300 DE THI THU THPTQG 2022 (GIAI CHI TIET) CUM TRUONG Ki THI TOT NGHIEP THPT NAM 2022 THUAN THANH BAC NINFs, Bai thi: KHOA HQC TY NHIEN; Mén thi thanh phan: HOA HQC Thoi gian lem bai: 50 phuit khong ké thai gian phat dé Ho va tén thi sinh... bao danh Ma dé: 201 * Clic thé tich ki déu do 6 diéu kign ti DE THI GOM 40 CAU (TU CAU. CAU 40) DANH CHO TAT CA Tai SINH Ciw 1: Kim lon phn img duge véi nase o niet de AL Ag. B.Cu. va D. Ba. C4u 2: Thiiy phan triolein trong dung dich NaOH, thu i mudi X. Céng thite cia X a A. CHsCOONa B. Ci7H:sCOONa SC. CefH:3COONa D. CisHsiCOONa Céu 3: Chat nao sau dy thudc logi hidrocacbon thom A. Btan, B. Toluen. ¢ fa len. D. Isopren. Cu 4: Tinh bot, saccaroza, glucoze déu 1d \ SS eae A. Cacbohidrat B. Disaccarit ny D. Polisaccarit. Céu 5: Kim loai nio sau day c6 nhigt d6 néng chay thap ole AW. B. AL a D.Hg. Cau 6: Cho 8,9 gam hin hop bt Mg va Zn tae dung véi dd a fhe (a, sau phan img thu duge dung dich chita m (gam) mudi va 0,2 mol khi Hp (dkte). Gid trj cia m Li Seto A161. B.28,1 C2857 D. 20,6. Cau 7: Chit nao sau day thude loai chit dign li manh? oN y\ ‘A. CH3COOH. B. E20. C.NaGy D. C:HsOH. Cu 8: Dét chay hoan toan 0,15 mol mét amin X no, don chite, mach-hg e hi oxi vita di thu durge 1,2 mol hén hgp gdm CO», H20 va No. so dong phan bac mot cua X 1a A.2 1 C4 \ QQ \ D.3 CAu 9: C3HsOH c6 tén goi la v A. etylen glicol. B. glixerol. C.ancol Bl D. ancol etylic. Cu 10: Metyl axetat c6 cong thite Ia \ A, HCOOCHs. B. CH;COOCHS. C. CHsCOOCHCHE”.. DD. C2HsCOOCHS. C4u 11: Tinh chat nao sau day khéng phai la tinh chat vat li chung cita kim hoai?. A. Tinh cimg. B. Tinh din dign, C.C6 anh kim. Tinh déo. CAu 12: Cho 4,78 gam hén hgp CH ~ CH(NH2) ~ COOH va H2N ~ CHa ~ Gonirin’ img vita di voi dung dich chira a mol HC, thu duge 6,97 gam mudi. Gi tri cita a la A. 06. B.0,03 Cau dn toi tir vong. Nguyén nhn gay ngé dc la do khi AN2 B. Hh. Website: thukhoadaihoc.vn THAY CO CAN FILE WORD LIEN HE: 085,23.23.888 Trang 1300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Clu 14: S6 cng thite ciu tao cia dipeptit X mach ha tgo tir 1 gde Ala va I géc Gly 1a A.2 B3 gn C5 D4 Cu 15: Cho cae chat sau: lysin, anno tee Nnislanin, glyxin, axit glutamic, s6 chat lam gidy quy tim dm chuyén sang miu xanb li A A. C2 DI Cau 16; ft 7 ‘A. HCOOCHS. . CHS C. CHsCOOCHs. D. CH3COOH. Cau 17: Cho diy ede chat: phenyl axd} hi thiy phan trong dung dich NaOH 16g nelyl axetat, etyl fomat, tripanmitin, vinyl axetat. $6 chat trong day ‘dun néng sinh ra ancol la Ad B.S C3 D.2 Caw 18: Cho 8,1 gam Al phan img hoi t6i9-v64 kb} Ch du, thu duge m gam mudi, Gid tr etiam la AL 36.07 B. cote Le C. 40,05. D. 7,64. CA 19: S6 nguyén tir ca ogitreteo la ALL “S C.10. D.6 Cau 20: C6 cde chat sau: (1) tinh bot; (2) xen! % saccarozo; (4) fructozo. Khi thay phan cée chat trén thi nhiing chat chi tgo thanh glucozo la: A34. B. 2,3. D. 12. Cu 21: Phan tir polime nao sau day cé chita nito” A. Poli(vinyl clorua). B. Polibutadien. €. Poli(metyl metacrylat). Poliacrilonitrin. Cf 22: To nio duéi day thude loai to nhin tao? \ A. To nilon — 6,6. B. To capron. \ ONG} To axetat. D. To tim. ‘CAu 23: O nhiét 46 thudng, kim loai Fe tac dung duge \ci-ding dich nao sau day? A. NaCl. B. Cu(NOs)2. ( C.NWOH. D. Mg(NO3): ‘Cau 24: Aminoaxit la hop chat hitu co tap chite, chira dé i thom A. ~ NH va ~ COOH. B. ~ OH va ~ Nib. \C--NEb va ~ CHO. D.