by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” 2. Atomic Structure 2. ATOMIC STRUCTURE Fundamental Topic Wise Q. {a) Half ofthe potential energy Discovery and Properties of anode, (0) Twice of the Loans my cathode rays neutron and Nuclear structure fe) Ona feultol he piensa (a) None ofthese . 9. The density of neulrons is of the order INCERT 1980) 1, Anneutral atom (Atomic no. > 1) consists of fa) 10°kg/ce {b) 10°kg/ce (opr 1982) (6) 10°kg/ee (6) 10" gree (2) Only protons 10. The discovery of neutron becomes very late because (b) Neutrons + protons (CPMT 1987; AIMS 1998) (@) Neutrons + decrons {o) Neutrons are present in nucleus {b) Neutrons are highly unstable particles a (a Neuron + poton + electron {ay Neuron + proton + elec +e) Neutrons are chargeless (a). Neutrons do not move “The nucleus of he atom consists of [CPNT 1973, 74, 78, 83, 84; MADT Bihar 1960: 11. The fundamental patles present in the nucleus ofan 210m {CPMT 1983, 84) DPMT 1982, 85; MP PMT 1999] are (a) Proton and neutron (a) Alpha particles and electrons (b) Proton and electron (b) Neutrons and protons (o) Neutrons and electrons Neston an econ “ (d) Electrons. neutrons and protons (8) Proton, neutron and electron 12. The order of density in nucleus is The sizeof nuceusis ofthe order of INCERT 1981, CPT 1981, 2003] \eronr 1962; MPT 1591) fa) 10%kg ce (b) 10%kg/ee (2) 10m {b) 10°%m () 10°kg/ee {d) 10"kg/ec (107m (4) 10% 13. Cathode rays are [JIPMER 1991; NCERT 1976) Positive ions are formed from the neuta atom by the (0) Protons (b) Electrons 7 [CPMT 1976) {c) Neutrons {d) a -particles (a) Increase of nuclear charge 14. Number of neutron in C'? is [BCECE 2005) (b) Gain of protons fa) 6 (b) 7 {(c)_ Loss of electrons i) & (a) 9 (d)Loss of protons: oO 15, Heaviest particle is [DPMT 1983; MP PET 1999] “The electron is (a). Meson (b) Neutron (©) Proton (4) Electron [DPMT 1982; MADT Bihar 1980] (b) P-reypatticle 7 16, Penetration power of proton is [BHU 1985; CPMT 1982, 88) (0) roy pride (0) Hydogen ion (@) Psion {0} More than clecion —_(b) Less than electron ‘Who discovered neutron {@ More than neutron {d) None TIT 1982; BITS 1988,CPMT 1977; NCERT 1974 17, An elementary parle (cen 1973) [MPPMT199%; MP PET 2002} {a). An clement preset in @ compound {o) domes Chick (b) Wiliam Crooks {b) Anatom presentin an element (6) 8s. Thomson (a) Rutherford {9 Asublatomie price The loc ge and mass wu be reser for (2) Afogrest fan stom Panu 2005) 18: The nucleus of helm contains (0) Proton (b) Blecton 1 Foun {cporr 1972; pre 1982) (6) Nesron hae (b) Four neutrons [BCECE 2005) ‘Magnitude of KE. in an orbits equal fo 155 | Vidvo kendsA - Head Off: 108, Kingsway camp (Near GTB Nar Metro station Gate No.-3), Delhi ~ Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014. waww.vidyakendra.com a TE TE UTeee eS ON honoured by “Shiksha Ratna» 7 2 (6) Two neutrons and two protons (a) Chadwick (0) Thomson (@) Four protonsand te etcrons (<) Goldstein (2) Bohr 19. Which is comet satemen about proton 30.. The minimum chron ay pri which ca ey, (CPOET 1979; MP Pat 1985; NCERT 1985; MP PET 1999) is (a}_ Proton s nuceus of deuterium (b)_Protonis ionized hydrogen molecule (6) Proton s ionized hytrogen atom (2) Protonis «particle 20. Cathode rays axe made up of Amu 1983) (a) Positively charged particles (bo) Negatively charged particles (e)_ Neutral parices (@) None ofthese 21. Anode rays were discovered by (opr 1985), {9)__Goldsein [b) J.Stoney (e) Rutherford (8) JJ. Thomson 22, The radius of on alomis ofthe order of, [aMU 1982; IT 1985; MP PT 1995] (@) 10cm {b) 10cm fe) 10em (a) 10°%em 23. Neutron possesses lepmr 1982), (a) Positive chorge (b) Negative charge le) No charge (d) Allare conect 24. Neutron is fundamental particle coming IcPMT 1990) (a) A charge of +1 unit and a mass of} unit (b) No chargeand 2 mass of 1 unit {e) No charge and no mass (2) A.charg of-1 and a mass of 1 unit 25. Cathode rays have [cPwT 1982) (a), Mass only (b) Charge only €) Nomass and charged) Mass and charge both 26. The sie of nucleus is measured in - IEAMCET 1988; CPT 1994} () Angsrom (@) em 27. Which phrase woud be incorrect fo use [AMU (Engg.) 1999] - (a) emu (¢). Fermi (a) A molecular ofa compound (b) A molecule of an element (c} Anatom ofan element (d) None of these 28, Which one ofthe following pais is not comrectly matched (MP PET 2002) (2) Rutherford-Proton (b) JJ. Thomsom lection (6) JAH. Chadwick Neutron (€) Bohr-lsotope 29. Proton was discovered by [APMC 2004) 16 | Vidva kendra - Head Off: 111, a1 32. 33. 34, 35. 36. 37. 38, 39. 40. ai. ‘ingsway camp (Near GTB Nar Metra station Gate No Corporate Office : D-32, Hardev Nagar, Jharoda. (Near Burari by-pass), Delhi-84. Ph-011-47024312, M.-9555 87 50 87, 9312 10 2014, (RT 2009) (©) 1.6% 10 Coulomy (€) Zer0 The nature of anode rays depends upon, fo) 16%10° Coulomb {e) 48%10"" Coulomb MP PET 2005) (6) Nature orsidua ag (6) Noture of aischarge tube (d) All the above One would expet proton to have very large (a) Nature of electrode (>. CET 2004 (b) Radius (4) Hydration energy The mass of» mol of proton ond election is (2) 6.023x10%) (2) lonization poteniial (4) Charge (6) 1.0089 and 055mng (@) 2am The average distance of an electron in an at (a 91910 kg fom from its madlesis ofthe dere ~~ TRE gg — (2) 10% (0) 10m (©) 10°%m (4) 10m ‘Tisitass of mole of lcrons is (. CET 2004) (@) 91x10°%y (b) 1.008mg (2) 055mg (4) 9.1x107"9 Theo of specie dhage ofa olan anton PARSE. — IMP PET 1999) (2:1 fb) 1:2 (aa (@ as Ratio of masses of protonand electron is [BHU 1998) (a). Infinite (0) 18x10" (9 18 (2) None ofthese Spitting of signals is caused by (Pb. PAT 2000) (0) Proton (b) Neutron {€) Positon (Electron The poton and neuiton are collectively called as (oP PET 2001) (e) Deutron (0) Positron (2) Meson (a) Nucleon ‘Which of the following has the same mass as that of an electron [ANC 2002) (2) Photon () Neutron (2) Positon (@) Proton ‘Whats the ratio of mass ofan electron fo the mass of proton [UPSEAT 2008) 1), Delhi yaww.vidyakendra.com2. Atomic Structure (yy ted (@) 3 (a) 1:2 (e) 151837 Atomic number, Mass number, Atomic spec 1, The number of electrons in an atom of an element is equal toits [BHU 1979} (a), Atomic weight () Atomic number (6) Equivalentueight ——_(d) Electron affinity ‘The nucleus of the element having atomic number 25 ond atomic weight SSuill contain ICPNT 1986; MP PMT 1987) (2) 25 protonsand 30 neutrons (b} 25 neutrons and 30 protons (6) 55 protons (4) 85 neurons 7 3. If Wis atomic weight and N isthe atomic number of an “Blefnent then [CPM 1971, 80, 89) (2) Number of e? = WN (0) Number of ga! = W-N (€) Number of ,H* = WN (4) Number of gn! = N 4, The total number of neutrons in dipostve zinc ions with ‘mass number 701s UIT 1979; Bihar MEE 1997) (2) 34 (o) 40 le) 36 (a) 38 5. Which ofthe following are isoelectronic wth one another INCERT 1983; EAMCET 1989} (e) Nav and Ne (b) K* and O “~ (e) Ne and (4) Na* and K* 6. Thenumber of electrons in one molecule of CO, are [irr 1979; MP PNT 1994; RPDIT 1999) (2) 22 (bo) 44 (6 (8) 88 7. Chlorine aiom fers rom chlovde ion in the number of INCERT 1972; MP PMT 1995) (a) Proton (b) Neutron (6) Electrons (d) Protons and electrons 8. CO has same elections as or the ion that is isoelectronic with CO is (CPT 1984; IIT 1982; EANCET 1990; CBSE PMT 1997) (a) Ng (o) oN” {Of (a) 03 9, The mass of an atom is constituted mainly by IDPMT 1984, 91; AFMC 1990) (0) Neutron and neutrino (b) Neutron and electron (€) Neutron and proton _(d) Proton and electron 10. The atomic numberof an element represents ICPMT 1983; CBSE PMT 1990; NCERT 1973; AMU 1984) (0) Number of neutrons in the nucleus (b) Number of protons in the nucleus by S.K, Singh (FMS, IIT & BARC)’, honoured by “S| ML 2. 13. “4 15. 16. a7, 18. 19. 20. Ph-011-47024312, M. 9312 10 2014. iksha Ratna” [e}_ Atomic weight of element {d)Valancy of element ‘An atom has 26 electrons and ils atomic weight is 56. The ‘number of neutrons in the nucleus of the atom will be [cPer 1980) (2) 26 (by 30 (0 36 (a) 56 “The most probable radius {in pm) for finding the electron in He’ is aims 2005) (2) 00 (b) 529 (9 265 (a) 1058 ‘The number of unpaired electrons in the Fe ionis IMP PET 1989; KCET 2000), {o) 0 (b) 4 9 6 (a) 3 ‘A sodium cation has different numberof electrons Irom (a) 0% () F ou (@ ar ‘An atom which has lst one electron would be IcPMT 1986) (a) Negatively charged (b) Positively charged (@) Electrically neural (4) Carry double postive charge [Number of electrons in the outermost orbit ofthe element of ‘atomic number 15is IcPMT 1988, 93) @1 () 3 5 (a7 The atomic weight of an element is double its atomic IF there are four electrons in 2p orbital, the— umber ‘element is [au 1983) (aC (oN 0 (a) Co ‘An atom has the electronic configuration of 1s*.2s*2p%, 38*3p*3d"",4s74p%. Ils atomic weight is 80. Its atomic ‘number and the number of neutrons in its nucleus shall be IMP PMT 1987) (0) 35 and 45 (b) 45.and 35, () 40and 40 (4) 30 and 50 Which of the following particles has more electrons than neurons (a) c (b) F () OF (d) ar? Compared with an atom of alomic weight 12 and atomic number 6, the atom of atomic weight 13 and atomic number 6 INCERT 1971) (a) Contains more neutrons (b) Contains more electrons {e) Contains more protons (4) Isa different element Inthe nucleus of 3yCa® there are ICPMT 1990; EAMCET 1991] (2) 40 protons and 20 electrons (b) 20 protons and 40 electrons 17 | Vidya kendrA - Head Off: 108, Kingsway camp (Near GTB Ngr Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. www.vidyakendra.com2 22, 23. 