300 DE THI THU THPTQG 2022 (GIAI CHI TIET) S86 GIAO DUC VA DAO TAO Ki THI TOT NGHIEP THPT NAM 2022 LAN 2 HA TINH Bai thi: KHOA HQC TU NHIEN; Mén thi thanh phan: HOA HQC Thoi gian lem bai: 50 phuit khong ké thai gian phat dé Ho va tén thi sinh. bao danh Ma dé: 201 * Cho nguyén tit khdi ctia cdc b N=14; P =31; Na = 23; Mg i * Céic thé tich Khi déu do 6 diéu kigh sac dn; gid thet cde Kil sinh ra 1 khong tan trong mabe. DE THI GOM 40 CAU (TUCAU-DEN CAU 40) DANH CHO TAT CA THI SINH (Cau 1: Etyl propionat I este c6 mii thom etches Ang thie eta etyl propionat la A. HCOOGHs. B. C3HsCOOC2HY C. CHsCOOCH:. D. CHsCOOCHs. Cu 2: Ion kim loai nao sau day c6 tinh oxi hoa Yiyatihh AL Mg. B. Fe". pt : D. Cur. Céu 3: Cong tite eiia axit oleic 1a A. CriHs;COOH. B. CoHsCOOH. Oe : D. CHyCOOH. (Cfu 4: Phin tir xenlulozo duge tgo nén tir nhidu gde{, S) A. a fructozo. B.a~ glucozo. " . D.a— fructozo. (Cfiu 5: Kim logi nao sau day din dign tét nat? AAg. B. Au. D.Al CAu 6: Kim loai Fe khéng phan img véi dung dich nio See A. CuSOs. B. Zn(NO)3. " . D. Fex(SO4)3. CA 7: Chat nao sau day 1d ding phan ciia glucozo? A, Fructozo. B. Xenlulozo. D. Mantozo. C4u 8: Géc glucozo va géc fructozo trong phan tir saccarozo 1 e i nhau qua nguyén tir A. oxi. B. nito. i D. cacbon, (C4u 9: Amin nao sau day 1a amin bac 2? o~ A. CoH:NEb. B. CoHsNH2. . bs D. (CH):NH. CAu 10: Amino axit HNCH2COOH c6 tén goi la AL lysis B. alanin, C. glyxiit. D. valin, Céu Li: S6 lign két peptit trong phan tir Gly ~ Ala ~ Ala ~ Gly (mach hb) I AL2 B.1 C4 CL D.3 Cfu 12: Loai to nao sau day duge san xuat tir xenlulozo? é A. to visco. B. to nilon ~ 6,6. C.to tim, 7 D. to capron Cu 13: Polime no sau day thude logi poliamit? rs A. Tinh bot. B. Nilon ~ 6,6. C. Polietilen, +> >) D. Poli (vinyl clorau) Céiu 14: Chat nao sau day 1a chat dién li yeu? Ca A. NaCl B. HCI. CH3COOH. D. KOH (Céu 15: Cong thite chung cita este no, don chite, mach hé li A.C\H,,,0,(n23) BB. C\H,,..0, (n= 2) C. C,H,,0, (n= 2) D. C\H,,..0; (n> 3) Website: thukhoadaihoc.vn THAY CO CAN FILE WORD LIEN HE: 085,23.23.888 Trang 1300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Cau 16: G nhiét d6 cao, khi CO khir dugc oxit nao sau day? A. Ca0. B. AlOs. C. Mg0. D. Fe03 xit axetic phan tg véi chat ndo sau day? A. CaCO: C. NaCl. D. Dung dich Bro Cu 18: Cho vai giot dung digh phendfphthalein vao dung dichNHs thi dung dich chuyén thanh A. mau vang. Bemiere ean, C. mau héng, D. mau xanh. Cfu 19: Vio mita déng, nhiéu gia disfiSir dung bép than dat trong phing kin dé sudi Am gay ng6 dc khi, ¢6 thé dn t6i tr Vong. Nguyén nhan ga¥.ng6 dpe Ia do khi nao sau day? A. Hp, B. Qa C.Nz. D.CO. Cu 20: To lapsan la sin phim etafhin-hg ding tring ngung gitta ‘A. axitterephtalie va etylen glicot, B. axit terephtalic va hexametylendiamin. C. axit caproic va vinyl xianua D. axit adipic va etylen glicol. (fu 21: Cap dung dich nao sau day phat ee hau tao ra chat khi A. NHiCl va AgNOs.—_B, NaOH eH #SQ, C. Ba(OH): va NH:Cl. DD, NasCOs va KOH. Cfiu 22: rong hop chat NaNO> nito ¢6 sé ox lin, A42 B.+1 << ts D.#3. (Cau 23: Cap cht ndo sau day Khong cine 7a ong mot dung dich? A. NaOH va Nant a B. Cu(NO3)2 va H2SO.. C. CuSO, va NaOH. D. FeCl; va NaNO3. Cw 24: Hop chit no sau diy visti dung iy YOidung deh HICI via te dung duge v6i dung dich NeOHT A. Metylamin, B, Trimetylamin C. Anilin, D. Axit glutamic. Céu 25: Polime X la chat rin trong sudt, c6 kl, Sean ‘nh sing truyén qua tét nén durge diing ché tao thity tinh hitu co plexiglas. Tén goi cia X 1a A. poliacrilonitrin. B. poli(metyl metacrylat) C. poli(vinyl clorua). / D. polietilen. Cu 26: Thity phan disaccarit X, thu duge 2 nonce Seis f¥4.Z. Oxi hoa Y hofe Z bing dung dich AsNOWNHs, thu duge chat hitu co T. Hai chat X, T lan luot 1a \ A. saccarozo va axit gluconic 2°~'B, satcaroza va amoni gluconat. C. tinh bot va glucoza \-<-Deslucoza va fructozo. CAu 27: Cho ac chat sau: alanin, etyl axetat, Ala ~ Gly, goin sé chit phan img duge véi dung dich NaOH a A3 B.4 D.1 D.76,91%. g {/Aé mol 