- OH va — Cfu 25: Cho cdc dung dich sau: long trang trimg, metyl axe Bh sacearozo. s6 chit tée dung v6i Cu(OH)2 6 nhigt a6 thudng 1A CSS AB B.6 cx a D.5 Cw 26: Hn hop X gdm propin, buta ~ 1,3 —dien va mot am ine dfon\ hc, mach he. Dem dt chay hoantofin 23,1 gam X can ding vita ding 2,175 mol O2 nguyén chat thu rie! tidp sin phim Y gdm COo, H20 va khi Nz. Dan toiin b6 Y qua binh chéa dung dich NaOH dic du, khi thea “hige 2,24 lit (6 dkte). Céng thite cita amin li A. CH. B. CHDN Cf 27: Trong cic chat drsi day, chat ndo 1a dipeptit? ‘A. HN ~ CH2 ~ CO ~ NH ~ CH(CHs) ~ COOH. B. HN ~ CH ~ CO ~ NH ~ CH(CH) ~ CO = NH ~ CH = COOH C. HaN ~ CH2 ~ CO ~ NH ~ CH ~ CH: ~ COOH. D, HN ~ CH(CHs) ~ CO — NH ~ CH ~ CO ~ NH ~ CH(CHs) ~ codty} yh ‘C4u 28: Cho m gam hén hgp gom cac triglixerit tac dung voi dung dich NaQ] Ma dit), thu duge hén hgp mudi X gdm CnHxCOONa, CnHyCOONa vit CisHsiCOONa (c6 ti 1g mol twong gag la 3: 4 2). Dat chéy hod toin X can vita di 4,47 mol Op, thu duge NazCOs, H20 va 3,07 mol COs. Gia tri rol, axit axetic, Gly ~ Ala, hé tinh bét, c. CHB. D. CaN. A. 46,64. B. 52,84. se (C, 51,92. D. 48,72. C4u 29: Tién hinh tring hop 1 mol etilen 6 diéu kign thich hop, dem san pham{gaiiflitg hop tic dung véi dung dich brom dur thi lugng brom phan tg li 36 gam. Higu sudt phan ig tring hgy fj Iuvong polietilen (PE) thu duge 1a eo A. 70% vi 23,8 gam. —_B.77,5% va 21,7 gam. C.77,5 % va 22,4 gam Céu 30: Nhiin dinh nao sau day 1a déng? ‘A. Phan tir amilozo e6 mach phan nhanb, khdng dudi thang ma xofn nur 1d xo. B. Anilin Li mt bazo nén lam quy tim chuyén sang mau xanh, C. Trong phan tir peptit mach ho Gly ~ Ala ~ Val e6 3 nguyén tir oxi. D. M@ Ign ho3e dau dira cé thé ding Lim nguyén ligu dé sin xuat xa phong. 1B. 85% va 23,8 gam. # Website: thukhoadaihoc.vn §=THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 2300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Cu 31: Thay phan hodn toin m gam hon hop oligopeptit gom Ala — Val - Ala Gly — Ala va Val— Gly— Gly thu duge X gam Ala; 37,5 gam Gly va 35,1 gam Val. Gia tri cia m, X lan lugt li A. 99,3 va 30,9. B. 92,1 va 26,7. C. 84,9 va 26,7. D. 90,3 va 30,9. Cu 32: Poli(metyl metacrylat) va nilon ~ 6 duge tao thanb tir cée monome tuong ting la ‘A. CH ~ COO ~ CH=CH va HpN ~ [CH] - COOH. B. CH>=C(CHs) ~ COOCPk va H2N ~ [CH2]s~ COOH. “H2=C(CHs) ~COOCH va HN [CH2]s — COOH. CH -coos A. 291,25. C. 268,82. D. 246,25. ‘Cfu 34: Polisaccarit X la chagrin yng soi, mau tring, khéng mii vi. X c6 nhiéu trong béng ndn, go, day, gai... Thuy phan X thu duge monoSacesit-¥: Phat bicu nio sau day ding? A. Y khéng tan trong nud ray B. X 6 cau trie mach phin . Phan tir khoi eta X Ta 1624 .Y tham gia phan ‘img v6i dif dicheA@NOs trong NH tg0 ra amoni ghuconat. Cau 35: Dun néng 14,8 gam hon m (CHsCOOCHS, HCOOC:Hs, CsHsCOOH) trong 100,0 mi dung dich chiza NaQH 1,0M va KOH aM{phaerimg vita du) thi thu duge 4,68 gam hén hgp hai ancol (ty I¢ mol 1: 1) va m gam mudi. Vay gid tri m la: A. 18.28, B. 16,72, C. 14.96. D.19,72. ‘Cfiu 36: Trong phong thi nghiém, ety itd ge diéu ché theo cde bude: Bude 1: Cho | ml GHsOH, | ml aoa chat va 1 giot HoSOx dae vao éng nghiém. Bude 2: Lic déu, dong théi dun cach thiyrS3 & phiit trong ndi nude néng 65 — 70°C. Bude 3: Lam lank 16i rét thém vio éng /2 ml dung dich NaCl bao hoa. Cho eae phat bigu sau, phat biew dling la AA. Sau bude 2, trong Ong nghigm van con €: Hepl-ra.CHLCOOH. B. Dé higu suat phan ting cao hon, ta nén diadupedich ancol 10°. C. Dung dich NaCI bao héa duge thém vao Snginghigm dé phan img dat higu sudt cao hon. D, Sau bude 3, chat long trong ong nghigm tab dultg dich dong nhat joa tan hodn toan 14,80 gam hon hop ‘goth Fg va Cu vao 96,00 gam dung dich HNOs 52,5%, sau khi kim logi tan hét thu duge dung dich X. Cho soomaadeKON IM vio dung dich X thu duge ket tiia Y va dung dich. Loe lay ¥ ri nung trong khéng khi dé khi-eing kh6ng d6i thu duge 20,00 gam chat rin. C6 ean Fe(NOs)s c6 trong dung dich X gin nhat v\giét) jo sau diy? AL 16% B. 12% A4% Dz 18% Cfu 38: Hén hgp X gém alanin, axit glutamic va h yoxylic no, don chire, mach ha, ké tiép nhau trong day ding ding. Cho m gam X tie dung vita dt Vlich NaOH 1M thu duge 42,45 gam hén hop 6 Ii Khi oxi. Cho sin phim chay qua dung dich HzSO, dic, dur thu duge 22,96 lit hén hgp khi CO2 vi No (bi8tye- kign tiéu chun), Thinh phan phan trim theo khdi lugng cia axit cacboxylic e6 phan iff ces A, 28,30%. B. 19,08%. 