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C. Y. Wang
the superhydrophobic surface, and z is the distance from the enve-
Department of Mathematics, lope of the surface into the liquid. The coefficient K is known as
Michigan State University, the temperature jump coefficient, which depends on the micro-
East Lansing, MI 48824 structure of the surface, but not on the temperature field itself.
This linear temperature jump condition is supposed to be valid for
heat transfer problems in which the nonlinear effects due to inertia
Mathematical models are developed for heat conduction in creep- and convection are negligible near the surface. The temperature
ing flow of a liquid over a microstructured superhydrophobic sur- jump coefficient, which has the dimension of length, can also be
face, where because of hydrophobicity, a gas is trapped in the interpreted as the temperature slip on the surface per unit tempera-
cavities of the microstructure. As gas is much lower in thermal ture gradient near the surface. It is analogous to the effective slip
conductivity than liquid, an interfacial temperature slip between length in Navier’s velocity slip condition for flow over a superhy-
the liquid and the surface will develop on the macroscale. In this drophobic surface.
note, the temperature jump coefficient is numerically determined Similar thermal interfacial conditions involving temperature
for several types of superhydrophobic surfaces: a surface with jump have been investigated in the context of heat transfer at the
parallel grooves, and surfaces with two-dimensionally distributed boundary between a fluid layer and a porous medium [3,4]. There
patches corresponding to the top of circular or square posts, and have also been some studies on thermal transport in a channel
circular or square holes. These temperature jump coefficients are composed of superhydrophobic walls (e.g., Refs. [5–9]), but these
found to have a nearly constant ratio with the corresponding works are mainly concerned with, in the context of convective
velocity slip lengths. [DOI: 10.1115/1.4026499] heat transfer in a channel, the effect of a superhydrophobic surface
on the reduction in drag (as represented by the friction factor) and
Keywords: temperature jump, superhydrophobic surface, heat reduction in heat transfer rate (as represented by the Nusselt num-
conduction ber). They can be regarded as macroscale analysis because they
solved the full momentum and energy equations in their problems.
1 Introduction No analytical work seems to exist in the literature that particularly
looks into the thermal jump boundary condition on a superhydro-
Velocity-slip and temperature-jump boundary conditions have phobic surface from a microscale perspective. Our objective here
long been known and intensively studied for rarefied gas flow. Ve- is to perform such a near-surface asymptotic analysis, which
locity slip and temperature jump are also of significance for flow yields upon averaging over the microscale an effective coefficient
of a liquid over a superhydrophobic surface, where the cause of for a jump boundary condition to be used in a macroscale
slip is different from that in gas flow. While the hydrodynamic analysis.
slip for superhydrophobic surfaces has been drawing much atten- In this note, we determine the temperature jump coefficient for
tion in the past decade (e.g., see recent reviews by Rothstein [1] several types of superhydrophobic surfaces: a surface with parallel
and Vinogradova and Dubov [2]), the temperature jump for grooves, and surfaces with two-dimensional patterns arranged on
superhydrophobic surfaces has nevertheless received much less a square lattice. For these micropatterned surfaces, the hydrody-
attention than it deserves. namic slip properties have been studied by many authors (e.g.,
A superhydrophobic surface is an engineered surface featuring Choi et al. [10], Maynes et al. [11], Ybert et al. [12], Lee et al.
micropattern or nanopattern, such as grooves, posts, cones, turf, or [13], Teo and Khoo [14], Ng and Wang [15, 16], Ng et al. [17],
holes. If the surface is made of hydrophobic (i.e., nonwetting) ma- Lund et al. [18]).
