Course Outline NIVERSITY OF CHEM 102: UNIVERSITY CHEMISTRY II FALL 2014 TIME T ABLE — Dr. Roy Jensen WINTER 2014 (CHEM 102 (H1) (CHEM 102 (H1)_ (CHEN 105 401) (CHEM 105 (H01) TLE 1-001 ETLE 1001, CHEM 102 D1) CHEM 102 D1) ‘CHEM 102 D1) ccc1s12.200, ccis.2-200 cc1s12-200 (CHEM 105 (KOL) CHEM 105 (K01) Chemistry E1-60 Chemisty E1-60 Tealiatte va drop-in and iy apolar Office: Chemistry E5-33F Email: Roy Jensen@UAlberta.ca Phone: 780.248.1808 Weise: sin eClssCourse Information Hours: Lecture: 3 Lab: 3 Seminar: 1 Description: Rates of reactions, thermodynamics and equilibria, electrochemistry, modem applications of chemistry. Objectives: + to Jearn principles that influence the spontaneity, rate, extent, and direction of chemical reactions + to applying these principles to logically solve chemical problems + to develop a better understanding of the role chemistry has in our lives + to leam to think critically about chemical issues Prerequisite: CHEM 101/3 or equivalent Required Resources: Silberberg Chemistry, 6" ed., MeGraw Hill. CHEM 102 University Chemistry Laboratory Manual, 2013/14 ed. Laboratory coat and safety glasses Optional Resources: Student Solution Manual to Chemistry, by Silberberg Evaluation (CHEM 102 Term Exam T 10% | Wednesday, 29 January Gaaas) Term Exam Il 20% | Friday, 14 March (inclu) Laboratory Course 25% | Scheduled by the laboratory coordinator. Final Exam 45% | Monday, 14 April (1400~ 1700) (aeaniveloation TBA) ‘The laboratory manual has the weighting of the experiments and laboratory final exam. Questions are assigned, from multiple sources, approximately once every two weeks. The assigned exercises are to assist you in learning the course material to the expected depth. You are strongly encouraged to keep up with the assigned exercises. As an incentive, a few assigned ‘questions may also appear on ferm exams and final exams. Answers will be posted one to two weeks afier the questions are assigned Students are responsible for verifying the date, time, and location of the final exam when the final exam schedule is posted later in the tem. Copies of selected student exams may be taken and used to thwart or investigate academic misconduct, prepare future exams, ete. (CHEM 102 (DI) - Course Outline.doe =a Roy JensenGrading Grades are assigned according to specifications in the Grade GPA University Calendar (section 23.4.4). This course will be Ae 40 marked following a combination of absolute and relative | excefient AL 40 criteria. Grades in this class (which is comprised of ao) a7 CHEM 102 (D1)) will be assigned in a manner similar to : 33 that used in all other sections of introductory general i 30 chemistry. 139 A student absolute score will be converted to a percentile ce 3 ranking which will be used as the primary evaluation of | satisfactory © 2.0 performance. Within this class, the weighted totals will be ST] 7 computed (sum of each assessment multiplied by its "pass D+ 13 weight) and all students will be ranked based on their | poor D 10 overall total fail FIFA 0.0 The instructor will look at the overall totals to assess variations in achievement (je., excellent, 2004, satisfactory, pass, poor and failure performances). This assessment will be used as the basis for assigning letter grades. In previous years, the average GPA in this course has been between 25-2. Important Dates 06 Jan 14 1" first day of classes 17 Jan Last day for program changes (add/érop courses) 17-21 Feb Reading break (no classes or laboratories) 02 Apr Last day to withdraw without academic penalty 09 Apr Last day of instruction 12-28 Apr Final examination period 18 Apr Good Friday (no classes or laboratories) 21 Apr Easter Monday (no classes or laboratories) Lecture information ‘You should only attend the lecture section you are registered in, and you are expected to attend every lecture class. In teaching this course, I make certain assumptions regarding, your input into this course; these assumptions set the instruetional level and evaluation level. Students are assumed to + have prepared for this course by reviewing the prerequisite material + pre-read the chapter before it is presented in class + review the notes taken in class before the next class + work on the assigned questions regularly and be able to independently solve similar problems during the examination + ask for clarification if they cannot understand a concept or cannot solve an exercise + have attempted to solve an exercise before asking for assistance with the exercise inClass Live The instructional material and the instructor’s audio is broadcast and available on eClass after class. Recorded