Professional Documents
Culture Documents
Teaching Assistants
Mr. Mrinal Bhowmik
Ms. Makkitaya Swarna Nagraj Dr. R. Anandalakshmi
Research Scholars Department of Chemical Engineering
Indian Institute of Technology Guwahati Indian Institute of Technology Guwahati
Guwahati -781039, India Guwahati -781039, India
Email: mrinalbhowmik@iitg.ac.in & Email: anandalakshmi@iitg.ac.in
swarn176107002@iitg.ac.in
Course Objectives
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Course Structure
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Lecture 1: Solar Energy: An Overview of
Thermal Applications
Basic Concepts of Energy
Types of Energy
Air Mass
Clausius Statement
It is impossible to construct a device which, operating in a cycle, will
produce no effect other than the transfer of heat from a low temperature
body to a high temperature body
Chemical Energy
Energy stored in the bonds of atoms and molecules
Examples: Batteries, biomass, petroleum, natural gas, and coal. Fossil fuels “store”
electromagnetic energy from the sun. When combusted, the original energy in the bonds of
the reactants = the heat energy released plus the chemical energy of the newly formed
compounds (including carbon dioxide)
Mechanical energy
Energy stored in objects by tension
Examples: Compressed springs and stretched rubber bands
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Types of Energy
Nuclear Energy
Energy stored in the nucleus of an atom – the energy that holds the nucleus together
Large amounts of energy can be released when the nuclei are combined or split apart
Examples: Fusion powers the stars – such as the fusion of two hydrogen atoms to form
helium (sun). Fusion powers nuclear bombs
Gravitational Energy
Energy stored in an object's height
The higher and heavier the object, the more gravitational energy is stored
Examples: Gravity forces water down through a hydroelectric turbine to produce
electricity
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Types of Energy
Kinetic (motion): Kinetic energy is the motion of waves, electrons, atoms, molecules,
substances, and objects
Thermal Energy
Comes from the movement of atoms and molecules in a substance
It increases when atoms and molecules move faster and collide with each other
Example: Geo-thermal energy
Radiant
Electromagnetic energy that travels in transverse waves
It includes visible light, x-rays, gamma rays, and radio waves
Example: An illuminating object or source such as the sun or a lamp
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Types of Energy
Electrical Energy
Energy caused by moving electric charges called electrons
Example: Lightning
Motion energy
Energy stored in the movement of objects
The faster they move, the more energy is stored
It takes energy to get an object moving, and energy is released when slows down
Example: Wind
Nonrenewable Energy
• It cannot be used again
and again but one day it
Oil will be exhausted
• It is present in limited
**Electricity generation by burning some fossil fuel (coal, gas, diesel), quantity
the norm is ~ 1kg of CO2 equivalent is generated per kWh of electricity.
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Renewable Energy
• Can be harnessed without the
release of harmful pollutants
Solar
• Essentially inexhaustible
Geo-
Wind • It can be used again and again
thermal Renewable throughout life
Energy
• These are the energy resources
which cannot be exhausted
Biomass Water
• It has low carbon emission and
hence environment friendly
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Quality and Source of Energy
Secondary energy resources (not occur in nature but are derived from primary energy
sources)
Electric energy from coal burning, hydrogen obtained by electrolysis of water
Energy Alternatives
Fossil Fuels
Oil provides 30% of world’s need for energy from commercial
sources (2015). Fuel for transportation systems.
Alternatives
No threat as of now for natural gas (2025)
Solar
Little later for coal (2050)
Nuclear
Manufacturing of organic chemicals
Tar sands and oil shale
Other sources
Water Power
Tidal
Environmental concerns in storing large amounts of water
Geo-thermal
Hydrogen
Nuclear power
Fission reactions in pressurized water/heavy water reactors
using U235 isotope
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Solar Option
The Earth receives 1.7×1018 W
Clean source and available in abundant in all parts of the world where people live
Solar radiation flux available rarely exceeds 1 kW/m2. Total radiation over a day is at its best
of 7 kWh/m2. Large collecting areas are required in many applications.
Availability with time (Day-night cycle), seasonal changes (due to earth’s orbit around the
Sun)
https://www.irena.org/Statistics
Current Energy Scenario
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https://www.irena.org/Statistics
Current Energy Scenario
3 MW - 229 MW
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https://www.irena.org/Statistics
The Earth
• It revolves around the Sun in an elliptical shape once per year
• The inner core of the Earth is a solid comprising iron and nickel unlike the Sun. Its outer core
constitutes a melted state of iron and nickel.
• The outer core is the Earth’s mantle comprises solid rock. The outermost crust that covers the
mantle also constitutes solid rock.
• Nearly 70% of the Earth is covered by water, and the remaining 30 % is land.
