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2021 2023

Sets, Relations and Functions Sets and their representations,


different kinds of sets (empty, finite and infinite), algebra of
sets, intersection, complement, difference and symmetric
Sets Relation difference of sets and their algebraic properties, De-Morgan’s
Maths
& Function laws on union, intersection, difference (for finite number of
sets) and practical problems based on them. Cartesian
product of finite sets, ordered pair, relations, domain and
codomain of relations, equivalence relation
Function as a special case of relation, functions as
Real valued functions of a real variable, into, onto mappings, domain, codomain, range of functions, invertible
and one-to-one functions, sum, difference, product functions, even and odd functions, into, onto and one-to-one
and quotient of two functions, composite functions, functions, special functions (polynomial, trigonometric,
absolute value, polynomial, rational, trigonometric, exponential, logarithmic, power, absolute value, greatest
exponential and logarithmic functions integer etc.), sum, difference, product and composition of
functions.

Algebra of complex numbers, addition,


multiplication, conjugation, polar representation, Algebra of complex numbers, addition, multiplication,
properties of modulus and principal argument, conjugation, polar representation, properties of modulus and
triangle inequality, cube roots of unity, geometric principal argument, triangle inequality, cube roots of unity,
interpretations. Quadratic equations with real geometric interpretations. Statement of fundamental theorem
coefficients, relations between roots and of algebra, Quadratic equations with real coefficients,
coefficients, formation of quadratic equations with relations between roots and coefficients, formation of
given roots, symmetric functions of roots. quadratic equations with given roots, symmetric functions of
Algebra
Arithmetic, geometric and harmonic progressions, roots. Arithmetic and geometric progressions, arithmetic and
arithmetic, geometric and harmonic means, sums geometric means, sums of finite arithmetic and geometric
of finite arithmetic and geometric progressions, progressions, infinite geometric series, sum of the first n
infinite geometric series, sums of squares and natural numbers, sums of squares and cubes of the first n
cubes of the first n natural numbers. Logarithms natural numbers. Logarithms and their properties,
and their properties. Permutations and permutations and combinations, binomial theorem for a
combinations, binomial theorem for a positive positive integral index, properties of binomial coefficients.
integral index, properties of binomial coefficients.
2021 2023
Matrices as a rectangular array of real numbers, Matrices as a rectangular array of real numbers, equality of
equality of matrices, addition, multiplication by a matrices, addition, multiplication by a scalar and product of
scalar and product of matrices, transpose of a matrices, transpose of a matrix, elementary row and column
matrix, determinant of a square matrix of order up transformations, determinant of a square matrix of order up
Matrices to three, inverse of a square matrix of order up to to three, adjoint of a matrix, inverse of a square matrix of
three, properties of these matrix operations, order up to three, properties of these matrix operations,
diagonal, symmetric and skew-symmetric matrices diagonal, symmetric and skew-symmetric matrices and their
and their properties, solutions of simultaneous properties, solutions of simultaneous linear equations in two
linear equations in two or three variables. or three variables.

Random experiment, sample space, different types of events


Addition and multiplication rules of probability,
(impossible, simple, compound), addition and multiplication
Probability & conditional probability, Bayes Theorem,
rules of probability, conditional probability, independence of
Statastics independence of events, computation of probability
events, total probability, Bayes Theorem, computation of
of events using permutations and combinations.
probability of events using permutations and combinations.
Measure of central tendency and dispersion, mean, median,
mode, mean deviation, standard deviation and variance of
grouped and ungrouped data, analysis of the frequency
distribution with same mean but different variance, random
variable, mean and variance of the random variable.

Trigonometric functions, their periodicity and


graphs, addition and subtraction formulae,
Trigonometric functions, their periodicity and graphs,
formulae involving multiple and sub-multiple
addition and subtraction formulae, formulae involving
angles, general solution of trigonometric equations.
Trigonometry multiple and sub-multiple angles, general solution of
Relations between sides and angles of a triangle,
trigonometric equations. Inverse trigonometric functions
sine rule, cosine rule, half-angle formula and the
(principal value only) and their elementary properties.
area of a triangle, inverse trigonometric functions
(principal value only).
2021 2023
Two dimensions: Cartesian coordinates, distance
between two points, section formulae, shift of
origin. Equation of a straight line in various forms,
angle between two lines, distance of a point from a
line; Lines through the point of intersection of two
given lines, equation of the bisector of the angle
between two lines, concurrency of lines; Centroid,
orthocentre, incentre and circumcentre of a
triangle. Equation of a circle in various forms,
equations of tangent, normal and chord. Parametric
Analytical Two dimensions: Cartesian coordinates, distance between
equations of a circle, intersection of a circle with a
Geometry two points, section formulae, shift of origin.
straight line or a circle, equation of a circle through
the points of intersection of two circles and those
of a circle and a straight line. Equations of a
parabola, ellipse and hyperbola in standard form,
their foci, directrices and eccentricity, parametric
equations, equations of tangent and normal. Locus
problems. Three dimensions: Direction cosines and
direction ratios, equation of a straight line in space,
equation of a plane, distance of a point from a
plane.
Equation of a straight line in various forms, angle between
two lines, distance of a point from a line; Lines through the
point of intersection of two given lines, equation of the
bisector of the angle between two lines, concurrency of
lines; Centroid, orthocentre, incentre and circumcentre of a
triangle. Equation of a circle in various forms, equations of
tangent, normal and chord. Parametric equations of a circle,
intersection of a circle with a straight line or a circle,
equation of a circle through the points of intersection of two
circles and those of a circle and a straight line. Equations of
a parabola, ellipse and hyperbola in standard form, their foci,
directrices and eccentricity, parametric equations, equations
of tangent and normal. Locus problems. Three dimensions:
Distance between two points, direction cosines and direction
ratios, equation of a straight line in space, skew lines,
shortest distance between two lines, equation of a plane,
distance of a point from a plane, angle between two lines,
angle between two planes, angle between a line and the
plane, coplanar lines.
2021 2023

