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Vidyamandir Classes: Innovating For Your Success

General Instructions
1. The test is of 3 hours duration and the maximum marks is 198.

2. The question paper consists of 3 Parts (Part I: Physics, Part II: Chemistry, Part III: Mathematics). Each Part
has Three sections (Section 1, Section 2 & Section 3).

3. Section 1 contains SIX (06) questions. The answer to each question is a SINGLE DIGIT INTEGER ranging from
0 TO 9. BOTH INCLUSIVE.

4. Section 2 contains 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE OR MORE THAN ONE CHOICE is correct.

5. Section 3 contains 6 Numerical Value Type Questions. The answer to each of the question is a numerical
value. For each question, enter the correct numerical value of the answer. If the answer is a decimal
numerical value, then round-off the value to TWO decimal places. If the answer is an Integer value,
then do not add zero in the decimal places. In the OMR, do not bubble the  sign for positive values.
However, for negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)

6. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code,
Roll No. and Group properly in the space given in the ANSWER SHEET.

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Marking Scheme
SECTION - 1 (Maximum Marks: 18)
 This section has SIX (06) Questions. The answer to each question is a SINGLE DIGIT INTEGER, ranging
from 0 TO 9, BOTH INCLUSIVE.
 For each question, enter the correct integer corresponding to the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question in unanswered.
Negative Marks: –1 In all other cases.

SECTION - 2 (Maximum Marks: 24)


 This section consists of SIX (06) Questions. Each question has FOUR options. ONE OR MORE THAN ONE
of these four option(s) is(are) correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen, and it
is a correct option
Zero Mark: 0 if none of the options is chosen (i.e. the question is unanswered)
Negative Marks: –2 In all other cases.

SECTION - 3 (Maximum Marks: 24)


 This section has SIX (06) Questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer. If the numerical value has more
than two decimal places, truncate/round-off the value of TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered.
Zero Marks: 0 In all other cases.

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PART I : PHYSICS 66 MARKS

SECTION 1
SINGLE DIGIT INTEGER
This section consists of SIX (06) questions. The answer to each question is a SINGLE DIGIT INTEGER ranging from 0
TO 9. BOTH INCLUSIVE.
1. A plane mirror is suspended vertically at the centre of a large thin-walled
spherical flask filled with water. The diameter of the flask is 10 inches. An
observer whose eye is 35 inches from the mirror as shown in figure tries to
see an image of his own eye. What is distance of the image from the eye (in
inches)? Neglect the effect of the thin glass walls of the flask. If it n  3 .
 4
Find the value of n.  Take  water  
 3

2. An equi-concave lens of radius of curvature  50  1 cm is made out of a transparent material of


refractive index 1.50  0.01 . The percentage uncertainty in the focal length of the lens, when it is
placed in air of refractive index 1, is ________.
3. A certain volume of copper is drawn into a wire of radius a and is wrapped in shape of a helix having
radius r ( a). The windings are as close as possible without overlapping. Self-inductance of the
inductor so obtained is L1 . Another wire of radius 2a is drawn using same volume of copper and wound
L1
in the fashion as described above. This time the inductance is L2 . Find the value of .
L2

4. One mole of Argon gas is enclosed in a container at initial pressure P0 and volume V0 . The gas is taken
P
to final pressure 0 and volume 3V0 through two processes in succession: an isobaric expansion, followed
2
by an isothermal expansion. If the work done by the gas in the two processes is W1 and W2 respectively,
W
and the ratio 2   ln(2), then  is _______.
W1
5. A particle of mass 1 g and carrying charge 0.002 C is moving in the vertically upwards direction. At an
instant (t  0) when the speed of the electron is 100 m/s, a vertically directed uniform electric field is
switched on. It is found that the electron is moving at velocity 50 m/s in the vertically downward direction
at t  3 s. Taking the acceleration due to gravity to be 10m/s 2 , the magnitude of the electric field
(in V/m) is _________.
6. A cylindrical container has cross-section area of A = 0.05 m2 and
length L = 0.775 m. Thickness of the wall of the container as well as
mass of the container is negligible. The container is pushed into a
water tank with its open end down. It is held in a position where its
closed end is h = 5.0 m below the water surface. 2n 3 force (in
Newton) is required to hold the container in this position. Assume
temperature of air to remain constant. Find the value of n.
(Atmospheric pressure P0  1 105 Pa ; Acceleration due to gravity
g  10 m / s 2 , Density of water = 103 kg / m3 )

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SECTION 2
MULTIPLE CORRECT ANSWERS TYPE
This section consists of SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.