1:1) trong dung dich KOH lay du. Sau phan img thu duge m gam muéi khan. Gié trj m bing A. 18,20 gam. __B. 15.0 gam. C.21 Gym, D. 20,23 gam. hin hop gém glucozo va sacearozo thinh 2 phan bi ay? vira du V Lit khi O2 (iki i, lay toan b9 rang monosac dich AgNOs trong NH thu dugc t6i da 10,8 gam Ag. Gia tri cha V 1a, A. 10,08, B.6,72. C12. D. 13,44. Cfu 31 at hiru co X, mach ho. (CrHi90s) tac dyng voi dung dich NaQH dy, dun néng, thu duge san pham hitu co gdm mudi (CsHsO;Nap) va ancol. s6 cOng thire cau tg A AG B.1 C4. CAu 32: X 1A tripeptit Gly — Ala — Glu; Y 1A tripeptit Ala — Val i nghiém sau: ‘Thi nghiém 1: Cho m gain hén hgp X, Y tic dung hoan toin vi KOH thi ‘de 0,85 mol. ‘Thi nghiém 2: Thiy phan hodn toan 111 gain hén hgp X, Y trong HC1 dur thw wren +41,85) gain mudi. Gia tri cia m la A. 83.9, B.79,4. C.74.9. D. 72,85. CAu 33: Thay phan hoan toin hdn hop X g6m 3 triglixerit trong dung dich NaOH, thu duge glixerol, natri stearat va natri oleat. Dét chdy hoan toan m gam X thu duge H20 va 6,84 mol CO>. Mat khéc, x phong héa hoan toan nh phan mg voi lrgng dur dung Website: thukhoadaihoc.vn §=THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 2300 DE THI THU THPTQG 2022 (GIAI CHI TIET) m gam X bing KOH vita diy ldy to’ b mudi sau phan tmg dem dat chay trong oxi du thi thu durge ti daa gam CO:. Gi tri cua a gan nhat v6j-gid tri nao sau day? A. 277. D. 270. (Cfiu 34: M@t binh kin chi 5 .5 mol), 0,65 mol) va mot it bt nilcen. Nung néng binh mt thoi gian, thu dude, uot hin hgp khi X. Cho ton b6 hén hop X phan tig v6i lugng dur dung dich AgNO; trong dung dich NH¥y ‘Hiduipe hén hop khi Y va 26,4 gam két tua. Hon hop khi Y phan img tdi da a mol Br: trong dung dich. Gia tri ca Ja“ A013 Cfiu 35: (@) Di C.0,11 D.0,39 (c) Cé thé ding nhiét dé han va ‘uOn 6g phva PVC. (d) Nuée ép cua qua nho chin 6 ka piimy tham gia phan img tring bac. (e) Trong to tim 6 chira ede (g) Cao su luu héa cé tinh dan héi, ‘S6 phat biéu ding la A.3. B.S. Cu 36: Cho cde phuong trinh héa hoe sa X+3NaOH —"> Y +Z+T + H20( Y + HCL —> CaH,O3 + NaCl 2) Z + 2HEK ES. > CoHsO3 + 2NaCl (3) T + 2AgNOs + 3NH3 + Xi "> CoH/OnN, € Bh 2Xsi (4) (a) C6 4 c6ng thite céu tgo phit hop véi X. (b) Dét chay 1 mol Y thu duge 2 mol CO> (©) Z la hgp chat hit co tap ehite (d) Trong phan tir Z s6 nguyén tir cacbon bing sO (e) X2 phan tmg véi NaOH theo ti 18 s6 moi 1:1 (g) X c6 khdi long phan tir 250 dvC. S6 phat biéu ding li Al. B. fu 37: Chat X (C.HyOsNo) 12 mot amino axit. Cho m gam E gém X va Y (c6 NaOH dun ong, thu duge 1,568 lit (dkte) hén ) 14 mudi amoni cia i Izgng du dung dich A. 48,13%, B.48,92%. iw 38: Cho m gam hin hgp A gdm Fe, Cu, Fe,0s vi FesOs tke véi 600 ml dung dich hén hgp chita HCI 2M va KNOs 0,2M thu duge dung dich X chita (m + 47,54) fan vi hn hop khi Y chita 0,05 mol NO va 0,04 mol NO2 (khéng c6n san pham khir khac), Cho mét eee Mg vao X sau phan ting thu duge dung Z,(m ~ 0,89) gam chat rin va thay thoat ra hén hop khi T gdm'NAyA He cé ti khOi hoi so voi He 1a 35/44. Biét cic phan img hoan toan. Tong kl : A. 60,30. B. 55,62. D, 59,18. Cu 39: X la este hai chize, mach ha, Y 1d este don chire. Bot chy hodn aysio tin hop T (gém X va Y) thu duge 230,208 gam CO2 vai 51,84 gam HzO. Mat khe, thiy phan hoin toan T Ganfdtng 113,028 gam dung dich NaOH 50,96%, c6 can dung dich sau phan img thu duge chat rin Z gom 3 mudi (Sir G-phan tir khdi > 90 dvC). Ngung tu phin hoi thu duge 94,3 ml ancol etylic 40°, Biét khoi long ring eita ariGol etslic nguyén chat bang 0,8 g/ml va cia nuée bang | g/ml. Khdi long cua mudi eé phan tir khoi nho nhat trig? la 1a} A, 61,664 gam. B, 66,24 gam. C.67,68 gam, D. 64,288 gam. (Céu 40: Tién hanh thi nghiém theo ede bude sau: Busée 1: Nho vai gigt dung dich iot vao Ong nghigm chira 1 ~ 2mI dung dich h6 tinh bat. Buse 2: Dun néng éng nghiém mét lat trén ngon ra dén edn, Bue 3: Nging dun, dé dung dich trong éng nghiém ngudi dan vé nhiét 46 thudng. D. 54,64%, i hong chat tan ¢6 trong Z | Website: thukhoadaihoc.vn §=THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang3300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Cho ede phat bigu sau: : (a) Sau bude 1, ung dich trong éng nghigm e6 mau xanh tim. (b) Sau buéc,2;dung-dich bi nhat mau hoae mat mau. (c) O bitde 3, rgaiti'xdnintim ciia dung dich sé xuat hién lai. (@) Néu thay thang dightinh b6t trong thi nghiém bing xenlulozo thi hign twgng 6 bude 1 van thu duge dung dich mau xanh tin} . . (e) Néu nho vai Git dung dich I: lén mie edt cd khoai lang twoi cing xuat hign mau xanh tim, (g) O bude 2, iot G-oX Hida tinh bot, Trong ac phat bigu éh,-s0 phat biéu dang la AS _-B,2, D4 Website: thukhoadaihoc.vn §=THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 40 DE THI THU THPTQG 2022 (GIAI CHI TIET) Ki THI TOT NGHIEP THPT NAM 2022 Bai thi: KHOA HOC Ty NHIEN; Mén thi thanh phan: HOA HOC f Thoi gian lem bai: 50 phuit khong ké thai gian phat dé Ho va tén thi sinh... Sé bao danh Ma dé: 201 1B 2D 3A 11D | 12.4 13.B 2c | 22D | 23.C 31D | 32.C | 33.4 6B TA 8A 9D 10.C 16D | 17.4 18.C 19.D | 20.4 26.B | 27.A | 28.C | 29A | 30.B 36.C | 37.C | 38A | 39B | 40.D DE THI GOM 40 CAU (TU CAU ‘CAU 40) DANH CHO TAT CA THI SINH Cau 1: Etyl propionat li este ¢6 mii thom eta dita. Céiig.shirg cua etyl propionat la A, HCOOCHs, B.CHsCOOGHs. __{__-€, CHsCOOCH. D. CHsCOOCHs. Au 1: Chon dap an B ae 2 Loi gid { OO’ Phuong phap gia reed Dua vao ly thuyét vé este. en ‘ Gia chi tidt: {Q Céng thiic cua etyl propionat la CHsCOOCHs ¥_ Chon dap in B (Cu 2: Ion kim loai nao sau day c6 tinh oxi ha manh nhat? ‘A. Me". < Ly thuyét vé day dign ho Ks Nat Mg AB* Zn Fe! Smit POE HY Cu Fe AQ” A Tinh ox hoa ca kim loa tang K_Na Mg Al Zn Fe Ni Sn Pb H Cu fe Ag Au Tinh Ed ca km ol gidm ‘Mgo nhé: KL nao cé tinh khit cing manh thi tinh oxi héa cia ion kim logi d6 cang yéu. thukhoadaihoc.vn o (085,23.23.888 Trang 50 DE THI THU THPTQG 2022 (GIAI CHI TIET) chi tit: Dua vio day dign gece kh Togi ta c6 si so sinh vé tinh oxi hoa: Na* Cu> Au> Al> Fey Chon dap an A C4u 6: Kim logi Fe khéng phan img voi dung dich nao sat A. CuSOs B. Zn(NOs)s D. Fex(SO4)s Cau 6: Chon dap an B 2 Loi git Phuong phap giai: Quy tic alpha trong day dign hoa: B™ => mA+nB™ mA" +nB Giai chi tiét: A: Fe+ CuSOs— FeSOx+ Cu. B: Khong phan tmg. C: Fe + AgNOs — Fe(NO3)2 + 2Ag. D: Fe + Fe2(SOx)s —» 3FeSOs. ¥ Chon dap én B Cau 7: Chat nao sau day li dong phin cia glucoza? A. Fructozo. B. Xenlulozo. C. Sacearozo. D. Mantozo. thukhoadaihoc.yn co FILE EN HE: 085,23.23,888 Trang 6300 DE THI THU’ THPTQG 2022 (GIAI CHI TIET) Cau 7: Chon dap an A i Loi gid Phuong phap gi Dua vao ly thuyét vé c: chi tiéts ‘~ Fructozo la déng phan \ Seneca Jéu c6 CTPT li CoHi20s. ¥_ Chon dip an A > 5 Cau 8: Gée glucozo va g6e fiuctor6, tyong phan tir saccarozo lién két voi nhau qua nguyén tir A. oxi. C. hidro. D. cacbon. fu 8: Chon dap an A Loi gidi: Phuong phap giai Dya vao ly thuyét vé cacbohidra chi tiét: Géc glucozo va gée fructozo trong’ eda lién két véi nhau qua nguyén tir Chon dip an A Sy Cau 9: Amin nao sau day 1a amin bac 24, A. CoHsNEb. C. (CH3)3N. D. (CHs)2NH CoHsNH2 > Amin bac 1. B: CoHsNH2 — Amin bac 1. C: (CHs)sN > Amin bac 3. D: (CHs):NH — Amin bic 2. ¥_ Chon dap an D Céu 10: Amino axit H2NCH2C A. lysin. DOH cé tén goi li alanin. D. valin, Céu 10: Chon dap dn C & Loi gi Phuong phap gi Dya vio ly thuyét Giai chi tiét: Amino axit H2NCH2COOH c6 tén goi la glyxin, amino axit. ¥_ Chon dip an C Céu [1: S6 lign két peptit trong phan tir Gly — Ala ~ Ala Gly (ofp 1h A.2 B.1 C4 D.3 (Cu 11: Chon dap an D & Loi gid Phuong phap giai: Peptit 6 n mit xich s€ ¢6 (n - 1) lign két peptit. chi tit: , : Gly-Ala-Ala-Gly c6 4 mit xich — e6 3 lién két peptit. ¥_ Chon dap an D Cau 12: Loai to nao sau day duge san xuat tir xenlulozo? : A. to visco. B. to nilon ~ 6.6. C.to tim, D. to capron fu 12: Chon dap din A «Loi gidi: Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 7300 DE THI THU’ THPTQG 2022 (GIAI CHI TIET) Phuong phap gi: Dua vio ly thuyét vé vat ligu polime. Giai chi