24, 25. 26. 21. 28, 29. 30. 31. 32. Atomic Structure (©) 20 protons and 20 neutons {a} 20 protons an 40 neurons Noon is itoslectoni with | {CPNT 1990) () ur (0) Mg? Co? (a) Bo? Ca has atomic no, 20 nd atomic weight 40. Which ofthe ving statementsis nol conect about Co alom following statements is nt comet abot aoe (a). The numberof eectons is same a the numberof neutrons (0) The numberof nodeonsisdouble ofthe number of eens (@) The numberof preter half the number of neutrons (4) The rumber of radconsis double ofthe alomie number Pick out the isoelectronic srucures from the folowing CH; yO" NH, CHs wr 1993) v 1 ow w la) Jand th (b) tandiv {Tend tt (e) Mlland iv Number of electrons in ~CONH, is [amu 1988) (a) 22 (by 24 a) 20 (@) 28 The atomic number of an element having the valency shel electronic configuration 434° is [MP PMT 1991) (a) 35 (b) 36 (e) 37 (@) 38 ‘The present atomic weight scale is based on EANCET 1988; MP PMT 2002) fac? (y) oF oH ic? ‘boeectronic species are {EANCET 1959) (a) Kcr {b) Ne*,Cr (ce) No,Ar {¢) No" ,Ar 1 the atomic weight of an element is 23 times that of the lightest element ond ithas 11 protons, then it contains IEANCET 1986; AFUIC 1989) {0} 11 protons, 23 neuttons, 11 electrons ~ (O) 11 protons, 11 neutrons, 11 electrons (6) 11 protons, 12 neutrons, 11 electrons (@) 11 protons, 11 nevirons,23 electrons Which of the following oxides of nitrogen is isoelectronic wih CO, {CBSE PNT 1990), a} NO, (b) NO (a No (8) NO, ‘The ratio between the neurons in C and Si with respect to ‘atomic masses 12 and 28’ IEANCET 1990), (@) 2:3 (b) 3:2 (3:7 (@) 7:3 The atomic number ofan element is always equal to IMP PMT 1994), {a} Atomic weight divided by 2 {(b) Number of neutrons inthe nucleus 18 | Vidva kendrA - Head Off: 111, King Corporate Office : Ph-011-47024312, 33. 34, 35. 36. 37. 38, 40. 41. 42. 43, 44. sway camp (Near GTB Ngr Metro station Gate No-1), -32, Hardev Nagar, Jharoda, (Near Burati by-pass), Delhi-84. -9555 87 50 87, 9312 10 2014. by Se Singh (PS ES Se Honoured by "Shiksha Rainy 9 (6). Weight of he mucous (4) Becca charge of the nucleus hie of heen is isocedonc wth crbon jon INP PME 1954 Usa 2g (bo) AP (a) (a) Nov (9 oF CO, is isostructural with UT 1986; HP FOKT 1986, 95 9 () so, : (3) All the atove ‘The hydride ions (H") are isoelectronic with {AFHC 1995; Bihar MEE 199) (a) SnCl, (ec) HgCl, (i (o) Hee () He (@) Be ‘The number of electrons in the nucleus of C2 is TAFMC 1995) (0) 6 (bo) 12 (0 (a) 3 ‘An element has electronic configuration 2, 8, 18.1 His atomic eight is 63, then how many neute (ONS wil be Dresent.inits nucleus __ ae le) 30 () 32 = (9 34 (a) 33 ‘The nucleus ofthe element 9, contains (2) 45 protons and 21 neutrons {b) 21 protons and 24 neutrons (221 protors and 45 neurons (€) 24 protons and 21 newtons Neutrons ae icone aTonS ofa elements exeepTin IMP PT 1997) (2) Chlorine {b) Oxygen. (€) Argon (a) Hydrogen ‘The mass number of an anion, X*, is 14. If there are ten electrons in the anion, the number of neutrons in the nucleus of atom, Xp of the element willbe IMP PMT 1999) (@) 10 (14 7 (5 Which of the following ate isoelectranie species 1 = CH3,lI~ NHI NHj,IV-NHg (PMT 1999) Om (>) aa. © un (@) Vand ‘The charge on the atom containing 17 protons, 18 neutrons and 18 electrons TADMS 1996) (a) 4 (o) -2 ) (a) Zero Number of unpaired electrons in inet gas is (CPNT 1996) {0} Zero (bo) 8 4 (a) 18 ‘mn neutral atom, which particles are equivalent [RPT 19971 Delhi-9.2. Atomic Structure 45. 46. 47 48. 49. 50. 51. 52. 53. 54. 55. 56. a) pie (o) &°,e oer (a) pia? Nuclei fend fo have more neultons. than protons at high rmass numbers because {Roorkee Qualifying 1998} (o). Neutrons are neutral particles (b) Neutrons have more mass than protons (Mote neutrons triniize the coulomb repulsion (4) Neuitons decrease the binding energy ‘hich one ofthe folowing isnot isoelectronic with O (COSE PMT 1994) fo) N* () F (9 1 (a) No* ‘The number of electrons in [33K] (CPMT 1997; AFMC 1999) (19 (b) 20 (18 (@) 40 ‘The number of electrons and neutrons of an element is 18 ‘and 20 respecivey Is mass number is ICPMT 1997; Pb. PMT 1999; MP PMT 1999) (a) 17 (o) 37 (2 (a) 38 [Number of protons, neutrons and electrons in the element BY is IAFMC 1997] (0) 89,231,89 (0) 89,89, 242 (o) 89,142, 89 (4) 89.71,89 Be? isisoeectonic wih IEAMCET 1998] (2) Mg? (b) Now @ou (oH An isostereis IUPSEAT 1999) (2) NO} and 0, (0) N03 and POR (0) CO,.N20,N05 (4) ClO; and OCN INitregen atom hasan atomic number of 7 and oxygen has ‘an atomic number 8 The folal number of electrons in a nitrate ion willbe (b. PMT 2000] () 8 (b) 16 to 32 (cy 64 I molecular mass and atomic mass of sulphur are 256 and 32 respectively, is atomicity is {RPET 2000}, (2) 2 (b) 8 (a4 (a) 16 “The nitride ion in lithium nitride is composed of {KCET 2000) (6) 7prolons + 10lectrons {b) 10 proton + 10 electrons {6} 7 protons + 7 protons (4) 10 protons + 7 electrons ‘The atomic nunter of an element is 17. The number of obits conating electron pais ints valence shells {CPNT 2001) (e) Eight (0) Six (0) Thee (@) Two “The atomic number ofan elements 35 and mass number is 81. The numberof electrons in the outer most shell is 19 | Vidva kendra - 58. 60, 61 62. 63. 64. 65. 66. 67. 68. 69. Head Off: 108, Kingsway camp (Near GTB Nax Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014, by S.K. Singh (FMS, IIT & BARC)’, honoured by “Shiksha Ratna” {UPSEAT 2001) fa} 7 (b) 6 i 5 (a) 3 Which of he folowingis not isoelectronic (MP PET 2002) (2) No" (b) Ma” {) 0% (d) Ch ‘The charge of an elecron is -1.6x 10°C. The value of free charge on Lion wil be IAFMC 2002; KCET (Engg) 2002) (a) 26r10°%C (b) 110°C (9 16x10" (a) 2.6r10%C leoclectronic species [nprer 2002) (a) F,0% () FO (FO () F.07 ‘An clement have atomic weight 40 and it's electronic configuration is 1s°2s*2p*3s?3p*. Then its atomic number and number of neutrons willbe (PMT 2002), (a) 18.and 22 {b) 22 and 18 (€) 26 and 20 (0) 40 and 18 ‘The nucleus of tritium contains tp Pst 2002) a) 1 proton + Ineutron (b) I-proton-+ Sneutron—— {c) 1proton +O neutron (d) 1 proton + 2 neutron Which one of the following groupings represents a collection ‘of isoelectronic species (AIEEE 2003), (a) No*,Co?Mg®™ = (b)_-N*.F°.Na® (0 Be,al®.c1 (8) Co®.C3°.Br Which of the following are isoelectronic and isostructural NO5,COF*.C105,S05 NTT Screening 20031 7 (a) NO3,CO% (0) $03,NOg (e) C1O;,COx” (a) CO},SO; ‘The numberof elecronsin Cl” ionis IMP PMT 2003) (9 (b) 20 (o)-18 (d) 35 ‘The numberof newton in rium is {cer 2003) fe) 1 {b) 2 3 (a) 0 ‘Tritium is the isotope of {CPMT 2003) fa) Hydrogen (b) Oxygen (¢) Carbon (d) Sulpier The atomic number of an element is 35. What is the total number of electrons present in all the p-orbitals of the ground stale atom ofthat element IEAMCET (Engg) 2003) (2) 6 (oy 11 7 (a) 23 ‘The nvdteus of an element contain 9 protons. Its valency would be [MP PET 2004) @1 (b) 3 (2 (a) 5 ‘The compound in which cations ixoelectronic with anion is wnww.viduvakendra.comeee ered by “Shiksha R, -¥ atna” [UPSEAT 2004] (®) Spectrum of atom orion containing one lect ae o fe (6) Thespectum of hydrogen molenie ereeeed em A oo (d) The solr spectrum 10. Which among th flowing specs have the some ur © TT 6 uemnwienhlnateen., ere in ition se defection, ches pas cut nde 3 irae is because (MNR 1979; NCERT 1980; are yp a {0} The fre of rpuson onthe moving alpha wg oF (@) Co” small Partick ig 71. Six protons are found inthe nucleus of (b) The force of attraction on the alpha penile ICPMT 1977, 80, 81; NCERT 1975, 78) ‘oppositely charged electrons is very small ee (0) Boron () Lakin {0} Thete is onl ; (©) Theres only one nucleus and ge sun (a) Carbon (¢) Helium electrons m rember 72. The ton atom has 7 protons and 7 electrons the nite ie nucleus occupies much smal = ion (N? ust have INCERT 1977] to the volume ofthe atom lame compas (a) 7 protons and 10 electrons 6. Positronium consists of an elects nd ; ; neectron nd a piton {B74 protons and 7 electrons wich has the same mass as an eecon bu eoenct eta aes horse orig round thei commen cee of at Har eeraso eee Cate vale the yg consent tis an 73. Number of neutrons in heavy hydrogen atom is (a) Rela Fle IMP PMT 1986) (c) 2R, (@) R, (a) 0 fo) - nes eee Wien «ports are sen through.thin meta fd most f 2 @3 tham go sigh thooch the ol beaut (one ovr 74. Which ofthe following is always a whale number Ll Nested @ fone o mare are ur 1989) ICPMT 1976, 1. 