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Waste Management
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Evaluating the cost and carbon footprint of second-life electric vehicle


batteries in residential and utility-level applications
Dipti Kamath a, Siddharth Shukla a, Renata Arsenault b, Hyung Chul Kim b, Annick Anctil a,⇑
a
Department of Civil and Environmental Engineering, Michigan State University, East Lansing, MI 48824, USA
b
Research & Innovation Center, Ford Motor Company, Dearborn, MI 48121, USA

a r t i c l e i n f o a b s t r a c t

Article history: The volume of end-of-life automotive batteries is increasing rapidly as a result of growing electric vehicle
Received 1 February 2020 adoption. Most automotive lithium-ion batteries (LIBs) are recycled but could be repurposed as second-
Revised 19 May 2020 life batteries (SLBs) since they have 70–80% residual capacity, which can be adequate for stationary appli-
Accepted 25 May 2020
cations. SLBs have been proposed as potential, inexpensive, low-carbon energy storage for residential and
Available online xxxx
utility-level applications, with or without photovoltaics (PV). However, it is unknown whether SLBs will
be better than new batteries and whether SLBs will provide similar cost and carbon emission reduction
Keywords:
for the different stationary applications in all locations. This work compared the levelized cost of electric-
Second-life battery
Rooftop PV
ity and life-cycle carbon emissions associated with using SLBs and new LIBs in the US for three energy
Peak shaving storage applications: (1) residential energy storage with rooftop PV, (2) utility-level PV firming, and
PV firming (3) utility-level peak-shaving, leading to a total of 41 scenarios. SLBs reduced the levelized cost of elec-
Life-cycle assessment tricity by 12–57% and carbon emissions by 7–31% compared to new LIBs in the considered applications,
with higher reductions for utility-level applications. SLBs still provided benefits at the residential level
when compared to rooftop PV alone by reducing the levelized cost by 15–25% and carbon emissions
by 22–51%, making SLBs attractive to residential consumers as well. SLBs offer an opportunity to utilize
an end-of-life product for energy storage applications, provided the uncertainty in SLB quality and avail-
ability is addressed.
Ó 2020 Elsevier Ltd. All rights reserved.

1. Introduction world, and uncertainties associated with the full recycling costs
(Mayyas et al., 2019). Additionally, LIB chemistries are moving
With the growing electric vehicle adoption, the volume of end- towards cheaper low-cobalt and high-nickel chemistries, which
of-life automotive batteries is increasing rapidly in the US (Ai et al., can further reduce recycling revenues (Mayyas et al., 2019;
2019) and globally (Stringer and Ma, 2018). Most electric vehicles Wuschke et al., 2019). Including other EV parts, such as power
(EVs) are powered by rechargeable lithium-ion battery (LIB) sys- electronics and magnets, in the recycling stream can still increase
tems, which are typically replaced when their capacity is reduced the recycling profit (D’Adamo and Rosa, 2019).
by 20 to 30% (Canals Casals et al., 2019; Tong et al., 2017). EV LIBs Previous studies have suggested combining recycling with
are responsible for approximately 30% of the EV manufacturing repurposing and reuse (Choi and Rhee, 2020; D’Adamo and Rosa,
cost (Lutsey and Nicholas, 2019) and 37% of the EV manufacturing 2019), which can help utilize the remaining 70–80% capacity in
carbon footprint (Kim et al., 2016). EOL batteries. Repurposing EOL batteries as second-life batteries
Recycling is the main end-of-life (EOL) management method for (SLBs) involves disassembling batteries to the module- or cell-
automotive LIBs, and once fully established, it could provide rev- level, inspecting, repairing, testing, and repacking of cells or mod-
enue and reduce the energy consumption and carbon emissions ules into battery packs that meet original equipment manufactur-
compared to battery production with virgin materials (Qiao et al., ers’ quality requirements. Using SLBs can increase EV LIB life while
2019; Xiong et al., 2020). However, LIB recycling is still in a devel- reducing primary raw material extraction, cumulative energy
opmental stage, and some of the challenges are the low volumes of demand, and carbon emissions compared to new battery manufac-
collected LIBs, low governmental support in certain parts of the turing (Ahmadi et al., 2017, 2014; Canals Casals et al., 2019;
Cicconi et al., 2012; Richa et al., 2017a, 2017b). The high capital
⇑ Corresponding author.
costs associated with new LIBs can hinder the large-scale deploy-
E-mail address: anctilan@msu.edu (A. Anctil).
ment of energy storage (Bhatnagar et al., 2013), which could also

https://doi.org/10.1016/j.wasman.2020.05.034
0956-053X/Ó 2020 Elsevier Ltd. All rights reserved.