Limit and continuity of a function, limit and


continuity of the sum, difference, product and Limit of a function at a real number, continuity of a function,
quotient of two functions, L’Hospital rule of limit and continuity of the sum, difference, product and
evaluation of limits of functions. Even and odd quotient of two functions, L’Hospital rule of evaluation of
functions, inverse of a function, continuity of limits of functions. Continuity of composite functions,
composite functions, intermediate value property of intermediate value property of continuous functions.
continuous functions. Derivative of a function, Derivative of a function, derivative of the sum, difference,
derivative of the sum, difference, product and product and quotient of two functions, chain rule, derivatives
Differential
quotient of two functions, chain rule, derivatives of of polynomial, rational, trigonometric, inverse trigonometric,
calculus
polynomial, rational, trigonometric, inverse exponential and logarithmic functions. Tangents and
trigonometric, exponential and logarithmic normals, increasing and decreasing functions, derivatives of
functions. Derivatives of implicit functions, order two, maximum and minimum values of a function,
derivatives up to order two, geometrical Rolle’s theorem and Lagrange’s mean value theorem,
interpretation of the derivative, tangents and geometric interpretation of the two theorems, derivatives up
normals, increasing and decreasing functions, to order two of implicit functions, geometric interpretation of
maximum and minimum values of a function, Rolle’ derivatives.
s theorem and Lagrange’s mean value theorem.

Integration as the inverse process of differentiation, Integration as the inverse process of differentiation,
indefinite integrals of standard functions, definite indefinite integrals of standard functions, definite integrals
integrals and their properties, fundamental theorem as the limit of sums, definite integral and their properties,
of integral calculus. Integration by parts, fundamental theorem of integral calculus. Integration by
integration by the methods of substitution and parts, integration by the methods of substitution and partial
Integral
partial fractions, application of definite integrals to fractions, application of definite integrals to the
Calculus
the determination of areas involving simple curves. determination of areas bounded by simple curves. Formation
Formation of ordinary differential equations, of ordinary differential equations, solution of homogeneous
solution of homogeneous differential equations, differential equations of first order and first degree,
separation of variables method, linear first order separation of variables method, linear first order differential
differential equations. equations.

