POC & Chemistry in Everyday Life 12.

Chapter 12 POC &

Chemistry in Everyday Life
INTEXT EXERCISE: 1
4. (b) As carbon is missing in it.
5. (a) blood colouration due to [Fe(SCN)]2+ hence S
and N both should be present in compound.
6. Compound contian (Cl, N) hence we get the ppt of
AgCl as well as AgCN.
28 0.4
7. % of N = 6×12 + 5 + 28 + 35.5 ×100 = 2 ×100
10×1
8. Moles of NH3 = 1000 ×2 = 0.02
Moes of N = 0.02
0.02×14 10.
% of N = 0.5 ×100 = 56%

9.

EXERCISE 1
1. (d) hydrazine does not contain carbon. 12. C H N
40 13 46.67
3. (d) compound should contain N and S. atom ratio 12 1 14
0.23 1 4 1 CH4N
×32
5. % of sulphur = 233
0.32 ×100 13. C H O
49.3 6.84 44.86
6. Na2S + HNO3 H2 3
atom ratio 12 1 16
NaCN + HNO3 3 5 2 C3H5O2
3

8. CH2==CH CH2Cl + AgNO3 14. C H N O

20 6.66 46.66 26.7
+
atom ratio 12 1 14 16
CH2 = CH - CH2 + AgCl
stable due to resonance

24
10. (c) C2H6 % of C = 30 ×100 = 80%
15. CaCl2 — H2O is 0.15 gm
% of H = 100 80 = 20 %
KOH — CO2 is 0.1873 gm
11. C H O
0.1873
%m 52.2 13.04 34.75 Wt of C is 44 ×12 gm
52.2 13.04 34.75
atom ratio 12 1 16 0.15
Wt of H is 18 ×2 gm
2 6 1 C2H6O
mol wt = 12 × 2 + 6 + 16 = 46 % of 0 is 100 % of C and % of H.
12.2 Chemistry
16. Wt of C is 0.01 × 12 gm
Wt of H is 0.005 × 2 gm 23. Compound should contain or
0.01×12
% of C is = 0.36 ×100 24. Should contain acidic hydrogen, aldehyde or ketone
0.005×2 group, should be cyclic and must contain 6 carbon
% of H is = 0.36 ×100
atoms.
50
×22.4 ×28 ×100
25. Answer correction (A)
17. % of N is 1000
0.29 acid react with NaOH and it changes color of
PV 28 phenopthalein
18. % of N = RT × w ×100
26.
1×0.0207 28
= 0.082×288 × 0.2 ×100
23.85 27. Only one degree amine give positive test.
19. Moles of NH3 = 0.115 × 1000
23.85 28. Only one degree amine give positive test.
Moes of N = 0.115 × 1000
30. Molisch test is for carbohydrate.
23.85
Wt of N = 0.115 × 1000 ×14 gm 31. Acidic hydrogen and 3o alcohol.
0.115×23.85
1000 ×14 32. All are more acidic then H2CO3.
% of N = 0.2160 ×100%
33.
100×0.5 - 0.5×65.5
1000 ×14
20. % of N = 0.445 ×100%

22. Phenol give +ve test with FeCl3. Lucas reagent give 34. Compound containing both N and S.
positive test with 2oalcohol.
38. Na2S + Pb(OAC)2 — PbS .
Black
46. Octane number of isooctane is 100 and heptane is
zero.
EXERCISE 2
1. 18. 1 mole occupy 22.42
2. Acetone and methanol has very less boiling point 1×45
hence 45 ml has 22.4×1000 moles
difference hence fractional distillation. mass
mol. wt = moles
3. Different boiling point.
0.24
mol.wt
= 22.445
×1000 VD = 2
4. 19. Normality of diluted H2SO4 solution is N
1
N×25 = 20.4× 10
20.4
N = 250
20.4 5
Normality of original solution = 250 × 1
20.4
= 50 = 0.408N
0.35
233 .5 ×32 ×100%
11. % of S = 0.2595 Normality used = 0.5 0.408 = 0.092 N
0.092×100
2×0.228 0.162 Moles of NH3 = 1000×2 moles
12. m - 2 + 108×2 = 108
0.092
where m is molecular wt of acid ×14
% of N = 200.6 ×100
13. Carious method give ppt. of AgX where X is halogen
14. (b) it does not have carbon.
 POC & Chemistry in Everyday Life 12.3
0.350 25. Pressure of N2 = 732.7 12.7
20. % of S = 233 .5 ×32 ×100 = 720 mm Hg
0.2595
PV 720×28.8
21. Lets assume mol. wt of dibasic acid is m Moles N2 = RT = 760×1000×0.082×288
0.25 Moles of N2 ×28
moles of acid = m % of N2 = ×100
0.216
0.25×2 0.5
moles of H+ = m = m 62 0.222
26. % of P = 222 × 0.1 ×100
0.5 1 24.6
moles of H+ = m = moles of OH = 60 × 1000
17
0.5 1 24.6 29. Moles of N = moles of NH3 = 22.4 moles
m = 60 × 1000
22. Lets assume mole wt of diacidic base in M.
0.184 amide assume molecular wt M
Moles of base = M
17
Moles of OH = M ×2
0.184 14
% of N = M ×100 = 22 .4 ×14 ×100
59
0.184×2 59×22.4
Moles of OH = M M= 17 = 77.75
1 25.6 1
Moles of H = 8 × 1000 × 2
+ 77.75 42 = 33.75
1×10 None is correct.
×2×14
24. % of N = 10000.5 ×100