861° “> (a) Alpha particles ae much heavier than electrons (0) Atomic weight (0) Atomic rei (0) Alpha pars ae postvely charged {ec} Equivelent weight (€)_ Atomic number oe F Atomic models and Planck's quantum theory (2) Alpha particles move with high velocity TTT ae errr ectrojomarirom L 10 K shell ~ 1. Rutherford experiment on satering of particles showed for {cra 1983) the fist ime thatthe stom has (0) Energy is absorbed IN 1981; NCERT 1981; CMC Vellore 1991; (b) Energy is released (CPMT 1984; Kurukshetra CEE 1998} (6). Energy is sometimes absorbed and sometimes released (e) Electrons: (b) Protons (4) Energy is neither absorbed nor released (6) Nudes ~~ +8) Newtons When benium is bombarded with «pares, exenely 2. Rutherford scattering experiment is lated tothe size of the Fenetaing raations which como! be daectel by INT 1983; MADT Bihar 1995; BHU 1995) ect! or mogneti id are given out oe (con 1989 (2) Nucleus (>) Atom (2) Abeamotproions —(b) a-rays (e) Electron {d) Neutron peg fener (@) Abeam ofneutions —() X-rays Rulon aphe patil sallerng experiment eventually . eee 10. Which one of the flowing is not the charceisic of led to the conchsion that (wr 1986; RPMT 2002) Planck's quantum theory of radiation {ANIM 1991] (2) Mass and eneray are rated {6} The energy is not absorbed or emited in whale number {b) Electrons occupy space around the nucleus or multiple of quantum: (0) Neurons ore buried deep inthe ruceus (b) Radiation sasocited wth eneray {d) The point of impact with matter can be precisely. {c) Radiation energy is not emitted or absorbed conti determined ruoesy bain the form of smal packets ealed quota 4. Bohs mode can explain prises, (2) This magnitude of energy associated with a quantum 5 the equ {a) The spectrum of hydrogen atom only ee LL. The spectrum of He is expected to be similar to 20 | Vidya kendrA - Head Off: 111, Kingsway camp (Near GTB Ngt Metro station Gate No-1), Delhi9- Corporate Office : D-32, Hardev Nagar, Jharoda, (Near Burari by-pass), Delhi-84- Ph-011-47024312, M9555 87 50 87, 9312 10 2014, wnu,vidvakendra.com 32. Atomic Structure [AIMS 1980, 91; DPMT 1983; MP PMT 2002) () Lr (No (a) Hee 12. Energy of orbit {DPMr 1984, 91) (0) Increases as we move auay from nucleus (0) Decreases as we move away from nucleus (0) Remains same as we move away from nucleus (4) None of these 13. Bohr model of an atom could not eccount for (0). Emission spectrum () Absorption spectrum {) Line spectrum of hydrogen (4) Fine spectrum 14, Existence of positively charged nucleus was established by [CBSE PMT 1991) fo) H “To}" Positive ray analysis [b)_ -ray scattering experiments (e) X-ray analysis (4) Discharge tube experiments 15, Electron occupies the availabe orbital singly before pairing in any one orbital occurs, itis ICBSE PMT 1991) (2) Paul's exclusion principle () Hund’s Rule (0) Heisenberas principle (0) Prout’ hypothesis 16. The wavelength of a spect ine for an electronic transition is inversely related to tur 1988) (2), The numberof electrons undergoing the transition () The nuclear charge of the atom (a) The difference in the energy of the energy levels involved inthe transition (d) The velocity ofthe electron undergoing the trnsition 17. When an electron drops from a higher energy evel to 9 low energy level, then iid TAMU 1985) (a) Energy is emitted [b) Energy is absorbed el Atomic number increases (@) Atomic number decreases 18, Davisson and Germer’ experiment showed that IMADT Bihar 1983} (2) -partcis are electrons {) Electrons come from nucleus (2). Electrons show wave nature (4) None of the above 19. When an electron jumps from lower to higher orbit, ils energy (MADT Bihar 1982) (2) Increases () Decreases (€) Remains the same (4) None of these 20. Experimental evidence for the existence of the atomic ‘cleus comes from ICBSE PMT 1989) 21 | Vidva kendra - Head 01 22. 24, 25. 26. 27. 28, 29, by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” (0) Miittans cil drop experiment {b) Alomie emission spectrorcopy () The magnetic bending of cathode rays (4) Alpha scattering by a thin meta foil Which ofthe folowing statements does not form part of oh’simodel of the hydrogen atom (CBSE PMT 1989} (2) Energy of the elections in the orbil is quantized {) The elecron in the orbit nearest the nucleus has the lowes energy (©) Hectrons evolve in dllerent obits eround the nucleus (8) The poston and velocity ofthe electrons in the orbit cannot be determined simultaneously When particles ae sent through a fin metal foil. most of ‘hem go sraight through the foilas—_EAMCET 1983} (0). f-paticies are much heavier than electrons (0) P-porices are postvely chorged {6} Most par of the atom is empty space (6). -patces move with high velocity ‘The energy of second Bohr oxbit of the hydrogen atom is ~328, ‘cd mot bence the energy of fourth Bohr orbit would be ICBSE PMT 2005) (2) 44d mot! — —oy-=13124d mot! — — le), -164 ks mot (¢) ~82kd mot! When an electron revolves in a stationary erbit then (MP PET 1993] {0} Ihabeorbs energy {b) Itgsins kinetic energy (2) Itemits edition (8) ts enegy remain constant ‘A moving pare ay have wave moto, (a) Its mass is very high (0) ls velo is negible (6) lismassis neglible (d) ts mass is very high and velocity is negligible The postulate of Bohr theory that electrons jump from one ‘orbit to the other, rather than flow is according to (2) The quantisation concept (6) The wave nature of election Z E (2 The probability expression for electron (@) Heisenberg uncertainty principle The frequency of an lectomagnetic radiation is 2x10°He, What is its wavelength in metres (Velocity of light = 3x 10° ms") fe) 60x10" (o) 15x10 (o) 15x10? {@) 0.66107 ‘Whats the packet of energy called IAFMC 2005) (a) Electron (&) Photon {e) Position (4) Proton ‘The energy of an electron in n* orbit of hydrogen atom is (MP PET 1999) 108, Kingsway camp (Near GTB Nar Metro station Gate No.-3), Delhi. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84., Ph-011-47024312, M. 9312 10 2014. wuww.vidvakendra.com2. Atomic Structure 30. 31. 32, 33, 34. 36. 37. 38, 39. Ph-011-47024312, M.-9555 87 50 87, 9312 10 oe eer eee Seana iat eee ees tt aiksha Ratna» a (a) Increases with increas in speed of electron wo) BSev to) ev tb) Remains some inaspectve of sped of electron 2 136 [Decreases with increase in speed of e wo B8e @ ew (a) Iszer0 i 3 The element used by Rutherford in his famoy oven of phton 2210 "m n= 65x10% sec, 40. The cement sed by Ruther f mes sate i 1 then momentum of photon is (MP PET 1999} (0) Gold (&) Tin 998) (a) 3x10kgms {b) 3.33%10%kgms" {c) Silver (4) Lead 4 f from n=3 to n=2..th ii0igeet ul Gmpel0@ lyme 41, electron fs en emited en fe) Lasae 10 hs @) IAFMC 1997; MP PET 2003 The expression for Boh’ radius of an atom is fo) 1026 () Roo vee (c} 19eV (4) 0.65ev tee wre ai 42, The radius ofthe nucleus i related to the mass qumber 4 arin atime’: wy (EAMCET 1569 neh nf fa) R=R,AY? (b) R= RA Oreo @ a Ga*mez armas’ lo) ReR,A? (a) R=R,a'? ay The energy of an electron revolving in n"* Bohr’ orbit of an ae eet iatmi ‘atom is given by the expression upp 1999) 43+ Thespecife charge of protonis 9.6%10°C kg” then rane eatmtets? aatme’at paride twill be loti CET 1999) (a) E, aren (0) Ey =-—a fa) 38.4%10"Ckg? {b) 19.2x107 Cig? 2atmeta? Damtets® [ej 244107Ckg? (4) 4.8107 Cig? @ £,--2 @) £,- ati —"" "FZ — 44> In hydrogen specrum the diferent lines of Lyman sets are ‘Who modified Bohr theory by introducing elipticl orbits presents TUPSEAT 1999) for electron path [CBSE PMT 1999; AFMC 2003) (2) Ufa (b) IRield (0) Hund (6) Thomson (©) Vise ila (@) Fer IR feta (0) Rutherlord (4) Sommerfeld 45. Which one of the following is considered as the main Boh’ radius can have {DPHT 1996) postulate of Bokr’'s model of alom + {AMU 2000) (a) Discrete values (b) +e values: (a) Protons are present in the nucleus (0 -ve values (4) Frectional values (b) Electrons are revolving around the nucleus. “The frst userof quantarrthecry toreptstriesrecture of ———l6 Centrifugal farce produced due to the revohing ‘atom was made by [IT 1997; CPMT 2001; J&K CET 2005] clectrons balances the force of attraction between the electron and the protons Wavelength associated with electron motion 22 | Vidva kendrA - Head Off: 111, [BHU 1998) Corporate Office : D-32, Hardev Nagar, Jharoda. clectronic transition causes third line Kingsway camp (Near GTB Ngr Metro station Gate No. 2014, (0) Heisenberg (6) Bohr (0 Phonck (8) Einstein (8) Argiarmmentancfee¥en san nega mpc A Ae dectert imedionfom leita ofan om cones = 46 ane sectonk: yl of the hydrogen atom inthe : (GIPMER 1997] Bohr’ theory are called [AMU 2000) (2), Absorption of energy (2) Rydberg levels {b) Orbits _ (0), Release of energy (C1 Ground states (4) Orbitals (6) Both release or absorption of energy 47. The energy of a photon iscaculated by Pb. PMT 2000) (2) Unpredictable . (a) E=hy (b) h=Ev Ii an element going awoy from nucleus, the energy of E h pale tReMT 1997), no e-% (2) Decreases {b) Not changing i (e) Increases (4) None ofthese comes ee oni meer The a-portde. scattering experiment of Rutherford (2) rund (b) Lyman concluded that (Orissa JEE 1997] = (¢). Balmer (2) Brackett (0) The nucleus is made up of protons and neuiens 49. Radius ofthe first Boh’ orbit of hydrogen atom is (9) The number of dectons is exaely equ 10 number of (RPET 20001 protons in (©) The pesitive charge of the atom is concentrated in a fone eae very small space (2) 028.4 (2) 053 A (4) Electrons occupy discrete eneray levels 50, In Balmer series of hydrogen atom spectrum which [oP PDT 2000) 1), Delhi.9. (Near Burari by-pass), Delhi-84. wuw.vidvakendra.com2, Atomic Stru 51. 