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  • Problema 3.34: Tranformar Los Datos

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    Maricruz Avila
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    This document contains the results of an experiment measuring the concentration of two substances, CA and CB, over time. It provides the initial and final concentration measurements for 10 trials. It then performs various calculations and regressions on the data to determine the rate constants k0, k1, and k2. It finds that k0 = 0.02801467 min-1, k1 = -0.000104813 min-1, and k2 = 0.012301749 L/mol min. It notes that k1 is negative, which is not physically possible. Plots of the experimental and estimated reaction rates show good agreement, suggesting the model fits the data well despite the unphysical k1 value.

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    multireaccion

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    C03p34_18032282_Maricruz_Avila

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    This document contains the results of an experiment measuring the concentration of two substances, CA and CB, over time. It provides the initial and final concentration measurements for 10 trials. It then performs various calculations and regressions on the data to determine the rate constants k0, k1, and k2. It finds that k0 = 0.02801467 min-1, k1 = -0.000104813 min-1, and k2 = 0.012301749 L/mol min. It notes that k1 is negative, which is not physically possible. Plots of the experimental and estimated reaction rates show good agreement, suggesting the model fits the data well despite the unphysical k1 value.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    12 views2 pages

    Problema 3.34: Tranformar Los Datos

    Uploaded by

    Maricruz Avila
    This document contains the results of an experiment measuring the concentration of two substances, CA and CB, over time. It provides the initial and final concentration measurements for 10 trials. It then performs various calculations and regressions on the data to determine the rate constants k0, k1, and k2. It finds that k0 = 0.02801467 min-1, k1 = -0.000104813 min-1, and k2 = 0.012301749 L/mol min. It notes that k1 is negative, which is not physically possible. Plots of the experimental and estimated reaction rates show good agreement, suggesting the model fits the data well despite the unphysical k1 value.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 2

    PROBLEMA 3.

    34
    t1= 90

    inicial despues de 90 s

    Experimento CA0, M CB0, M CA1, M CB1, M


    1 2.000 1.750 1.858 1.689
    2 1.750 1.750 1.626 1.697
    3 1.500 1.750 1.393 1.704
    4 1.250 1.750 1.161 1.712
    5 1.000 1.750 0.929 1.719
    6 2.000 1.250 1.875 1.206
    7 1.750 1.250 1.640 1.212
    8 1.500 1.250 1.406 1.217
    9 1.250 1.250 1.172 1.222
    10 2.000 1.250 1.875 1.206

    Tranformar los datos:


    mp mp exp mp mp mp mp mp mp mp mp mp
    CA , M CB , M (-rA) CA ^2 CA * CB CA ^2*CB CB ^2 CA *CB ^2 CA ^2*CB ^2 (-rA)*CA (-rA)*CB (-rA)*CACB
    1.929000 1.719500 0.094667 3.721041 3.3169155 6.39833 2.95668025 5.703436202 11.00192843 0.182612 0.16277933 0.31400133
    1.688000 1.723500 0.082667 2.849344 2.909268 4.91084438 2.97045225 5.014123398 8.463840296 0.13954133 0.142476 0.24049949
    1.446500 1.727000 0.071333 2.09236225 2.4981055 3.61350961 2.982529 4.314228199 6.240531089 0.10318367 0.12319267 0.17819819
    1.205500 1.731000 0.059333 1.45323025 2.0867205 2.51554156 2.996361 3.612113186 4.354402445 0.07152633 0.102706 0.12381208
    0.964500 1.734500 0.047333 0.93026025 1.67292525 1.6135364 3.00849025 2.901688846 2.798678892 0.045653 0.08209967 0.07918513
    1.937500 1.228000 0.083333 3.75390625 2.37925 4.60979688 1.507984 2.921719 5.660830563 0.16145833 0.10233333 0.19827083
    1.695000 1.231000 0.073333 2.873025 2.086545 3.53669378 1.515361 2.568536895 4.353670037 0.1243 0.09027333 0.1530133
    1.453000 1.233500 0.062667 2.111209 1.7922755 2.6041763 1.52152225 2.210771829 3.212251468 0.09105467 0.07729933 0.11231593
    1.211000 1.236000 0.052000 1.466521 1.496796 1.81261996 1.527696 1.850039856 2.240398266 0.062972 0.064272 0.07783339
    1.937500 1.228000 0.083333 3.75390625 2.37925 4.60979688 1.507984 2.921719 5.660830563 0.16145833 0.10233333 0.19827083
    SUMA= 15.467500 14.792000 25.0048053 22.61805125 36.2248457 22.49506 34.01837641 53.98736205 1.14375967 1.049765 1.67540052

    mp
    Calculo demostrativo de C A : (CA2+CA1)/2= =(E11+C11)/2
    mp
    Calculo demostrativo de CB : (CB2+CB1)/2 =(D11+F11)/2
    exp
    Calculo demostrativo de (-rA) : (CA1-CA2)/t2-t1)=((C11-E11)/$G$6)*60

    SCA2 SCBCA SCA2CB k0 (-rA)SCA

    SCBCA SCB 2
    SCACB 2
    x k1 = (-rA)SCB

    SCA2CB SCACB 2
    SCA2CB2 k2 (-rA)SCACB

    25.004805 22.618051 36.224846 x k0 = 1.1437597


    22.618051 22.495060 34.018376 k1 1.0497650
    36.224846 34.018376 53.987362 k2 1.6754005

    =MINVERSA(B48:D50)

    k0 = 1.520661682 0.29832908 -1.208327343 x 1.1437597 0.028015


    k1 = 0.298329078 1.00237857 -0.831791265 1.0497650 = -0.000105
    k2 = -1.208327343 -0.8317913 1.353421563 1.6754005 0.012302

    k0 = 0.02801467 min-1
    k1 = -0.000104813 min-1
    k2 = 0.012301749 lt/molmin

    Comprobacion de unidades:

    ko[=]r/CA[=]M/Mmin[=]min-1
    k1[=]r/CB[=]M/Mmin[=]min-1

    k2[=]r/CACB[=]M/M2min[=]M-1min-1

    GRAFICOS

    Residual de (-rA)
    mp mp exp est exp est
    CA , M CB , M (-rA) (-rA) (-rA) - (-rA)
    1.929000 1.719500 0.094667 0.09466393 0.000003
    1.688000 1.723500 0.082667 0.0828972 -0.000231
    1.446500 1.727000 0.071333 0.07107328 0.000260
    1.205500 1.731000 0.059333 0.05926057 0.000073
    0.964500 1.734500 0.047333 0.04741826 -0.000085
    1.937500 1.228000 0.083333 0.08341865 -0.000085
    1.695000 1.231000 0.073333 0.07302399 0.000309
    1.453000 1.233500 0.062667 0.06262415 0.000043
    1.211000 1.236000 0.052000 0.05220943 -0.000209
    1.937500 1.228000 0.083333 0.08341865 -0.000085

    MINIMO= 0.047333
    MAXIMO= 0.094667

    0.1 0.0004

    0.09 0.0003

    0.08 0.0002
    (-rA)est

    0.07 0.0001
    (-rA)est

    0.06 0.0000
    0.04 0.06 0.08 0.10
    0.05 -0.0001

    0.04 -0.0002
    0.04 0.06 0.08 0.10
    (-rA)exp -0.0003
    (-rA)exp

    El modelo parece ajustar bien los datos


    pero k1 resulta negativa

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