EXERCISE 3
2. N and S should be present in compound. 5×0.01×16
% of O2 = 0.46 ×100
4. (c) option correction NH2 NH2. data incorrect.
Ans (c) as it does not contain carbon.
8. KOH is basic hence used with base otherwise acid
5. II and III produce stable carbocation after removal base reaction.
of Cl hence AgCl forms
9. 2 mol wt = 24 + 3 + 14
= 41

both are resonance stabilze. 11.

6. C H N
mass ratio: 9 1 3.5
9 1 3.5
atom ration: 12 1 14
3 1
4 1 4
3 4 1 C3H4N1 12. +ve Tollen’s reagent hence terminal alkyne.
EF C3H4N EFW = 12 × 3 + 4 × 1 + 14 × 1 13. (i) acidic hydrogen, +ve
= 54 (ii) acidic group, +ve
108
n = 54 = 2 Molecular formula : (C3H4N1)2: C6H8N2 (iii) Aldehyde group, +ve
coke (iv) Lucas reagent (not given by phenol)
7. 0.46 gm of compound O2 CO
14. 3o amine does not give Hinsberg’s reagent.
I2O5 + 5CO I2 + 5CO2
15. (c) does not contain carbon.
2.54
254 mole 16. C6H5 CH2 CHO
5×2.54 aldehyde group hence positive Tollen’s test and
Moles of CO consumed = 254
5×2.54 DNP test but not Iodoform test as no CH3 CHO
wt of oxygen = 254 ×16 group. Mol wt = 12 × 8 + 16 + 8
= 120
12.4 Chemistry
17. Should contain, double bond, 2o or 3o alcohol
30.

must for yellow ppt with I2 + NaOH.

Hence
31. All are more acidic then H2CO3

18. 32.

19. No Aldehyde group.

20. Aniline derivative will form dye with option b.
21. Hensberg test is used to differentiate 1o, 2o, 3o amine.

22.

23. CH3—CH==O give test for Aldehyde and 33. aldehyde, formic acid, glucose also contain aldehyde
group hence. Iodoform test. group hence give +ve test
24. (c) Phenol does not give lucas reagent list. 181
34. Lowest Mol. wt of protein = 2.2 ×100
25. C5H8
= 8227.3
32×2
35. Mol. wt of cystine = 26.7 ×100
terminal alkyne give test
= 239.7
36. Benzene and aniline have different boiling point
26.
hence distillation.
Dil HCl react with aniline and it is insoluble in
it.
38. Those compound which contain N, S both give
blood red coloration.
40. C H O Cl
Mass %: 60.5 5.55 16.1 17.9
27. 60.5 5.55 16.1 17.9
Atom ratio: 12 1 16 35.5
Multiply try 2: 10 11 2 1
28. [Fe(SCN)]2+ blood red. C10 H11 O2 Cl is formula of compound
46. Crowded ketone does not react with NaHSO3
29. 47. (a) R NH2 is basic
(b) Ph COOH react with Na2CO3 produce CO2
49. a, b, c has acidic hydrogen.