tiét: Ta visco duge san xudt tit xenlylodo. >> ¥ Chon dapan A (Ly C4u 13: Polime nao sau day thuéc oat ‘poliahit? A. Tinh bot B. Niton 8.6, C.Polictilen. D. Poli (vinyl clorau) Céu 13: Chon dip an B we 2 Loi gid - Phuong phap giai: ; Poliamit li cde polime chia lign két Giai chi tiét: Nillon-6,6: [-OC-(CH2)s- rene ee = Cé chita lién két -CONH- thude loai poliamit. ¥_ Chon dap én B Cfu 14: Chat nao sau day 1a chat dién li yeu? A. NaCl. B. HCl. Cfu 14: Chon dap an C Loi gidi: Phuong phap giai ~ Chat dign li manh gom: + Axit manh: HNOs, H2SOz, HCl, HCIOa ... + Bazo manh: KOH, NaOH, Ba(OH)2, Ca(OH)s, ... + Hau hét ede mudi (trir HgCh, HgCl, Hg(CN)2, Cul ~ Chat din li yéu gom: * Axit yéu: CHsCOOH, HCIO, H2S, HNO2, HF, H2C + Bazo yéu: Mg(OH)2, Fe(OH)3, Cu(OH)., ... * Mt sé mudi + Nude chi tit: ‘A: NaCl — Na’ + CI: B: HCl > H* + Cr. C: CHsCOOH = CH3COO" +H”. D: KOH — K* + OH- C.CHsCOOH. D. KOH ¥_ Chon dap an C “o>, ‘CAu 15: Céng thite chung ciia este no, don chirc, mach hé 1a os C,H,,.,0;(n23) —B, C,H,, ,0,(n>2) C. C,H, QQ D. C,H,,..0, (23) Dua vao ly thuyét vé este. Giai chi tiét: Céng thire chung cia este no, don chiro, mach hé li CaHanO> (n> 2). ¥_ Chon dap én C Cau 16: 6 nhigt d6 cao, khi CO khir duge oxit nao sau day? A.Ca0. B.ALOs. C.Mgo. Cu 16: Chon dap an D «Loi giti Phuong php gisi: Khi CO chi khir duge céc oxit ciia kim logi ding sau Al trong day dign héa 6 nhiét d6 cao. Giai chi tiét: Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang &300 DE THI THU’ THPTQG 2022 (GIAI CHI TIET) Khi CO chi khir duge cdc oxit ciia kim loai dimg sau Al trong day dign héa 6 nhiét d6 cao. = CO khir duge Fe20s. PTHH: 3CO + FesOsth4-+to 2Fe + 3CO2 ¥_Chon dap gn-D5_. C4u 17: Axit axetic'parrth Tg.¥6i chat ndo sau day? ‘A. CaCOs. SB. HCL C. NaCl. D. Dung dich Bry Cu 17: Chon dip ang” _/ © Loi gidi: — =. Phuong phap giai Dy vao tinh chit hoa hye Gi Gia xi aor Giai chi tiét: eg 2CH COOH + CaCOs 3G GieGoy.ca +CO21 +120 Chon dap an A aX Cu 18: Cho vai giot dung dich;pheriphthalein ‘vao dung dichNHs thi dung dich chuyén thinh ‘A. mau vang. Bimawgam. C. mau hong. D. miu xanh, Céu 18: Chon dap an C C cA Lit gid O) Phuong phap giai: -MT axit va MT trung tinh kong (2 44gi mau phenolphtalein. - MT kiém lam phenolphtalein chu repens hong. chi tiét: Dung dich NHs ¢6 mdi truomg kiém NY Gilpteniiain tir khong miu chuyén sang mau hdng. ¥_ Chon dap én C Cfu 19: Vio mia déng, nhigu dan t6i tit vong. Nguyén nhén gay ngé déc ldo A. Eb. B. Os, . h sir ean dat trong phong kin dé sudi am gay ng6 déc khi, c6 thé Spinto sau day? s_C.N2 D.CO. CAu 19: Chon dap an D 5 Loi gid \S Khi dét than trong phong kin s@ sinh ra khi coe, 6 thé dn t6i tir vong Chon dap én D Cau 20: To lapsan 1 san phim ciia phan ing dong ing om fing gta A. axit terephtalic va etylen glicol. . axit terephtalic va hexametylendiamin. C. axit caproic va vinyl xianua _-) Dua vao ly thuyet vé polime. rs Giai chi tiét: {C2} To lapsan la san phim ctia phan tg dong tring ngung shea bid terephtalic va etylen glicol. nHOOC-CoHs-COOH + nHO-CH2-CH:-OH — (-OC-CéH4¢€Q0-CH2-CHa-O-)n + 230 ¥_ Chon dap an A e 5 Céu 21: Cap dung dich nao sau day phan img v6i nhau tgo ra cht Kh. A. NH4Cl va AgNOs. B. NaOH va H2SO.. Cc. atolls NHACL. D. NaC; va KOH. Cu 21: Chon dap din C — i Loi gidi: a \ oe Phuong phap giai: z ei Dua vao tinh chat héa hoe cla cde chat Giai chi tiét: A: NHiCl + AgNOs — NH4NOs + AgCl |. B: 2NaOH + H2SO4 —> NaySOs + 2420. Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 9300 DE THI THU’ THPTQG 2022 (GIAI CHI TIET) C: Ba(OH): + 2NHsCI > BaCh + 2NH; ¢ + 2H20. D: Khong phan img. ¥_ Chon ee ¢ ALD Bol C45 D.+3 Cau 22: Chon dap eT Be) 2: Loi gidi: a, Phuong php gisi: eS Quy te xe dinh s6 et 1. Trong cde don chat, s6 SiG etdipguyén 16 6 bing 0 2. Trong m6t phan tit, tng <6 oxi,héd cita cc nguyén t6 nhan voi sé nguyén tir cia timg nguyén t6 bing 0. 