material may only be used for personal study, and is not to be used or distributed for any other purpose. (CHEM 102 (D1) - Course Outlinedoe Roy JensenLaboratory information ‘You must register for a laboratory section separate from the lecture section. You may only attend the laboratory section you are registered in, and you are expected to attend every laboratory class. Failure to do so will result you failing this course. Laboratory classes begin the week of 20 January. Room assignments will be posted outside E2~ 34 and on the Chemistry Laboratory web site. Chemistry Department policy requires that students arrive to att. laboratory periods (including ‘Check In and Check Out) wearing proper Personal Protective Equipment (PPE): approved safety glasses, a lab coat, wearing long pants, and wearing closed shoes. Students without proper PPE ‘must purchase or rent the missing items from Chemistry Stores (W1-32) before entering the lab. During all laboratory sessions, you ae required to wear PPE at all times and comply with all the laboratory regulations. The laboratory regulations are listed in the laboratory manual. Prior to attending your first laboratory session, you must read the instructions, introduction, introductory laboratory experiment, and complete the prelaboratory assignment. The laboratory and lecture components of this course are not synchronized. For some experi- ‘ments, you will be expected to independently find and learn material to understand and complete the experiment. This requires independent learning — a skill expected of students. Ifyou took this course previously at the University of Alberta and failed, you may be eligible for a laboratory exemption. To apply for an exemption, contact Dr. Norman Geo, the lab coordinator, in E2-34B ot via phone at 780.492.3438, Seminar information The hours and location for the seminar are given below. These are not structured classes and are intended to provide you with tutorial assistance for the lecture, homework, and laboratory. These sessions are taught by teaching assistants. You may attend any seminar session you wish. ‘Schedile subject ro change. ‘Available via drop-in. Staffed by teaching assistants, (CHEM 102 (DI) - Course Outline.doe Roy JensenQuestions? Questions on lectures, exams, or problem sets: contact Dr. Jensen. Questions on registration changes and scheduling of lectures and laboratories: contact Dr. Gee. Assistance with laboratory reports, lecture topies, and assignment questions: contact the teaching assistants in the seminar room, Student Responsibilities Students are expected to be aware of their academic responsibilities as outlined in §23 (Academic Regulations) of the University Calendar. The policy about course outlines can be found in §23.4(2) of the University Calendar. Acapemic INtEGRITY. The University of Alberta is committed to the highest standards of academic integrity and honesty. Students are expected to be familiar with these standards regarding academic honesty and to uphold the policies of the University in this respect. Students are particularly urged to familiarize themselves with the provisions of the Code of Student Behaviour (online at www.governance.ualberta.ca) and avoid any behaviour which could potentially result in suspicions of cheating, plagiarism, mistepresentation of facts and/or participation in an offence. Academic dishonesty is a serious offence and can result in suspension or expulsion from the University All forms of dishonesty are unacceptable at the University. Any offense will be reported to the Senior Associate Dean of Science who will determine the disciplinary action to be taken. Cheating, plagiarism, and misrepresentation of facts are serious offenses. Anyone who engages in these practices will receive at minimum a grade of zero for the exam or paper in question and no opportunity will be given to replace the grade or redistribute the weights. As well, in the Faculty of Science the sanction for cheating on any exam will include a disciplinary failing grade (no exceptions) and senior students should expect a period of suspension or expulsion from. the University of Alberta. ExaMNations. All exams are cumulative and closed book. A data sheet will be provided by the instructor. Please bring your student ID to all exams. Permission to use the washroom during ‘exams is at the discretion of the instructor and may require accompaniment. §23.5.1(8) of the University Calendar states that students must promptly cease writing when the signal is given to end the exam. If a student does not stop at the signal, the instructor has the