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
2 D. Kamath et al. / Waste Management xxx (xxxx) xxx

be overcome with SLBs (Cready et al., 2003; Neubauer et al., 2012). SLBs can potentially provide inexpensive, low-carbon energy
While the purchase price of new LIBs was reported to be $209/kWh storage. However, it is unknown whether SLBs will be better or
in 2017 (Chediak, 2017), those for SLBs are expected to be lower. worse than new batteries and whether SLBs will provide similar
Earlier studies and reports have estimated SLB price to be $38– cost and carbon emission reduction for residential and utility level
147/kWh (Canals Casals et al., 2019; Cready et al., 2003; stationary applications in all locations. Previous studies have
Desarnaud, 2019; Neubauer et al., 2012), which are expected to fall determined the cost or life-cycle carbon emissions of SLB use in
in the future (Canals Casals et al., 2019; Sun et al., 2018). residential and utility-level applications for specific locations and
generalized load demands. It is important to compare the applica-
1.1. SLBs in stationary applications tions under different scenarios of electricity pricing, electricity grid
carbon intensity, electricity consumption needs, and solar insola-
In residential applications, energy storage is either used to tion, as these locational factors can impact the cost and carbon
leverage time-of-use pricing or increase self-consumption of roof- emissions of SLB applications. We sought to ascertain the relative
top solar generation and consequently results in cost and carbon levelized cost of electricity and life-cycle carbon emissions of SLBs
savings. Adding lithium-ion batteries to rooftop PV in the US can and new LIBs in the US for three applications: residential energy
reduce the electricity cost by increasing PV self-consumption by storage, utility-level photovoltaic firming, and utility-level peak
up to 17% (Tervo et al., 2018). However, studies have identified shaving. We also compared SLB use to the existing conventional
the capital cost of adding LIBs as a limitation to the associated elec- technology (baseline) for the application, and thereby inform
tricity cost reduction (Johann and Madlener, 2014; Uddin et al., strategic prioritization of second-life EV battery use.
2017). To address this, many studies have considered SLBs as an
alternative and have found electricity cost reductions when adding
2. Methods
SLBs to residential PV systems in Portugal (Assunção et al., 2016),
the UK (Gladwin et al., 2013), Germany (Madlener and Kirmas,
Three applications for new LIBs and SLBs were considered: (1)
2017), and certain locations in China (Bai et al., 2019). Typically,
residential energy storage, (2) utility-level PV firming, and (3)
SLBs are not economical for leveling residential loads alone with-
utility-level peak-shaving, in the US, leading to a total of 41 scenar-
out PV (Heymans et al., 2014; Mirzaei Omrani and Jannesari, 2019).
ios. Fig. 1 shows the three applications, along with the scenarios con-
Life-cycle assessment (LCA) studies, mostly European case stud-
sidered, the corresponding energy system components, and the
ies, have shown SLB use with rooftop PV to reduce the carbon foot-
demand + battery storage profiles. The levelized cost of electricity
print (Bobba et al., 2018; Cusenza et al., 2019), in some cases
for each application scenario was calculated by minimizing the net
subject to the carbon emissions of the electricity generation
present value of system components that met the electricity demand
sources and battery efficiency (Faria et al., 2014). In a previous
(see Section 2.1). Using life-cycle assessment, the carbon emissions
study, the locational differences—PV generation, electricity price,
for each scenario were calculated based on a 10-year project lifetime,
and electricity generation sources— were found to impact the leve-
excluding the first-life and transportation of SLBs, and the end-of-life
lized cost of electricity and carbon footprint of using SLBs for com-
treatment of the system (see Section 2.2). Five locations were cho-
mercial fast-charging (Kamath et al., 2020). However, the effect of
sen—Detroit, Los Angeles, New York City, Phoenix, and Portland—
these differences for residential applications with SLBs has not
due to their diversity in solar radiation, climate, electricity pricing,
been studied widely, nor have SLBs been compared with new LIBs.
and electricity grid carbon intensity. Section 2.3 provides the details
Potential utility-level applications of new LIBs, as well as SLBs,
of the load/consumption, the scenarios, and the energy system com-
include renewables (PV) firming and peak shaving (Hossain et al.,
ponents in each scenario for each application.
2019). PV firming with energy storage supplements PV generation
to maintain steady power output for integration into the electricity
grid (Ferreira et al., 2014). On the other hand, peak shaving with 2.1. Levelized cost of electricity for SLB applications
energy storage reduces the power demand during peak times, reduc-
ing the need for peaking generators, which are operated only during A net present value approach was used to determine the eco-
high demand times (Denholm et al., 2019). This, in turn, reduces high nomically optimal energy system for each scenario using the
peak time electricity costs. Based on a US-based study that evaluated Homer Pro software (HOMER PRO Version 3.7 User Manual, 2016).
the potential value of using SLBs in utility-level applications, SLBs We ran multiple simulations of energy systems for each scenario,
generated revenue for both PV firming and peak shaving (Neubauer with differing component capacities that met the electricity
and Pesaran, 2011). However, the study did not include balance-of- demand over the project life of 10 years from 2017 to 2027. The
energy system with the minimum net present cost was determined
system costs and had considerable uncertainty from assumed
depth-of-discharge, discharge duration, and revenue benefit range. along with the component capacities, i.e. the amount of electricity
purchased from the grid (kWh), the SLB capacity (kWh), the PV
Studies on energy storage—new LIBs and SLBs—for PV firming
have typically focused on system design to reduce variation in capacity (kW), and the inverter capacity (kW). The net present cost
(NPC) can be obtained using Eq. (1) (He et al., 2018; HOMER PRO
PV production (Cardo-Miota et al., 2019; Karandeh et al., 2019;
Patel et al., 2020; Saez-de-Ibarra et al., 2016) and not carbon emis- Version 3.7 User Manual, 2016), where CAnn is the annualized cost,
CRF is the capital recovery factor (given in Eq. (2)), i is the discount
sions explicitly. For peak shaving, using SLBs lowered the carbon
emissions compared to using lead-acid batteries (Richa et al., rate, and N is the number of years.
2017b, 2017a) and electricity generated from natural gas cAnn
NPC ¼ ð1Þ
(Ahmadi et al., 2014; Sathre et al., 2015). However, these studies CRF
modeled generalized conditions of battery cycling (daily dis-
charges) or electricity generation (coal power plants). SLBs can N
ið1 þ iÞ
be cheaper than new LIBs, but they can also have a comparatively CRF ¼ N
ð2Þ
ð1 þ iÞ  1
shorter life, needing more frequent replacement. Therefore, to
understand the relative benefits of using SLBs for residential and The annualized cost was used to compare the yearly cost
utility level applications, SLBs need to be compared with new LIBs incurred in SLB-based scenarios with those in new LIB-based sce-
or existing baseline technologies, based on their associated leve- narios and the baseline. The levelized cost of electricity (LCOE)
lized cost of electricity and carbon emissions. and economic payback time were other metrics used to compare

