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LAS Week 4-6
LAS Week 4-6
08/12/2021
P1° – P1 = ∆P
∆Tb ∞ m ∆Tf ∞ m Π∞M
= x²P1°
Nonelectrolyte liquids have higher boiling point than electrolyte solution. For every
mole that dissolves, equal ions will be added to the mix. Electrolytes have a dissociation
property when dissolved in water. Depression of the freezing point.
Aqueous Solution = 1.00m ∆Tb = Kbm Tb = Tb° + ∆Tb
Kb = (°C/m) of H2O = 0.52°C/m ∆Tb = (0.52°C/m)(1.0m) Tb = 104.42°C + 0.52°C
∆Tb = 0.52°C Tb = 104.94°C
When the temperature drops, ∆E < 0 is used, and when the temperature rises, ∆E > 0 is used.
We can have ∆E < 0 and ∆E > 0 when the temperature remains constant.
The mechanism depicted in Diagram A is closed, so heat cannot escape. The temperature
rises as the system loses heat to the outside. Expected to fall In the opposite direction, this
implies that the mechanism. Heat cannot be released as shown in Diagram B.