52, 53. 5a. 55. 56. 37. 58. 59. 61. ture (a) Filth Bohr orbit to second one (6) Filth Bohr orbit to frst one (6) Fourth Bohr orbit to second one (a) Fourth Bohr oxbit to first one Energy of electron of hydrogen atom in second Bohrorbitis 2+ inp PMT 2000) () -5.44x10°%F (0) ~844210° (2) -844x10" cal (4) 5.4410 ev change in energy (8E}= 310°, = 6.6410) and ¢= 310° ms, then wavelength of he lights {CBSE PHT 2000} (2) 636x10°A (2 636%10°A, {c) 664x10%A (4) 636x104 ‘The radius of first Bohr’s orbit for hydrogen is 0.53 A. The radiusof third Bohr's orbit would be [MP P3T 2001) fa) 079A (o) 159A, 63. () 318A () 477A Rutherford’s. aepartcle scattering experiment. proved that atom has (MP PMT 2001), (0) Electrons (0) Neutron {e) Nodeus (2) Orbitas 6a. Wavelength of spectal ne emited is invereely proportional —_ 0 (CPM 2001) (a) Radius (b> Energy (6) Velocity (4) Quantum number ‘The enery of a radiation of wovelenath 8000 Ais Ey and ‘energy ofa radiation of wavelenghh 16000 is E».Whatis 65, the relation between these two {Kerala CET 2005} (0) E=6E, (b) Ey =2E, () Ey=48, () E,=1/2E, ane te) E,=E be The formation of energy bonds in solids are in accordance with tOce 2001) (a) Heisenberg’ uncertainty principle (0) Bote’s theory 67. (9) Obm'staw (4) Rutherford’ aiomie model ‘The frequency of yellow light having wavelength 600 nm is a IMP PET 2002], (0) 50x10" He (b) 25x10? He 68. (oS 0x10? He (8) 25x10" He The value of the energy for the fist excited state of hydrogen atom wil be mp PET 2002), (a) -136eV (b) -3.40eV hat (9 -151ev (@) -085ev Bohr model of atom is contradicted by (MP PMT 2002) {o) Paul's exclusion principle ut (b) Planck quantum theory (@) Heisenberg uncertainty principle (¢) Allol these Which of the following is not tue in Rutherford's nuclear 9, model of atom {Orissa JEE 2002] (2) Protons and neutrons are present inside nucleus () £,=-S 2 amort (o) &, by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” [b) Volume of nucleus is very small as compared to volume ‘of atom le) The number of protons and neutrons ae always equal (2) The numberof electrons and protons are always equal ‘The emission spectrum of hydrogen is found to satisy the expression forthe energy change. AE (in joules) such that ap2anea{ b-2) J whe ny 128.0988 me 5 2.3. dics The spectral lines comespond to Paschen setes to [UPSEAT 2002} (0) my =1 and ny =2,3,4 (0) ny =3 and ng = 4, 5.6 (2) myaland ny =3,4,5 (6) my =2 ond my =3.3,5 (e)_ ny =1 and ny = infinity The rao between kinetic energy and the total energy of the electrons of hydrogen atom according to Bohn's model is. Pb. PMT 2002) (a) 2:1 () ded (©) dred (@) 1:2 Energy ofthe electon in Hydrogen atom is given by [AMU (Enga) 2002) “33138 0 Fy--B Suma a) Ee Tacha seed nites tor insistent (2) 2 (bo) 4 {) 3 {d) 5 “The teqpeny oveprtng to tenn n= on} invvirsen son ine Soe (0) 15.6610" He (0) 24.66%10" He (©) 3057x10" He (@) 4057%10" He ‘The mass of a photon with a wavelength. equal to 154x10%am is (Po. PMT 2003} (0) 0.826810 kg (b) 1.2876 x10"kg (2 14285x10%kg (a) 1.8984x10°%4g Splitng of spetal lines under the infuence of magnetic field is called IMP PET 2004) {e) Zeemanelect (b) Siaketect (2) Pholooecticetect (a) None ofthese The radius of electron in the fist excited state of hydrogen atoms IMP PMT 2004) (®) 9% (0), 49 (0) 209 (8) Bo ‘The ratio of area covered by second orbital to the fist orbital is TAFMC 2003] (o) 1:2 (b) 1:16 (©) 8:1 (a) 16:1 ‘Time taken for an electron to complete one revolution in the Bohr orbit of hydrogen atom is [Kerala PMT 2003), 23 | Vidya kendrA - Head Off: 108, Kingsway camp (Near GTB Ngr Metro station Gate No.3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph.011-47024312, M. 9312 10 2014. ‘www vidyakendra.com,eee atm? » 2H 0) oh © ane th h em Sant 72, The radius of which ofthe fllowing otitis same as that of the ist Boh's orbit of hydrogen atorn [NTT Screening 2008) (2) He*(n = 2) (b) Li*(n= 2) () L@=3) (6) Be in=2) nals 73. The frequency of radiation emited when the electro from ned 10 n=] ine bydogen atom willbe (Given H=2.18%10"*J atom" and jonization energy of h=6625210%Us) {CBSE PMT 2008} (a) 308x10%5 (b) 200x10!%5 (@) 154x10%s7 (d) 1.031057 74, The wavelength of the radiation emitted, when in a hydrogen ator electron fl from infinity 10 stationary sate 1, would be (Rydberg constant =1.097%107 m™) [AIEEE 2004) (2) 406 nm (0) 192m (9 9tnm (@) 9.00% nm 15, ~hrBohrs mode: atomic tadier ofthe fst orbit 7 the redius of the 3% orbits (MP PET 1997; Pb. CET 2001) (9) 113 wy @ % (% 76. According to Bohr’s principle the relation between principle quantum number (n) and ads of rb (BHU 2008) () ren () rant — trad lee : 77. The ionisation potential of a hydrogen atom is -13.6 eV. ‘What willbe the energy ofthe atom corresponding to n= 2 {Pb. CET 2000) () 34ev y) 48a @ 70 (a) -27ev 78. The energy of election in hydrogen atom in is grounds sate is -136 eV. The energy of the level corresponding to the = quantum number equal 05 is (Pb. CET 2002] (0) -054ev (b) -085 ev (e) -064 ev ~ {) -040 ev 79. The positive charge of an atom i tarmic 2002) {a} Spread all over the atom (b) Distibuted around the nuceus (@) Concentrated at the nucleus (4) Allof these ‘80. Ametal surface is exposed fo solar radiations. {DPMT 2008) (2) The emitied clecttons have endrgy less than a ‘maximum value of eneray depending upon frequency of incident radiations {b) The emitted electrons have energy less than maximum value of energy depending upon intensity of incident rediation (0) The emitted electrons have zero energy 81. 8 9. —atngy (4) The emitted electrons have ener photos of incident light Which of the following transtions ha 8 el 19 ere ve mit wavelength (01 ‘ign Par (a) mm 1b) mn, 2005) (2) me (4) mn, Dual nature of electron De brogle equation describes the relationship f associ wh emotion ofan eton nd a (o) Mats (0) Energy (6). Momentum (6) Charge “The wave nature of an electron was fist ven by [CMC Veto 199%; Po. PHT 1956, ara (a) De-Brogie (0) Heisenberg (e) Mosley (6)"Sémmeres ‘Among he flowing for which one mathemati exresiog stands 86) Pp (a) De Broglie equation (b) Einstein equation {e) Uncedainy equation () Bohr equation Which one ofthe folowing explains light both asa steam ef particles and as wave motion [AIMS 1989; 111992: UPSEAT 2003) {0} Diffraction () 2=hp (c) Interference (4) Photocectic effect In which one of he fllowing pits of experimental obsewatins ‘and phenomenon does the experimental cbseration cone ‘2ccount for phenomenon (ams 1985) Experimental observation Phenomenon (a) X-ray spectra CCharge‘on the nucleus ~ (b) cr-paricle scattering Quantized electron obit (6). Emission spect The quantization of energy (4) The photoelectric effect The nuclear atom Which of the following expressions gives the deBrogie relationship [MP PNT 1996; 2004; MP PETPOT 1958) ) ned ty ae nm ’ (aa a © an @ as de-Broglie equation is (4P PMT 1999; CET Pune 1998) (b) E=hy (at mo (0) nd = 2dsind () E=me? ~ ‘The de-Broglie wavelength of a particle with mass 1gm and velocity 100m/sec is [CBSE PMT 1999; EAMCET 1997 AFMC 1999; AIMS 2000] (2) 6.63x10%m (b) 6.63x10%m_ (@) 663x10%m (4) 665x10%m Minimum de Bro wavelenghh i associated wih(RPMT 1999] (2) Electron (6) Proton (€) CO, molecule (d) SO, molecule 24 | Vidya kendrA - Head Off: 111, Kingsway camp (Near GTB Ngx Metro station Gate No.-1), Delhi-9- Corporate Offic 1.32, Hardev Nagar, Jharoda. (Near Burari by-pass), Delhi-84 Ph-011-47024312, M.-9555 87 50 87, 9312 10 2014, vu vidyakendra J2. Atomic Structure ‘The deBroglic wavelength ossociaed wih 9 material pares (wirMeR 20005 {@) Direly proportional its enewy (b) Direcly proportional to momentum {0} Inversely proportional to its energy {4) Inversely proportional to momentum 11. An electron has kinetic energy 28x10. de-Broglie wavelength wll be nearly (m, = 9.15107hg) 10. 