discretion either not to grade the exam paper or to lower the grade on the examination. ELEctRonics. Unless explicitly stated herein, electronic equipment is not permitted during class or during examination periods. Students are permitted to take notes electronically, but are not permitted to audio and/or video any instructional environment, During exams, only stand-alone calculators are permitted. In CHEM 102, I expect you to have a calculation with the Sorver function. The following calculators have this fimetionality (please advise me of others). * Casio FX-300MSPlus * Sharp ELWS16XBSL * Casio FX-991MS + Texas Instruments TI-36X, TI-8x and TI-9x series (CHEM 102 (D1) - Course Outlinedoe Roy JensenAudio or video recording of lectures, labs, seminars, or any other teaching environment is allowed only with the prior written consent of the instructor or as a part of an approved accommodation plan. Recorded material is to be used solely for personal study, and is not to be used or distributed for any other purpose without prior written consent from the instructor ABSENCES. An excused absence is a privilege, not a right, and is granted at the discretion of the instructor (term exams) or the Faculty (final exam). Permissible excuses include incapacitating illness, severe domestic affliction, or other compelling reasons (including religious conviction) Students applying for an excused or deferred exam must provide the instructor/Faculty with appropriate documentation — UofA medical form, doctor’s note, UofA coach’s letter, Statutory Declaration, etc. — within 48 hours of the missed exam. See Section 23.3 of the University Calendar for more information. ‘Missep TERM EXAMINATIONS. No makeup exams are given. An excused absence will transfer the weight of the missed exam to the final exam. An unexcused absence from an exam will result ina score of zero for that exam. DEFERRED FINAL EXAMINATION. Defer final exams are granted by the student's Faculty. Applications for deferrals must be initiated within two working days of the missed exam. Misrepresentation of facts to gain a deferred exam is a serious breach of the Code of Student Behaviour. Upon obtaining a deferral, the student must write a deferred final exam. The deferred final exam for Chem 10x is scheduled for Tuesday, 13 May 2014, from 1300 — 1600 in Chemistry 3-25 LATE ASSIGNMENTS. As due dates for assignments are known well in advance, medical and other excuses are generally not accepted as a reason for submitting late assignments. SrupeNts WiTH DISABILITIES. Students who require accommodation in this course due to a disability are advised to discuss their needs with Specialized Support & Disability Services (2- 800 Students’ Union Building). ACADEMIC SUPPORT CENTRE. Students who require additional help in developing strategies for better time management, study skills or examination skills should contact the Academic Support Centre (2-708 Students’ Union Building) VALBERTA EMAIL. All students are given a @UAlberta.ca email address. This email address is used to communicate with students. Check your UAlberta.ca email regularly or forward it to an email address you do check regularly. To protect your privacy, you must communicate with your instructor from your UAlberta.ca email account. DISCLAIMER: The information in this Course Outline is subject to change. Any changes will be announced and distributed in class and, if applicable, in the laboratory. (CHEM 102 (DI) - Course Outline.doe ~6- Roy JensenChemistr Past Ltag te ak Textbook sections presented in CHEM 102) MODULE 1: Chemical Kineties 16.1 Focusing on Reaction Rate 162. Expressing the Reastion Rate 163. The Rate Law and Its Components 16.4 Integrated Rate Laws 165. Theories of Chemical Kinetics 166. Reaction Mechanisms 16.7 Catalysis: Speeding up « Reastion MODULE 2: Che sal Equi ia 1 The Equilibrium State nd the Equilibrium Constant 3 Expressing Equilibria with Presstne Terms: K, and Ky 2 The Reaction Quotient and the Equilibrium Coostant “4 Comparing Q and K to Determine Reaction Direction 6 How to Solve Equilibrium Probleme Reaction Conditions and Equilibrium 18.L_ Acid and Bases in Water 182. Autoionization of Water andthe pH Seale 183. Proton Transfer and the Bronsted-Lowry Definition 184. Solving Problems lavolving Wenk-Acid Equilibria ISS Weak Bases and Their Relation to Weak Acids 186 Molecular Properties and Acid Strength 187 Acid-Base Properties of Salt Solutions 188 Generalizing the Brousted-Loury Concept 189. Electron-Peir Donation andthe Lewis Definition 19.1 Equilibria of Acid-Base Butfers 192 Acid-Bose Titration Curves 4.3. Precipitation