terial, the voids in the microstructure will not be filled with liquid Using the analytical method of eigenfunction expansion where
until the capillary pressure is exceeded. In this so-called Cassie the coefficients are determined by matching of solutions on the
(fakir) state, the liquid flow is restricted to the top of the micro- liquid–solid and liquid–gas interfaces, we shall numerically obtain
structure, and the cavities in the microstructure are filled with gas the temperature jump coefficient as a function of the solid area
which offers little resistance to the flow. Hence, the liquid experi- fraction for each of the patterned surfaces considered. In the case
ences mixed hydrodynamic boundary conditions on approaching of grooved surface, the heat transfer in both liquid and gas phases
the surface: no-slip on the part of the liquid being in contact with is considered, and hence the groove depth and the ratio of thermal
solid, and nearly no-shear on the part in contact with voids. It is a conductivities are also parameters affecting the temperature jump
spatial average of these micro-effects that will lead to an effective coefficient. In the case of two-dimensional patterned surfaces, we
velocity slip on the macroscale. shall for simplicity assume that the gas phase is perfectly noncon-
As the thermal conductivity of gas is much lower than that of ducting, and hence the surface is simplified to be a plane surface
liquid, the gas pockets on a superhydrophobic surface also give with mixed boundary conditions. Our results show that the tem-
rise to thermal insulation of the surface from the liquid. Hence, perature jump coefficient can increase sharply as the solid area
the liquid also encounters mixed thermal boundary conditions on fraction of the surface diminishes.
1
Corresponding author. 2 Surface With Parallel Grooves
Contributed by the Heat Transfer Division of ASME for publication in the
JOURNAL OF HEAT TRANSFER. Manuscript received March 26, 2013; final manuscript
We first consider two-dimensional heat transfer near a superhy-
received January 13, 2014; published online March 7, 2014. Assoc. Editor: Robert drophobic surface, which is made up of parallel grooves of the
D. Tzou. microscale. Figure 1 shows a cross-sectional view of one periodic
The coefficient T^0 is the average temperature jump over the sur-
face. Back to the dimensional quantities, we may express the tem-
perature jump as linearly proportional to the far-field temperature
gradient:
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@T
T0 Ts ¼ K asz L (8)
@z
Fig. 1 Cross section view of one periodic unit of a grooved sur-
face, where the cavity (Region I) is filled with a gas, the solid rib
where K is the temperature jump coefficient, which has dimen-
(shaded area) has a constant temperature Ts, and the space sions of length. Using Eq. (2), this jump condition gives that the
above the surface (Region II) is occupied by a liquid with a con- nondimensional temperature jump T^0 is simply equal to the nor-
stant far-field temperature gradient. The period length is 2L, and malized temperature jump coefficient
the cavity has the dimensions of b for depth and 2a for width.
T^0 ¼ K^ (9)
unit of the grooved surface. The Cassie state is assumed: the liquid
interface is restricted to the top of the solid ribs, and the cavity
where K^ ¼ K=L is the temperature jump coefficient normalized
between the ribs is filled with a gas phase. The meniscus is
by half the period length L. Like the hydrodynamic slip length,
ignored, and the liquid–gas interface is idealized to be a flat sur-
the temperature jump coefficient can also be regarded as a thermal
face without penetration into the groove. As shown in Fig. 1, the
slip length, the depth into the envelope of a surface at which the
domain is decomposed into Regions I and II, which are filled with
temperature difference would extrapolate to zero.
a gas and a liquid, respectively.
The unknown coefficients in Eqs. (4) and (6) are determined by
The period length is 2L, and a cavity has the dimensions of 2a
imposing matching conditions on the interface of the two regions.
(width) and b (depth). Assume a constant temperature, Ts, on the
First, the continuity of heat diffusive flux across the liquid–gas
solid surface, and a constant temperature gradient, ð@T=@zÞ1 , at a
interface gives
distance sufficiently far from the surface z L (but still very
close to the surface from a macroscopic view of the surface).