Addition of vectors, scalar multiplication, dot and Addition of vectors, scalar multiplication, dot and cross
Vector cross products, scalar triple products and their products, scalar and vector triple products, and their
geometrical interpretations. geometrical interpretations.
2021 2023
Units and dimensions, dimensional analysis; least
General Units and dimensions, dimensional analysis; least
count, significant figures; Methods of measurement
count, significant figures; Methods of measurement and
and error analysis for physical quantities pertaining
error analysis for physical quantities pertaining to the
to the following experiments: Experiments based
following experiments: Experiments based on using Vernier
on using Vernier calipers and screw gauge
calipers and screw gauge (micrometer), Determination of g
(micrometer), Determination of g using simple
using simple pendulum, Young’s modulus - elasticity of the
pendulum, Young’s modulus by Searle’s method,
Physics General material Surface tension of water by capillary rise and effect
Specific heat of a liquid using calorimeter, focal
of detergents. Specific heat of a liquid using calorimeter,
length of a concave mirror and a convex lens using
focal length of a concave mirror and a convex lens using u-v
u-v method, Speed of sound using resonance
method, Speed of sound using resonance column,
column, Verification of Ohm’s law using voltmeter
Verification of Ohm’s law using voltmeter and ammeter, and
and ammeter, and specific resistance of the
specific resistance of the material of a wire using meter
material of a wire using meter bridge and post
bridge and post office box.
office box.
2021 2023
Kinematics in one and two dimensions (Cartesian
coordinates only), projectiles; Uniform circular Kinematics in one and two dimensions (Cartesian
motion; Relative velocity. Newton’s laws of motion; coordinates only), projectiles; Uniform circular motion;
Inertial and uniformly accelerated frames of Relative velocity. Newton’s laws of motion; Inertial and
reference; Static and dynamic friction; Kinetic and uniformly accelerated frames of reference; Static and
potential energy; Work and power; Conservation of dynamic friction; Kinetic and potential energy; Work and
linear momentum and mechanical energy. Systems power; Conservation of linear momentum and mechanical
of particles; Centre of mass and its motion; energy. Systems of particles; Centre of mass and its motion;
Impulse; Elastic and inelastic collisions. Law of Impulse; Elastic and inelastic collisions. Rigid body, moment
gravitation; Gravitational potential and field; of inertia, parallel and perpendicular axes theorems, moment
Acceleration due to gravity; Motion of planets and of inertia of uniform bodies with simple geometrical shapes;
satellites in circular orbits; Escape velocity. Rigid Angular momentum; Torque; Conservation of angular
body, moment of inertia, parallel and perpendicular momentum; Dynamics of rigid bodies with fixed axis of
axes theorems, moment of inertia of uniform bodies rotation; Rolling without slipping of rings, cylinders and
with simple geometrical shapes; Angular spheres; Equilibrium of rigid bodies; Collision of point
momentum; Torque; Conservation of angular masses with rigid bodies. Forced and damped oscillation (in
Mechanics
momentum; Dynamics of rigid bodies with fixed one dimension), resonance. Linear and angular simple
axis of rotation; Rolling without slipping of rings, harmonic motions. Hooke’s law, Young’s modulus. Law of
cylinders and spheres; Equilibrium of rigid bodies; gravitation; Gravitational potential and field; Acceleration
Collision of point masses with rigid bodies.Linear due to gravity; Kepler’s law, Geostationary orbits, Motion of
and angular simple harmonic motions. Hooke’s law, planets and satellites in circular orbits; Escape velocity.
Young’s modulus. Pressure in a fluid; Pascal’s law; Pressure in a fluid; Pascal’s law;Buoyancy; Surface energy
Buoyancy; Surface energy and surface tension, and surface tension, angle of contact, drops, bubbles and
capillary rise; Viscosity (Poiseuille’s equation capillary rise. Viscosity (Poiseuille’s equation excluded),
excluded), Stoke’s law; Terminal velocity, Modulus of rigidity and bulk modulus in mechanics. Stoke’s
Streamline flow, equation of continuity, Bernoulli’s law; Terminal velocity, Streamline flow, equation of
theorem and its applications. Wave motion (plane continuity, Bernoulli’s theorem and its applications. Wave
waves only), longitudinal and transverse waves, motion (plane waves only), longitudinal and transverse
superposition of waves; Progressive and stationary waves, superposition of waves; Progressive and stationary
waves; Vibration of strings and air columns; waves; Vibration of strings and air columns; Resonance;
Resonance; Beats; Speed of sound in gases; Beats; Speed of sound in gases; Doppler effect (in sound)
Doppler effect (in sound).
2021 2023
Thermal expansion of solids, liquids and gases;
Thermal expansion of solids, liquids and gases; Calorimetry,
Calorimetry, latent heat; Heat conduction in one
latent heat; Heat conduction in one dimension; Elementary
dimension; Elementary concepts of convection and
concepts of convection and radiation; Newton’s law of
radiation; Newton’s law of cooling; Ideal gas laws;
cooling; Ideal gas laws; Specific heats (Cv and Cp for
Specific heats (Cv and Cp for monoatomic and
monoatomic and diatomic gases); Isothermal and adiabatic
Thermal diatomic gases); Isothermal and adiabatic
processes, bulk modulus of gases; Equivalence of heat and
Physics processes, bulk modulus of gases; Equivalence of
work; First law of thermodynamics and its applications (only
heat and work; First law of thermodynamics and its
for ideal gases); Second law of thermodynamics, reversible
applications (only for ideal gases); Blackbody
and irreversible processes, Carnot engine and its efficiency;
radiation: absorptive and emissive powers;
Blackbody radiation: absorptive and emissive powers;
Kirchhoff’s law; Wien’s displacement law, Stefan’s
Kirchhoff’s law; Wien’s displacement law, Stefan’s law.
law.

Coulomb’s law; Electric field and potential;


Electrical potential energy of a system of point
charges and of electrical dipoles in a uniform Coulomb’s law; Electric field and potential; Electrical
electrostatic field; Electric field lines; Flux of potential energy of a system of point charges and of
electric field; Gauss’s law and its application in electrical dipoles in a uniform electrostatic field; Electric field
simple cases, such as, to find field due to infinitely lines; Flux of electric field; Gauss’s law and its application in
long straight wire, uniformly charged infinite plane simple cases, such as, to find field due to infinitely long
sheet and uniformly charged thin spherical shell. straight wire, uniformly charged infinite plane sheet and
Capacitance; Parallel plate capacitor with and uniformly charged thin spherical shell. Capacitance; Parallel
without dielectrics; Capacitors in series and plate capacitor with and without dielectrics; Capacitors in
parallel; Energy stored in a capacitor. Electric series and parallel; Energy stored in a capacitor. Electric
current; Ohm’s law; Series and parallel current; Ohm’s law; Series and parallel arrangements of
Electicity &
arrangements of resistances and cells; Kirchhoff’s resistances and cells; Kirchhoff’s laws and simple
Magnetism
laws and simple applications; Heating effect of applications; Heating effect of current. Biot–Savart’s law and
current.Biot–Savart’s law and Ampere’s law; Ampere’s law; Magnetic field near a current-carrying straight
Magnetic field near a current-carrying straight wire, wire, along the axis of a circular coil and inside a long
along the axis of a circular coil and inside a long straight solenoid; Force on a moving charge and on a
straight solenoid; Force on a moving charge and on current-carrying wire in a uniform magnetic field. Magnetic
a current-carrying wire in a uniform magnetic field. moment of a current loop; Effect of a uniform magnetic field
Magnetic moment of a current loop; Effect of a on a current loop; Moving coil galvanometer, voltmeter,
uniform magnetic field on a current loop; Moving ammeter and their conversions. Electromagnetic induction:
coil galvanometer, voltmeter, ammeter and their Faraday’s law, Lenz’s law; Self and mutual inductance; RC,
conversions. Electromagnetic induction: Faraday’s LR, LC and LCR(in series) circuits with d.c. and a.c. sources.
law, Lenz’s law; Self and mutual inductance; RC,
LR and LC circuits with d.c. and a.c. sources.
2021 2023
Electromagnetic waves and their characteristics.
Electromagnetic spectrum (radio waves, microwaves,
EM waves
infrared, visible, ultraviolet, x-rays, gamma rays) including
elementary facts about their uses.