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
D. Kamath et al. / Waste Management xxx (xxxx) xxx 3

Fig. 1. Summary of scenarios considered and energy system components for (a) residential energy storage, (b) utility-level PV firming, and (c) utility-level peak shaving, with
the different components considered. The demand + battery storage profiles show the typical load demand, PV production, and battery charge and discharge for the battery
storage scenario.

SLB with the baseline. The LCOE is calculated by dividing the annu- Electric Company, 2014; Los Angeles Department of Water and
alized cost by the annual electricity consumption of the scenario as Power, 2017; Portland General Electric Company, 2017), which
given in Eq. (3) (HOMER PRO Version 3.7 User Manual, 2016). The were used in this study. Table 2 provides the specific pricing plan
economic payback time was calculated for residential applications for each location and the corresponding summer months. The elec-
by dividing the net present cost of the SLB, PV, and inverter (the tricity pricing structure in Portland varied only on an hourly basis,
‘‘investment”) by the annual electricity cost savings due to the while the one in Los Angeles was characterized by seasonal varia-
reduction in grid purchase. The economic payback time or PT is cal- tion with high prices during the summer afternoons. New York City
culated using Eq. (4) (He et al., 2018). had a pricing structure with a combination of hourly and season-
ally variation. The increase in the residential electricity prices over
cAnn
LCOE ¼ ð3Þ the period of 2017–2027 was based on the US EIA projections (U.S.
Electricity ser v ed Energy Information Administration, 2018a). For PV firming, the
electricity prices were obtained from the regional prices reported
Excess of the alternate system
PT ¼ Savings from the alternate system
¼ Annualized cost of battery storage;PV; and invertor
Savings from the alternate system
by the US EIA’s Annual Energy Outlook 2018 (U.S. Energy
Information Administration, 2018b). For peak shaving, overnight
ð4Þ
cost, fuel cost, and plant efficiency were based on previous studies
Table 1 summarizes the assumptions used as inputs in Homer on natural gas peaking plant and energy storage (Denholm et al.,
Pro for the project life and discount factor, along with the price 2019; Lin and Damato, 2011; U.S. Energy Information
and performance details of the PV, SLB, and inverter. A 30% rebate Administration, 2016; U.S Environmental Protection Agency,
on the system purchase (the PV and inverter system) was assumed 2019). The baseload generation cost for charging the battery was
based on the 2017 Residential Renewable Energy Tax Credit, which assumed to be $0.1/kWh based on the average cost of electricity
has been scaled down to 26% in 2020 (U.S. Internal Revenue over the last ten years (U.S. Energy Information Administration,
Service, 2018). The rebate can only be applied to the portion of 2017).
the battery system charged from PV, not the grid. A battery
charged only by PV would receive a 30% rebate, while a battery 2.2. Life-cycle carbon emissions for SLB applications
that is charged 20% of the time by PV would receive only a 6%
rebate. The yearly solar radiation profiles and temperature data For each scenario, the grid purchase and capacities of PV, SLB,
were obtained from the National Renewable Energy Laboratory’s and inverter were used to calculate the life-cycle global warming
(NREL’s) National Solar Radiation Database (Sengupta et al., potential (GWP) at each location. The life-cycle GWP of the appli-
2018) and the NASA Surface Meteorology and Solar Energy Data- cation scenarios, excluding the SLB first-life and the end-of-life
base (Stackhouse, 2011), respectively. treatment of the system, was calculated over 10 years using the
Fig. 2 presents the hourly and seasonal variation in the 2017 TRACI 2.1 method (Bare, 2011) in SimaPro v8.5 (PRé
residential electricity pricing structures from the main utilities in Sustainability, 2018) software. The functional unit defines the
each location (Arizona Public Service Electric Company, 2017; function, or the service provided by the considered system or
Consolidated Edison Company of New York Inc., 2012; DTE application. Therefore, for this study, the functional unit changed

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
4 D. Kamath et al. / Waste Management xxx (xxxx) xxx

Table 1
Assumptions for efficiency and costs of system components along with other project details for the reference year of 2017.

