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BẢNG VIẾT TẮT CÁC THUẬT NGỮ VÀ TÁC NHÂN THƯỜNG GẶP

Tên viết tắt Tên đầy đủ Công thức cấu tạo

9-BBN 9-borabicyclo[3.3.1]nonane

Ac acetyl

acac acetylacetonate

ADDP 1,1’-(azodicarbonyl)dipiperidine

Ar aryl (các gốc thơm nói chung)

AIBN 2,2’-azobisisobutyronitrile

Alloc allyloxycarbonyl

n
Am amyl (n-pentyl)

i
Am isoamyl

An p-anisyl

aq aqueous (môi trường nước)

AQN anthraquinone

AZADO 2-azaadamantane-N-oxyl

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BHT 2,6-di-tert-butyl-4-methylphenol

2(R)-2’(R)-bis(diphenylphosphino)
BICP
-1(R),1’(R)-dicyclopentane

2,2’-dihydroxy-1,1’-binaphthyl
BINAL-H
lithium aluminium hydride

BINAP 2,2’-bis(diphenylphosphino)-1,1’-binaphthyl

BINOL 1,1’-bi-2,2’-naphthol

bipy 2,2’-bipyridyl

BMS borane – dimethylsulfide BH3.Me2S

Bn benzyl

Boc tert-butyloxycarbonyl

BOM benzyloxymethyl

benzotriazol-1-
BOP yloxytris(dimethylamino)phosphonium
hexafluorophosphate

BPD bis(pinacolato)diboron

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BPO benzoyl peroxide

BQ benzoquinone

brosyl
Bs
(p-bromobenzenesulfonyl)

Bt 1-benzotriazolyl

Bz benzoyl

n
Bu (Bu) n-butyl

i
Bu isobutyl

s
Bu sec-butyl

t
Bu tert-butyl

cericammonium nitrate
CAN Ce(NH4)2(NO3)6
(cerium(IV) ammonium nitrate)
cericammonium sulfate
CAS Ce(NH4)4(SO4)4
(cerium(IV) ammonium sulfate)
cat catalyst (xúc tác)

CBS (tác nhân) Corey-Bakshi-Shibata

Cbz benzyloxycarbonyl

CDMT 2-chloro-4,6-dimethoxy-1,3,5-triazine

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CDI 1,1’-carbonyldiimidazole

CHIRAPHOS 2,3-bis(diphenylphosphino)butane

Cp cyclopentadienyl anion

CSA camphorsulfonic acid

Cy (Chx) cyclohexyl

DABCO 1,4-diazabicyclo[2.2.2]octane

dba (DBA) dibenzylideneacetone

DBN 1,8-diazabicyclo[4.3.0]non-5-ene

DBPO dibenzoyl peroxide

DBU 1,8-diazabicyclo[5.4.0]undec-7-ene

DCC 1,3-dicyclohexylcarbodiimide

DCE 1,1-dichloroethane

DCM dichloromethane CH2Cl2

DCU N,N’-dicyclohexylurea

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DDQ 2,3-dichloro-5,6-dicyano-1,4-benzoquinone

diastereomeric excess
de (dư lượng đồng phân lập thể không đối
quang/dư lượng phi đối phân)

DEAD diethyl azodicarboxylate

DEIPS diethylisopropylsilyl

3-(diethoxyphosphoryloxy)-1,2,3
DEPBT
-benzotriazin-4(3H)-one

DET diethyl tartrate

DHP 3,4-dihydro-2H-pyran

DHQ dihydroquinine

(DHQ)2PHAL bis(dihydroquinino)phthalazine

DHQD dihydroquinidine

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(DHQD)2PHAL bis(dihydroquinidino)phthalazine

DIAD diisopropyl azodicarboxylate

DIBAL
i
diisobutylaluminum hydride Bu2AlH
(DIBAL-H)
DIPEA
i
N,N-diisopropylethylamine Pr2NEt
(DIEA)

DIPT diisopropyl tartrate

DMA N,N-dimethylacetamide

DMAD dimethyl acetylenedicarboxylate

DMAP 4-N,N-dimethylaminopyridine

DMDO dimethyldioxirane

DME dimethoxyethane

DMF N,N-dimethylformamide

DMFDMA N,N-dimethylformamide dimethyl acetal

DMI 1,3-dimethylimidazolidin-2-one

directed metalation group

DMG
(nhóm thế định hướng sự kim loại hóa)

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DMP Dess-Martin periodinane

1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-
DMPU pyrimidone
(N,N-dimethyl propylene urea)

DMS dimethylsulfide Me2S

DMSO dimethylsulfoxide

dimethyl(methylthio)sulfonium
DMTSF
tetrafluoroborate

DNCB 2,4-dinitrochlorobenzene

DPPA diphenylphosphoryl azide

dppb 1,4-bis(diphenylphosphino)butane

dppe 1,2-bis(diphenylphosphino)ethane

dppf 1,1-bis(diphenylphosphino)ferrocene

dppm bis(diphenylphosphino)methane

dppp 1,3-bis(diphenylphosphino)propane

DTBP 2,6-di-tert-butylpyridine

DTBMP 2,6-di-tert-butyl-4-methylpyridine

DTBS di-tert-butylsilylene

ethyldimethylaminopropyl
EDC (EDCI)
carbodiimide

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EDDA ethylenediamine diacetate