7. A solenoid is fixed with its axis along the Y-axis as shown. A bar magnet placed along the Y-axis and
initially at a very large distance from the solenoid is moved at a constant velocity in the –Y direction.
Until the magnet is again at a very large distance from the solenoid, the current induced in the solenoid :

(A) is constant in magnitude (B) reverses its direction once


(C) reaches its maximum magnitude twice (D) is in the same direction throughout
8. A particle moves in xy-plane such that its position as a function of time is given by x  2sin 2t ;
y  2 1  cos 2t  , where all parameters are in S.I. units. Then choose the correct statement(s) out of the
following.
(A) Path of the particle is symmetrical about y-axis
(B) Net force on the particle is always directed towards origin
(C) Speed of the particle is changing with time
(D) Average speed of the particle in the time-interval t  0 to t  2sec is 4 m / sec

9. Select correct alternative/s. If both plates of parallel capacitor plate are given positive charge as shown in
figure and at t  0 switch is closed, then choose the correct statements.

(A) current in resistance ‘R’ will flow from A to B


(B) electric field intensity between plate of capacitor will decrease continuously
Q t / RC
(C) current in the circuit at t is e
2 RC
Q2
(D) total heat developed in the circuit long after switch is closed is
4C

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10. An infinitely long wire carrying a current I in vertically upwards direction (y-direction) is placed near the
surface of earth as shown in figure. Neglect the earth’s magnetic field.

At some time t a particle is at point A (a, 0) and moving towards origin with velocity V. If the
acceleration of particle at point A is 2g in downward direction then choose the correct options.
(A) particle is negatively charged (B) particle is positively charge
 amg 
(C) magnitude of charge on the particle is  
 0VI 
 2amg 
(D) magnitude of charge on the particle is  
 0VI 
11. Two blocks A and B of mass 1.9 kg and 2.1 kg are suspended using an
ideal, massless pulley and string as shown. Initially, both blocks are at a
height 40 cm from the ground. The system is released from rest at t  0 . At
t  1.0 s , the string suddenly breaks at the point it is attached to block B. At
t  1.1 s , the velocity of the blocks A and B are v A and vB respectively and
their height above the ground is hA and hB respectively. Which of these
options is/are correct ?  g  10 m/s 2 
(A) v A  0.5 m/s, downward
(B) vB  1.5 m/s, downward
(C) hA  25 cm
(D) hB  5 cm

12. A uniform rod of mass m and length is released from rest in the vertical position on a rough square corner
A, shown in figure, then choose correct options :

(A) If the rod just begins to slip when   37 with vertical, then the coefficient of static friction 
between the rod and the corner is 0.3
(B) If the end of the rod is notched so that it cannot slip, then the angle  at which contact between the rod
and the corner ceases is 53°
(C) If the rod just begins to slip when   37, then the coefficient of static friction  between the rod and
the corner is 3/4
(D) If the end of the rod is notched so that it cannot slip, then the angle  at which contact between the rod
and the corner ceases is 37°

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SECTION 3
NUMERICAL VALUE TYPE QUESTIONS
This section has Six (06) Questions. The answer to each question is a NUMERICAL VALUE. For each question,
enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-off the
value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal pl aces. In
the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be bubbled.
(Example: 6, 81, 1.50, 3.25, 0.08)

13. Wind is entering in a wind mill with a velocity of 20 m/sec, facing area of the windmill is 10m2 and density of

air is 1.2 kg/m3. If wind energy is converted into electrical energy with 33.3% efficiency, find electrical power
produced by the wind mill (in kW).