Parameters Unit Value Ref.


SLB New LIB
Battery cost $/kWh 65 209 (Cready et al., 2003; Neubauer et al., 2012, Chediak, 2017)
Battery roundtrip % 91% 95% (Assunção et al., 2016; Bobba et al., 2018; DTE Energy Advanced
efficiency Implementation of Energy Storage Technologies Final Technology
Performance Report)
Battery lifetime kWh/kWh 2,000 3,400 (Ahmadi et al., 2014, 2017; Assunção et al., 2016;
throughput Debnath et al., 2016)
PV module cost $/kW 600 for utility level, 650 for (Fu et al., 2017)
residential level
PV derating factor % 90.50% (Fu et al., 2017)
PV module lifetime years 30 (Fu et al., 2017)
Inverter cost $/kW 100 for utility level, 130 for (Fu et al., 2017)
residential level
Inverter efficiency % 98% (Fu et al., 2017)
Inverter lifetime years 15 (Fu et al., 2017)
Project lifetime years 10 Assumed
Discount rate % 6.9% (Fu et al., 2017)
Inflation rate % 2.5% (Fu et al., 2017)
PV rebate % 30% only for residential (U.S. Internal Revenue Service, 2018)
level

Fig. 2. Hourly and seasonal residential electricity pricing structures for all locations. Electricity prices increase from blue (low) to red (high). The variation in time-of-use price
is denoted as hourly or seasonal for each location. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.)

with each application. For instance, the functional unit for the res- 2.3. Scenarios considered
idential application was the delivery of electricity to meet the
demand of the house with or without EV charging over the project 2.3.1. Residential energy storage application
lifetime of 10 years. For PV firming, the functional unit was the Two energy demand cases were considered for the residential
delivery of one kWh of firmed PV output over 10 years, whereas, energy storage system application. In the first one, the system
for peak shaving, it was the delivery of electricity to meet one was designed to meet the residential energy storage demand (Case
kWh of peak demand over 10 years. We also considered a second R). In the second case, the electricity required to charge an EV was
functional unit for the residential application to compare it with added to the residential energy storage demand (Case REV). Fig. 1
the utility-level applications, where we calculated the GWP for (a) shows the three residential energy storage application scenar-
every kWh of electricity delivered to meet the demand of the house ios, grid only (R0/REV0), grid with PV (R1/REV1), grid with PV
with or without EV charging over the project lifetime. and battery (R2/REV2), where the consumption corresponds to res-
The life-cycle inventories for the PV system and other material idential energy storage (R) and with the additional demand of EV
inputs were taken from Ecoinvent 3 (Wernet et al., 2016) and charging (REV). The demand and battery storage profiles for the
DATASMART LCI databases (LTS, 2016). The DATASMART inventory application are also shown for the scenario where the rooftop PV
for electricity was updated with the mix of fuels representative of is complemented by an energy storage system and the excess gen-
the 2016 US EPA eGRID subregion for each location (also shown in eration is stored for later use.
Table 2) (U.S. Environmental Protection Agency, 2018). The EV SLB The residential electricity consumption profiles for representa-
inventory was based on a previous publication on electric vehicle tive buildings were modeled for all locations using NREL’s BEOpt
lithium-ion battery manufacturing (Kim et al., 2016) and the software (Christensen et al., 2006). The structural, thermal, and
repurposing process was assumed to take place in the US. Com- electrical components of the house were selected from building
pared to a new lithium-ion battery, the material required for the and thermal codes of the respective locations using the same
enclosure was assumed to be 30%, while the same amount of pri- methodology as in previous work (Kamath et al., 2019; Shukla
mary energy for pack assembly was required, as assumed in previ- et al., n.d.). The weather files for the locations were taken from
ous work (Kamath et al., 2020). Details of the life-cycle inventory the National Solar Radiation Database (NSRDB) compiled by NREL
are provided in Section S3 of the Supplementary Material. The (Wilcox and Marion, 2008). The EV was assumed to have a 30
assessment excluded the first-life and transportation of SLBs and kWh battery that charged with a 6.6 kW Level 1 home charger
the EOL treatment of the system. for four hours per day. The charging was assumed to start either

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
D. Kamath et al. / Waste Management xxx (xxxx) xxx 5

Table 2
Utility and electricity pricing structure, and eGRID region for residential application in the five cities.