Rectilinear propagation of light; Reflection and refraction at


Rectilinear propagation of light; Reflection and
plane and spherical surfaces; Total internal reflection;
refraction at plane and spherical surfaces; Total
Deviation and dispersion of light by a prism; Thin lenses;
internal reflection; Deviation and dispersion of light
Combinations of mirrors and thin lenses; Magnification.
Optics by a prism; Thin lenses; Combinations of mirrors
Wave nature of light: Huygen’s principle, interference limited
and thin lenses; Magnification. Wave nature of
to Young’s double slit experiment. Diffraction due to a single
light: Huygen’s principle, interference limited to
slit. Polarization of light, plane polarized light; Brewster's
Young’s double-slit experiment.
law, Polaroids.

Atomic nucleus; α, β and γ radiations; Law of


Atomic nucleus; α, β and γ radiations; Law of radioactive
radioactive decay; Decay constant; Halflife and
decay; Decay constant; Half-life and mean life; Binding
mean life; Binding energy and its calculation;
energy and its calculation; Fission and fusion processes;
Modern Fission and fusion processes; Energy calculation
Energy calculation in these processes. Photoelectric effect;
Physics in these processes. Photoelectric effect; Bohr’s
Bohr’s theory of hydrogen-like atoms; Characteristic and
theory of hydrogen-like atoms; Characteristic and
continuous X-rays, Moseley’s law; de Broglie wavelength of
continuous X-rays, Moseley’s law; de Broglie
matter waves.
wavelength of matter waves.

Concept of atoms and molecules; Dalton’s atomic


Concept of atoms and molecules; Dalton’s atomic theory;
theory; Mole concept; Chemical formulae; Balanced
Mole concept; Chemical formulae; Balanced chemical
chemical equations; Calculations (based on mole
Chemist equations; Calculations (based on mole concept and
Gen Topics concept) involving common oxidation-reduction,
ry stoichiometry) involving common oxidation-reduction,
neutralisation, and displacement reactions;
neutralisation, and displacement reactions; Concentration in
Concentration in terms of mole fraction, molarity,
terms of mole fraction, molarity, molality and normality.
molality and normality.
2021 2023
Gas laws and ideal gas equation, absolute scale of
Absolute scale of temperature, ideal gas equation; temperature; Deviation from ideality, van der Waals equation;
Deviation from ideality, van der Waals equation; Kinetic theory of gases, average, root mean square and most
Gaseous & Kinetic theory of gases, average, root mean square probable velocities and their relation with temperature; Law
Liquid State and most probable velocities and their relation with of partial pressures; Diffusion of gases. Intermolecular
temperature; Law of partial pressures; Vapour interactions: types, distance dependence, and their effect on
pressure; Diffusion of gases. properties; Liquids: vapour pressure, surface tension,
viscosity.

Bohr model, spectrum of hydrogen atom, quantum


numbers; Wave-particle duality, de Broglie
Bohr model, spectrum of hydrogen atom; Wave-particle
hypothesis; Uncertainty principle; Qualitative
duality, de Broglie hypothesis; Uncertainty principle;
quantum mechanical picture of hydrogen atom,
Qualitative quantum mechanical picture of hydrogen atom:
shapes of s, p and d orbitals; Electronic
Energies, quantum numbers, wave function and probability
configurations of elements (up to atomic number
density (plots only), shapes of s, p and d orbitals; Aufbau
Atomic 36); Aufbau principle; Pauli’s exclusion principle
principle; Pauli’s exclusion principle and Hund’s rule.
Structure & and Hund’s rule; Orbital overlap and covalent bond;
Orbital overlap and covalent bond; Hybridisation involving s,
Chemical Hybridisation involving s, p and d orbitals only;
p and d orbitals only; Molecular orbital energy diagrams for
Bonding Orbital energy diagrams for homonuclear diatomic
homonuclear diatomic species (up to Ne2); Hydrogen bond;
species; Hydrogen bond; Polarity in molecules,
Polarity in molecules, dipole moment; VSEPR model and
dipole moment (qualitative aspects only); VSEPR
shapes of molecules (linear, angular, triangular, square
model and shapes of molecules (linear, angular,
planar, pyramidal, square pyramidal, trigonal bipyramidal,
triangular, square planar, pyramidal, square
tetrahedral and octahedral).
pyramidal, trigonal bipyramidal, tetrahedral and
octahedral).