Based on these quantities, the following normalization is intro- @ T^II @ T^I
¼ kr on 0 x^ a^; ^z ¼ 0 (10)
duced (distinguished by an overhead caret) @^z @^z
In Region II ðj^
xj 1; 0 ^z < 1Þ, the solution that satisfies the where 1 m N, and 1 n M. Next, for m ¼ 1; …; M, we
^ x ¼ 0 at x^ ¼ 0, and (ii) @ T=@^
boundary conditions (i) @ T=@^ ^ z¼1 multiply Eq. (11) by cosðb^m x^Þ, which is then integrated with
as ^z ! 1, is given by respect to x^ from 0 to 1. The resulting equation is
X
N agreement with this analytical formula (symbols). Hence, in this
^
2 1 e2^an b Inm An Bm ¼ 0; m ¼ 1; …; M (14) limiting case where the gas is assumed to be perfectly nonviscous
n¼1 and nonconducting, the temperature jump coefficient is identical
to the longitudinal velocity slip length. As expected, kr ¼ 0 gives
Finally, by integrating Eq. (11) itself with respect to x^ from 0 to 1, the maximum possible jump coefficient for any given value of /s .
we get an equation for the temperature jump For a more realistic value of kr ¼ 0.04, the jump coefficient is
X
N
An ^
T^0 ¼ ð1Þnþ1 1 e2^an b (15)
n¼1
a^n
modestly reduced (by less than 10%) for not too small of the solid periodic unit of the domain over the surface. The constant temper-
area fraction /s > 0:1. For a very small solid area fraction, say ature on the solid surface is denoted by Ts, and the temperature
/s ¼ 0:01, the difference in K^ between kr ¼ 0 and kr ¼ 0.04 can gradient, ð@T=@zÞ1 , at a distance sufficiently far from the surface
be as much as 20%. As kr further increases, or the gas phase z L (but still very close to the surface from a macroscopic per-
becomes more conducting relative to the liquid phase, the temper- spective) is also constant over the surface. Based on these quanti-
ature jump coefficient will be further reduced. ties, the following normalization is introduced (distinguished by
an overhead caret)
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As in the two-dimensional problem, the coefficient T^0 is the aver- as a function the solid area fraction of the surface. For grooved
age temperature jump over the surface. Hence, Eqs. (8) and (9) surface, the jump coefficient becomes unaffected by the groove
are also applicable here: T^0 is simply equal to the temperature depth when the depth is larger than one half the period length of
jump coefficient K, ^ which is normalized by half the period the pattern. The ratio of the gas to liquid thermal conductivities is
length L. also influential. For a solid area fraction no less than 10%, the
We truncate the infinite series in the solution to a finite number jump coefficient given by a conductivity ratio of 0.04 (corre-
of terms: An and Bn each to N terms, and Cnm to N N terms. To- sponding to air and water at 20 C) is only slightly lower than that
gether with T^0 , there are N 2 þ 2N þ 1 ¼ ðN þ 1Þ2 unknowns in given by a conductivity ratio equal to zero (i.e., perfectly noncon-
the solution yet to be determined. In this study, we use the method ducting gas). In the latter case, the temperature jump coefficient is
of point matching to determine these coefficients. We devise a identical to the hydrodynamic slip length for Stokes flow over lon-
gitudinal no-shear slots. For simplicity, we have built our model
scheme of even distribution of ðN þ 1Þ2 points in the domain for the two-dimensional patterned surfaces based on the ideal con-
ð0 x^ 1; 0 y^ 1; ^z ¼ 0Þ, which is one-quarter of one unit of dition that the gas is perfectly nonconducting, which gives the
pattern on the surface. At those points which are within the region upper bound value of the temperature jump coefficient. For these
overlying the solid phase, the constant temperature condition is two-dimensional patterned surfaces, the temperature jump coeffi-
imposed: T^ ¼ 0. At other points, the zero flux condition is cient is found to be larger in magnitude than the corresponding
^ z ¼ 0. The system of ðN þ 1Þ2 equations is then
imposed: @ T=@^ hydrodynamic slip length, although both coefficients will increase
solved for the same number of unknowns. We have found that sharply as the area fraction of the surface diminishes to a very
N ¼ 100 gives sufficiently accurate solutions. Similar numerical small value.