City eGRID region (U.S. Environmental Electricity pricing structure (residential) details
Protection Agency, 2018)
Utility (Pricing Plan) (Reference) Summer months
Detroit, MI WECC California (CAMX) DTE Energy (Residential Time-of-Use Service) (DTE Electric Company, 2014) Jun-Oct
Los Angeles, CA RFC Michigan (RFCM) LADWP (Time-of-Use Residential Rate (R-1B)) (Los Angeles Department Jun-Sept
of Water and Power, 2017)
New York City, NY NPCC NYC/Westchester (NYCW) Consolidated Edison (Time of Use Rates: Residential) (Consolidated Jun-Sept
Edison Company of New York Inc., 2012)
Phoenix, AZ WECC Southwest (AZNM) Arizona Public Service (Rate schedule R-3: Residential Service Saver May-Oct
Choice Max) (Arizona Public Service Electric Company, 2017)
Portland, OR WECC Northwest (NWPP) Portland General (Schedule 7: Residential Service) ( Portland General No difference
Electric Company, 2017)

at 8 pm or when low time-of-use pricing began, whichever was application was modeled for a region’s demand and not a location,
later (Idaho National Laboratory, 2015). it was evaluated for two states—Michigan and Oregon, chosen due
For case R, three scenarios were considered with different sys- to the differences in their electricity demands and the carbon emis-
tem components. For R0, we considered the electricity grid only; sions associated with their electricity generation. The peak shaving
for R1, PV was added to the grid; and R2, SLB was added to R1. operation depends on the demand profile as the peaking capacity is
R2n was a sub-scenario of R2 with new LIBs instead of SLBs. Sim- determined based on the peak demand. Since state-level demand
ilarly, three scenarios were also considered for case REV with EV data was not readily available, we used the historic generation data
charging. For REV0, we considered the electricity grid only; for from all of the balancing authorities operating in a state and pro-
REV1, a PV was connected to the grid with PV; and for REV2, SLB portionally reduced the data to match the annual demand of the
was added to REV1. Similar to R2n, REV2n was a sub-scenario of corresponding state in the year 2017. Michigan’s electricity
REV2 with new LIBs instead of SLBs. The rooftop PV size was demand was obtained by reducing the Midwest Independent Sys-
assumed to 5 kW. tem Operator generation data proportionally to Michigan’s annual
demand (U.S. Energy Information Administration, 2019a). For Ore-
2.3.2. Utility-level PV firming application gon, the demand was obtained by reducing the generation data
The utility-level PV-firming application considered a 5 MW from Bonneville Power Administration and Portland General Elec-
utility-level PV plant connected to the electric grid. The baseline tric Company proportionally to Oregon’s annual demand (U.S.
scenario, denoted as PVF0, consisted of 5 MW of installed PV mod- Energy Information Administration, 2019a).
ules, without energy storage. Energy storage reduce fluctuations in Similar to the NREL report on the potential of battery storage
PV generation due to cloud coverage or solar angle and to obtain peaking power (Denholm et al., 2019), we determined the net peak
steady or, in other words, ‘firmed’ PV output from a PV plant. SLBs demand target to be 80% of the annual peak. Any load below this
or new LIBs were charged when the PV generation was above a threshold was met by the baseload electricity grid power and
preset threshold and discharged when the PV generation fell below any demand above it was denoted as peak demand. The system
the threshold. PVF1 considered the 5 MW PV plant with SLB for components for the two scenarios considered to meet the peak
firming. PVF1n was a sub-scenario of PVF1 with new LIBs instead demand are (1) PS0: Electricity grid with an added natural gas
of SLBs. The scenarios are illustrated in Fig. 1(b), along with the power plant, and (2) PS1: Electricity grid with an added SLB storage
typical firming operation showing a steady PV output with energy for peak shaving. PS1n is a sub-scenario with new LIBs used instead
storage. of SLBs in PS1. The baseload generation that was used to charge the
The hourly global horizontal irradiance (GHI) (Wilcox and battery energy storage was assumed to be the present generation
Marion, 2008) was merged with the 1-second firming duty-cycle without the peaking capacity natural gas generation. The natural
from (Schoenwald and Ellison, 2016) (also shown in Supplemen- gas peaking plant was assumed to have a capacity equal to 20%
tary Information (SM) Section S1) to simulate the fluctuating PV of maximum demand and the costs were based on the US EIA
output from a utility-level PV plant. The obtained PV output was assumptions (U.S. Energy Information Administration, 2016). The
converted to a signal with 1-minute averaged interval, since PV peak shaving scenarios, PS0 and PS1, are shown in Fig. 1 (c) along
firming is characterized by limiting the signal fluctuations in a 1– with the modified demand profile with the reduced peak demand
15 min time interval (Schoenwald and Ellison, 2016). The firmed when using energy storage.
signal was obtained using a 3rd order least squares estimator
(LSE) filter, also known as the Savitzky-Golay filter over a 15- 3. Results
minute moving time window, as proposed in previous literature
(Atif and Khalid, 2020). Eq. (5) represents the general equation 3.1. Residential application
used for a Savitzky-Golay filter.
Pn The residential electricity demand for each location without EV
i¼n Ai ykþi charging was modeled in BEOpt. Phoenix had the highest electric-
ðyk Þs ¼ P n : ð5Þ
i¼n Ai ity demand in both summer and winter since electricity is used for
both heating and cooling, whereas natural gas is used for heating in
where Ai is the set of weighted coefficients or convolution integers other locations. The annual electricity demand for each location is
derived each time from the constituents of the moving window. shown in Fig. 3 and is also available in the SM Section S4. Based on
the modeled electricity demand for each location, the energy sys-
2.3.3. Utility-level peak shaving application tem components with the minimum net present cost were deter-
The peak shaving application was modeled to meet the peak mined, along with the associated LCOE and life-cycle GWP for all
demand by using either conventional peaking power from natural scenarios. Tables S3 and S4 provide the component capacities,
gas or energy storage (SLB and new LIB). Since the peak shaving the annualized cost, LCOE, and GWP for all scenarios of the residen-