2%. CAu 39: Hén hgp M gdm hai este: X don cl Y hai chite® chay hoan to&n a gam M trong oxi dur thu duge H20 va 2,5 mok dung dich NaOH thu duge 47,2 gam hén hgp Z gm 2 mudi va hi ich nude tao anken). Dot chiy hoan to’n 47,2 gam hén hop Z thy‘duGe. CO>. Khéi lugng cia Y trong a gam M 1a B. 22,2 C. 29,2. D. 32,0. jin hop T gdm ba este X, Y, Z (Mx < My < Mz < 150) déu'e6Shg\thite phan tir dang C,H,,O, « Dot chy hoan toin m gam hén hgp T ein vita dit 53,76 lit oxi (dktc), sau pling thu duge nude va 96,8 gam CO>. D. 29,25%. v chi chita nhém chire este, mach hé). Dét Mat khde, a gam M te dung via dit véi g6m 2 ancol (2 ancol déu cé kha ning 120; 37,1 gam NazCOs va 15,4 gam Website: thukhoadaihoc.vn §=THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang3300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Néu xi phing héa hou toi 19,9 gam hon hop T ein vita di dung dich ¢6 chita 0,25 mol NaOH thu duge phan hiru eo gm hai ar(Col-va 54,05 gam hin hop M chita 3 mudi G, U, V (80 < Ma < Mu 3CiH33COONa + C3Hs(OH)s Chon dap an C (Cu 3: Chat nao sau day thude loai hidrocacbon thom thukhoadaihoe.vn (085,23.23.888 Trang 5300 DE THI THU THPTQG 2022 (GIAI CHI TIET) ‘A. tan. B. Toluen. C. Propilen. D. Isopren. Cfu 3: Chon-dap an B eoreage Phirorig } shir ia Hidrgetichonctiom la hidrocacbon e6 vong thom Giai one tibt: Hidroc§chon dhom la toluen ¥_Chion dip an B Cau 4: Tinksbgtesi¢garoza, glucozo d&u Ii A. Cacbohidrat-"\__B. Disaccarit. C. Monosacearit. D. Polisaccarit. Cau 4: Chon ap ina’ & Loi gidi: Phuong Se Dya vao ly thuverv ‘ab, saccarozo, glucozo. chitiét: 5 Tinh bot, saccarof, gluéozo déu la cacbohidrat. ¥_ Chon dap au°A_. (Céiu 5: Kim logi nao sdu Gay’ ep nhigt d6 nong chay thap nhat? AW. AL, c.Na D. Hg. Céu 5: Chon dap anD \ Loi gidi: Los ") Phuong phip gidi: | _- ‘Dua vao tinh chat vat li ctiykin| fp Giai chi tiét: “A Kim loai 6 nhiét 46 néng thipnhdt la He. ¥ Chon dipénD (N (Cu 6: Cho 8,9 gam hon hop bot Mgs% Zh tac dung voi dd chia m (gam) mudi va 0,2 mol khi Ha éékteyGid tri iia m 1a A. 16,1 B. 28, rie C. 28,5. D. 20,6. (Os loang (du), sau phan img thu duge dung dich Cu 6: Chon dap an B : Loi gidi: Phuong phép gia 7) = ngoe = mia = Madi = Min chi tet ‘g Toh ur2so4 = Nsos” = nu = 0,2 = Moudi = Meintogi + MH ¥ Chon dap in B (a Cu 7: Chat nao sau day thuge loai chat dign lagtank?” A. CHsCOOH. B. 10. C. NaCl. D. C:HsOH. Cfu 7: Chon dap an C we) Loi git Phuong phap giai Nhimg axit manh, bazo manh va hau hét cdc onl ién li manh. Giai chi tiét: eat Chat dign li manh la NaCl. — ¥_Chon dap an C LH Céu 8: Dot chay hoan toin 0,15 mol mot amin X no, don chic, mach ho bang Khi oxi vita di thu duge 1,2 mol hn hop gdm COz, H2O va No. s6 dng phin bie mot eta X Li A.2 B.1 C.4 D.3 Cau 8: Chon dip an A Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 6300 DE THI THU’ THPTQG 2022 (GIAI CHI TIET) & Loi gid Phuong php giai: Amin no, don chirc, mach hé e6 CTTQ li: CyHon-sN CoHansN — nCO2 + (p*4,5)HZO + 0,5N2 = noon + nino +m =H 9 = S6 ding phin bic 1 Giai chi tiét: Amin no, don chite, mgehbniicd ero Ta: CoHaneaN CoHansN > nCOr + (RE4SIELO + 0,5N2 0,15 — 0,15n > 0, Ig 5) = 0,075 = neor + mizo + ny2 = 0,151 isa + | 1,5) + 0,075 = 1,2 =n=3 3X: GHN Dong phan bac I cia X: cuscqiccig 2; CHs-CH(NH2)-CH3 = C62 déng phan bac I ciia X \ ¥_ Chon dap an A ¢ Cfiu 9: C2HsOH cé tén goi la c A. etylen glicol. B. glixerdt“—> C.ancol metylic D. ancol etylic. Cu 9: Chon dap an D c «Loi gi: Phurong phip gi Dua vio danh phap ciia ancol. Giai chi tiét: CoHsOH cé tén goi la ancol etylic. Chon dap én D Céu 10: Metyl axetat 06 cng thite Th A. HCOOC2Hs, B. CHyCOOCH 5, CHsCOOCH=CHp, “sHsCOOCHS. ‘CAu 10: Chon dap an B & Loi gidi Cau 13: Vio mia dng, nhitu ga intr dung bép than dat trong phong kin dé sudi dm gay ng@ dc