21, IMP PET 2000) (0) 9.2810 7m fe) 928%10°% m (4) 928x190 ®m 12. What uill be de Broglie wavelength ofan decron moving with, (a) 9.28%10" m a velciy of 1.210% ms" (P PET 2000) (0) 6.06810" (b) 3.133107 i ($626.10 (a) 6018x107 13. The de-Broglie wavelenglh associated with a particle of mass 10°kg moving with a velocity of 10.ms is {MIMS 2001) (0) 663%10%m (6) 663210? m () 6.63%10" m ~() 663210 m—— — 14. What is the de-Broglie wavelength associated with the hydrogen electron in its thd orbit - {AMU (Engg.) 2002), (2) 9:96%10%em (6) 996%10%em lo) 996%10em (a) 9.96x10%em 15. If the velocity of hydrogen molecule is 5x10"emsec.', then is de-Broglie wavelength is imp past 2003) fo) 2A —(o}-4A —— ———. ( 8A (4) 100A 16. A.200g golf balls moving with a speed of 5 m per hour. The associted wave length is (h = 6.625x10™*J - sec) IMP PET 2003) (@) 10m (6) 10m 3. () 102m (@) 10m 17. A cricket ball of O5kg is moving with 9 velocity of 100m/see. The wavelength associated wih its motion is _ (DCE 2004} (0) 1/100em (0) 66x10™m (9 132x10%m (@) 66x10%m 18, Dual nature of particles was proposed by [DCE 2004), {0} Heisenbers (b) Lowy (0) de-Brogle (¢) Schrodinger 19. Calculate de-Broglie wavelength of an electron travelling at 1% of the speed of light [DPM 2004} (a) 2.73x10 (b) 242x10” 1 fe) 242.2%10" (4) None ofthese 20. Which is the corect relationship between wavelength and ‘momentum of particles (Pb. PMT 2000) fb) w= (a) t by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” (ah The de-Brosglie equation applies {0} To electrons only {6} To neutrons only {€) To protons only (a) Allthe material object in motion mp PMT 2008) Uncertainty principle and Schrodinger wave equation “The uncertainty principle was enunciated by * INCERT 1975; Bihar MEE 1997} (0) Einstein (0) Heisenberg (e) Rutherford (a) Paul ‘According to heisenberg uncertainty principle IAMU 1990; BCECE 2005} (0) Ex me? to) aexap2 A ah h ask (0) axxap= “The position and velocity of a small particle ike electron cannot be simullaneously determined.” This statement is INCERT 1979; BHU 1981, 87] (a) Heisenberg uncertainty principle (0) Principle of de Brogl’s wave nature of electron (e). Poulis exclusion principle |e) Aufoau's principle a bs Hoses wet esion actor Be 39 — -stands for a (2). Uncertainty in energy (6) Uncertainty in velocity (2) Uncertainty in momentum (¢)_ Uncertainty in mass Which one i not the comect relation in the following, nek () E=me? ©) axxape @a-k ‘The maximum probability of finding an electron in the dy obital is (MP PET 1996) {@) Along the x-axis (0) Along the y-axis (¢) At an anglecf 45° from the x and yoxes (2) Atan angle of 90° from the x ond y-axes position and [BHU 1979) Simultaneous determination of exact ‘momentum of an electron is {0} Possible (b) Impossible (c) Sometimes possible sometimes impossible (4)_ None of the above 25 | Vidva kendrA - Head Oif: 108, Kingsway camp (Near GTB Nar Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burarl by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014. www vidyakendra e¢2. Atomic Structure in the position of an electron is ze. the © pcetaiinisaementn oid be [CPM 1988) h (2) 2e0 et : inte oe {4} Infinit 9. The ait frog om econ a el ws (0) Ruerlord (0) Botr (€) Heisenberg (6), Schrodinger 10. _Uncertainy principle gave the concept of (0) Probability (b) An otbita {6} Physical meaning of Y the W? (a) Althe above 11. Tasruncertanty principle and the concep of wave nature of matter was proposed By vu. an. spectively Ip PET 1997) (o) Heisenberg, de Broglie (0) Heisenberg Plnck (b) de Bogle, Heisenberg (a) Phnck, Heisenberg 12, The uncensiny in momentum of an election is 1%10kg m/s. The-uncertainty-in ils postion will be (= 662%10°%kg=m? /s) {APMC 1998; CBSE PMT 1999; JPMER 2002) (a) 1.05%10°%m {b} 1.05107 m (2) $27x10°%m (@) 825210 m 18, The uncertiny inthe positon of a moving bullet of mass 10.gmis 10m. Caleuate the uncetany in its velocity {cE 1999} (b) 30x10 m/sec () 310% m/sec 14, The euaton axape gE shows (a) 52x10 m/sec (e) 52x10%m/see t Lop PET 2000) (2) de-Brogle relation (b)Heisenberg's uncertainy principle * (@) Aufbau principle = (2) Hund’é rue 15, Which quantum number is not realed with Schrodinger equation (RPM 2002) (2) Principal (0) Acimuthal (2) Magnetic 4a) Spin 16. Uncertainty in position of a 0.25 g pattie is 10°. Uncertainty of velocity is (h= 6.610 Js) {AIEEE 2002) (0) 1.2610" (0) 21010 () 16x10" (a) 1.7%10? The uncertainty in momentum of an election is 1410*kgm/s. The uncertainty in is postion will be (h= 6.6310" Js) (2) 528%10%m 17, (Pb. CET 2000) (b) 525x107 m 26 | Vidya kendrA - Head Off: Corporate Off 111, Kingsway camp (Near GTB N. D-32, Hardev Nagar, Ph-011-47024312, M.-9555 87 50 87, 93 by S.K. Singh (FMS, IS enone ey Shiksha Ratna» (c} 1.05% 10° m (4) 2.715%10%p 18, According to Heisenberg’ uncertainty princi, th of uncertainties in position and velocities for an eet mass 9.110" kg is {BH 2005) (a) 28%10°%m?s (b) 3.8x10Sm2_4 {c) 58x10 m?s" (6) 6.810% m5 19, For an election i he unceroiny in veloiy is bg uncentinty in poston ts) iain, tDper gt hm 4a ©) tase (nar h 4am ) ‘ 0 ay 20, Orbital is (ora 2 {0}, Greular path around the nucleus in which the eecigy revolves {b) Space around the nucleus where the probability of finding the elect is maximum (€) Amplitude of electrons wave (d) None ofthese Quantum number, Electronic configuration and Shape of orbitals mosrere e DE Sope OF orbitals 1. Bes dth electron will have four quantum numbers (HN 1985) notom os 1 0 0 +2 (oy 2 1 st ane (2 0 0 -12 2 1 0 +12 2, The quantum-number hich specifies the locaton of an electron as wellas energy is (DPM 1983), (a) Principal quantum number (0) Azimuthal quantum number (2) Spin quantum number () Magnetic quantum pumber 3. The shape of an orbital is given by the quanturh number INCERT 1984; MP PHT 1996) () I (a) s 4. Ina given atom no tio electrons can have the same values forall the four quantum numbers. This is called {BHU 1979; AMU 1983; EAMCET 1980, 83; MADT Bihar 1980; CPMT 1986, 90, 92; NCERT 1978, 84; RPMT 1997; CBSE PMT 1991; MP PET 1986, 99] (0) Hund’s rule (b) Aufoau's principle (0) Uncertainty principle (4) Pauls exclusion principle (a) n (em 5. Nitrogen has the electronic configuration 1s?,25?2p!2p!ap! and not 1s?,2s*2p?2p!2p? which is determined by (DPMT 1982, 83, 89; MP PMT/PET 1988; EAMCET 1988) {0} Aufbau’s principle (b) Paul's exclusion principle iar Metro station Gate No.-1), Delhi-9- ‘aroda. (Near Burari by-pass), Delhi-84- 12 10 2014, ‘www .vidyakendra.com2. Atomic Structure (0) Hund’s rule (4). Uncertainty principle 6 Which one of the following configuration represents a noble gs ICPMT 1983, 89, 93; NCERT 1973; MP PHT 1989; (DPMT 1984), (e) 157.26? 2p8 ae? {b) 1s?.2s?2p8,35! {e)_1s?.25%2p8 (a) 152.25%sp63s*3ph as? 7. The electronic configuration of silver atom in ground state is creer 1984, 93) (2) tKri3a" ast (by Ixe14y"*5a% 6st fo) Ikri4d"5s (a) (Kr}ad?5s? 8. Principal, azimuthal and magnetic quanium numbers are respectively elated to ICPMT 1988; AUMS 1999) (0) Size, shape ond orientation (6) Shape, size and orientation (6) Size, orientation and shape {)_None of the above 9. Correct set of four quantum numbers for valence electron of mbidium (2 = 37) UIT 1984; JIPMER 1999; UPSEAT 2003) 1 1 (0) +h fo) 5,1,043, () 5.00.+5 ) : : cree eee @ start Tar 60.002 2 2 10, The comec gourd sale eecronic configuration of chromium stom 171989, ss MP PNET 1993; EAMCET 1997: 15M Dhanid 1994 AFMC 1997, Bihar MEE 1996, MP PET 1995, 97; CPM 1999; Kena PT 2003) (2) (aniad? 4s! (b) (Ari3d%4s? (©) (aRpa*as? (a) (Ariad?as? 11. ~2porbitals have ——INEERT298T; MP POIT1995-977 (e) n=1l=2 (0) n=11=0 () neQle1 (@) n=2I=0 12, Blctronic configuration of H* is {cPMT 1985) (o) 13° (b) 1s! (os? (a) st2s 13. The quantum numbers for the outermost electron of an The * elenent are gen Sw at n= 2 Om r= atoms is [EANCET 1978) fe) Lithium {b) Beryllium (2) Hydrogen (a) Boron 14, _Piincipal quantum number ofan atom represents (EANCET 1979; ITT 1983; MNR 1990,UPSEAT 2000, 02) (0) Sie ofthe orbital a (©) Spin angular momentum (6) Otbital angular momentum (4) Space orientation of the orbital 15. An element has the electronic 1s*,25?2p*.35"3p?. tis valency electrons are INCERT 1973} configuration @ 6 (o) 2 27 | Vidya kendrA - Head Off: 108, Kingsway camp (Near GTB Nar Metro station Gate No.-3), Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84, Ph-011-47024312, M. 9312 10 2014, by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” 3 4 16. The magnetic quantum number specifies [MINA 1986; BHU 1982; CPMT 1989, 94; MP PET 1999; AFMC 1999: AMU (Enga.) 1999) (0} Size of orbitals (b) Shape of orbitals {e) Orientation of orbitals (d) Nuclear stability 17. Which of the following sets of quantum numbers represent ‘an impossible arrangement (INT 1986; MP PET 1995} noioom om, 1 3 2 -2 Ws 1 m4 0 0 me 1 3 2 3 ty 1 ms 3 0 as 18. If n=3, then the value of 'F which is incorect [cpor 1994) (a) 0 1 (2 (@ 3 19. Which orbital is dumbbell shaped (MP PMT 1986; MP PET:PMT 1998) (a) s orbit (0) p-orbital fe) d-oibital (4) f-orbital 20. The tool number of unpaired electrons ind orbitals of (CPMT 1983} ‘atoms of element of eipmic number 29 is (a) 10 (1 0 (a) 5 21. The shape of 2p orbitals ICPMT 1983; NCERT 1979) (a) Sphericat () Elipsoidat (©) Dumb-bell (4) Pyramidal 22, The magnetic quantum number for an election when the value of principal quantum number is 2 can have (cPMT 1984} (a) Svalues () 2 values (o) 9values (d) 6 values 23. Which one’s the correct outer configuration of chromium [AlIMS 1960, 91; BHU 1995) ft) [titty t ty Galt ) [t[t[t[t]t t @ fT) oF 24, The following has zero valency. (DPMT 1991) (a) Sodium {b) Beryllium (¢) Aluminium (@) Krypton 25. The number of electrons in the valence shell of calcium is (071975) fa) 6 (bo) 8 fo) 2 (da 26. _Thevalence electron inthe corbon atom are _ (MNR 1982} uiunw.vidyaendin com2. Atomic St by S.K. Singh (FMS, IIT & BARC)*, honoured by oe 2 (b) n=3,1=2m=-2. ; (a (a) 6 27. For the dumbbell shaped orbital, the value of I is 1 28, 29, 30. 