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
6 D. Kamath et al. / Waste Management xxx (xxxx) xxx

Fig. 3. Annual residential electricity demand without EV charging, as modeled in BEOpt, for (a) Detroit, (b) Los Angeles, (c) New York City, (d) Phoenix, and (e) Portland.

tial energy storage application (R) and residential energy storage capacity of 15–20 kWh was required (REV2), while the required
application with EV charging (REV), respectively. capacity for new LIBs was 5–20 kWh (REV2n). The battery capacity
The battery capacity required with the 5 kW residential rooftop requirement did not change drastically with the addition of EV
PV was dependent on whether EV charging was considered or not charging since the extra electricity demand occurred at night
and also on the solar insolation (higher capacity to store higher PV (low-peak pricing time). The capacity requirement in Los Angeles,
generation) or the battery type (higher capacity with lower round- however, was 20 kWh for both SLBs and new LIBs since the elec-
trip efficiency of SLBs). For the residential energy storage applica- tricity purchase had to be reduced due to the high low peak pricing
tion (R), a SLB capacity of 15–20 kWh was required with the (as seen in Fig. 2).
rooftop PV (R2), while a new LIB capacity of 5–15 kWh was Fig. 4 shows the LCOE, GWP, and economic payback time for the
required (R2n). Locations with higher solar insolation needed the residential energy storage application with and without EV charg-
highest battery capacities to store the excess PV generation. For ing. Replacing new LIBs with SLBs for residential rooftop PV
residential energy storage with EV charging (REV), a similar SLB reduced the LCOE by 14–27% for residential energy storage appli-

Fig. 4. Levelized cost of electricity and global warming potential for SLBs in the residential energy storage application in (a) Detroit, (b) Los Angeles, (c) New York City, (d)
Phoenix, and (e) Portland; (f) Economic payback time of all scenarios for all the locations. The LCOE, GWP, and payback time when using SLBs (R2/REV2) are compared to Grid
only (R0/REV0), Grid with PV (R1/REV1), and Grid with PV using new LIBs (R2n/REV2n).

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D. Kamath et al. / Waste Management xxx (xxxx) xxx 7

Fig. 5. Levelized cost of electricity and global warming potential for (a) PV firming application for scenarios: PVF0 (PV only), PVF1 (PV firmed with SLB) and PVF1n (PV firmed
with new LIB), and (b) Peak shaving application for scenarios: PS0 (Natural gas), PS1 (SLB), PS1n (new LIB).

cation (R2 vs. R2n) and by 7–15% when adding EV charging SLB (R2/REV2) compared to the grid only (R0/REV0) or rooftop
demand (REV2 vs. REV2n). Irrespective of whether EV charging PV scenarios (R1/REV1) in all locations for both residential applica-
was added or not, SLBs reduced the LCOE when added to rooftop tion cases. The detailed results for the residential applications are
PV compared to grid only scenario (R0/ REV0) as well as rooftop provided in Section S5.
PV only scenario (R1/REV1). Our LCOE results for new LIBs with Fig. 4 (f) shows the economic payback times of the various sce-
PV were similar to those obtained for the US-based study ($0.11– narios considered for residential application for SLBs. The eco-
0.16/kWh) (Tervo et al., 2018). Our results showed that adding nomic payback time for rooftop PV was reduced with the
SLBs to PV provided an average annual cost reduction of $343 in addition of SLBs in all locations. The difference in payback time
the US, comparable with a study that found a cost reduction of ~ for the five locations depends not only on the PV generation but
$313/ year for an average house in Portugal (Assunção et al., also the electricity pricing and electricity demand (Young et al.,
2016). Another study also found adding SLBs with PV to be prof- 2018). For SLB use in both residential applications, the lowest pay-
itable in Stuttgart, Germany (Madlener and Kirmas, 2017). back time was in Los Angeles and the highest was in Portland. Even
The addition of the EV charging demand (REV) did not increase though Portland had the highest payback time for rooftop PV, add-
the LCOE savings substantially even with an increase in electricity ing SLBs reduced it by 37–39% for both residential application
consumption, leading to lower percentage savings in all locations. cases, which indicates potential economic benefits when rooftop
The LCOE reduction for the residential applications (R and REV) solar is combined with SLBs in Portland.
depended on the electricity pricing structure. For residential
energy storage application (R), a seasonally varying pricing struc- 3.2. Utility-level PV firming application
ture along with high solar insolation led to maximum percentage
savings in electricity cost, as seen in Los Angeles (53% with rebate). PV firming with energy storage is used to reduce fluctuations in
In contrast, when EV charging was added, SLBs with PV (REV2) had PV generation. Implementation of PV firming with both SLBs and
the maximum percentage savings compared to the baseline (REV0) new LIBs increased the annual electricity production in all five
when pricing structures varied both daily and seasonally. The locations (Section S5). Production in Phoenix increased the most
hourly variation in the electricity pricing was important since the (~18%), whereas it only increased by 8% in Los Angeles
EV charging occurred at low-peak times, and the locations with (Table S5). Fig. 5 (a) shows the LCOE and life-cycle GWP for
hourly variation had lower LCOE when EV charging was added to utility-level PV firming applications for all scenarios considered
residential energy storage demand. This effect was most promi- in each location. The results indicate that the LCOE and GWP
nent in cities with high differences in electricity pricing, such as increased, even though the electricity generation increased with
New York City, where the LCOE halved for all scenarios when EV firmed PV output when batteries were used. The LCOE of the base-
charging was included, compared to meeting the residential line was comparable with the results of a previous study on PV
energy storage demand only. firming (Perez et al., 2019).
Compared to new LIBs (R2n), the life-cycle GWP reduced by 10– The LCOE and GWP values were lower with SLBs compared to
44% for the residential energy storage demand, as shown by the bar new LIBs in the majority of the locations. The maximum LCOE
graphs in Fig. 4 (a)-(e). When adding the EV charging demand, the reduction by adding SLBs compared to new batteries was in Phoe-
GWP reduction for SLB (REV2) was lower in all locations (2–16%) nix (46%), with no change in Detroit. The LCOE change depended
compared to new LIB use (REV2n). The exception was Los Angeles, on the minute-by-minute fluctuation of solar insolation for each
where the differences in roundtrip efficiency between the two 20 location—higher change with higher fluctuation like in New York
kWh batteries increased the grid electricity consumption with City and Portland. Using SLBs instead of new batteries reduced
SLBs. The lower GWP reduction when adding EV charging (REV) the GWP the most in Portland (39%) and the least in Detroit
in all scenarios can be explained by the 5 kW capacity limit (0.4%). This difference is due to the required battery capacity for
imposed on the rooftop PV size, which was a reasonable practical PV firming, the changes in grid electricity needed, and the grid car-
constraint. Larger PV capacity would be necessary to replace grid bon intensity at each location. The detailed results of the utility-
electricity purchases. The GWP also reduced significantly with level PV firming are provided in Section S5.