Reactions 19.3, Equilibria of Slightly Soluble Tonic Compounds 194 Equilibria Involving Complex Tons MODULE 5: Coordination Chemistry 23.1. Properties ofthe Transition Blements 233 Coordination Compounde 23. Theoretical Basis fr the Properties of Complexes (CHEM 102 (D1) - Course Outlinedoe MODULE 4: Thermodynamics 1 Forms of Energy and Their Intercouversion 2 Enthalpy: Chemical Change at Constant Pressure 4 Stoichiometry of Thermochemical Equations ‘5. Hess's Law Finding OH of Any Reaction {6 Standard Enthalpies of Reastion 84 Bond Energy and Chemical Change 63 Calovimety: Messuring the Heat of Reaction The Second Law of Thermodynamics Calculating the Entropy Change of a Resetion Entropy, Free Energy, aad Work Free Energy, Equilibrium, and Reaction Ditection MODULE : Electrochemistry 1 Redox Reactions and Electrochemical Cells 2. Voltaic Cell: Generate Elestrical Energy 3. Cell Potential: Ouput ofa Voltaic Cell 4 Free Energy and Electrical Work 5. Electrochemical Processes in Batteries 6 Corrosion: An Environmental Voltie Cell Electrolytig Cells: Using Elestical Energy 1 1 7 Approximate Timeline Intro 1 hr Term exams ~2 hrs ‘Term exam review —0.5 bre Ch 16- She Ch. 6-4 brs cht chars ch. 20-4 ch. 18-4 Ch. 19-3 4 chs Roy JensenLearning and study guide Koonences ests as nenral nenworks i the Brain, Leanne isa biophysical process and occurs when new connections are farmed benveen neurons, expanding the neural nenvork. These connecions ars not permanent Repeated ws, in varied for, 1s erteal (0 strengthening the connections and expanding them to omer networks. WPtiou repeon andl continued we, connections degenerate 1. Read the text before class. Dow’ expect to understand it all jut read it Reading the tutbook bee class aust you withthe infomation 49a he ‘aston ie where Yow ee the sana or the econ te Yon Sind youself saying, "OM,s ho wht he teehoak eae 2. When studying, don’t just read, write and talk! saline ae fom of eve lenin “Taking gots, rewning your notes, and completing asignmeats uses motor skis father suengthen and expand the seul setworksRewiting Sou ote (ocekly and gain the ea of tem) frees You to eel ete the formation, ell he rasratthoopht ofthe soto and repent ts YR cen woe nora. Yow end ip wth 2 amaller bm cope tof ‘ote om ick ah! When ssa, wor vol exeroae na smulnted ccamiston meron! se. wtb! come ‘he soln vssal). Cue eats ora super susazary of your sees ae agent Sd) tel These coun cay the fo concepts ‘and key pow: ead ey point and th il he deta i your mind. “Tallies forces you to dyamically formulate your Enowiedge sto core ttre, agin sing and expanding the seal sotworks. Woekag i per soups (Oo to sux props) 6 an excallat Way Wo pool aud sie kaouledge, Stueuts een expla ‘oncope ns tht pers an reat and tating van eet ay lee 3. Don’t pall ‘all nighters’. ‘Your ably to lean when fied is very low Fushemae, your ands biiy to eal infomation ad dam fvlate samen in inter fou gets ood night sleep ative ffeaffe ce ‘Don’t study right up to the exam. “Take at east furor ben efor he exam Get ache go for + wat, tothe gym. ee. Your mind cat eter conse what {ou fave Teabed if you aeat cramming moe in You tibd wll be eeeshad for the exams and You wil be abet real Bmation acer Exam-taking suggestions 1. Read the exam start to finish. “This sould ke no mare han a fe nies but wil give you aa oveviw of thee exam. Your mind wil ein procesing ll the qustons Some msrstrs even ge hits amr 0 esto in ote quetons ow may times have ou been stumped on a question during the exam and. wl walking away, bad a revelation on how fo answer it You weve chakingsbou were yu? Now conse your mil had Ween uncoascious)precesing Hat gueston fr 2 le longer ike fom the a of he exam) 2. Go through the exam and answer questions you know ‘by heart’. ‘Your tam-ofthouph shouldbe, “One: Tino how ta do this. Five ike hie caaswer Si ‘Rereading th questions wil Keo your mind working on then. Whea th felon ses “Oh yea, das how question thoes one! go bck and complete tre wl sl esh mone mind Ifyou ae soon a question, move onto he net ene 3. Go through the exam and write something for questions you haven’t tried yet As you tke higher devel cores, questions become mere complex and ther may be more than one path to the comet ans. ‘Wiig my spr sien Try evaitng the question in your owe words ad joing dao es, Do tbe nid to wre someting ‘uty be wous Lfaohing che, puting sens ou paper ues the asivcorsomedaing mak! J Reread each question and your answer. you bea secon: guet Yousel leav the fs anewer Stages have sown thatthe at answer i more olen correct. 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