EE ethoxyethyl

Et ethyl

EVE ethylvinylether

eq equivalent (đương lượng)

hexafluorophosphate azabenzotriazole
HATU
tetramethyl uronium

HFIP 1,1,1,3,3,3-hexafluoro-2-propanol

HMDS hexamethyldisilazane TMS2NH

HMPA hexamethylphosphoramide

HMTA hexamethylenetetramine

IBA iodosobenzoic acid

IBX o-iodoxybenzoic acid

KAPA potassium 3-aminopropylamine

LAH lithium aluminum hydride LiAlH4

i
LDA lithium diisopropylamide Pr2NLi
LDEA lithium diethylamide Et2NLi
LHMDS
lithium hexamethyldisilazide TMS2NLi
(LiHMDS)
LTA lead (chì) tetraacetate Pb(OAc)4

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m-CPBA m-chloroperoxybenzoic acid

Me methyl

MEM (2-methoxyethoxy)methyl

Mes metisyl

MMPP magnesium monoperoxyphthalate

MOM methoxymethyl

oxodiperoxymolybdenum(pyridine)-
MoOPH
(hexamethylphosphoric triamide)

MOP methoxypropyl

Ms mesyl

MTM methylthiomethyl

MVK methyl vinyl ketone

NBA N-bromoacetamide

NBS N-bromosuccinimide

NCS N-chlorosuccinimide

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NFSI N-fluorobenzenesulfonimide

NIS N-iodosuccinimide

NMM N- methylmorpholine

NMO N-methylmorpholine N-oxide

NMP N-methyl-2-pyrrolidone

NPSP
N-phenylselenophthalimide
(N-PSP)

NPSS N-phenylselenosuccinimide

nosyl
Ns
(p-nitrobenzenesulfonyl)

NSA 2-naphthalenesulfonic acid

Oxone® potassium peroxymonosulfate 2KHSO5.KHSO4.K2SO4

PCC pyridinium chlorochromate

PDC pyridinium dichromate

Ph phenyl

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iodosobenzene bis(trifluoroacetate)
PIFA
(bis(trifluoroacetoxy)iodobenzene)

Piv pivaloyl

PMB p-methoxybenzyl

PPA polyphosphorous acid

PPTS pyridinium p-toluenesulfonate

n
Pr n-propyl

i
Pr isopropyl

PTSA p-toluenesulfonic acid

PTSH 1-phenyl-1H-tetrazole-5-thiol

benzotriazol-1-yl-
PyBOP oxytripyrrolidinophosphonium
hexafluorophosphate

pyr pyridine

Red-Al® sodium bis(2-methoxyethoxy)aluminum

(SMEAH) hydride

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4,5,6,7-tetrachloro-2',4',5',7'-
Rose Bengal
tetraiodofluorescein

room temperature
rt
(nhiệt độ phòng, khoảng 22 – 25 oC)
1-chloromethyl-4-fluoro-1,4-
Selectfluor ®
diazoniabicyclooctane
bis(tetrafluoroborate)

SEM 2-(trimethylsilyl)ethoxymethyl

Sia2BH disiamylborane

n
TBAF tetra-n-butylammonium flouride Bu4NF

TBDPS (BPS) tert-butyldiphenylsilane

t
TBHP tert-butyl hydroperoxide BuCOOH

TBDMS (TBS) tert-butyldimethylsilyl

TCDI thiocarbonyldiimidazole

TEMPO 2,2,6,6-tetramethylpiperidinyloxy

2,2,6,6-tetramethyl-4-hydroxyl-
TEMPOL piperidinyloxy
(4-hydroxyl-TEMPO)

2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy
TEMPONE
(4-oxo-TEMPO)

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TES triethylsilyl

TEOF triethyl orthoformate

triflouromethanesulfonyl
Tf
(triflate)

trifluoroacetic acid
TFA
(hoặc: trifluoroacetate)

TFAA triflouroacetic anhydride

TFE trifluoroethanol

THF tetrahydrofuran

THP tetrahydropyranyl

TIPS triisopropylsilyl

TMAO trimethylamine N-oxide Me3NO

TMEDA tetramethylethylenediamine

TMS trimethylsilyl

TMOF trimethyl orthoformate

Tol p-tolyl

TosMIC (p-tolylsulfonyl)methyl isocyanide

TPAP tetrapropylammonium perruthenate [nBu4N][RuO4]

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TPP tetraphenylporphyrin

Tr trityl

Tris triisopropylbenzenesulfonyl

Ts tosyl

2,2,2-trichloroethoxycarbonyl
Troc
(2,2,2-trichloroethyl carbamate)

TTMSS tris(trimethylsilyl)silane

UHP urea-hydrogen peroxide CO(NH2)2.H2O2

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