50. Compound having group perform iodoform

reaction but acid and acid derivative does not give
iodoform reaction.
 POC & Chemistry in Everyday Life 12.5

51. 60. (b)

Fehling does not give +ve test with aromatic

61.
Aldehyde.

52.
ROH + CH3Mg Br ROMgBr + CH4

53. 62. 63 & 64

0.04
moles of H 18 ×2 = 0.0044
0.195
moles of C 44 ×1 = 0.0044
54. (a) phenol give it
wt of O 0.2 - 0.0044×1 - 0.0044×12
(b) acidic hydrogen is there
= 0.1428
0.1428
(c) group is present moles O 16 = 0.0088
(d) acid group is absent C H O
3 moles 0.0044 0.0044 0.0088
55. (a) 3 acidic hydrogen hence 1 mole liberate 2 mole
of H2 1 1 2
(b) phenol group present EF CHO2 EFW 12 + 1 + 32
(c) acid group present 45
(d) terminal alkyne give +ve tollen’s test assume molecular wt = M
56. 0.5 0.355
2× M - 2 + 216 = 108
57.
M = 90.
hence molecular formula = (CHO2)2
= C2H2O4
65. 66 & 67

59. this behave as ketone in its

reaction with hydroxylamine
forming the Tris (oxime)
12.6 Chemistry
68. 69 & 70 1×48.6
50 ml, 75. % of N = 1000 ×0.082×300 28 ×100
Compound
Conc excess
NH3 0.2 m NaOH 0.45
H2 SO 4 KOH
76. EFW = 12 + 2 + 16 = 30
50×0.2 120
Moles of N = moles of NH3 = 1000 moles n = 30 = 4 MF = (CH2O)4
= 0.01 moles MF C4H8O4
0.01×14
% of N = 0.365 ×100 = 38.35 % hence 4 oxygen atom
Answer correction (d)
77. C H N
CnH2n+3 N 12n + 2n + 3 + 14 % M: 40 13 46.67
14n + 17 40 13 46.67
Atom ratio: 12 1 14
If n = 5 then 14 × 5 + 17
= 87 3.33 13 3.33
1 4 1
C—C—C—C—C—NH2

78.

79.

71. ROH + CH3MgBr — ROMgBr + CH4

11.2
22.4 ×10 moles
-3
11.2 ml at STP
11.2
22.4 ×10 moles
-3
80.
0.037
M = 0.5×10
-3

0.037 37
M= = = 74
0.5×10 -3 0.54 81.
72. C C C I + alc KOH C C==C
34 gm 36% mol wt 36 + 6
yield 42
Mol wt = 43 + 127
= 170 82.
34
Amount of propene form = 170 ×0.36×42gm
= 3 gm
73. Assume molecular mass of compound M
83. CH3 CHO, H3C CH2 CHO, HCHO, HCOOH
2.65 20 1 1
2× M × 500 = 12× 6 × 1000 n
84. n number of active hydrogen $ 2 H2
2.65×1000×2 112 1
M= 25×2 moles of H2 = 22.4×1000 = 200
= 2.65 × 40
0.45 1
= 26.5 × 4 moles of compound = 90 = 200
= 106. hence 1 molecule of compound has 2 hydrogen

74. C n H2n + 2 + b O2 $ nCO2 + ]n + 1g H2 O (,)

3n + 1 l 86. Those compound which contain S and N
15 ml 2 0 0
357

357 15 × b 2 l 15n
3n + 1
0

357 15 × b 2 l + 15n = 327

3n + 1

n = 3 hence mol wt
12 × 3 + 6 = 44
 POC & Chemistry in Everyday Life 12.7
87. Na S O
% M: 17.03 47.4 35.55 90. PCC convert 1o OH or 2o OH into
17.03 47.4 35.55 NBS allylic bromination
Atom ratio: 23 32 16
0.74 1.48 2.22 AlPO4 CH3COOH CH2 = C = O + H2O
1 2 3 Li+ liq NH3 C = C anti addtion of H2
EF NaS2O3
EFW = 23 + 64 + 48 = 135
270
n = 135 = 2 MF (NaS2O3)2
MF Na2S4O6

1. Compound ‘X’ should be (b).

Due to presence of —COCH3 group, it undergoes 12.
iodoform test.
Due to presence of 3° amine group it does not
participate in azo dye test. 13. does not give iodoform test as no
On the other hand, presence of PhCOCH3 group, it
readily undergoes DNP test. type formate.

3. In Kjeldahl’s method nitrogen containing compound 15. CH3CHO, HCHO, both are aldehyde.
when react with H2SO4 then (NH4)2SO4 is formed
& this means NH3 must be released. Only in (III)
option NH3 may be released. 16.
141×10 -3
7. % of Br = 188 ×80 ×100
250×10 -3 17.
= 24 %

18.
8.

19.
R N"
CHCl3
9. R CH2 NH2 KOH
=C

b 60 × 1 ×2 - 20 × 1 ×1 l ×14
1000 10 1000 10
10. % of N = 1.4 ×100
]1.2 - 0.2g
= 1.4 ×14
21.
14
= 1.4 = 10%

2. (c) Phenelzine is antidepresent drug

4.
12.8 Chemistry