methods have been used by the authors [16,21] to determine effec- The focus of the present work is on evaluating the effective
tive hydrodynamic slip for Stokes flow over a two-dimensional coefficient for a thermal jump boundary condition, which is to be
patterned surface. applied to macroscale heat transfer over a superhydrophobic sur-
Figure 4 shows the temperature jump coefficient K^ as a function face. What we have performed is a “near-surface” analysis. The
of the solid area fraction /s for the four types of two-dimensional issues of momentum and heat transport far from the surface have
patterns shown in Fig. 3(a). Recall that patterns (i), (ii), (iii), and not entered into the present analysis. It is worth pursuing studies
(iv) correspond to circular posts, square posts, circular holes, and in the future to solve the coupled momentum and energy equa-
square holes, respectively. We also show in the insets the ratio of tions for convective heat transfer in a channel with superhydro-
the hydrodynamic slip length to the temperature jump coefficient, phobic surfaces.
where the slip lengths were computed and have been presented in The jump coefficients evaluated in this paper are valid for low
Ng and Wang [16]. These are the effective slip lengths arising Reynolds number and low Peclet number near the surface. It is
from Stokes flow over the four types of patterned surfaces, where also worth studying in the future how the temperature jump coeffi-
the free stream velocity is in the x direction, and no-slip and no- cient may vary as a function of the Reynolds number, channel
shear conditions are satisfied on the solid and void parts of the sur- height confinement, curvature of the liquid–gas interface, thermo-
face, respectively. From Fig. 4, the following observations can capillary, and so on.
made. First, by comparing (a) with (b), it is found that two curves
are almost the same. In other words, the same solid fraction /s
Acknowledgment
will give nearly the same values of the jump coefficient K^ for the
circular and square posts. This suggests that, for the solid phase The work was initiated when the second author visited the
distributed in the form of isolated patches on the surface, it is University of Hong Kong in December, 2012. Financial support
more the area fraction of the solid phase than the exact geometry was given by the Research Grants Council of the Hong Kong Spe-
of the solid patches that determines the temperature jump coeffi- cial Administrative Region, China, through Project No. HKU
cient. The geometry becomes more influential in the case of holes, 715609E.
however. By comparing (c) with (d), it is found that K^ for circular
holes is slightly larger than K^ for square holes of the same solid Nomenclature
area fraction. Second, as /s ! 0; K^ increases sharply. On compar- a¼ half-width of cavity (m)
ing this figure with Fig. 2(b), we find that the temperature jump An ¼ coefficients
coefficient will increase more sharply, as the solid area fraction b¼ depth of cavity (m)
decreases, in the case of a two-dimensional patterned surface than Bn ¼ coefficients
in the case of a one-dimensional patterned surface. Third, for suf- Cnm ¼ coefficients
ficiently small solid area fraction, say /s < 0:25, the temperature Imn ¼ integrals defined by Eq. (13)
jump coefficient can be several times larger for posts than holes of k¼ thermal conductivity (W/m K)
the same solid area fraction. Fourth, in all cases, the ratio of the kr ¼ ratio of thermal conductivity of gas to that of liquid
slip length to the temperature jump coefficient is nearly invariant K¼ temperature jump coefficient (m)
with the solid fraction of the surface, and the ratio is approxi- l¼ side length of square patch (m)
mately 0.75 for patterns (i) and (ii), and 0.67 for patterns (iii) and L¼ half-period length of surface pattern (m)
(iv). Hence, the temperature jump coefficient for these surfaces is m¼ integer
some 30–50% higher than the corresponding velocity slip length. M¼ integer
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c^nm ¼ eigenvalues defined by Eq. (20) Phys. Fluids, 18, p. 087105.
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