khi, e6 thé din ti te vong. Nguyen nhani ganda ldo khi nao sau diy? ANd C.0s D.CO. C4u 13: Chon dp an D Loi gidi: Phuong phép giai \< Dye vao ly thuyét héa hoe voi i ma) Giai chi tiét: at than sinh ra kh dge, khi dje 46 se ¥_ Chon dip an D Ysa Cu 14: S6 céng thie cau tao cua dipeptit® ih tao tir | g6c Ala va I goc Gly li A.2 B.3 at, C.5 D.4 Cau 14: Chon dp an A a & Loi gid ~*~ Phuong phép giai iO} Se eg No) chi tiét: oN Ala-Gly va Gly-Ala fad) = 2 dong phan ae! ¥_ Chon dap an A - Cau 15: Cho cde chat sa sang mau xanh la A. Céu 15: Chon dap dn B & Loi gi Phuong phap giai: Sw déi mau ctia quy tim khi gap amin, amino axit: *Amin: - Amin ¢6 nguyén tir N gin true tiép vai vong benzen 6 eS yéu, khong lim di mau quy tim. - Cc amin khéc lam quy tim chuyén xanh. L *Amino axit: . \ - SO nhém NH2 = so nhom COOH = Khéng lam doi mau to } - So nhém NH} > s6 nh6m COOH = Lim quy tim héa xanh - $6 nhém NEP < s6 nhom COOH = Lam quy tim héa do ( sm chi tiét: : si (OQ) Cée chat lam quy tim chuyén xanh g6m lysin, amoniac, metylamins) ¥ Chon dap an B 4 Céu 16: Chat nao sau day cho phan tmg tréng bac? SS A. HCOOCH. B. CH3NH2. CCl COCA. D. CH3;COOH. Cu 16: Chon dap an A ss Loi gia: an Phuong phap giai >) Hap chat hitu eo chtta nhém chite ~CHO c6 kha nang tham gia phan img trafig baet Giai chi tid ms Chat cé phan img trang bac la HCOOCH3 ¥_ Chon dap an A Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang &300 DE THI THU THPTQG 2022 (GIAI CHI TIET) iw 17: Cho diy cde chgtaphenyl axctat, metyl axetat, etyl fomat, tripanmitin, vinyl axetat. S6 chat trong day khi thay phan trong dyag’dicb°NaOH loang, dun néng sinh ra ancol la AA, ( Be C3 D.2 Cau 17: Chon dip age a Loi gid oO) Tir tén goi = cong hie i chit = viét PTHH dé xéc dinh san phim, Giai chi tiét: oA CH3COOCsHs + 2Na0eS » CACOONa + CoHsONa + H20 => Logi phenyl axetat on. CH3COOCH: + NaOH jGQONa + CH;OH = Thoa man ‘metyl axetat és ~ HCOOC:Hs + NaQH > H&QONA™ C:HsOH = Thoa man cetyl fomat Le (CisHs:COO);C3Hs + 3NaOH To SCAHsICOONa + CsHs(OH); = Thoa man tripanmitin —. CH3COOCH=CH: + NaOH > rege CH:CHO = Logi vinyl axetat \/} ¥_ Chon dip an C (Cau 18: Cho 8,1 gam Al phan img hoan foga N&i'khi Clo dur, thu duge m gam mudi. Gia tri ctia m 1a A, 36,07. B. 26,04, C. 40.05. D. 7.64. Cu 18: Chon dap an C & Loi giai: nal Al + 1,5Ch to>—10 AICI a 03 = 03 C-—~ = marcy = 0,3.133,5 = 40,05 gam a) ¥_Chon dip an C oy Cfiu 19: S6 nguyén tir cacbon trong phan tir saccarozo & AL B.12 D.6 Cu 19: Chon dap an B & Loi gidi: Phuong phap giai: Dua vio c6ng thite phan tir saccarozo. chi tiét: CTPT saccarozo la CiH22011 ¥_ Chon dip in B CA 20: C6 cde chat sau: (1) tinh bot; (2) xenlulozo; (3) saccarozo;(4-fuctozo. Khi thiy phan cde chat trén thi nhimg chat chi tgo thanh glucozo Ia: ALBA. B.2, 3. Cc... D.1,2. Cau 20: Chon dap an D Loi gidi: Phuong phap giai: Dua vio cau tao cic chat, Giai chi tiét: Nhiing chat khi thiy phan chi tgo glucozo Ia (1) tinh b6t, (2) xenlulozer ¥_ Chon dap an D Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 9300 DE THI THU THPTQG 2022 (GIAI CHI TIET) ‘Cau 21: Phan tir polime nio sau day c6 chita nito? A. Poli(vinyl clorua). B. Polibutadien, C. Poli(metyl metacxytat}, D. Poliacrilonitrin. Cau 2: Chon dip fP- xs L6i gid Ee —\ Phuong phap gi Dia vao céu tao a Giai chi tiét: os Phan tir polime 06 chig‘nite-ti poliacrilonitrin [CHs-CH(CN)-In. ¥_ Chon dap an B-~ Cf 22: To nao dusi day thu A. To nilon ~ 6.6. C. To axetat D. To tim. Au 22: Chon dap dn C & Loi gid Phuong phap giai: Dya vio ly thuyét Giai chi tiét To mhan tao la to axetat, ¥_ Chon dap an C Cau 23: G nhigt d6 thudng, kim loai Peta€ dung duge v6i dung dich nao sau day? A, NaCl. B. Cu(N@sp~ C. NaOH. D. Mg(NOs)p. Cau 23: Chon dap an B we) Loi gidi: am Phuong phap gi : f ob ly Dua vio tinh chit héa hoc cba sit. Gii chi tiét: G nhigt 46 thudmg, kim loai Fe tic dung oe dich Cu(NOs)>. = Fe+Cu(NOsp > Cul + Fe(NOsp KOS ¥_ Chon dap an B = a CAu 24: Aminoaxit la hop chat hifu co tap chite, gh A.