31. 32. 33, 34, 35. 36. ICPMT 1987, 2003) fa) 3 (o) 1 0 (a2 Chromium has the electronic configuration 4s!3d° rather than 45°34" because (0) 4s and 34 have the same encray (b) 45 has. higher energy than 3d (6) 4s! is more stable than 4s? (4) 4s"3a® hollsiedis more stable than 4323 ‘The electronic configuration of caleium ion (Co?*) is [CMC Vellore 1991) (0) 15?.26?2pt.asPapt as? (0) 18?,26°sp".36%3p" as! (a) 1s.25?2p6.3:" 3p" aa? (8) 15% 25%ep!.36?3p%ag (e) 152.25? 2p* asap as? The structure of external most shell of net gases is (uIPMER 1991) (a) sp? (bo) s2p° “stp? (a) as? The two electons in K sub-shell wl differ in (MNR 1988; UPSEAT 1999, 2000; Kerala PHT 2003} (0) Principal quantum number {0} Azimuthal quantum ndmber (6). Magnetic quontum number (3). Spin quantum number Acompletely filled d -orbital (d") (2). Spherically symmetial (b) Has octahedral symmetry (c) Has tetrahedral symmetry . (d) Depends on the atom I magnetic quantum number of a given atsin represented by-3, then what willbe its principal quantum number {HU 2005) (oan 19877- “ay 2 ) 3 a4 (5 The total number of orbital in an eneray level designated by principal quantum number n is equal to [ans 1997; Jax cet 2005) (0). 2n? (a) n® the fourth principal quantum (a) 2n a The number of orbitals in ‘number will be (4 (o) 8 fe) 12 (a) 16 Which set of quantum numbers ate nol possible from the following 1 (a) n=31=2m=0s=-2 (a) 2m=0.s—-% 28 | Vidya kendrA - Head Offs Corporate Office : 40 Sha ans () n=31=3.m=-35= (A) n=31=0.m=05 2 37. The for quntum suber he wens ey last electron of sodium (2 = 11) is MTOM of . IMP py n= Lm=-1s=-4 my to)ne hate -Lse-t ) e310 O.m=0.50 63 (0) n= 3) 2m=-252- 1 2312 2m=2s044 - (8) n=3te2mea2s0 04 38. The explanation forthe presence of intheitogen stom ean be guen op INCERT 19171998, DCE 19s cher 2001 wera atz: Pa ce (a) Paulis exclusion principle (b) Hund’s rule {c) Aufbau’s principle {8) Uncertain principe hee unpaired eee, 39. The maximum energy is present in any eleczon at (2) Nucleus (b) Ground state (c) First excited state (4) Infinite distance from the nucleus 10. _The election density between Is and 2s orbitals (2) High (b) Low (c) Zero (4) None of these 41. For ns enbital, the magnetic quantum number has vale fa) 2 {b) 4 (c) =1 -w ee Ad) 0 42, The maximum number of electrons that can be ‘accommodated in the M™ shell is fa) 2 {b) 8 (9 18 (a) 32 43. For a given value of quantum number 1, the numberof allowed values of m is given by fa) 142 (db) 2142 (c) 241 (d) I+1 44. The number of radial nodes of 3s and 2p opbitals are respectively. TEE 2005) (a) 2,0 {b) 0,2 ie te (d) 2,1 45. Which ofthe sub-shellis circular (a) 4s (b) 4f (9 4p (a) 4a 46, Which lectonie configuation for oxygen is conse according to Hund’s rule of mulipicity 111, Kingsway camp (Near GTB Nr Metro station Gale No.-1), Delhi-9. 0-32, Hardev Nagar, Jharoda. (Near Burari by-pass), Delhi-84. Ph-011-47024312, M..9555. 87 50 87, 9312 10 2014, www. vidyakendra.com——— = by $.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” 2, Atomic Structure a7. 48. 49. 50. 51 52. 53. 54. a) 1s?.2s?2pf2p}2p}—{b)_1s?.2s*2pF2p5 2p) fc) 182.28"2p22ph2p? —(d) None of these If value of azimuthal quantum number I is 2, then total possible values of magnetic quantum number will be (a) 7 (5 fe) 3 (2 ‘The typeof orbitals present in Fe is (a) s (b) 5 and p fe) sp ondd (8) spd and f The shape of d,, orbital willbe {a) Circular (b) Dumbbell (@) Double dumb-bell (4) Trigonal Inany atom which sub-shell wil have the highest eneray in the following (0) 3p (o) 3d Cm (0) 36 Which electonie configuration is not observing the (n+) rule (a) 1s725%2p'.35°3p°ad", {b) 1s?,26"sp°,3s?3p°3a" 4s? Ue) 15%2s?2p8,as7SpP3d° As! (a) 1s%2s22p.3s?ap%aa8 as? The four quantum numbers of the outermost orbital of K {atomic no. =19) are IMP PET 1993, 94) ro (a) n=21=0m=0, 1 “a =2ma-1s247 ‘The angular momentum ofan electron depends on (2) Principal quantum number (6) Azimuthal quantum number 4) Magnetic quantum number (2) Allof these ‘The electronic configuration of copper (39Cu) is IDPMT 1983; BHU 1980; AFMC 1981; ‘CBSE PMT 1991; MP PMT 1995) (2) 1s?,25?2p°,35?3p%3d° 4s? (b) 1s,25%2p°35?3p%3d™ as! () 1s?.25?2p°,3s?3p°,4s?4p* (6) 1s?2s?2p%,3s?3p%ad"® The number of orbitals in 2p sub-shells INCERT 1973; MP PMT 1996) (o) 2 a4 () 6 9 3 29 | Vidya kendrA - Head Off: 108, 56. 57. 58. 59. 6s 62. 63. 66. ingsway camp (Near GTB Ngr Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84, Ph-011-47024312, M. 9312 10 2014. “The number of ovitals in d sub-shellis (MNF 1983) (0) 1 (v) 3 te) 5 7 ‘A subsshell I= 2 can ake how many electrons INCERT 1973, 78] (v) 10 (a) 3 (a) 6 5 Poul’ exclusion principle states that, [nvr 1983; AMU 1984) ‘Two electrons in the same atom can have the some energy “Two electrons in the same ato cannot have the some spin ‘The electrons lend fo occupy different orbitals as far as possible Electrons tend To occupy lower energy orbitals preferentially (e} None of the above For d electrons, the azimuthal quantum number is IMIR 1989; CPDT 1984) (0) ) ) (a) (a) 0 (1 (2 (a 3 For p orbital. the magnetic quantum number has value (a) 2 (b) 4,-4 (o) -1,0, 41 (a) 0 For n=3 energy level, the number of posible orbitals (all Kinds) are {BHU 1981; CPMT 1985; MP PMT 1995} (1 () 3 (4 Be = dh = ‘Which of the following ions is not having the configuration of neon (a) F (bo) Mg? (d) cr = fue reenter en ssn nite fa rely discovered elamet sur fo have an atomic number 106, ils electronic configuration will be [AIMS 1980) (a). [Rnj5J™,6c*,75? (b) [Rn5" 64,257 (o) [Rnb *,60,75° (a) Wani5,6a°,73" Tons which have the same electronic configuration are those of» (a) Lithium and sodium (b) Sodium and potassium {c} Potassium and calcium (4) Oxygen and chlorine When the azimuthal quantum number has a value of 1 = 0, the shape of the orbital is, IMP PET 1995), {a) Rectangular (b) Spherical (c) Dumbbell (a) Unsymmetical ‘The magnetic quantum number for valency electrons of sodium is ICPMT 1988; MH CET 1999] www. vidvakendra,comStructure (bo) 2 (a0 yration of an element with atomic = ICPMT 1982, 84,87) (a) 3 1 67. The electonic confi umber 7 ie. nitrogen atoms (a) 1s?,25),2p? {b) 1s*.25"2p?2p), {c) 1s?25*2pl2p}2p, (dd 1s?,25°2pl2p) 68. Ina maiseon aor whi of he felon ei desert three quantum members will have the serait in the ese of mage and lc els : [AIEEE 2005), oO (2) n=2,1=0,m=! (8) n= 32m () n=11=0 (9) n=21= m= (8) n=3,1=2,m=0 (0) and @2) =o) (end a) (e) (ana 4) (2) (@)and (5) 69, Which of the following represenis the electronic configuration of an element with atomic number 17 TAMU 1982), (o} 1s%26%2p8,35! 3p (b) 16% 26%2ph,3s*p* 4s? () Astastap',as*3p* (a) 1s%.25?2p.35!Sp' 4s? 70. The shape of s orbitals INCERT 19781) (2) Pyromidal (6) Spherical (©) Tetahedal (6) Dumb-bell shaped 71. When 3d orbital is complete, the new electron will enter the [EAMCET 1980; MP PMT 1995) (@) 4p-orbital (©) 4f-orbital (@) ds-orbital =~ > Jay adreibita 72. In 9 potassium atom, electronic energy levels are in the following order [EAMCET 1979; DPT 1991) (a) as>34 (b) 45> 4p (9 4s<3d _ 8) 45<3p 73. Fe (atomic number = 26) atom has the electronic arrangement INCERT 1974; MNR 1980) (0) 2,8, 8,8 (b) 2,816 (eo 2,814,2 (2) 2,8,12,4 74. Cu will have the following electronic configuration (oP PNT 1985] (a) 32 25%2p¢ 352apt ag (b) 1s2,2222p6,3523p630 4s! (0) 1s*2s?2p8 3s?3p'3q? (d) 15%2s?2p8,35*aptad” 4s! 75. Which ones the electronic configuration of Fe‘? [MADT Bihar 1982; AIMS 1989) (a) 1s?,25%2p%,3s?apSaq6 (0) 1s*.2s?2p°,35?3ptadt as? by S.K. Singh (ris, ie M.9555 87 50 87, 9312 10 2014, =2_vemoiia Ratna (o) 1s%, 2s?2p*.3s*3p*ad*,4s! (6) None of hese 76. How mony elections can be fit into the o comprise the 3% quantum shell n= 3. (MP PMT 1986, 87; Ossa ee y ©) 2 (bo) 8 (8 (6) 32 77. Which lament & represented by the flowing ecne configuration tore its hay 997), 2p a [ult | as [i w (0) Nitrogen = {b) Oxygen (0) Fluorine (2) Neon 78. the value of azimuthal quantum numbers 3, he possible values of magnetic quantum number would be IMP PMT 1987; RPMT 1999; AFMC 2002; KCET 2009) {2} 0,1,2,3 (6) 0.