Intensive and extensive properties, state functions, First law


First law of thermodynamics; Internal energy, work
Chemical of thermodynamics; Internal energy, work (pressure-volume
and heat, pressure-volume work; Enthalpy, Hess’s
Thermodyna only) and heat; Enthalpy, heat capacity, standard state, Hess’
law; Heat of reaction, fusion and vapourization;
mics s law; Enthalpy of reaction, fusion and vapourization, and
Second law of thermodynamics; Entropy; Free
(Energetics) lattice enthalpy; Second law of thermodynamics; Entropy;
energy; Criterion of spontaneity.
Gibbs energy; Criteria of equilibrium and spontaneity.
2021 2023
Law of mass action; Equilibrium constant, Le Law of mass action; Significance of ΔG and ΔG0 in chemical
Chatelier’s principle (effect of concentration, equilibrium; Equilibrium constant (Kp and Kc) and reaction
Chemical & temperature and pressure); Significance of ΔG and quotient, Le Chatelier’s principle (effect of concentration,
Ionic ΔG0 in chemical equilibrium; Solubility product, temperature and pressure); Solubility product and its
Equlibrium common ion effect, pH and buffer solutions; Acids applications, common ion effect, pH and buffer solutions;
and bases (Bronsted and Lewis concepts); Acids and bases (Bronsted and Lewis concepts); Hydrolysis
Hydrolysis of salts. of salts.

Electrochemical cells and cell reactions; Standard


Electrochemical cells and cell reactions; Standard electrode
electrode potentials; Nernst equation and its
potentials; Electrochemical work, Nernst equation;
relation to ΔG; Electrochemical series, emf of
Electochemis Electrochemical series, emf of galvanic cells; Faraday’s laws
galvanic cells; Faraday’s laws of electrolysis;
try of electrolysis; Electrolytic conductance, specific, equivalent
Electrolytic conductance, specific, equivalent and
and molar conductivity, Kohlrausch’s law; Batteries: Primary
molar conductivity, Kohlrausch’s law;
and Secondary, fuel cells; Corrosion.
Concentration cells.

Rates of chemical reactions; Order and molecularity of


reactions; Rate law, rate constant, half-life; Differential and
Rates of chemical reactions; Order of reactions; integrated rate expressions for zero and first order reactions;
Chemical
Rate constant; First order reactions; Temperature Temperature dependence of rate constant (Arrhenius
Kinetics
dependence of rate constant (Arrhenius equation). equation and activation energy); Catalysis: Homogeneous
and heterogeneous, activity and selectivity of solid catalysts,
enzyme catalysis and its mechanism.

Classification of solids, crystalline state, seven Classification of solids, crystalline state, seven crystal
crystal systems (cell parameters a, b, c, α, β, γ), systems (cell parameters a, b, c, α, β, γ), close packed
Solid State close packed structure of solids (cubic), packing in structure of solids (cubic and hexagonal), packing in fcc, bcc
fcc, bcc and hcp lattices; Nearest neighbours, ionic and hcp lattices; Nearest neighbours, ionic radii and radius
radii, simple ionic compounds, point defects. ratio, point defects.

Henry’s law; Raoult’s law; Ideal solutions; Colligative


Raoult’s law; Molecular weight determination from
properties: lowering of vapour pressure, elevation of boiling
Solution lowering of vapour pressure, elevation of boiling
point, depression of freezing point, and osmotic pressure;
point and depression of freezing point.
van’t Hoff factor.
2021 2023
Elementary concepts of adsorption (excluding Elementary concepts of adsorption: Physisorption and
adsorption isotherms); Colloids: types, methods of Chemisorption, Freundlich adsorption isotherm; Colloids:
Surface
preparation and general properties; Elementary types, methods of preparation and general properties;
Chemistry
ideas of emulsions, surfactants and micelles (only Elementary ideas of emulsions, surfactants and micelles
definitions and examples). (only definitions and examples).

Radioactivity: isotopes and isobars; Properties of


α, β and γ rays; Kinetics of radioactive decay
Nuclear
(decay series excluded), carbon dating; Stability of No longer mentioned in syllabus
Chemistry
nuclei with respect to protonneutron ratio; Brief
discussion on fission and fusion reactions.

Classification Modern periodic law and the present form of periodic table;
of Elements electronic configuration of elements; periodic trends in
Earlier not mentioned in the syllabus and atomic radius, ionic radius, ionization enthalpy, electron gain
Periodicity in enthalpy, valence, oxidation states, electronegativity, and
Properties chemical reactivity.