— NH vi— COOH. _B, ~ OH va ~ NH.” D.—OH va — COOH. Cu 24: Chon dap dn A & Loi gid Phuong php gidi: Dua vio edu tg0 cia aminoaxit. Giai chi tiét: Aminoaxit ld hgp chit hitu co'tap chite, chita déng thoi om va-COOH ¥ Chon dap an A (Tak) Cau 25: Cho _B. 6, (Cu 25: Chon dap an Loi gid: Phuong php gidi: Cée chat téc dung duge voi Cu(OH)> & nhigt d6 thudmg la axit Goan co chita nhiéu nhém -OH lién kg, peptitchira 3 mit xich ta Ién, protein. ta) chi tiét: C Céc chat tic dung véi Cu(OH)» 6 nhigt d6 thudmg la ling tring tring, glixerol, axit axetic, saccarozo. ¥_ Chon dap én C Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 10300 DE THI THU-THPTQG 2022 (GIAI CHI TIET) (Ci 26: Hon hop X gdm propin, buita — 13 — dien va mOt am in no, don chire, mach hd. Dem dot chay hodn toin 23,1 gam X ean ding vira'@Gng’2,75, mol 2 nguyén chat thu duge hén hgp san pham Y gom CO: N2. Dan toan b6 Y qua biniychita, dutig dich NaOH dac du, khi thoat ra do duge 2,24 lit (6 dktc). Cong thite cua CAG. C. CsHoN.. D. CHiN. = X: CaHy (a), CyHo (b) va cond Ser = mx = mess + mesis+ Manin (YA +) nor = 4.ncans + 5,5.ncins + (1,51 175 ,adhin Q. Chon gia trj cla n phi hgp véi a,b. Giai chi tiét: ic 1 = Manin = 0,2 ig = X: CaHs (a), CsHo (b) va CoHansN 0, a, = mx = mess + Mess + Manin = 23, NS “oa S4b + 0,2.(14n + 17) +) noo = 4.ncsis + 5,5.ncsne + (1,50 + 0,75) Foe, = 2,175 = 4.a + 5,5.b + (1,5n + 0,75).0,2 § SS) Chon n= 1 = a=-0,05; b=-0,35, Sy n=2=9a=b=0,15 — = CHIN (mah ~ ¥_ Chon dap én B = Cu 27: Trong cde chat dudi day, chat nio la dipeptip>—I>\, ‘A. EDN ~ CH ~ CO ~ NH ~ CH(CHs) ~ COOH. B.ILN - Cth,~ CO - NIT CH(CH)~ CO- NH ~ CH - Cl Phuong phip giai: C- Cée a-aminoaxit lién két véi nhau tgo thinh peptit. Dien smi xich o-aminoaxit va 1 lién két peptit. Giai chi tiét: ©} Dipeptit li H3N-CH2-CO-NH-CH(CH3)-COOH. Aes ¥_ Chon dap in A ‘C4u 28: Cho m gam hon hop gdm cée triglixerit tic dung voi dung dich’NaOH (vira di), thu duge hon hgp mudi X gdm CnHxCOONa, CnHyCOONa vi CisHsiCOONa (c6 ti Ie mol, tigolg tmg la 3 : 4 : 2), Dét chy hoan toan X cin vira dui 4,47 mol Oz, thu duge NaxCOs, H2O va 3,07 mol CO2. nnwou = 30+ 4a +2a=9a => BINT Na: nxa2cos = 4,54 el BTNT C: 18.nci7ixcoona + 18.nc17HyCooNa + 16.NC15431COONa = Neo? + Nats => a BINT O = nino = BTKL: mmudi = mi20 + Mco2 + MNazco3 - Moz Ta e6: nesus(o1s = 1/3.nxson = BTKL: m= mauéi + means(on3 - MNoHt Giai chi tiét: X gém Ci7H\COONa (3a), Ci7HyCOONa (4a) vi CisHs}COONa (2a) Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 ‘Trang 11300 DE THI THU THPTQG 2022 (GIAI CHI TIET) = nnaon = 3a + 4a + 2a=9a => BTNT Na: nxaacos = 4,5a BINT C: 18.3a5?184a + 16.2a = ncor + nvazcos = 3,07 +4,5a => a= 0,02 BINT O: nfizo.=2:8-0,02 + 2.4.0,02 + 2.2.0,02 + 4,47.2 - 2.3,07 - 3.4,5.0,02 = 2,89 = BTKL: Mndyi.ingh + mco2 + mysacos - mo2 = 53,6 gam Ta c6: nesisiS}3=] 7 nxsou = 9.0,02:3 Cfu 29: Tién hanh ring p | mol etilen 6 diéu kién thich hop, dem san pham sau tring hgp tac dung voi dung, dich brom du thi Lug img 1a 36 gam. Higu suat phan tg tring hgp va khoi Iugng polietilen (PE) thu duge A. 70% va 23,8 gami, “77.5% va 21,7 gam. C. 77,5 % va 22,4 gam. D. 85% va 23,8 gam. CAu 29: Chon dap an B, £ L6i gidi: Phuong phép gi n.CH2=CH2 E> CH2=CHb x + Br Br Aconeta = 1 mol; nears a= Hoye) \ = ners pu = noe \ n.CH2=Clb to,p,xt-———K10, CH2=CHo a + Br: > Br-CH2+ neana ba = 1 mol; ne2Hs ae = Nee = neous pa = 1 - 0,225 = 0,775 = Phe => H=0,775:1.100% = 775%. mpe = 0,775.28 = 21,7 gam. Chon dap én B (CA 30: Nhin dinh nao sau diy 1a dmg? AA. Phan tir amilozo ¢6 mach phan nhiinb, Khang duerthing ma xodn nh 10 xo. B. Anilin la mot bazo nén kim quy tim chuéerSéng.anu xanh, . Trong phan tir peptit mach ho Gly ~ Ala "vale nguyén tir oxi. D. M@ Ign hote dau dira cé thé ding lam ngugn Jigd dé sin xuat xa phong. Cfu 30: Chon dap an D (0) © Loi gid Phuong phép giai Dua vio ly thuyét vé chat béo, cacbohidrat, amin, ee ~ Gili chi tiét: { Q \ A sai, amilozo c6 mach thing. B sai, anilin c6 tinh bazo yéu va khong lim d6i mau aim. C sai, Gly-Ala-Val e6 4 nguyén tir oxi. , D ding, més lgn chira céc chat béo 6 thé tham gia phan ine So hing hhéa tao xa phong ¥_ Chon dip én D =" ~ Ala Gly ~ Ala va Val~ Gly ~ Gly uot la (Cfu 31: Thuy phan hoan ton m gam hon hgp oligopeptit gom_ \ Ala thu duge X gam Ala; 37,5 gam Gly va 35,1 gam Val. Gid tri ciia mie A. 99.3 va. 30.9. B. 92,1 vi 26.7. C.84.9-Va 26,7. D.90,3 vi 30,9. ‘Cau 31: Chon dap an C — Loi gidi: Phuong phip gia: Dit sé mol cua Ala-Val-Ala-Gly-Ala va Val-Gly-Gly lan lugt la a va b. ney =a+2b va nva=atb Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 120 DE THI THU THPTQG 2022 (GIAI CHI TIET) Sab. Sas 3a x= 26,7 gam, Giai chi tiét: Dat s6 mol ciia Ala-Val ie Lip va Val-Gly-Gly lin lugt 1a a va b. ¥_ Chon dap an C urge tao thanh tir cde monome tuong tng la COOH. Céu 32: Poli(metyl metacrylat) va nilon = ‘A. CH ~ COO ~ CH=CH va mec B, CH:=C(CHs) ~ COOCHS vi HX Ae; ign dap dn C 2 Loi gidi: Phuong phap gia Dua vao ly thuyét vé polime. ii chi tiét: ™, Poli(metyl metacrylat) va nilon-6 duge ‘ao gang ie monome tung img la CH2=C(CHs)-COOCH, va HpN-{CHa]s-COOH. es ¥_ Chon dap én C y Cau 33: Dot chay hoan toan mot hong hon hop X\chuie glucSza, fructoza, xenluloza va metyl fomat can ding. vita dit 28 lit khi Oo (dkte) thu due CO2 va HO. Cho tedif b6 sin phim chay qua dung dich Ba(OH)? dur thay c6 m gam két tia xuat hign. Gid trj cla m la an A. 291,25 B. 310,86. D. 246.25. Céu 33: Chon dap dn D & Loi gi Phuong phép giai: Xét thay hén hgp X cae chat déu c6 dang C(H20)n. = C,(H20)m + nO2—+ nCO;+ mH0 oz = Noor = Mascos = flco2 => Mnacos. chi tiét: fioz = 1,25 mol. ei Xét thay hén hop X ede chat déu e6 dang C,(H2O)m. = C,(H20)m + nO2—> nCO; + mH;0 125 — 1,25 = nncos = neor = 1,25 mol = mnicos = 246.25 gam. Chon dap én D 3 Cu 34: Polisaccarit X 1a chat ran dang soi, mau tring, khong mbi vi. X € shiéy trong bong ndn, go, day, gai... Thay phan X thu duge monosaecarit Y. Phat biéu nao sau day ding? A. Y khang tan trong nude. B. X cé cau tric mach phan nhénh C. Phan tir khdi cia X 1a 162. D.Y tham gia phan img véi dung dich AgNOs trong NH tao ra amoni gluconat. CA 34: Chon dap an D & Loi git Phuong phap giai: thukhoadaihoe.vn CO CAN FILE WORD LIEN HE: 085.23.23.888, Trang 13300 DE THI THU THPTQG 2022 (GIAI CHI TIET) ‘Dua vao dé bai xac inh XY, r9ethon phat biéu dit Giai chi tiét: ee X li xenlulozo va Y la ghifeo#o. < = Asai vi glucozo tan dive a) nude. B sai vi xenluloza 6 cai ricahgch khong phan nhanh, C sai vi PTK cia oitoyeibon 1a 162n. D ding, ¥_Chon dap an D = mn Cu 35: Dun néng 14,8 gam hon hop X_gorm (CHsCOOCH:, HCOOCAH. 1,0M va KOH aM rang fig vira da) thi thu duge 4,68 ©,HsCOOH) trong 100,0 mi dung m hdn hp hai ancol (ty 1G mol 1: 1) C. 14,96, D. 19,72. Phuong phap giai: Vi 2 ancol ti lé 1:1 => newon = ne2Hs0H x fc >} => Manco > X = neycoocts = mricoocarts = x ® Mx =74=9 nx => NC2HSCOOH = NX - NCHICOOCHS - NHCOOC2HS ‘S naoti + MKOH = Nx => NKOH = Nx = No \, NeaHsCOOK \O ao BTKL: mauéi = mx + mycoH + MKoH = MH20 - Ma Giai chi tiét: ‘Vi 2 ancol ti 1é 1:1 = ncuson = nc2nson = xX = 32x + 46x = neuscoocts = nucoocaris = 0,06 Mx =74 => ny 14,8:74 = 0,2 = neauscoow = nx = Ncuscoocis = MuCoOCaHS = 0.2 = 0,060.06 = NaOH + NKOH = NX => NKOH = NX - NNO. ha = neauscoon = 0,08 Sate centre err inne Teel = A Gere 0,1.56 - 0,08.18 - 4,68 = 18,28 gam. ¥_Chon dip in A (Oj Céiu 36: Trong phong thi nghiém, etyl axetat duge diu ché theo sac Buée 1: Cho | ml CHsOH, | ml CHyCOOH nguyén chat va. gi6t H280s dae vao dng nghigm, Buse 2: Lac déu, dong thoi dun cach thay 5 ~ 6 phut trong ndi