14. Water (density 1000 kg/m3 ) emerges vertically from a tap of circular cross-section of area 5 cm2 at a
constant volumetric rate 2000 cm3 /s . The water strikes a fixed horizontal surface at a height 45 cm below
the opening of the tap. Assuming that the flow of water always remains laminar, and that the vertical
component of velocity of every particle of water becomes zero after collision with the surface, the force
exerted by the water on the surface (in Newton) is ________.
 density of water  1000 kg/m , g  10 m/s 
3 2

15. A radioactive element X undergoes  - decay with a half-life of T days to form a stable element Y.
Initially, a vessel contains mass m of 100% pure X. After every time interval of exactly T days, half of
the sample in the vessel (by mass) is removed. The mass of the element Y in the vessel after 4T days from
mf
the start (just before half the sample in the vessel is removed) is m f . The value of  100 (to the
m
nearest integer) is ________.

16. A closed steel cylinder is completely filled with water at 0°C. The water is made to freeze at 0°C.
n  108 Pa is the rise in pressure on the cylinder wall. It is known that density of water at 0°C is
1000kg/m3 and the density of ice at 0°C is 910 kg/m3. Bulk modulus of ice at 0°C is nearly 9  109 Pa.
Find the value of n.
17. A thin insulating rod of mass m and length L is hinged at its upper end
(O) so that it can freely rotate in vertical plane. The linear charge
density on the rod varies with distance (y) measured from upper end as
L
  ay 2 ;0  y 
2  .
 Where a and b are positive constants. When a
n L
 by ;  y  L 
2 
horizontal electric field E is switched on the rod is found to remain
a
stationary. Find the value of .
b
18. A hot body is suspended inside a room that is maintained at a constant temperature. The temperature
difference between the body and the surrounding becomes half in a time interval 20 mins. The duration in
1
which the temperature difference between the body and the surrounding will becomes the original
4
value in min is ________.

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PART II : CHEMISTRY 66 MARKS

SECTION 1
SINGLE DIGIT INTEGER
This section consists of SIX (06) questions. The answer to each question is a SINGLE DIGIT INTEGER ranging from 0
TO 9. BOTH INCLUSIVE.
1.  Al3 (g)  3e is 5140 kJ/mol.
The ionization enthalpy of Al(g) is 577.5 kJ mol–1 and H for Al(g) 
If second (IE 2 ) and third ionization enthalpy (IE 3 ) values are in the ratio 2 : 3 and the value of IE 2
(in kJ/mol) is 18.25 10x , then what is the value of x .

2. Among the given molecules, total molecules which have dipole moment zero is :
H 2 O2 , CIF3 ,CO 2 ,SO 2 , P4 ,S8 , CH 2 (CN) 2 ,C2 (CN) 4

3. Consider the following reaction,


Mg  HNO3 
 Mg(NO3 )2  N2O  H2O
Calculate the number of moles of HNO 3 required as oxidising agent to oxidise 6 moles of Mg.

4. The total number of S–O bonds having equal length in HSO4 is a. The total number of S–O bond having
equal length in S3O62 is b. What is the sum of values of a and b ? (a and b are integers from 0 to 9)

5. For Aspartic acid , the pKa1 , pKa 2 and pKa 3 are 2, 4 and 10

respectively and for Arginine , the pKa1 , pKa 2

and pKa 3 are 2, 9 and 13 respectively. If isoelectric point of aspartic acid is x and of arginine is y then
y  x is:

6. Among the following compounds the total number of compounds having internal plane of symmetry is:

(a) (b) (c) (d)

(e) (f) (g)

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SECTION 2
MULTIPLE CORRECT ANSWERS TYPE
This section consists of SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.

7. Which of these statement(s) is/are correct?


(A) In XeF2 , central atom Xe is sp 2 d hybridized
(B) The order of bond angle PF3  PCl3
(C) N 2 and NO have same bond order
(D) +3 oxidation state of Bi is more stable than +5 oxidation state
k1s 1
8. Consider the reversible reaction A B,
k 2s 1

for, this reaction following graph is given


k1  6 102 s1 . Which of the following is/are correct statement(s) ( n2  0.7)

(A) Equilibrium constant is 3.0


(B) Time taken for the completion of 50% of equilibrium conc. of B is 7.8 sec.
(C) X represents kinetic region and Y represents equilibrium region
(D) Rate constant of backward reaction is 3 102 s –1

9. Which among the following statement(s) is (are) true for the production of iron and steel?
(A) The oxide ore is primarily reduced to iron by solid coke according to the reaction
2Fe2O3  3C 
 4Fe  3CO2
(B) The oxide ore is reduced by the carbon monoxide according to the reaction
Fe2O3  3CO 
 2Fe  3CO2
(C) Major silica impurities are removed as calcium silicate slag by addition of a fluxing agent
limestone
(D) The silicate slag is used in manufacturing cement

10. Which of these reactions is/are correct?


(A) CuSO4  K 4 [Fe(CN)6 ] 
 Cu 2 [Fe(CN)6 ] 2K 2SO4
Re d brown ppt.