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
8 D. Kamath et al. / Waste Management xxx (xxxx) xxx

3.3. Utility-level peak shaving application tial level when compared to rooftop PV alone by reducing the leve-
lized cost by 15–25% and carbon emission by 22–51%, making SLBs
The 2017 demand profiles for Michigan and Oregon used to attractive to residential consumers as well. In comparison, SLBs did
model the peak shaving application are provided in SM Section S2. not reduce cost and carbon emissions for the utility-level applica-
Fig. 5 (b) shows the LCOE and life-cycle GWP for all scenarios of tions in all scenarios. While PV firming with SLBs increased the
peak shaving considered for both Michigan and Oregon. Due to LCOE and GWP compared to unfirmed PV, the LCOE and GWP
the differences in the peak demand power and time, the cost varies reduction for SLB-based peak shaving compared to natural gas
substantially between the two states. The LCOE obtained for the plants depended on electricity consumption profile and generation
baseline and energy storage scenarios were lower than those sources.
reported for a study based in California (Lin and Damato, 2011). We were also able to identify important implications that can
The California-based study considered lead-acid battery storage affect the cost and carbon emissions for each application. In the
with lower efficiency, and the load profile in California was also case of residential applications, electricity pricing was the key to
not explicitly modeled, which can explain the differences. For the LCOE and GWP reduction. The levelized cost of electricity for roof-
PS0 scenario with a natural gas peaking plant, the LCOE in Oregon top solar PV with SLBs was always lower than that for rooftop solar
was lower than in Michigan. SLBs providing peaking power (PS1) PV only, irrespective of whether the residential tax credits were
reduced the LCOE by 39% in Michigan but increased it by 61% in applied or not (Tables S3–4). Adding SLB storage to rooftop solar
Oregon. New LIBs (PS1n) did not lower the LCOE in both states PV can provide financial benefits that may otherwise be lost as res-
compared to a natural gas peaking plant. The consumption profile idential tax credits for PV panels get scaled down to 0% by 2022 (U.
was found to be an important factor in considering the potential S. Internal Revenue Service, 2018).
economic benefit from SLB use for peak shaving. For utility-level PV firming, curtailment (limiting the PV power
The GWP of SLB use for peak shaving depended on the baseload output) has been touted as an economical method to obtain low-
used to charge the energy storage. In Michigan, there was an cost firmed output (Perez et al., 2019). However, PV generation
increase in GWP with SLBs and new LIBs for peaking power com- coincides with high peak times when the cost of generation is high,
pared with natural gas for two reasons: (1) an increased electricity making the curtailed electricity valuable. PV firming using energy
consumption due to roundtrip efficiency losses, and (2) the use of storage can also increase the reliability and stability of PV genera-
baseload generation in Michigan instead of natural gas generation. tion (Center for Sustainable Energy, 2015). For grid-connected PV,
Similarly, in Oregon, new LIBs increased the GWP in comparison including the avoided cost of electricity production and the cost
with natural gas. However, SLBs reduced it by 27% compared to of reliability services can increase the value of curtailed electricity
natural gas. This reduction by SLBs was because Oregon’s baseload and make energy storage and SLBs economically beneficial.
generation is less carbon-intensive than the generation from natu- The analysis of utility-level peak shaving revealed that the car-
ral gas. The detailed results of the utility-level peak shaving are bon emission reduction depended on the baseload generation
provided in Section S5. sources. At present, the carbon intensity of electricity generation
sources in many locations is higher than that of a natural gas
3.4. Comparison between all applications power plant. Therefore, global warming potential can increase
when SLBs are used with the current electricity grid (as seen in
Fig. 6 (a) and (b) compare the LCOE and life-cycle GWP of con- Michigan). However, as more renewable energy sources are added
ventional, SLB, and new LIB scenarios for various applications at at the utility-level (U.S. Energy Information Administration,
residential and utility levels, with no rebate. Using EV SLBs instead 2019b), SLBs will eventually deliver lower overall GWP opportuni-
of new batteries has the potential to reduce the levelized costs and ties than natural gas peaking plants (as already seen in Oregon).
global warming potential for all applications. The maximum reduc- Identifying potential applications for SLBs is only the first step
tion was obtained for utility-level applications. in the successful deployment of SLBs. To understand if the demand
Comparing SLBs with the application baseline gave insight into for the potential applications can be met by the available SLBs, we
prioritizing SLB applications. SLBs provided benefits at the residen- considered a scenario where 50% of the total available SLBs passed