nude Tong 65 — 70°C, Bude 3: Lam lanh réi rét thém vao Sng nghigm 2 ml dung dich NaC], ba hoa. Cho ede phat biéu sau, phat biéu ding li c A. Sau bute 2, trong éng nghiém vin con C2HsOH va CHsCOOH. B. Dé higu suat phan img cao hon, ta nén ding dung dich ancol 10°, C. Dung dich NaCl bao héa duge thém vio éng nghiém dé phan img, D. Sau bude 3, chat long trong dng nghiém tao dung dich dong nhat, (Cau 36: Chon dap an A phan img este héa Giai chi tiét: A ding. B sai, dé dung dich c6 higu suat cao cin ding dung dich ancol c6 46 edn cao, sai, trong thi nghigm thiy phan este trong moi trudng axit khdng cin NaCI bao hoa. D sai, sau bude 3 chit long trong éng nghiém phan lop Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 14300 DE THI THU THPTQG 2022 (GIAI CHI TIET) Chon dap an A (Cfu 37: Hoda tan hoan foah in gam hn hgp A gdm Fe va Cu vio 96.00 gam dung dich NOs 5 kim logi tan hét thu deg dung dich z. Loc liy Sing trong khdng khi dén khoi Tugng khong ddi thu duge 20,00 gam chat rin. C6 ean dung dich Z duge chat rip FO Iugng khéng 46i thu duge 49,55 gam chat rin. Nong a6 phin trim ctia mudi Fe(NOs)s 6 trong dur 4 sau day? A. 16% [Be C.14% D.18% Cau 37: Chon dip in B ( -~ & Loi giai: Phuong phap giai: —\ Dit: nre = a; Neu = b => Ss Yi = 0,50 = Min tgs VA Mont = a; b. Tit manitsin = Hon hop rin foi ‘va KOH du. = NKNo2 + NKOH du = NKOH bd “ipes MKOH du = Mein = DKNO2; NKOH de ) Gia sir trong X cé ca mudi Fe** Se [Fe (y) => HNOs hét = manos = ny ai + NOS = AN Gi hese = = mw aah = 0,25 +) npe’” + ne?” = ne val MNOS" (to ms SS + 2.npe"” + 2.ney"* =xy BT e: 3x +2y +2.0,1 + 2noany = 5. “Ry” => Mad x = MKL + Mad HNOS - Mekhi = C%ranos = chi tidt: e> a Dit: nee = a; icy = b = nF<203 = Y4 Me = = 56a + 64b = 14,8 va 160.0,5a + 80b = a=0,15;b Gia sit Z chi c6 m NOs = chit rin thu she aa img la KNO> = non = neon = 0,6 => manor = 51 # 49,55 eA = Chat rin gm KNO» va KOH du. OB => nkno2 + KOH de = NOH ba = 0,6 va 85.nkNo2 + Seid, 55 => nko = 0,55; nKoH du = 0,05 Gia sir trong X e6 ci mudi Fe" (x) va Fe’* (y) => aoe a => DHN03 = DN (kh) + MNOS” = TN (kh) + DKNOZ 08 = My 949 + 0,55 = my any = 0,25 +) x+y=0,15 va mNos (mo moti = 3x + 2y +2.0,1 =osh (O) ) = x= 0,05; y= 0,1 —. BT e: 3x +2y +2.0,1 + 2noany=5.0N ani) a = = no ain = 035 OY = maax = MeL + maa ANOS ~ Muni = 14,8 + 96 - 0.35.16 - awn 7 gam => C%reaios)s = 0,05.242:101,7.100% = 11.9% 4 ¥_ Chon dap én B Céiu 38: Hon hop X gom alanin, axit glutamic va hai axit cacboxyli¢ né;can chitc, mach ho, ké tiép nhau trong diy dong ding. Cho m gam X tie dung vira dit véi $00 ml dung dittrNaOH 1M thu durge 42,45 gam hén hop mudi, Mat khde, dot chay hoin toan m gam X edn ding 21,00 lit kl Cho sin phm chay qua dung dich O, dic, dur thu duge 22,96 lit hn hgp khi CO> vi N> (biét cdc thé teh Khi Yo 6 digu kign tiéu chuan). Thanh phan phan trim theo khdi long ciia axit cacboxylic cé phan tir khdi lénihop-trong X la B. 19,08%. C. 23.37%,“ D. 29,25%. Phuong phap giai: C3H;NO2 = CH, + CH2 + NH + COO Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 15300 DE THI THU THPTQG 2022 (GIAI CHI TIET) (CsHoNOy = CH + 2CH2 + NH +2COO CoHa102 = CHy 430+ COO = Quy ddi hin ee x thanh: CHs (a); CHo (b); NH (c) va COO nooo = nxson hwo” = BTKL: my 1 Ae myion (1). +) m2 = 0.5.00 pie + nei + neo => nen = Na + +) noz = 2neus + 1; eee .25.nvu (3). = ab; ¢ = nesvoa + resins > max= news ~ MN +) 100 (amino ast) + NC ee EAC => Nesiirno2s NesiieNos = BINT C: 3.ncatrrsor € shed, + (6 Crp axit)-Max = Noo? = 86 Croan = 2axit, “7 = %maxcsrrKunton, — Giai chi tiét: ¢:. (C3H;NO? = CH, + CH2 + NH COI (CsHyNOy = CHy + 2CH2 + NH +(3C (CxHz02 = CHs + CH + COO \” = Quy ddi hn hop X thinh: cH (b); NH (©) va COO ‘ooo = nNson = 0,5 = N10 QS = BTKL: mx = mms + miz0 - m = 16a + 14b + 15¢ + 0,5.44 2.4550: - 0,5.40 = 31,45 (1). +)nx2 = 0,5.nnu = 0,5¢; ncor = nena neil) iaitip =a +b +0,5 = moh uw = nn2 + cor => 1,025 =a + ee 5 (2). +) nor 2acn +150 + 0.25, nn =" 2a + 1,5b+0,25e (3). = a=0,45;b = ncwso2 + Nestonos = myn = 0,15 ay gts nelipacs Pango 02 = neaurno2 = 0,15 estpxos = 0,05 = BINT C: 3.ncsi7o2 + S.ncstionos + (86 caeaias Teo 3.041 + 5.0.05 + (86 Croat) 0.3 = 1,025 - 0,075 5-095 = 1< 86 Crp ai = 1,333 <2 = HCOOH va CHOON, = macoon + ncxscoon = 0,3 va mucoon + 2ncuscodu€ 04} = mucoon = 0,2; nciacoon = 0,1 eat J = Yomcuscoon = 0,1,60:31,45.100% = 19,08% as ¥_ Chon dap an B ico CAu 39: Hon hop M gm hai este: X don chiie va Y haichBc(X, Y chi chita nhém chite este, mach hd). Dot chay hoiin toi a gam M trong oxi dur thu duge HO va 2,5-ripl CO>. Mat khée, a gam M tée dung vita dit véi dung dich NaOH thu dugc 47,2 gam hén hgp Z gm 2 mudi ¥arhrtfigp T gdm 2 ancol (2 ancol déu cé kha ning tich nude tao anken), Bot chay hoin toan 47,2 gam hon hop 2 thet due HO; 37,1 gam NaxCOs va 15,4 gam CO», Khdi lugng cua Y trong a gam M ki A348 B. 22,2. C.29.2—" D.32.0. ‘Cu 39: Chon dap an A a) & Lii gidi: , Phuong phap giai: Ve 1002 aie M) = 2,5 mol; Ma2cos =? NNsoHt = 2M\s2003 = NCOO = MoH ano) Vi 2 ancol déu c6 kha nang tach nude tao anken => ancol don chite (# CH;OH) Ton (ancod TNs2cos + Nco2 (air mai) => Cong thite 2 mudi Website: thukhoadaihoe.vn THAY CO CAN FILE WORD LIEN HE: 085.23.23.888 Trang 160 DE THI THU THPTQG 2022 (GIAI CHI TIET) = $6 mol moi mudi = neste +) Nc (ancl) = NCC out = S6 Cr at cpap thiic 2 ancol = Sé mol nigigind € = Cong thite = my. Giai chi tiét: co2 de M - Txspton = 0,35 = mason = 2nxs2c03 = 0,7 = Ncoo = Nou (ans Vi 2 ancol déu c6 Khachiingytaich nude tao anken => ancol don chite (+ CHsOH) = Naneot = NOH anon E01 Nc (asi) = NNszcos * Moe TE ae 0,35 + 0,35 = 0,7 = ncoo = Trong mudi c6 s6 a => 2 mudi li HCOONa va (COONa): = miicoona + 2n(coonaj ¥4L.68.niiCOONa + 134.n(cooNa)2 = 47,2 = mnicoons = 0,3 va ncfvert=0, 3 +0,2=0; ae et => S6 Crp ancoi = 1,8:0, Isgtm 6 ancol CHsOH +) Gia siz: 2 ancol la CoHSOHW@CyfhOH = noousou + nesw70n = 0,7 oa + 3.ncsnron = 1,8 = neausou = 0,3; nesinon = 0,4 = 2este li HCOOCHs (0,3) Of aledocm: (0,2) (x) = my = 34,8 gam. po) a Chon dip CAu 40: Hon hop T gom ba este X, Y, £ (WE)-IM§,< Mz < 150) déu e6 cOng thite phan tit dang CH,,0, . Bot chay hoan toan m gam hén hgp T edn vi (di, 53:76 lit oxi (dktc), sau phan img thu duge nude va 96,8 gam CO». Néu xi phing héa hodn to’n 19,9 gam honamp {Tein vita dui dung dich c6 chita 0,25 mol NaOH thu duge phan itu co gdm hai ancol vi 24,05 gam hon bo Rent 3 3 mudi G, U, V (80 < Mo < Mu < My). Cho cae phat biéu sau a) X c6 kha ning tham gia phan img ia ‘Goon b) ¥ chiém 27,64% vé khdi long trong B; \ c) G va U li mudi cila axit cacboxylic no, dowtl 4) Trong M, mudi u chiém khdi Ivgng lén nha e) Z 66 bin cong thite céu tao théa min, v 'Sé phat biéu dang 1a A. 3. B.4 D.2 Cfu 40: Chon dap an D & Loi gic Phuong phap gi ie 3 este li CsHsO2 (X); ColleO2 (Y); CxHs02(Z) AS} V Vi thu duge 2 ancol va 3 mudi G, U, V (80 < Ma < Mu eNO = Cong thite este lan lugt \- X: CH=C-COOCHs ; Y: CH=C-COO-CH2-C=CH ; Z: Cl +) Xét TNI: no»; ncor = niz0 = 0,5.ncoz . => BTKL: mr = mo + mino - mor BTNT O: 2.nr = 2nco2 + nino - 2.nor => nr +) Xét TN2: mr= 19,9 gam = nr Dat: nx =a; ny =b; nz=¢ =atbt+e=nr +b+2c thukhoadaihoe.vn CO CAN FILE BN HE: 085.23.23.888 Trang 17DE THI THU THPTQG 2022 (GIAI CHI TIET) chi tigt: 3 este lt CaHsO> (X); CeHeO2 (¥); CsHsO> (Z) Vi thu duge 2 ancol yg 141 G, U, V (80 < Mo < Mu < Mv) = Cong thite este Tan Jr X: CH=C-COOCHS_Y+€H§C-COO-CH2-C=CH ; Z: CHsCOOCsHs +) Xét TNI: nox xa, 2 => nao = 0,5.nco2 = 1,1 = BIKL: mr= moo3-+ahigh - mo2 = 39,8 gam BINT O: 2.nr +) Xét TN2: mr Dat: nx = nc cm = 4a + 6b + Be = 2,2: = a= 0,05; b= 0,05; ¢ = my = meuec-coons = 9,2 (a) sai. (b) dung. (©) sai. (d) ding. (e) sai. ¥_ Chon dap én D thukhoadaihoe.vn (085,23.23.888 Trang 18