Nama : Rikha Khusniyyah

NIM : 5213420044
Matkul : Chemical Reaction Engineering
Rombel : C

Jawab :
−𝑟𝐴=(𝑘_3 𝐶_𝐴
𝐶_𝐸0)/(𝐶_𝐴+𝐶_𝑀 )

CM Michaelis constant

CA0 1
CE0 0.01

k3 ? Integral Method
CM ?
−𝑟𝐴=−𝑑𝐶𝐴/𝑑𝑡 𝑇=𝐶𝑀/(𝐾3.𝐶𝐸0).(ln⁡𝐶𝐴0/𝐶𝐴−𝐶𝐴)
+𝐶𝐴0/(𝐾3.𝐶𝐸0)

=(𝐾3.𝐶𝐴,𝐶
𝐸0)/ Compare with, Y = mx+c
(𝐶𝐴+𝐶𝑀)
𝑚=𝐶𝑀/
(𝐾3.𝐶𝐸0)
 =(𝐾3.𝐶𝐴,𝐶
𝐸0)/
(𝐶𝐴+𝐶𝑀)
𝑚=𝐶𝑀/
∫24_𝐶𝐴0^𝐶𝐴▒(−𝑑𝐶𝐴(𝐶𝐴+𝐶𝑀 (𝐾3.𝐶𝐸0)
))/(𝐾3.𝐶𝐴.𝐶𝑀)=∫24_0^𝑡▒𝑑𝑡
𝐶=𝐶𝐴0/
(𝐾3.𝐶𝐸0)
−(𝐶𝐴−𝐶𝐴0)−𝐶𝑀
ln⁡█(𝐶𝐴@𝐶𝐴0)=𝐾3.𝑡.𝐶𝐸0
CA (millimol/liter) t (hr) CA0 CA0/CA ln ((CA0/CA)-CA)
0.84 1 1 1.1905 -1.0485
0.68 2 1 1.4706 -0.2350
0.53 3 1 1.8868 0.3051
0.38 4 1 2.6316 0.8116
0.27 5 1 3.7037 1.2336
0.16 6 1 6.2500 1.8066
0.09 7 1 11.1111 2.3998
0.04 8 1 25.0000 3.2173
0.018 9 1 55.5556 4.0171
0.006 10 1 166.6667 5.1160
0.0025 11 1 400.0000 5.9915
12
f(x) = 1.4651986779097 x + 2.85446260254601
R² = 0.9819045217774
10

6 Column K
Linear (Column K)
4

0
-2.0000 0.0000 2.0000 4.0000 6.0000 8.0000

Slope 1.4652
intercept 2.8545

𝐶=2,8545=𝐶𝐴0/(𝐾3.𝐶𝐸0)

K3 35.0324
𝑀=𝑆𝑙𝑜𝑝𝑒=1,4652=𝐶𝑀/
(𝐾3.𝐶𝐸0)

CM 0.51329 mmol/liter

So, the konstan k3 is 35,032 and CM is 0,5133 mmol/liter.

Jawab :
−𝑟𝐴=(𝑘_3 𝐶_𝐴
𝐶_𝐸0)/(𝐶_𝐴+𝐶_𝑀 )

CM Michaelis constant

CA0 1
CE0 0.01

k3 ? Differential Method
CM ?
−𝑟𝐴=(𝑘𝐶_𝐴
𝐶_𝐸0)/(𝐶_𝐴+𝑚)

1/
(−𝑟𝐴)=(𝑚+𝐶_𝐴
)/(𝑘𝐶_𝐴 𝐶_𝐸0 )
1/(−𝑟𝐴)=𝑚/(𝐾.𝐶𝐸0.𝐶𝐴)+1/
(𝐾.𝐶𝐸0)

Ca t delta t CA0 1/CA -rA 1/-rA CA CA/rA

0.84 1 1 1 1.190476 6.25 0.16 1.086957 0.92 5.75
0.68 2 1 1 1.470588 6.25 0.16 1.315789 0.76 4.75
0.53 3 1 1 1.886792 6.666667 0.15 1.652893 0.605 4.033333
0.38 4 1 1 2.631579 6.666667 0.15 2.197802 0.455 3.033333
0.27 5 1 1 3.703704 9.090909 0.11 3.076923 0.325 2.954545
0.16 6 1 1 6.25 9.090909 0.11 4.651163 0.215 1.954545
0.09 7 1 1 11.11111 14.28571 0.07 8 0.125 1.785714
0.04 8 1 1 25 20 0.05 15.38462 0.065 1.3
0.018 9 1 1 55.55556 45.45455 0.022 34.48276 0.029 1.318182
0.006 10 1 1 166.6667 83.33333 0.012 83.33333 0.012 1
0.0025 11 1 1 400 285.7143 0.0035 235.2941 0.00425 1.214286

Differential Method slope = 1/k3CE0 =

k3 =
7
intersep = CM/k3CE0 =
6 CM =
5 f(x) = 4.93734443564535 x + 1.06708539695791
R² = 0.989318093640235 Differential Method
4 Linear (Differential
Method) So, the konstan k3 is 20,2540 and CM
3

2
6

5 f(x) = 4.93734443564535 x + 1.06708539695791

R² = 0.989318093640235 Differential Method
4 Linear (Differential
Method)
3

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 4.9373
20.2540
1.0671
0.2161

tan k3 is 20,2540 and CM is 0,2161 mmol/liter.