Position of hydrogen in periodic table, occurrence, isotopes,


preparation, properties and uses of hydrogen;

hydrides – ionic, covalent and interstitial;

physical and chemical properties of water,


Earlier not mentioned in the syllabus Hydrogen
physical and chemical properties of heavy water;

hydrogen peroxide-preparation, reactions, use and structure;

hydrogen as a fuel.
2021 2023
Alkali and alkaline earth metals-reactivity towards air, water,
dihydrogen, halogens, acids;

their reducing nature including solutions in liquid ammonia;

uses of these elements;


Preparation
and Oxides, peroxides, hydroxides, carbonates,
s-block general characteristics of their oxides, hydroxides, halides,
properties of bicarbonates, chlorides and sulphates of sodium,
element salts of oxoacids;
the following potassium, magnesium and calcium;
compounds:
anomalous behaviour of lithium and beryllium;
(s block)
preparation, properties, and uses of compounds of sodium
(sodium carbonate, sodium chloride, sodium hydroxide,
sodium hydrogen carbonate) and calcium (calcium oxide,
calcium hydroxide, calcium carbonate, calcium sulphate).

Preparation Oxidation state and trends in chemical reactivity of elements


and of groups 13-17; anomalous properties of boron, carbon,
properties of Boron, silicon, nitrogen, phosphorus, oxygen, nitrogen, oxygen, and fluorine with respect to other elements
p-block
the following sulphur and halogens in their respective groups.
compounds &
Non Metal:
(p block)

Boron: diborane, boric acid and borax; Group 13: Reactivity towards acids, alkalis, and halogens;
preparation, properties, and uses of borax, orthoboric acid,
Aluminium: alumina, aluminium chloride and diborane, boron trifluoride, aluminium chloride, and alums;
alums; uses of boron and aluminium.

Carbon: oxides and oxyacid (carbonic acid);


Properties of allotropes of carbon (only diamond
Group 14: Reactivity towards water and halogen; allotropes
and graphite)
of carbon and uses of carbon; preparation, properties, and
uses of carbon monoxide, carbon dioxide, silicon dioxide,
Silicon: silicones, silicates and silicon carbide;
silicones, silicates, zeolites.
Oxides and chlorides of tin and lead;
2021 2023

Nitrogen: oxides, oxyacids and ammonia; Group 15: Reactivity towards hydrogen, oxygen, and
halogen; allotropes of phosphorous; preparation, properties,
Phosphorus: oxides, oxyacids (phosphorus acid, and uses of dinitrogen, ammonia, nitric acid, phosphine,
phosphoric acid) and phosphine; Properties of phosphorus trichloride, phosphorus pentachloride; oxides of
allotropes of Phosphorus nitrogen and oxoacids of phosphorus.

Oxygen: ozone and hydrogen peroxide


Group 16: Reactivity towards hydrogen, oxygen, and
halogen; simple oxides; allotropes of sulfur;
Sulphur: hydrogen sulphide, oxides, sulphurous
preparation/manufacture, properties, and uses of dioxygen,
acid, sulphuric acid and sodium thiosulphate;
ozone, sulfur dioxide, sulfuric acid; oxoacids of sulfur.
Properties of allotropes of Sulphur

Group 17: Reactivity towards hydrogen, oxygen, and metals;


Halogens: hydrohalic acids, oxides and oxyacids of preparation/manufacture, properties, and uses of chlorine,
chlorine, bleaching powder; hydrogen chloride and interhalogen compounds; oxoacids of
halogens, bleaching powder.

Group 18: Chemical properties and uses; compounds of


Xenon fluorides
xenon with fluorine and oxygen.

Preparation and properties of the Oxides, chlorides


and sulphates of Fe2+, Cu2+ and Zn2+; Oxidation states and their stability; standard electrode
d-block potentials; interstitial compounds; alloys; catalytic
Preparation and properties of the Potassium elements properties; applications; preparation, structure, and
permanganate, potassium dichromate, silver oxide, reactions of oxoanions of chromium and manganese.
silver nitrate, silver thiosulphate.
f-block Lanthanoid and actinoid contractions; oxidation states;
Earlier not mentioned in the syllabus
elements general characteristics.

Groups I to V (only Ag+, Hg2+, Cu2+, Pb2+, Bi3+, Groups I to V (only Ag+ , Hg2+, Cu2+, Pb2+, Fe3+, Cr3+, Al3+,
Principles of Principles of
Fe3+, Cr3+, Al3+, Ca2+, Ba2+, Zn2+, Mn2+ and Ca2+, Ba2+, Zn2+, Mn2+ and Mg2+); Nitrate, halides
Qualitative Qualitative
Mg2+); Nitrate, halides (excluding fluoride), (excluding fluoride), carbonate and bicarbonate, sulphate
Analysis Analysis
sulphate and sulphide. and sulphide.
2021 2023
Metal ores and their concentration; extraction of crude metal
Commonly occurring ores and minerals of iron,
Ores & Isolation of from concentrated ores: thermodynamic (iron, copper, zinc)
copper, tin, lead, magnesium, aluminium, zinc and
Mineral Metals and electrochemical (aluminium) principles of metallurgy;
silver.
cyanide process (silver and gold); refining.
Chemical principles and reactions only (industrial
details excluded); Carbon reduction method (iron
Extractive
and tin); Self reduction method (copper and lead);
Metallurgy
Electrolytic reduction method (magnesium and
aluminium); Cyanide process (silver and gold).