~1,-2,-3 (9 0,21,22,23 (@) £1,22,23 79. Keypton (Kt) has the electronic configution i.) 45°,3d"°.4p®. The 37% electron will go into which one of the folowing sub-levels (CBSE PMT 1989; CPMT 1989; EANCET 1991) (b) 4¢ (a) 5s fa) 4f () 3p 50. on detonator of 2 a ‘magnetic quantum number of ~1, it cannot be presented in an [CBSE PMT 1989; UPSEAT 2001) (a) d-orbitat (b) f-orbital (e)_p-orbital (8) s-orbital “BI. ~The azimuthal quantum number is related to [BHU 1987, 95) (a) Size (&) Shape (€). Orientation (2) Spin The total number of electrons that can be accommodated in all the orbitals having principal quantum number 2 and ‘azimuthal quantum number1is — {CPNT1971, 89, 9) fa) 2 (b) 4 6 . ld) 8 83. Electronic configuration of C is fa) 1s*,25P2p? {b)_ 1s?,25?2p? 82. IcpMr 1975) {c) 152,25? (a) 1s?,2s?2p8 84, There is no difference between a 2p and a Spotbite regarding (BHU 1981] (2) Shape (b) Sie (©) Energy (d) Value of n _The electronic configuration of chromium is (Near GTB Ngr Metro station Gate No), Delhi. Nagar, Jharoda. (Near Burari by-pass), Delhi-84. way vidyakendra.com2, Atomic Structure IMP PMT 1993; MP PET 1995; BHU 2001; BCECE 2005) (0) INe}8s*3p43d" 4s? (bo) [Nel3s?3p*ad*4s! (©) [Nel3s?3p%45?4p* (a) INe}3s*Sp*3a! 45? ap? 86. The shape of p -otbital is IMP PMT 1993) (2) lipid (©) Spherical (2) Dumbbell (4) Complex geometrical 87, The clectronie configuration (outermost) of Mn’? ion (otomic number of Mn= 25 )in its round state is IMP PET 1993) fe) 34°43? (0) sa*ak (304s? (a) 3d?.astap? 88, The principal quantum number represents {CPMT 1991) {0} Shape of an orbital (b) Distance of electron from nucleus (e)_Number of electrons in an orbit (2), Number of otitals in an orbit 89, When the azimuthal quantum number has a value of I = 1. the shape of the orbital is IMP PET 1993}, (2) Unsymmetrcal (b) Spherical symmetrical (Dumbbell (a) Complicated .90;—How many electrons can be accommodated in a sub-shell forwhich n=3T=T [cBsE Pat 1990) (0) 8 (b) 6 (9 38 (a) 32 91, For azimuthal quantum number I=3. the maximum number of electrons will be [CBSE PMT 1991; EAMCET 1991; RPMT 2002; CBSE PMT 2002) 2 () 6 1 7 (a) 14 92. Anion has 38 electrons in the outermost shell itis [CBSE PMT 1990) (a) Cum {b) Th (9 cs (a) 93. The order of filing f electrons in the orbs of Bn atom will be (CBSE PMT 1991) (b) 45,34,4p.55.4d (@) 3d,4p.45,4d,5s may be designated by spd (0) 34,45 4p.4d.5s _ © $5,4p,34,4d.5s 4. The quantum number and f instead of number is BHU 1980), (a) (1 fm (a) m, Which of the following represents the correct sets ofthe four quaplum numbers of a 4d electron IMNR 1992; UPSEAT 2001; J&K CET 2005) (b) 42.1.0 1 () 4325 1 1 (2) 4.3-245 (4) 4.2b-5 5. Which of the following statements is not correct for an clectron that has the quantum numbers n=4 ond m= 2 31 by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” (seve 193) (a) The electron may have the quontum number s= +2 {b) The electron may have the quantum number I= 2 {c) The electron may have the quantum number I= 3 (€) The electron may have the quantum number 1201.23 97, The sel of quantum numbers not applicable for an electron inan atom bs IMR 1994) (a) n= 1 =m, =1m,=41/2 (b) n=1.1=O.m, =Om,=41/2 “12 +2 (c) n=1,1=0.m, =0.m, (a) n=21=0.m, = 0m, 98. Comect configuration of Fe"? [26}is ICPMT 1994; BHU 1995: KCET 1992} fo) 122,222 2p8 368 3p3a (b) 15°,2s%sp*,as?aptad?, (ec) 1s?.25?2p8.3s*3p*3a! (a) 152,25? 2p* 20" 3p83a8 ast 99. _Azimuthal quanturn number for lst electron of No atomis IBHU 1995), ag (o) 2 «0 fa) 1 (3 100. A Sp orbital has (a) Two spherical nodes (0) Two non-spherial nodes {) One spherical and one non-spherical nodes (a) One spherical and two non-sphericat nodes 101. All electrons on the 4p sub-shell must be characterized by 10171995) the quantum numbers) a PET 1996) (a) n=4m=0s<22 — (b) 1-1 2 (@ Is0s=24 @ 102, The electronic configuration of the element of atomic umber 27s (a): 15°, 2572p, 353p8, 4s (14) ap (TU(TH(TH) Ss (1) (b) 182, 25?2p6, 35?3pS3d (THITY}IN), 45 (4p Ct) (0) 152, 2522p 35° 3p8, 34 NTH ITY, as (1) (a) 15%, 25? 2p*, 35?3p6 34 HIT HTN 45 (1H) 103. When the value of the principal quantum number n is 3, the permed values of the azimuthal quantum numbers | ‘and the magnetic quantum numbers m , are 1 m 0 0 fa) +1,0,-1 2 42:41, 0,-1-2 Vidya kendrA - Head Off: 108, Kingsway camp (Near GTB Ngr Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014. ‘ww. vidvakendra.comE> SOME SOUCHUING 67. 68, 69. 70. n. 72. 73. m4. ws. by S.A. fa) 3 (b) 2 fe) 1 (do The electron configration of an element with temic number? i. nitrogen atom is (CPMT 1962, 94, 87) to) 18222! 2p (hy ut.2etoptag (©) 1882"2p!2phap! (a) s¢2st2p! apf | a mullilectron atom, which of the: following orbitals described by the three quantum members will have the some eneigy in the absence of magnetic and electric fields ft {AIEEE 2005) () ne1l=Om=0 (2) O.m=0 ()n=Qle1m=1 — (@) n=3.=2,m= (9) n=3)=2m=0 {0} (2) and (2) ~ (b) (2) and (3) (€) (8) and (4) (3) (4) and (5) Which of the following repesenis the _eecronic configuration of an element with amie number 17 [amu 1982) (a) 15°2s*2p%3s'3p* [by 1s%2s%2p* asPapt as! (o) 1s*2s*2pt.3s?3p* (a) 1e?,252 2p" 303pt gat The shape of s orbital is INCERT 19781 (2) Pyromidat (b) Spherical (6) Tetrahedral (6) Dumb-bell shaped ‘When 3d orbital is complete, the new electron will enter the [EAMCET 1980; MP PMT 1995), (2) 4p-orbital (0) 4f-orbital (0 4s-orbital a) 4asibital~ s In a potassium atom, electronic energy levels are in the following order IEANCET 1979; DPM 1991) (ob 45>3¢ (0) 45>4p (2 4s<3a (@) 42<3p Fe (atomic number = 26) atom has the electronic arrangement INCERT 1974; MNR 1980) (a) 2,8, 8,8 (bo) 2,8, 16 (o) 2,8,14,2 (4) 2,8,12,4 Cu? will have the following electronic configuration (MP Pair 1985), (a) 1s?25?2p*.353p*3al® (b) 1s?,25*2p8 35" 3p*3a? ast (o) 1s?,2s*2p8,35?3p% 3a? (4) Is*,2s?2p8,35?3pi 3a” 4s! ‘Which one is the electronic configuration of Fe“? IMADT Bihar 1982: ANIMS 1969] (a) 1s*,2s2p8,3s?3pSaq* (b) 1s%,2s?2p°,3s?3p'ad! 4s? 76. 7. 8. 79. 80. 82. 84, 85. 30 | Vidva kendrA - Head Off: 111, Kingsway camp (Near GTB Ngr Metro station Gate No~ Corporate Office : D-32, Hardev Nagar, Jharoda. (Near Burari by-pass), Delhi-84. Ph-011-47024312, M..9555 87 50 87, 9312 10 2014. ng ONS STR BANC, honoured by “Shiksha Ratng 4 (c} 1s*.25?2p8 35" 3p% 3a get (4) None of these How many electrons can be fit into 1 comprise the 3" quantum shell n= 3 (MP PMT 1986, 87; Orisa ME oral hy (0) 2 8 bade (8 (82 Which clement i represen Wich neti repented by ie on 2p , a [nyt as [it 7 {2} Nivogen = (b) Oxygen (6) Fluorine (@) Neon the volo aint! quaium numb, he pose IMP PMT 1967: RPMT 1999; AFMC 2002; KCET: (a) 0,1,2,3 (b) 0.-1,-2,-3 () 412223 (@) 41, £2, 43 eypton (Ki) has the elecroni configuation yg) 2002) 4s%.30"° 4p®, The 37* elecron wil go into which one of the folowing ub-levels (CBSE PMT 1989: CPMT 1989; EAMCET 1991) (v) 4¢ (a) 5s (a) af (© 3p Hon elton has sin quantum nants of +2 nd ‘magnetic quantum number of ~1, it eannot be presented in an [CBSE PMT 1989; UPSEAT 2001), (0) d-orbital [b) f-orbital (6) p-orbital (@)_s orbital ‘The azimuthal quantum number i related to BHU 1987, 95) (a) Size (0) Shape (6). Orientation (a) Spin ‘The total number of electrons that can be accommodated in all the orbitals having principal quantum number 2 and ‘zimuthal quantum number lis {CPMT 1971, 89, 91) (a) 2 wa 6 |= 8) 8 Electronic configuration of C is (cPnT 1975) (0) 1s*2s%2p? (b) 1s?,2s%2p? (co) 1s?2s? (a) 15°,2s%2p6 There is no diference between a 2p and a Spottitel regarding {BHU 1981) (2) Shape (0) Size (2) Energy () Value of n _The electronic configuration of chromium is D), Delhi. swww.vidyakendra.com2, Atomic Structure (oP Par 1993: MP PET 1995; BHU 2001; BCECE 2005) (a) [Ne}3s*3p'3d*,4s?—(b) [Ne}3s?3p*345.4s! {c) (Ne}3s?3p%4s?4p* —(d)_[Ne}Bs*3p*3d'.4s74p? 186, The shope of p -otital is (np parr 1993) (a) Elliptical (0) Spherical fe) Dumb-bell (2) Complex geometrical 1. The electronic configuration (outermas!) of Mn’? ion {atomie number of Mn= 25 Jin its round sat is IMP PET 1993) tb) ada (6) 342.45?4p? creer 199) (a) 30°45? (9 304s? 88. The principal quantum number represents, (0). Shape of an orbital {b) Distance of electron from nucleus {€)_Number of elections in an orbit (a) Number of orbitals in an orbit When the azimuthal quantum number has a value of ! = 1. the shape ofthe orbits IP PET 1993) {o) Unsymmetscal (b) Spherical symmetrical (Dumbbell (@)__ Complicated 90-—How many electrons can be accommodated in a sub-shell lor which n=3T=T {CBSE PMT 1990} (a) 8 (0) 6 (9 18 (a) 32 91. For azimuthal quantum number I=3, the maximum numberof electrons will be (CBSE PMT 1991; EANCET 1991; RPMT 2002; CBSE PMT 2002}, (a) 2 (o) 6 ——fe}-0- - = (a) ae 92. Anion has 18 electrons in the outermost shel its ICBSE PMT 1990] 89. (a) Cur (b) THe fe Cs @ 98. The order of filing 6f electrons in the orbitals of dn atom will be [CBSE PMT 1991) (0) 30,4s,4p,4d,5s (b) 45,3d.4p.55,4d ( $5,4p,344d.5s (a) 3d.4p.45,40,5s 94. The quantum number which may be designated by s.p.d and f instead of number is BHU 1980] (on (1 om (@) m, 15. Which of the following represents the correct sels ofthe four ‘quaplum numbers ofa 4d electron IMR 1992; UPSEAT 2001; J&K CET 2005) @ 4324 (b) 4,2,1.0 1 1 (48-245 (@) 4.24-5 6. Which of the following statements is not correct for an clectron that has the quantum numbers n=4 and m= 2 Vidya kendrA - Head Off: 108, Kingsway camp (N Corp. Office: D-32, Hardew Nagar, Ph-011-47024312, M. 