Fig. 6. Average (a) levelized cost of electricity with no rebate applied and (b) global warming potential for baseline, new LIB scenario, and SLB scenario for various
applications at residential (without and with EV charging) and utility (PV firming and peak shaving) levels.

Please cite this article as: D. Kamath, S. Shukla, R. Arsenault et al., Evaluating the cost and carbon footprint of second-life electric vehicle batteries in res-
idential and utility-level applications, Waste Management, https://doi.org/10.1016/j.wasman.2020.05.034
D. Kamath et al. / Waste Management xxx (xxxx) xxx 9

quality checks and were used to meet the US energy storage ply chain logistics (Canals Casals and Amante García, 2014; Jiao
demand. The US alone is expected to reach an annual EOL battery and Evans, 2016). Analysis of end-of-life battery availability
flow of 300–400 thousand battery packs in the next few years (Ai (Nassar et al., 2019; Richa et al., 2014) and the effect of market
et al., 2019). Considering an average capacity of 20 kWh, end-of- variables on the SLB supply chain (Alamerew and Brissaud, 2020)
life batteries could represent 6,000–8,000 MWh per year. Based can provide us with important lessons to ensure reliable SLB avail-
on the previous assumption, this battery volume translates to an ability. Strategies for successful repurposing have also been identi-
annual SLB availability of 3,000–4,000 MWh. At the same time, fied, such as design for disassembly, policy support, and
the energy storage demand in the US is expected to be more than standardization of product and component designs (Alamerew
4,500 MW by 2024 (Wood Mackenzie Power & Renewables, 2019). and Brissaud, 2020). Consumer perception of SLBs is another
The energy storage capacity addition in 2024 is projected to be important factor for large-scale adoption, which needs to be
close to 5,000 MWh for residential and 10,400 MWh for utility- addressed in future research (Brauer et al., 2016).
level front-of-the-meter sectors (assuming 4-hour energy storage). Extending the life of end-of-life electric vehicle batteries
Using SLBs instead of new LIBs can potentially meet 19–26% of the through the repurposing process provides an opportunity to utilize
residential and utility-level energy storage needs in 2024, reducing a product for energy storage applications that would otherwise be
the average costs by 11–15% and average carbon footprints by 7– considered waste. We anticipate the results presented in this paper
9%. Repurposing electric vehicle batteries for energy storage is, will help the strategic prioritization of SLB use. Coupling these
therefore, a promising end-of-life management option that can results with market variables, end-of-life battery availability, and
provide grid-level services and support to distributed solar. consumer perception will also allow for further research that can
ensure the successful deployment of SLBs.

4. Conclusions Declaration of Competing Interest

SLBs have the potential to lower the cost and carbon footprint The authors declare that they have no known competing finan-
for residential and utility-level applications. Compared to new LIBs, cial interests or personal relationships that could have appeared
SLBs lowered the levelized cost of electricity and global warming to influence the work reported in this paper.
potential in all applications and locations considered. However,
residential and utility-level storage applications will require SLBs Acknowledgments
in large volumes and capacities. The uncertainty in SLB quality
and availability may prove to be a limitation. The work has been financially supported by Ford Motor
As lithium-ion battery chemistries change over time, the corre- Company.
sponding battery degradation and second-life performance can
change (Bobba et al., 2018; Casals et al., 2017; Richa et al.,
Appendix A. Supplementary material
2017b). To ensure safety, economic viability, and avoid premature
failure, SLBs need thorough testing and characterization of second-
Supplementary data to this article can be found online at
life performance and lifetime (Cready et al., 2003), which has
https://doi.org/10.1016/j.wasman.2020.05.034.
resulted in testing protocols (Li et al., 2017) and an Underwriters
Laboratory standard UL1974 (‘‘ANSI/CAN/UL 1974: Standard for
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