3. Trong cic ion don nguyéi i héa cha nguyén 16 bing dign tich cua ion d6. Trong ion da nguyén tr, tng s6 s6 oxi héa cua cde nguy. ibis s6 nguyén tr cia timg nguyén t6 bing dign tich cia io 4, Trong hau hét céc hop chat, $6°Oxi héet cia H bing +1 (trr hidrua kim logi). S6 oxi héa ciia O bang -2 (trit OF> va peoxit). om) Gia chi tiét: c ns na a NaNO, —9(+1)+x+(-2).2= 1Gas3 ¥_ Chon dap én D \ Céu 23: Cap chat nao sau day khOng cing Tomtak trong mot dung dich? A. NaOH va NaxCOs. B. Cu(NOsh, @.MISO4. C. CuSOs va NaOH. D. FeCl; va NaNOs. Cau 23: Chon dap an C Ye & Loi gidi: 7 Phuong php giai Cée chat phan (mg voi nhau thi khong on tai aie ‘mot dung dich. Giai chi tiét: wo CuSO, va NaOH khéng cing tin tai do xy Gadde: CuSO4 + 2NaOH — Cu(OH)> | + NaxSO¥ ‘y edie. Chon dip an C me) Céu 24: Hop chat nio sau day vita tac dung duge véi-diing dielHC! vita tie dung duge voi dung dich NaOH A. Metylamin, B. Trimetylamin. : D. Axit glutamic. Cu 24: Chon dap an D x Loi gidi: Phuong phap giai: Dua vio tinh chat héa hoe cia amin, amino axit. Giai chi tiét: Axit glutamic vita téc dung véi HCI (do e6 nhém -NE) viylag-dilig véi NaOH (do e6 nhém -COOH). ¥_ Chon dap an D WO C4u 25: Polime X 1a chat rin trong suot, e6 kha ning cho anh 84 tinh hitu co plexiglas. Tén goi cia X la A. poliacrilonitrin C. poli(vinyl clorua). Cau 25: Chon dap an B © Loi giai: Phuong phép giai Dua vio ly thuyét vé vat ligu polime. Giai chi tiét: Poli(metyl metacrylat) la chat ran trong suét, c6 kha nang cho anh sang truyén qua tét nén duge ding ché tao. thiy tinh hitu co plexiglas. } a ¥_ Chon dip én B Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 10300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Cu 26: Thiy phan disaccarit X, thu duge 2 monosaccarit Y, Z. Oxi héa Y hoge Z bing dung dich AgNOs/NHs, thu duge chat hitu og'FsHai chat X, T lan lugt 1a A. saccarozayVi ay: B, saccarozo va amoni gluconat. C. tinh bot va gluci D. glucozo va fructozo. ‘Cu 26: Chon dap 4n-Be = Loi gi 3 Phuong phap ony Dya vao ly thuyét x€ cacBohidrat. Giai chi tiét: © \C- Sacearozo &) > Glusoref Fructozo (Z). Glucozo (Y)/Fructoza{(Z) sy Amoni gluconat ~ [¥_ Chon dap an B/ Cau 27: Cho cdc chat saul Alani, et¥l axctat, Ala — Gly, phenylamin. sO chit phan img duge véi dung dich NaOH la A3 G.2 D.1 Céu 27: Chon dap din A «Loi gidi: ~y\ Phuong phap giai: \) Dua vao tinh chit héa hoe eta &ste;ppip, amino axit. Giai chi tiét: CN Cf chat phan tg voi NaOH: ais Uy) axetat, Ala-Gly (3 chat). (CH3-CH(NH2)-COOH + NaOH —\CH:CH(NH2)-COONa + H20 CH COOC2Hs + NaOH toto C1 COP Ns ¢ HOH (CH-CH(NH3)-CONH-CH-COOH 4 aOfi > CHs-CH(NH2)-COONa + H2N-CH;-COONa + H:0 ¥_ Chon dip an A ae (Céu 28: Ha tan hoan toan 13,8 gain hon Hop Xgdm Al, Fe vio dung dich H2SO4 loding, thu durge 10,08 lit khi (dkte). Phan tram vé khoi lugng Al trong Xs A. 58,70%. B. 20,24%. C. 39.13%. D. 76,91%. Phuong phap giai - Dit an 1a sé mol mdi kim loai. ~ Lap hé 2 phuong trinh 2 an dya vao: + Khéi long cia hén hop + Bao toan electron: 3nai + 2nre=2min Giai hg tim durge s6 mol mdi chat. - Tir d6 xée dinh %ma\ chi tiét: 21x +56y =13,8 i eae 3x42y=2. ai y=015 = %my = 2227 100% =39,13% ¥_ Chon dap an C Cu 29: Xa phong héa 14,8 gain hon hop etyl fomat va metyl axetut (fi 1¢ mol 1:1) trong dung dich KOH lay du. Sau phan img thu duge m gam mudi khan, Gi tr} m bing A. 18,20 gam. B. 15,0 gam. C. 21,0 gam. D. 20,23 gam. Cau 29: Chon dap an A «Loi giai: Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 ‘Trang 11300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Phuong phap gi = Tit hoi ibn va ti Ié mol ta xéc dinh durge s6 mol mai este. - Xée gibi a phan ciia mudi — gid tri cia m. Gia dam Icuscoocs = X mol = tes fay} 14x = 148 > x =O:tinof 4 ~ Mui haem: HCOOK (0,1 mol) vi. CHsCOOK (0,1 mol) = Muti “sir =0,3.84 + 0,1.98 = 18,2 gam ¥_ Chori dag in A ia h-hgp-gom glucozo va saccarozo thinh 2 phan bang nhau: chéy oak toan phan m6t can vira dit V lit khi O2 (dkte), Phan 2: Thily plin-hotn {ban phan hai, lay toan bd lugng monosaccarit tao thanh phan img voi lung dur dung dich AgNO3 trong NB induc toi da 10,8 gam Ag. Gia tri cia V la A. 10,08. } B.6,72 