganate (II) Coordination no, of Mn = 6, Shape : octahedral. Oxidation state of Mn :x-6=~4,x=42 © E.C. of Mn* = 3d5 = #3, 9 ,.n=1,1= Sol. Coordination no. of Co = 6, Shap Oxidation state of Co: x +0. (©) Caesium tetrachloridoferrate, Coordination no. of Fe =4, Shape : tetrahedral Oxidation state of Fe 2242-1 or x= 43 EC. of Fe = 305 = 21%, 125; \5ETD = 5 =5.92BM. 42 Whatis meant by stability of a coordination compound in solution? State the factors which govem stability of complexes. Sol. See Copy _ 43 What is meant Sol: see Copy \Y 4 Discuss briefly the role of coordination compounds in: (a) biological systeins, (b) analytical chemistry, (c) medicinal chemistry, and (4) extraction/metallurgy of metals. Sol. ReferText. 45 How many ions are produced from the complex Co(NH,),Cl, in solution? @ 6 © 4 3 (@ 2 Sol. Ans. (0). Coordination number of cobalt =6. Hence, the complex is [Co(NH,),ICly. It ionizes in the solution as : [Co(NH,),ICh, _*2_ [Co(NH,),)°* + 2Cr-. Thus, three fons are produced. 46 Amongst the following ions which one has the highest magnetic moment value? G@) [CHRO ——(b) EFe(H:O)6* (©) [ZnH,0),F* Sol. Ans.(b). The oxidation states are: Cr(IIN), Fe(I) and Zn(I0). by:the chelate effect? Give an example. ADD='54, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANIALI BUILDING) AGRA, Phir 9012025629] : EE EQ?-CEEELEWE ACADENREIYV 47 Sol. 48 Sol. 49 Chemistry Coaching for XI, XII, lIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit a A Rata A lahat aetna tants CS Metal ion Electronic configuration No. of unpaired electrons Gm 303 3 Fe 3d6 4 Zn 3qi0 0 = Jn(n+2) . Hence (b) has highest magnetic moment. The oxidation number of cobalt in K[Co(CO),]is @ +1 ©) +3 © -1 @ -3 Ans. (0). Amongst the following, the most stable complex is G@) UFeCO)I —() [Fe(NHSI* (© FFe(C,00P-( «(A ecg Ans. (0). Feis in +3 state in each of the given complex. As C,0/-is didentate chel 3g ligand, it forms chelate rings and hence is the most stable complex. What will be the correct order for the wavelengths of absorption in the visible region for the following: INi(NO2)¢]*, [Ni(NHs)¢I**, [Ni(H,0),)* As metal ion is same, the increasing field strengths (CFSE values) of the ligands as per the spectrochemical series are in the order: “FO, P. Electronic configuration of Co™ is t',¢%, it has no unpaired electron and is diamagnetic. This is because for tettahiedral complexes, CFSE is lower than pairing energy. See Copy-C > O Both ‘haveFe*! \(3d°) configuration. Hybridisation is sp°d”. (Ans- 1.73 BM) The differencé is due to the presence of weak and strong ligands, If ligand is strong (high CFSE), electron in d-subshell pair up and magnetic moment will be low. If ligand is weak (low CFSE), electrons will not pair up. Number of unpaired is more and magnetic moment will be high, e.g., [CoF¢]* and [Co(NH;),] both are octahedral but former is paramagnetic while the latter is diamagnetic. H,O is weak ligand. Electron do not -pair up. In CuSO,.5H,0, 4120 molecules are present as ligand in coordination sphere whereas one water molecule is present in crystal lattice. Crystal filled splitting occurs and hence d-d transition occurs which gives it blue color. In anhydrous CuSO,, there are no HO molecules present as ligand. No crystal field splitting occurs and hence it is colorless. ‘ADD- 54, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANJALI BUILDING) AGRA. Ph : - 9412425629ERIO-CHEEYE ACADEXIWY Chemistry Coaching for XI, Xil, lIT/ AIEEE/ CBSE/ Medical Entrance Exam By: Dr. Mohit Dixit TOPIC-COORDINATION COMPOUNDS NCERT Text Questions 1. On the basis of the following observations made with aqueous solutions, secondary valences to metals in the following compounds: Formula ‘Moles of AgCl precipitated per mole of the compounds with excess AgNO, G@) Pacl,.4NH, 2 a (Gi) NiCL,.6H,O 2 7 (iii) PtC1,.2HC1 ° (iv) CoCl,.4NH, 1 ~ (v) PtCl,.2NH,, ° 5 Ans.(t) Secondary 4 (ti) Secondary 6 (iil) Secondary 6 (iv) Secondary 6” (v) Secondary 4 2. Write the formulae for the following coordination compounds: () Tetraammineaquachloridocobaltilil) chloride -\. (©) Potasstum tetrahydroxozincatettl) ct) (6) Potassium trioxalatoaluminate(tII) (4) Dichloridobis(ethane-1,2-diamine)cobalt() \.\ (©) Tetracarbonyinickel(0) = Ans.(a) [Co(NH,),(H,0)CIC1,, >, (b) K{Zn(0H),) (©) K,JAUC,0,)51 \. @[Cocl,len)I* X (©) INiCO),] Ww ‘ S. Write the TUPAC names of-the foliowing coordination compounds: fa) [Pt(VH,),ClINO,)] W (b) KylOr(C,0,)3] (©) CoCl,(en),ICl (@ICOWH,(COJICI —_(e) HglCofSCN),] Ans.(a)_ Diamminechloridonitrito-N-platinum(t) {b) Potassium trioxalatochromate(Itl) {c) Dichloridobis(éthane?1.2-diamine)cobalt{II) chloride (a) Pentaamminecarbonatocobalt(IIN) chloride (e) Mercury tetrathtocyanatocobaltate({Il) 4. Write the formulae for the following coordination compounds: (a) Tetraamminediaquacobaltiiil) chloride (©) Potassium tetracyanidonickelate(!!) {c) Tris(ethane-1,2-diamine)chromium(t!!) chloride {¢) Amminebromidochloridonitrito-N-platinate(I1) (e) Dichloridobis(ethane- 1,2-diamine)platinum(IV) nitrate () trontiit) hexacyanidoferrate(I) Ans.(a) (CotNH,),(11,0)}Cls (W)KINUCN),) (0) [Cr(en) IC), (4) [PUNH,JBrCliNO,) (e)IPtCI,(en}I(NOg)y (9 Fe,lFe(CN)gl, 5. Write the IUPAC names of the following coordination compoun (a) (Co(NH,) ICl, (b) [Co(NVH,),CNCL, (0) KgIFe(CNgl - (d) K{Fe(C,0,)3) (e) K, {Pach} {0 (PUNH,),CIINHCHg)ICI Ans.(a) Hexaamminecobalt(III) chloride (b) Pentaamminechloridocobalt(t1!) chloride (0) Potassium hexacyantdoferrate(|Il) (@) Potassium trioxalatoferrate(II1) (e) Potassium tetrachloridopalladate(tt) () Diamminechlorido(methylamine)platinum(t) chloride ‘ADD- 54, HANUMAN NAGAR, CHANKYA PURI (NEAR PUSPANJALI BUILDING) AGRA, Ph : - 9412425629 Z = J