• Average surface temperature of Earth is approximately 288 K. The earth receives radiation:
1.7 x 1018 W
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The Sun
• Largest member of the solar system
• Sphere of intensely hot gaseous matter
• Diameter: 1.36 × 109 m
• Average distance of the sun from the earth 1.496 × 1011 m
• Sun rotates it own axis approximately once 4 weeks
• Density (at its center): >105 kg/m3 (1.622 x 105 kg/m3), pressure (at its center): over 1
billion atmospheres (2.477 x 1011 bar)
• Centre core Temperature : 8-40×106 K (1.571 x 107 K) (several fusion reactions)
• 90% of the Sun’s energy is generated in a spherical region having a radius 0.23 times the
Sun’s radius. Black body temperature : 5777 K - A continuous fusion reaction
• Energy radiation: 3.8 x 1026 W 21
Sun–Earth Geometric Relationship
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Source of Solar Energy
• Energy generated in the region is due to several
fusion reactions. Convective zone
Photosphere
It reaches from the surface visible at the center of the solar disk to about 400 km
The temperature in the photosphere varies between about 6500 K at the bottom and 4000 K at the top.
Photosphere is covered by granulation.
Chromosphere
The chromosphere is a layer in the Sun between about 400 and 2100 km above the solar surface
The temperature in the chromosphere varies between about 4000 K at the bottom and 8000 K at the top
Transition Region
Very narrow (100 km) layer between the chromosphere and the corona where the temperature rises
abruptly from about 8000 to about 500,000 K.
Corona
Outermost layer of the Sun, starting at about 2100 km above the solar surface
The temperature in the corona is 500,000 K or more, up to a few million K
The corona cannot be seen with the naked eye except during a total solar eclipse, or with the use of a
coronagraph
The corona does not have an upper limit 25
Formation of the Atmosphere
The portion that is reflected by clouds and atmospheric aerosols (diffusive radiation) on a flat
surface oriented horizontally
C
p a th le n g th tra v e rs e d in th e a tm o s p h e re AB B
A ir m a s s =
v e rtic a l d e p th o f a tm o s p h e re AC ψ H0 CO2, O3,
mo 1 CO, H2O,
= sec z fo r z 0 Atmospheric optical dust, etc
Ho cos z path A Porous
Media
1
c o s 0 .1 5 9 3 .8 8 5 1 .2 5 3
m
z z
From the variation of air mass with the time of the day for the latitude of New Delhi
for different number of days of the year, it is observed that the sunshine hours are
shorter and the air mass higher for the month of December on the 21st compared with
other days as expected.
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Instruments for the Measurement of Solar Radiation and Sunshine
A pyranometer can measure solar irradiance in the desired location and solar radiation
flux density. The solar radiation spectru extends approximately between 300 and 2800
nm.
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Pyranometers
Temperature increases until radiation equals the rate of heat loss by convection,
conduction and reradiation
Hot junctions are attached to the black surface while the cold junctions are located under
a guard plate. Emf (0-10 mV) is generated. Read, recorded and integrated over a time.
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Design of Pyranometers
Thermopile – A sensor consisting of thermocouples connected in series and provided with a black coating
for absorbing all solar radiation. It exhibits a near-perfect cosine response (variation of the pyranometer's
calibration with θ) and a flat spectrum that covers 300 to 50000 nm. It is capable of producing a potential
that is relative to the temperature gradient.
Glass dome – This dome restricts the spectral response from 300 to 2800 nm from a field of view of 180
degrees. This hemispherical glass dome also shields the thermopile from wind, rain and convection.
Occulting disc – It is used for measuring the diffuse radiation and blocking beam radiation from the surface.
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Working Principle and Advantages
Key Benefits
A pyranometer is operated based on the
Very small temperature coefficient (relative
measurement of temperature difference between
change of a physical property associated
a clear surface and a dark surface.
with change in temperature)
Calibrated to ISO standards
The thermopile is used to measure this
More accurate measurements of performance
temperature difference.
index and performance ratio
Integrated measurement of the total available
The potential difference created in the thermopile
short-wave solar energy under all conditions
owing to the temperature gradient between the
two surfaces is used for measuring the amount of
Applications
solar radiation.
Predicting insulation requirements for
building structures
However, the voltage produced by the thermopile
Establishment of greenhouse locations
can be measured using a potentiometer.
Designing photovoltaic systems
Radiation data needs to be integrated by means
Meteorological and climatological studies
of an electronic integrator.
Measurement of solar intensity data
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Pyrheliometer
Use to measure duration of the day when there was bright sun shine give beam radiation
Construction winter
Thermal Storage (Thermal, electrical, mechanical and chemical): Sensible and latent
heat storage
Applications
1. S. P. Sukhatme and J. K. Nayak, Solar Energy: Principles of Thermal Collection and Storage, Tata
McGraw Hill, 2015.
2. Arvind Tiwari, G. N. Tiwari, and Shyam, ‘Handbook of Solar Energy: Theory, Analysis and
Applications ‘ Springer.
3. D. Y. Goswami, F. Kreith and J. F. Kreider, Principles of Solar Engineering, Taylor and Francis,
1999.
4. G. N. Tiwari, Solar Energy, Fundamentals, Design, Modeling and Applications, Narosa, 2002.
5. J. A. Duffie and W. A. Beckman, Solar Engineering of Thermal Processes, John Wiley, 2006.
6. H. P. Garg and J. Prakash, Solar Energy: Fundamentals and Applications, Tata McGraw Hill,
1997.
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