C112. D. 13,44. ‘Céu 30: Chon dap in # Loi gid Phuong php gia *Phan 2: Khi thay phair *Phan 1: Khi dot chay cat it thi ban chat la dét chy C (vi cacbohidrat c6 cau tao dang Cn(H20)n) C +02 CO ne. Giai chi tiét: *Phan 2: Khi thiy phan hoan GH tao ra CoHi20¢. Sau d6 dem CoH 120s di trang guong: CoHi20 > 2Ag ioe }) > mcati206 = Ya.tlag = 0,05 mol & ne = 0,05.6 = 0,3 mol. ao *Phan 1: Khi dt chay cacbohirat sh San is 1a dt chay C (vi cacbohidrat c6 céu tao dang Cx(H20)n) +02 CO2 C58 = no2 = ne = 0,3 mol — Vor = 6,72 ft"_}) ¥_ Chon dap an B ee Cu 31: Hop chat hitu co X, mach ho (CrHo@e)tay dung voi dung dich NaOH du, dun n6ng, thu duge san pham hau co gdm mudi (CsHsOsNaz) va ancol. sd, cog ire cau tao ctia X 1a A.6 1 C.4. D2 (Ciu 31: Chon dap an D (Q) Go Phuong phap gi SY = Mui CsHsOsNaz 06 cde ding phan: (CH2COONa)s 4 CHsCH(COONa): > Musi e6 2 x. ~ Mat khéc, X 6 s6 lign két n= 22 lg CD = Lién két x con lai nim trong ancol. MAX c6 7C, mudi e6 4C => Ancol la CH2=CH-CQOHi,.. - Tir dé xc dinh cc CTCT théa man cita X. “> ) chi tidt: C— = Mudi CsHOiNa2 c6 cic dng phan: (CHsCOONa): vi CHsCH(COONa)2 > Mubi c6 2 1. = Mit kha, X c6 sé lign két = 2-72-10 => Lién két x con lai nam trong ancol. MA X c6 7C, mudi cé 4C => Ancol li CH2=CH-COOH. Website: thukhoadaihoc.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 120 DE THI THU THPTQG 2022 (GIAI CHI TIET) Vay cdc CTCT cia X théa i; Boon, cry groOO# Ca COOCH,-CH-CHs *"\coocii,-cH-CH, aie ¥_ Chon dap an D (5 \ Ta tripeptit Gly ~ Ata Glu; Y Ia tripeptit Ala ~ Val ~ Lys. Tign anh 2 thi nghigm sau: Thi nghigm 2: Thuy phan of joa a 1 gain hn hop X, ¥ trong HCI dir thu duge (m+ 41,85) gain mudi ié tri cia m La A. 83.9, C.749. D. 72,85. (Cu 32: Chon dip an C Phuong phap giai: Ve - Khi cho peptit tic dung voi dd Kie@iMigH MOH = CONH + COOH H2O.iah m = COOH Cc = ~ Khi cho peptit tac dung voi HCI: { cy \ H2Ocin wits = CONH (OC) HCI =CONH + NH2 . chi tiét: AR Gia sir m gam hén hgp chita nx = x mol y: yes nol *INI 4 Gly-Ala-Glu + 4KOH — GlyK + AlaK + Gluike# 3h, xo 4x (Ot Ala-Val-Lys + 3KOH — AlaK + ValK + Lysk tH io a 3y > non = 4x + 3y = 0,85 (1) *TN2 Gly-Ala-Glu + 2H20 + 3HCI — Mudi x> ok x . Ala-Val-Lys + 2H20 + 4HC1 > Mui y> dy 4y Ta thay: mang = miz0 + myci —» 18.(2x + 2y) + 36,5.8x yea 85 (2) Giai (1) va (2) > x= 0,1 va y= 0,15. ce Vay m= 0,1.(75 + 89 + 147 - 18.2) + 0,15.(89 + 117 + 1464 ven liaen 7 Chon dip an C Z Cau 33: Thay phin hoan toan hon hop X gom 3 triglixerit trong oe ich NaOH, thu duge glixerol, natri stearat va natri oleat, Bot chy hoin toan m gam X thu duge HzO va 6,84 nol EQs. Mat khic, xi phong hoa hodn toin m gam X bang KOH vira di, léy toan bo mu6i sau phan img dem By ‘trong oxi du thi thu durge t6i da a gam CO:, Gi tri cua a gan nhat voi gid tri nao sau diy? A A. 277. B. 300. 285. \3_ A D.270. CAu 33: Chon dap din A 6 Loi gid - Phuong php gisi ~ Nhén thay cdc chat béo déu chira 57 nguyén tir C (do tao tir cde gée ing. va Ci7H33COO-). = nx = ncor/S7. - Khi cho X + dd KOH: + Tir s6 mol X tinh duge sé mol mudi + Bao toan K tinh durge sé mol KxCO; + Bao toan C tinh duge sé mol CO2 Giai chi tiét: thukhoadaihoe.vn CO CAN FILE WORD LIEN HE: 085.23.23.888, Trang 130 DE THI THU THPTQG 2022 (GIAI CHI TIET) = Chat béo o6 dang ARCQQRCSHs. stéasSit CisH%4COO- hode oleat Ci7HssCOO- -Khi cho X + dd KOM. Ta cé: nrcook = 3nx = 0,A6mob BTNT: K > nxacos = Ys-néoos 0,18 mol BINT: C —+ ncoa imi) = Magoa-Pney (m0) = 0,36.18 = 0,18 + nco2 ¢rNgr — nor (m2) =6,3 mol Ly = a=277,2 gam, Chon dap an A — Cau 34: M6t binh kin chi chita cac'etiff sau} axetilen (0,5 mol), hidro (0,65 mol) vi mot it bot nilcen. Nung néng binh mot thei gian, thu durge 0.56 mél hberfgp khi X. Cho toan bé hén hop X phan img véi lugng dur dung dich AgNO, trong dung dich NHs, thu duge Aon, ep khi Y va 26,4 gam_ ‘két ta, Hon hgp khi Y phan img t6i daa mol Br trong dung dich. Gid tri ciaali { () } A.0,13 B.0,19 C.0,11 D.0,39 fu 34: Chon dap an B 2 Loi gid Loy Phuong php gidi: rd - Trong phan img