(B) Hg2Cl2  SnCl2 


 2HgCl2  Sn
(C) SnS2  4HCl 
SnCl4  2H2S

(D)

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11. Find the correct options in regards to the compounds shown below:

(A) (II) is most basic compound


(B) In (II) lone pairs of nitrogen are not involved in resonance
(C) The extent of resonance in (II), (III) is same
(D) (IV) is most basic due to +I effect of two methyl groups
12. Consider the following organic reaction and find the correct statements:
(i) CH3MgBr
 CH3 3 CO Na  (ii) H3O
A   B  C 
NBS ozonolysis

(reductive)
 D 
(iii) PCC
E
(C8H10 ) (C8H9 Br) (C8H8 ) (C7 H6O)
 HCHO (iv) NH 2 NH 2 /OH 

(A) A and E are having identical structure


(B) If the number of geometrical isomers of compound C is x and molecular weight of compound E is
y then the value of (x + y) is 106
(C) If the number of geometrical isomers of compound C is x and molecular weight of compound E is
y then the value of (x + y) is 108
(D) D is Benzoic acid

SECTION 3
NUMERICAL VALUE TYPE QUESTIONS
This section has Six (06) Questions. The answer to each question is a NUMERICAL VALUE. For each question,
enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-off the
value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In
the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be bubbled.
(Example: 6, 81, 1.50, 3.25, 0.08)

13. A certain weak acid (HA) has Ka  2 105 . If the equilibrium constant for its reaction with a strong
base is represented as 0.2 10a then find the value of a. [Given: K w  1014 ]

14. How much of oxygen (in mg) is dissolved in 200 ml at 298K when the partial pressure of oxygen is 0.5
atm. Henrys constant of oxygen is 1.4  103 mol L1atm1 at 298 K.

15. Calculate the energy (in kJ) required to excite one litre of hydrogen gas at 1 atm and 298 K to the first
excited sate of atomic hydrogen. The energy for the dissociation of H–H bond is 436 kJ mol–1.
Use Avogadro constant as 6.02  1023 mol1. (Report your answer as nearest integer)

16. Find the degree of unsaturation of compound E?

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17. One mole of a monoatomic ideal gas initially at a pressure of 2.00 bar and a temperature of 273 K is
U
taken to a final pressure of 4.00 bar by a reversible path defined by P/V = constant, the value of for
w
this process is:

18. The solubility product constant of a metal carbonate MCO3 is 2  1012 at 25°C. A solution is 0.1 M
M(NO3 ) 2 and it is saturated with 0.01 M CO 2 . Also the ionization constant of CO 2 are
K a1  4  107 and K a 2  5 1011 at 25°C respectively. The minimum pH that must be maintained to
start any precipitation is________.

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PART III : MATHEMATICS 66 MARKS


SECTION 1
SINGLE DIGIT INTEGER
This section consists of SIX (06) questions. The answer to each question is a SINGLE DIGIT INTEGER ranging from 0
TO 9. BOTH INCLUSIVE.
x
1. If 2 f ( x)  f ( xy)  f   for all positive values of x and y , f (1)  0 and f '(1)  1 . Find f (e) .
 y
x2
2. Consider a parabola y  and the point F (0,1) Let A1  x1 , y1  , A2  x2 , y2  , A3  x3 , y3  ….
4
k
An  xn , yn  are ‘n’ points on the parabola such that xk  0 and OFAk   k  1,2,...n  .
2n
1 n

m
If lim FAk  . ‘m’.
n  n
k 1 

3. If z is a complex number satisfying the equation | z  i |  | z  i | 8 on the complex plane. Let m and M
be the smallest and the largest value of | z | respectively, the  m  M  
([.] denote greatest integer function)

4. Let y  f ( x) is an invertible function satisfying f (1)  5, f '(1)  2, f "(1)  4 , then the absolute value of

 
2. f 1 " (5) is equal to :