Definition, general characteristics, oxidation states


Transition
and their stabilities, colour (excluding the details of
Element (3-D
electronic transitions) and calculation of spin-only
Series)
magnetic moment;
Werner’s theory; Nomenclature, cis-trans and ionization
Coordination compounds: isomerism, hybridization and geometries (linear, tetrahedral,
nomenclature of mononuclear coordination square planar and octahedral) of mononuclear coordination
Transition
compounds, cistrans and ionisation isomerisms, Coordination compounds; Bonding [VBT and CFT (octahedral and
Element (3-D
hybridization and geometries of mononuclear Compund tetrahedral fields)]; Magnetic properties (spin-only) and
Series)
coordination compounds (linear, tetrahedral, colour of 3d-series coordination compounds; Ligands and
square planar and octahedral). spectrochemical series; Stability; Importance and
applications; Metal carbonyls.

Atmospheric pollution; water pollution; soil pollution;


Environmenta
Earlier not mentioned in the syllabus industrial waste; strategies to control environmental
l Chemistry
pollution; green chemistry.
2021 2023
Hybridisation of carbon; σ and π-bonds; Shapes of
simple organic molecules; Structural and
geometrical isomerism; Optical isomerism of
Hybridisation of carbon; σ and π-bonds; Shapes of simple
compounds containing up to two asymmetric
organic molecules; aromaticity; Structural and geometrical
centres, (R,S and E,Z nomenclature excluded);
isomerism; Stereoisomers and stereochemical relationship
IUPAC nomenclature of simple organic compounds
(enantiomers, diastereomers, meso) of compounds
(only hydrocarbons, mono-functional and bi-
containing only up to two asymmetric centres, (R,S and E,Z
functional compounds); Conformations of ethane
configurations excluded); Determination of empirical and
and butane (Newman projections); Resonance and
molecular formulae of simple compounds by combustion
hyperconjugation; Keto-enoltautomerism;
Concepts In method only; IUPAC nomenclature of organic molecules
Determination of empirical and molecular formulae
Organic (hydrocarbons, including simple cyclic hydrocarbons and
of simple compounds (only combustion method);
their mono-functional and bi-functional derivatives only);
Hydrogen bonds: definition and their effects on
Hydrogen bonding effects; Inductive, Resonance and
physical properties of alcohols and carboxylic
Hyperconjugative effects; Acidity and basicity of organic
acids; Inductive and resonance effects on acidity
compounds; Reactive intermediates produced during
and basicity of organic acids and bases; Polarity
homolytic and heterolytic bond cleavage; Formation,
and inductive effects in alkyl halides; Reactive
structure and stability of carbocations, carbanions and free
intermediates produced during homolytic
radicals.
andheterolytic bond cleavage; Formation, structure
and stability of carbocations, carbanions and free
radicals.

Homologous series; Physical properties (melting points,


Homologous series, physical properties of alkanes
Preparation, boiling points and density) and effect of branching on them;
(melting points, boiling points and density);
properties Conformations of ethane and butane (Newman projections
Combustion and halogenation of alkanes; Alkanes
and reactions only); Preparation from alkyl halides and aliphatic carboxylic
Preparation of alkanes by Wurtz reaction and
of alkanes acids; Reactions: combustion, halogenation (including allylic
decarboxylation reactions.
and benzylic halogenation) and oxidation.

Physical properties of alkenes and alkynes (boiling


points, density and dipole moments); Acidity of Physical properties (boiling points, density and dipole
alkynes; Acid catalysed hydration of alkenes and moments); Preparation by elimination reactions; Acid
Preparation,
alkynes (excluding the stereochemistry of addition catalysed hydration (excluding the stereochemistry of
properties
and elimination); Reactions of alkenes with KMnO4 Alkenes & addition and elimination); Metal acetylides; Reactions of
and reactions
and ozone; Reduction of alkenes and alkynes; Alkynes alkenes with KMnO4 and ozone; Reduction of alkenes and
of alkenes
Preparation of alkenes and alkynes by elimination alkynes; Electrophilic addition reactions of alkenes with X2,
and alkynes
reactions; Electrophilic addition reactions of HX, HOX, (X=halogen); Effect of peroxide on addition
alkenes with X2, HX, HOX and H2O (X=halogen); reactions; cyclic polymerization reaction of alkynes.
Addition reactions of alkynes; Metal acetylides.
2021 2023

Structure and aromaticity; Electrophilic


Structure; Electrophilic substitution reactions: halogenation,
substitution reactions: halogenation, nitration,
Reactions of nitration, sulphonation, FriedelCrafts alkylation and
sulphonation, Friedel-Crafts alkylation and Benzene
benzene acylation; Effect of directing groups (monosubstituted
acylation; Effect of o-, m- and p-directing groups in
benzene) in these reactions.
monosubstituted benzenes.