hidro héa hidrocacbon ie Rit pu = Mylan. - Sit dung phuong phap bio toan = ni pu + 2ncar2 au + NB poe Giai chi tiét: Két ta la AgoC2 > nagac rr Saree { aH i 50,56""(X) Hi, :0,65 ‘iz pu = Naim = (0,5 + 0,65) - 0,56 = 0,59 mol Sir dyng phuong phap bao toan lién két 2: 2nc2u2 ban din = MU pw + 2Mc2H2 dw + M2 pe + 2.0,5 = 0,59 + 2.0,11 + nope = no pu = 0,19 mol. ¥_ Chon dip in B (Cu 35: Cho ede phit biéu sau: (b) Gim an hoe chanh khir drge mii tanh cia cé (c) Cé thé ding nhiét dé han va uén dng nhya PVC. (a) Nuéc ép ciia qua nho chin 6 kha nang tham gia phan img tr (e) Trong to tim c6 chtra cdc géc a — amino axit. (g) Cao su luu héa ¢6 tinh dan héi, lau mon va kh6 tan hon cao su thaerig S6 phat bigu ding 1a < A. 3. B. 5. C.6 ” Cu 35: Chon dap an C = Loi gi Phuong phap gi Dya vao ly thuyét tng hop vé este, cacbohidrat, peptit, polime. Giai chi tiét: (@ ding. thukhoadaihoe.vn CO CAN FILE BN HE: 085.23.23.888, Trang 14ioe 2 a 0 DE TH FHU_-THPTQG 2022 (GIAI CHI TIET) (b) ditng, vi amin gay nx cen tanh; trong giam va chanh cé chira axit sé phan img véi amin tao ra mudi dé bi ria troi nén giém mii tatih 2ua}ca. (©) diing, PVC d& biGona-chay khi gap nhigt 46 cao. (d) ding, nude ép qui a alto cl ‘hita glucozo ¢é phan tmg tring guong. (e) ding, do ban chat Se (g) ding. Vay £6 6 phat biéu ding’ ¥ Chon dap anC_\-y ‘Cu 36: Cho cdc phuong trinhhéd hg T + 2AgNOs + 3NH3 + Xi —“4sEatiyt Cho cde nhén xét sau: (a) Co 4 cng thire cau tao phir oh bar (b) Dot chay 1 mol Y thu duge 2 motEO (©) Z lahgp chat hi co tap ehire.— { : (d) Trong phan tir Z s6 nguyén tir ae 16 nguyén tir hidro. (e) Xz phan ting véi NaOH theo ti Ig snot: (g) X c6 khdi long phan tir 250 dvC. ‘So phat biéu ding la A. 1. B. CA 36: Chon dap an C = Loi gid Phurong phap giai: Bign lun cau tao. chi tiét: - Tit (2): C2HiO3 18 HOCH2COOH = Y: Hoc ions ~ Tir (4): CoH7O2N la CH3COONHg => T: eater, g; X2: NHsNOs. - Tit (3): CoHsO3 6 ate 6= =4 (vong bofren) DY (COO) +1 (C=C) = CTCT cia Z: a NaO-CoHs-CH=CH-COONa (3 ding phan 0, m, p) NaO-CoHs-C(=CHz)-COONa (3 déng phino,m,p) y\ (NaO-)(NaOOC-)(CH2=CH-)CoHs (10 déng phin) = 4 (a) sai, Z c6 16 dong phan nén X c6 32 dng phan. SS (6) sai, HOCH;COONa —°> 0,5 NaCOs +1,5CO2. { (0) ding, tap cise mudi caa phenol vi mudi cua axit cacboxyli (d) sai, Z c6 9C va 6H. (e) diing, NHsNO3 + NaOH — NaNOs + NH + H: = (@ sai. vi du 1 dng phan eta X: HOCHsCOO-CoHs-CH=CH-C@OCH*CHs = Mx = 248 avC. Vay e6 2 phat biéu diing. —) ,O >} Noe ¥_ Chon dap an C Cu 37: Chat X (C,HyO4N2) la mudi amoni ctiaaxit eacboxylie da chite; chat Y (CalH,O2N2) Ia mudi amoni cua mét amino axit, Cho m gam E gém X va Y (c6 ti Ié mol tuong tg li 2 : 3) tae dung hét voi hrong du dung dich NaOH dun néng, thu duge 1,568 lit (dkte) hén hop Khé (g61 it hitu co 1a déng ding lién tiép) c6 ti khdi so Vi hidro bang 17,5 va 6,53 sam hon hop mudi. Phan tram khoi lugng cua Y trong E la A. 48.13%. B.48,92%, C. 48.38%. D.54,64%, Cf 37: Chon dap an C Loi gidi: Phuong php giai thukhoadaihoe.vn CO CAN FILE WORD LIEN HE: 085.23.23.888, Trang 15300 DE THI THY. -THPTQG 2022 (GIAI CHI TIET) Theo dé nx : ny = =O 3 ro ia dat nx =2a ak va ny = 3a mol saree gat 0,01, ),02 va ny = 0, Te sb mol moi kh vas mT s = X: CoHsNEhOOC-R- Coos ,02) Y: HaN-R-COONHACH (0,03) = Mui chita: R(COONa) (0,02) yé HaNAR-COONa (0,03) ‘Mmadi = 0,02.(R + 134) + 0,03.(R%, AS37083 = 2R + 3R'= 136 = R= 26 (-CH-CH-) va R’= 28 ve Aes man => Yommy = 48,387%, aan ¥_ Chon dap an C Lay Céu 38: Cho m gam hon hop A gom Fe\Cu; F9s0s va FesOs tae dung hét v6i 600 ml dung dich hon hop chita HCL 2M vit KNOs 0,2M thu duge dung dich Xefnta (m + 47,54) gam chit tan va hin hop khi Y chita 0,05 mol NO va 0,04 mol NO» (khéng con sin phat hc). Cho mot lung Mg vao X sau phan img thu duge dung a 6 ti khOi hoi so véi He li 35/44. Biét cdc phan img hoan toin. Tong khoi homie A. 60.30. B. 55,62. D. 59,18. Céiu 38: Chon dap din A Loi gidi: Phuong phap giai: Giai chi tiét: Do Mg vio dd X thu duge No = dd X 6 chira H Mos Fa *Thi nghigm 1: Dit