1
5. Let x   p. x  p  q , for an unknown vector. If x is expressed in terms of p and q as x  p  q
p2
1
then find this absolute value of   if p and q are taken as, p  2iˆ  ˆj  kˆ and q  iˆ  ˆj  kˆ :

6. There are 8 events that can be scheduled in a week, then the total number of ways that these 8 event are
scheduled on exactly 6 days of a week is given by 266  k ! where k  N , then k is :

SECTION 2
MULTIPLE CORRECT ANSWERS TYPE
This section consists of SIX (06) Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE THAN ONE CHOICE is correct.

7.      
Let f ( x)  x  1  x  x 2  1  x  1  x 2 x3  .....  1  x  1  x 2 ..... 1  x n 1 x n ;  n  4  then:

   1  xr 
n n
(A) f ( x)   1  xr (B) f ( x)  1 
r 1 r 1

 n 
r 1  n r x r 1 
f '( x)  1  f  x     
rx
(C) r  (D) f '( x)  f ( x)  r 
 r 1 (1  x )   r 1 (1  x ) 
x2 y 2
8. Let P  x1 , y1  be a point on the hyperbola   1 . The tangent at point P passes through the point
a 2 b2
 0, b   
and the normal at point P passes through the point 2 2 a,0 . If e denotes the eccentricity of the
hyperbola then which of the following is/are correct?
(A) x1  2a (B) x1  2a (C) y1  b (D) e2  2

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9.      
If a  b  c  a.b b   4  2  sin  b   2  1 c and  c . c  a  c , where b and c are non-collinear

vectors, then:
 
(A)  (B)  (C)  1 (D)   1
2 3
x2
 1 
10. For the function f ( x)    cos t
 1 dt , x  1 :

0

(A) f ( x) is an increasing function in the interval 1, 


(B) lim f "( x)  4
x 

(C) f (4)  f (6)  2 f (5)


(D) for at least one x in 1,   , f '  x  3  f '( x)  12

 /2

 tan
3
11. x cos5 x cos 7 x dx is equal to:
0
0 0
1 1
(A)
8sin 2 x sin 3 xdx (B) 
8  /2
sin 2 x sin 3xdx

1 1
(C) (D)
30 60

12. Let H : y  3 y  4 x   4 is a hyperbola and y  mx  c is its conjugate axis. Length of latus rectum of H
is L, eccentricity e and  x1 , y1  is one vertex with y1  0 , then:

(A) m2 (B) L 1 (C) 4e 2  5 (D) 5 y12  4

SECTION 3
NUMERICAL VALUE TYPE QUESTIONS
This section has Six (06) Questions. The answer to each question is a NUMERICAL VALUE. For each question,
enter the correct numerical value of the answer. If the answer is a decimal numerical value, then round-off the
value to TWO decimal places. If the answer is an Integer value, then do not add zero in the decimal places. In
the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign should be bubbled.
(Example: 6, 81, 1.50, 3.25, 0.08)

13. Three circles of radius 11, 11 and 50 units are touching each other externally and a fourth circle of radius
r is placed such that it touches all 3 circles externally then r is equal to:

14. Let z1 and z2 are two distinct roots of the equation z101  1 then the probability that z1  z2  2  3
is:

15. In a tournament four players are participating. Each player play with every other player. Each player has
50% chance of winning any game and there are no ties. If the probability that at the end of tournament
a
there is neither a winless nor an undefeated player is there is , where a and b are relatively prime
b
integers then | 2a  b | is equal to:

VMC | JEE-2021 | Paper-2 12 JEE Advanced Final Practice Test-6


Vidyamandir Classes: Innovating For Your Success
n

 f (2r )
r 1
16. Let f ( x) is a polynomial such that f ( x)  f "( x)  x  7 x , then lim
3
is
 2.3  ...  n  n  1
n 1.22 2 2

equal to:
3A
17. The area bounded by the curves y  6 x  x 2 and y  x 2  2 x is A, then value of is:
8

 2  5 4 
18. If cos5 x  cos5  x    cos  x    0 , then find the number of solution(s) in  0, 2 .
 3   3 

VMC | JEE-2021 | Paper-2 13 JEE Advanced Final Practice Test-6

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