Physical properties; Preparation, Electrophilic substitution


Acidity, electrophilic substitution reactions reactions of phenol (halogenation, nitration, sulphonation);
Phenols (halogenation, nitration and sulphonation); Reimer- Phenols Reimer-Tiemann reaction, Kolbe reaction; Esterification;
Tieman reaction, Kolbe reaction. Etherification; Aspirin synthesis; Oxidation and reduction
reactions of phenol.

Carbohydrates: Classification; Mono- and di-saccharides


Classification; mono- and di-saccharides (glucose
Carbohydrate (glucose and sucrose); Oxidation; Reduction; Glycoside
and sucrose); Oxidation, reduction, glycoside Bimolecules
s formation and hydrolysis of disaccharides (sucrose, maltose,
formation and hydrolysis of sucrose.
lactose); Anomers.

Amino acids; Structure of peptides (primary and secondary); Types of


Amino acids General structure (only primary structure for
Peptide proteins (fibrous and globular). Nucleic acids: Chemical
and peptides peptides) and physical properties.
linkage; composition and structure of DNA and RNA.

Drug-target interaction; Therapeutic action, and examples


(excluding structures), of antacids, antihistamines,
Chemistry in
Earlier not mentioned in the syllabus tranquilizers, analgesics, antimicrobials, and antifertility
Everyday life
drugs; Artificial sweeteners (names only); Soaps, detergents,
and cleansing action.
Properties
Types of polymerization (addition, condensation); Homo and
and uses of
copolymers; Natural rubber; Cellulose; Nylon; Teflon;
some Natural rubber, cellulose, nylon, teflon and PVC. Polymers
Bakelite; PVC; Bio-degradable polymers; Applications of
important
polymers.
polymers
2021 2023
Detection of elements (N, S, halogens); Detection
and identification of the following functional
Detection of elements (N, S, halogens); Detection and
Practical groups: hydroxyl (alcoholic and phenolic), carbonyl Practical
identification of the following functional groups: hydroxyl
organic (aldehyde and ketone), carboxyl, amino and nitro; Organic
(alcoholic and phenolic), carbonyl (aldehyde and ketone),
chemistry Chemical methods of separation of mono- Chemistry
carboxyl, amino and nitro.
functional organic compounds from binary
mixtures.

Alkyl halides:
Characteristic Rearrangement reactions of alkyl carbocation; Grignard
rearrangement reactions of alkyl carbocation,
reactions of Alkyl Halides reactions; Nucleophilic substitution reactions and their
Grignard reactions, nucleophilic substitution
the following stereochemical aspects.
reactions

Alcohols: Physical properties; Reactions: esterification, dehydration


esterification, dehydration and oxidation, reaction (formation of alkenes and ethers); Reactions with: sodium,
with sodium, phosphorus halides, Alcohols phosphorus halides, ZnCl2/concentrated HCl, thionyl
ZnCl2/concentrated HCl, conversion of alcohols chloride; Conversion of alcohols into aldehydes, ketones and
into aldehydes and ketones carboxylic acids.

Ethers: Preparation by Williamson’s synthesis; C-O bond cleavage


Ethers
Preparation by Williamson’s Synthesis reactions.

Preparation of: aldehydes and ketones from acid chlorides


Aldehydes and Ketones:
and nitriles; aldehydes from esters; benzaldehyde from
oxidation, reduction, oxime and hydrazone
Aldehyde & toluene and benzene; Reactions: oxidation, reduction, oxime
formation; aldolcondensation, Perkin reaction;
Ketone and hydrazone formation; Aldol condensation, Cannizzaro
Cannizzaro reaction; haloform reaction and
reaction; Haloform reaction; Nucleophilic addition reaction
nucleophilic addition reactions (Grignard addition)
with RMgX, NaHSO3, HCN, alcohol, amine

Physical properties; Preparation: from nitriles, Grignard


Carboxylic acids:
Carboxylic reagents, hydrolysis of esters and amides; Preparation of
formation of esters, acid chlorides and amides,
Acids benzoic acid from alkylbenzenes; reduction, halogenation,
ester hydrolysis
formation of esters, acid chlorides and amides.
2021 2023
Haloarenes:
Reactions: Fittig, Wurtz-Fittig; Nucleophilic aromatic
nucleophilic aromatic substitution in haloarenes
Haloarenes substitution in haloarenes and substituted haloarenes
and substituted haloarenes (excluding Benzyne
(excluding benzyne mechanism and cine substitution).
mechanism and Cine substitution)

Amines: Preparation from nitro compounds, nitriles and amides;


basicity of substituted anilines and aliphatic Reactions: Hoffmann bromamide degradation, Gabriel
Characteristic amines, preparation from nitro compounds, phthalimide synthesis; Reaction with nitrous acid, Azo
reactions of reaction with nitrous acid, azo coupling reaction of Amines coupling reaction of diazonium salts of aromatic amines;
the following diazonium salts of aromatic amines, Sandmeyer Sandmeyer and related reactions of diazonium salts;
and related reactions of diazonium salts; Carbylamine reaction, Hinsberg test, Alkylation and acylation
carbylamine reaction reactions.

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