no = amol i CCéng thite nhanh: nii“pe = no + 4nyo + 2nNo2 = 2a + Bom — mmo = %.nni"pe =a + 0,14 (mol) a Cae a Fe;Cu [HC1:1,2 a) e;Cu a B, Yas m(ga fp ie No gio 4754 (eam) x H oh crs NO; BTKL: mya +muci + mxxos = mx + myo + myoz + min0 — m + 1,2.36,5 + 0,12.101 = (m + 47,54) + 0,05. sty 14) = a=0,14, a BINT: H — na(aax) = nu” - 2nn20 = 0,64 mol. ah BTNT: N — nos" (as x) = MKNOS ~ NNO ~ NNo2 = 0,03 mol, a. *Thi nghigm 2: 7) Ta thay: mre + mey = my ~ Mo = m - 2,24 (g) < m - 0,89 => Chat rin fn, Me‘au = Fe** va Cu? chuyén hét thinh Fe va Cu; H* phan img hét. Do sau phan img thu duge Ho nén Y khong con NOs. Phan img c6 kha nang to Ny". Dt nye = x; m2 = ys nus” =z (mol) Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 16300 DE THI THU’ THPTQG 2022 (GIAI CHI TIET) Fe*;Cu™ FS > — {K*:0,12 K*:0,12 (—. ¥ re ee | Mg" Nyx X{H":0,64 }Me—— oy +H,0 f 35, NH}:z [H,:y ler:2 hee oon GienZ (1) Cong th Cnt ng thite nhang: wf (Q) BINT: N ey £2mn2 > 2x +2 = 0,03 SH: (3) Mini = 35/11 => Giai hé trén duge: (sf B2k “V2; 7 = 0,01. BIDT dd Y nx” + 2nu-="fiuye’ ner — ng” = 0,535 mol. Mehl an trong ¥ = MK ee + mer = 60,3 gam. ¥ ChondapinA {_. (Cu 39: X la este hai chite, mach ji XN don chite. Dat chay hoan toan hén hop T (gdm X va Y) thu duge 230,208 gam CO> va 51,84 gam tat khae, thiry phan hod toan T cin ding 113,028 gam dung dich NaOH 50,96%, c6 can dung dich sau phanang tHu durgc chat rin Z gém 3 mudi (du e6 phan tir khdi > 90 dvC). Ngung ty phn hoi thu durge 94,3 ml ancol eyytie, 40%, Biét khdi luong ring cita ancol etylic nguyén chat bang 0,8 g/ml va cila nude bang | g/ml. Khéi lu: 191 c6 phan tir khOi nho nbat trong Z 1a A. 61,664 gam, B. 66,24 pm C.67.68 gam D. 64,288 gam. (Cau 39: Chon dip an B ~ & Loi gidi: (¢ ory Phuong phap giai: Ye Giai chi tiét: “ 113,028 gam dung dich NaOH 50,96% chet seen NaOH va 55,428 gam H20 => myion = 1,44 mol 94,3 ml ancol etylie 40° ehira 37,72 ml cabesenfse ml H20 = meznson = 37,72.0,8 = 30,176 gam = ncysert=4 9,636 mol 6,58 gam a (56,58 - 55,428)/18 = 0,064 mol 2 = Y 06 dang RCOOCGHAR' (0,064) Ei MA ta thay: nysow = 2ncasots + Mste ca pho! (oO) = X c6 dang RCOO-R'-COOCoHS (0,656) BTKL: mr=me + ma + mo = 5,232.12 +2 (| 112,576 gam mr=0,064.(R + R' + 120) + 0,656.(R + R! + 117) = _\ = 0,72R + 0,064R' + 0,656.R! = 28,144 Cc i) = 45R +4R'+4IR! = 1759 WS DoR>1;R'2 1; R'> 14> R=25;R'=15;R!= 14 thdanin, Khi dé céc mudi go CH=C-COONa (M = 92): 0,72 => m= 66,24 gam. HOCHCOONa (M = 98): 0,656 CH3CsHsONa (M = 130): 0,064 ¥_ Chon dap in B Cfu 40: Tién hanh thi nghiém theo cac bude sau: Busée 1: Nho vii giot dung dich iot vio éng nghiém chia 1 ~ 2mibdfing dich hd tinh bot. Bude 2: Bun néng dng nghiém mot lat trén ngon lira dén e6) Cho ede phat (a) Sau bude 1, dung dich trong éng nghigm e6 mau xanh tim, Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 170 DE THI THU THPTQG 2022 (GIAI CHI TIET) (b) Sau byde 2, dung dich bj nhat miu hoje mat miu, © Sipke - $emau xanh tim ea dung dich sé xuat hign lai, (@)(Néwrtbay dung dich tinh bGt trong thi nghigm bang xenlulozo thi hign tugng 6 buée | van thu duge dung dich magL-xatih tint, (e) Nawhig Vai giot dung dich Iz lén mae ct cit khoai lang twoi eting xuét hign mau xanh tim, (g) O byt6¢ 2,Aot da oxi hoa tinh bot. Trong cat phat'higu trén, s6 phat bigu ding la chi tid - Tinh bét 6 nhif iGdo.ursing cé cdu tric xodn nén iot chui vao tao ra hgp chat xanh tim (hién tugng hdp phy). hi dun néng, edu fe-xoi ny dubi ra nén khong 66 hign twong hip phy — mat mau xanh im = Xenlulozo Hob ric xoin nhur tinh bot nén khdng tao mau xanh tim v6i iot. Dura vio tinh oe bot va xenluloze. (a) ding. ew (0 ing, do Kn duh aod thi chu tre xodn cha tin bot bj dnBi raking bp phy dune ft (©) diing, do dé nguditinbHg1 lai cé céu tric xoan. (@ sai, Vi xenlulozo khAgeg kau tric xodn. (©) ding, vi trong khoahliuig tipi ii c6 tinh bot. (® sai, iot da tich ra khot tink-bot thanh dang ty do. Vay e6 4 phat biéu ding. Chon dap an D thukhoadaihoc.vn cé FILE EN HE: 085.23.23.888 Trang 18