9312 10 2014. by S.K. Singh (FMS, IIT & BARC)’, honoured by “Shiksha Ratna” Ime 1999) (a) The electron may have the quantum number {b) The electron may have the quanturn number I= 2 {c) The electron may have the quantum number 1=3 (4) The electron may have the quantum number 11.2.3 97. The et of quantum numbers not applicable for an electron inanatom is rove 1998), (a) a12 o 42 ( ne3, 2 (4) n= 2) =0:m, =0.m, = 41/2 98. Correct configuration of Fe"? [261 is = [cPMT 1994; BHU 1995; KCET 1992} (0) 1s%,25%2p*,3s?aptad® [by 1s?,25?5p%.35*3p°30? As? (le) 1s?.2s?2p*,35*3p"3d* As? (d)_1s%,25%2p*3s"ap"ad* as! 99. Aimuthal quantum number fr lost electron of Na atomis IBHU 1995) (b) 2 (a) 1 (a) 0 3 100. A 3porbitel has {a} Two spherical nodes (0) Two non-sphercal nodes (0) One spherical and one non-spherical nodes () One spherical and two non-spherical nodes rT 1995) 101. All electcons on the 4p sub-shell must be characterized by the quantum number(s) IMP PET 1996) (a) n=44 20se4h 19 Intent 102, The electronic configuration of the element of atomic rwumber 27s (0): 157, 2522p, 35°36 ds (Ty ap (PIT IICTN) Ss) {by 1s?, 2522p, 3s23p%3d (MITE), ds (1) Ap it) (o) As%, 25?2p5,3s"ap6, 3a (TYTLYINNITY), 45 (1) (a) 18%, 25% 2p, 35%3p, 3d My TT MIN) 45 (00) 4103. When the value ofthe principal quantum number n is 3, the permitted values ofthe azimuthal quantum numbers ‘and the magnetic quantum numbers m , are 1 m 0 0 (1 41, 2 +241, 0-1-2 jear GTB Nat Metro station Gate No.-3), Delhi haroda Mazra (Near Burari by-pass), Delhi-84. waww.vidvakendra.comi 1 es +211 2 4302 1-2-3 0 0 a 1.23 2 3021-23 : a1 (@ 2 : ane 7 0123 104. The numberof posible spatial orientation fan electron in ‘an toms given bys (0) Spin quantum number (b) Spin angulor momentum {€) Magnetic quantum number (dLObital angular momentum 105. Which of the folowing ses of orbital: may degenerate le) 2529,.2p, () 353p,34,, [ed 15.2536 (a) 2p,.20,.2p, 106. The set of quantum numbers n= ‘bongs othe element ©) Mg (b) No fo Ne Fr 107. An electron hes principal quantum number 3. The number fis (i) sub shes ad (i) orbitals would be respectively (MP PET 1997) (@) Sands (6) 3and7 (3) 3end9 (4) ands, 108. What is the electronic configuration of Cu?“(2= 29) of least poston INP PENPMT 1998; MP PET 2001] () TarTts'3~ —— —(B) fArjds*aaapt (©) tan4s!aa” (@) (ar3a? 109. The conect electronic configuration of TlZ = 22) atom is IMP PT 1999) ~- (A_18?26?2p63s%3p6 stag? (b) 1s*2s?2p83s?3peaq* fe) 1s?2s?2p*3s*ap§ga* (8) s22stoptaetapt stag? 110. Which ofthe folowing coniguration is conect for ron [CBSE PHT 1999} (a) 1s°2s?2p83s?3p%agS (0) 1s?2stopFstaptastag® {e)_1s*2s?2p83s?3p6qs2aq7 (a) 15°2s?2p83s?3p8 qs?agé 111. Which ofthe following ‘fqn unbes tlon highest energy ira [cpr 1999) (a) n=41=0, (0) n=31=0m=0; () n= 30 =Lme1 (d) n=31=2m= 112. Which quantum number sl determine the shane subshell ICPMT 1999. py, Poriy oe (2) Principal quentum number (0) Azimuthal quantum number (6). Magnetic quantum number (2) Spin quantum number 13, For the m= 2 energy eel how many eb cat are possible (Bihar cee yet fe) 2 e) 3 78 4 @) 5 114, Which one is in the ground state (OP 5 (0) iT Ci it PLE ] fat ai 4 1 otal EE Tce fy @ + Tt ma G l (4) RT L] tt 115. When the principal quontum number (n= 3), the pestle values of azimuthal quantum number (1) is [Bihar MEE 1996: KCET 2000) (0) 0, 1,23 (o) 0.1.2 - 2-1, (1.2.3 (01 116. Which statement isnot conedt for n=5. m=3 {chor 1996) (Tea 0) 1 013s=43 (J 123 (4) Allere conect 117. 15°25?2p3s* shows configuration of ICPMT 1996) (0) AI ingroundstate —(b) Ne in excited sate (2) Mg” inexcited stele (8) None of tase 118. Five valence electrons of p'® are labelled as AB x Ty [z 3s 3p W the spin quantum of B end 2 is +h the group of electrons with three ofthe quantum number same are (uiPMER 19971 (e) AB, xYz,By (0 xv2,az (b) AB (a) 4B,xvZ2. Atomic Structure 119. Electronic configuration of Se™ is, (a) 15725? 2p*3s?3p*as?aat (b) 1572s? 2p°3s?ap*astad? (e) 1s?2s?2p3s?3p*as93a? (a) 18°25? 2p*3s?3p?astaa? 120. If m4 1=6. then total possible number of subshells would [oH 1997) be tmPMT 1997) 3 4 m2, 5 321. An lectfon having the quontum numbers n24=3.m=0, s=-2 would be in the oibital {Ortssa JEE 1997) 0) 3p (@ af 122. Which of the following sets of quantum numbers is not allowed! [Orissa JEE 1997) fe) 3s 94d 1 (0) n=1d=O.m=0.8=+5 m= 02-2 nen 2 1 () n=2t=1m i a 7 1 (a) n=21 51m 2 123, For which of the following sets of four quantum numbers an clectron will have the highest energy 7 “cuse PaT49931~ — no tom os m3 2 1 42 w4 2 1 #2 @4 1 0 ae @5 0 0 2 124, The electronic configuration of gadolinium (atomic no. 64) is {CBSE PMT 1997} a) [Xe}4s°5d°6s? {b) [Xe}4s75d"6s? le) [Xe]4s°50%6s? (a), 1Xeqas*5d76s? 125, An e has magnetic quantum number as —3, wha is its ‘rinepal quantum number [BHU 1998) (a) 1 (o) 2 a3 (4 126. The number of quantum numbers required to describe an clectton in an atom completely is [CET Pune 1998), (1 (b) 2 3 (a) 4 127. The electronic configuration 1s°2s?2p!2p}2p! {APMC 1997; Po. PHT 1999; CBSE PMT 2001; AIDS 2001 fa) Oxygen (b} Nitrogen 33 128. 129. 130. 131. 132. 133. 134, 135. 136. 137. by S.K, Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” (fc) Hydrogen (4) Flvorine Which one of the following set of quantum numbers is not possible for 4p elect IEAMCET 1998) 1 (an me nheet5 1 (b) ne Ale hm=0s=+5 fo ne4delm=2s045 = 2 nals lm=-Ls (a) n= 41. : Which ofthe folowing orbital isnot possible (RPMT 1999) (a) 3f (o) 44 (o) 5f (a) 6f Which set of quantum numbers for an electron of an atom is not possible > IRPMT; DCE 1999) Qm=0.s= 41/2 (@) nea) Electronic configuration of fetic fon is [RPET 2000} (o) tanadt (b) lari3a? fo) (ari3d® (a) tari3d® What is the maximum number of electrons which can be accommodated in an atom in which the highest principal {quantum number value is 4 IMP PMT 2000) (2) 10 (bo) 18 (o 32 (a) 54 ‘Which of the flowing electronic configurations isnot possible {cPMT 2000) @) 1s? 25? (b) 1s*2s?2p° fe) 3d!4s?4p* (a) 15?25? 2p73s! The electronic configuration of an element is 1e226%2p°3s*3ph3d° As! . This represents its IIIT Screening 2000}, (a) Excited tate {(b) Ground state {€) Cationic form {@) Anionic form Which of the following set of quanturn numbers is possible [alls 2001) ;m = 2 and $= +: iim=0 ends (o) i 2 1 2 i m=2 and s @ (@) n= Band s=+ 4% Which ofthe following set of quantum number isnot valid [alts 2001} (a) n=11=2 (b) 3=2m=1 {c) m=3,1=0 (a) 3=41=2 Which one pair of atoms or ions will have same configuration (JIPMER 2001) Vidya kendrA - Head Off: 108, Kingsway camp (Near GTB Ngr Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev’ Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014. wunw.vidvakendra.comSO fo} F* and Ne {b) Liv and He” fe) CI” and Ar {d) No and K i ich of jing sels of quantum number is nc (a) n=3i)=42:m= 1 (b) ne3:1=0m=08=-5 1 (6) n=3d-=Om=-ks= 45 1 (8) n=3=im=08=-5 139. Which of the following sot of quantum numbers is comet for the 198 dleeton of onium {DCE 2001} a tom s ® 3 0 0 -iR ® 3 2 2 @ 4 0 0 Ww @ 4 1 4 2 140. When the value of azimuthal quantum number is 3, magnetic quantum number cn have values (DPMT 2001) () +1,0,-1 4241, (@ -3,-2 @ #4-1 5 141. The quantum numbers n=2,1=1 represent (AFM 2002} @) Isorbital (b) 250% (0) 2porbital (a) 3d orbital 142, The magnetic quantum number of valence electron of sou No) is IRPMT 2002) 3 (b) 2 1 (a) 0 143. Azimuthal quantum number defines tats 2002) (2) elm rato of electron (©) Spin of electron. .— (@) Angular momentum of electron (4) Magnetic momentum of electron 144."Quintum numbers of an atom can be defined on the basis of [anns 2002) (@), Hund’s rule {b) Aufbau’s principle (Poul’s exclusion principle (a). Heisenberg's uncertainty principle 145. Which of the following has maximum energy. . (aus 2002) 34 | Vidya kendrA - Head Off: 111, Kin \gsway camp (Near GTB Ngr Metro station Gate No= Corporate Office : D-32, Hardev Nagar, Ph-011.47024312, M..9555 87 50 87, 9312 10 2014, » cal » WERE x 3 uM. CO as ” a © MELT TT) 3s 3p 4 © WOE TTT 396, The tl ante quo vanes “iomaee ee ) 2 tb) 021.42 () 0.1.2 5 147. The outer electronic structure 35°3p* is possessed by (Po. Pier 2002: P. cer 200) Otel 0 (9 Ar (3) Br 148. Which of the following set of quantum number is tot possible tb. Patt 2009 ” ' m m ® 3 2 1 +12 ry 3 2 1 -1 0 3 2 1 ° (a) 5 2 -1 +12 149. The configuration 1s?.2s?2p*.3s' shows Pb. PMT 2002 (2) Excited state of 05 (b) Excited sate of neon 7 (6) Excited sate of fuorine (@) Ground state of fuorine atom 150. The quantum number associated with (0) The elective volume ofthe etal (©) Theshape ofthe otal + {e)_Thesptil orientation ofthe orbital (8) The energy of the orbital in the absence of a magnetic field 151. Conect statement is (e) K=4s!, Cr=ad¥4s?, Cun ad!as? () K=4s?, Cra ad*4s?, Cu=3d!qs? (0) K=ds?, Cr=3054s!, Cu = 344s? (@) K=4s', Cr=3d54s!, Cun 3d!4s 152. Number of orbitas in h sub-shellis 1 (b) 15 7 (a) 19 153. Electronic configuration 1s?,2572p6,35?3p63a5,4s! represents of @ free gaseous atom is {AIMS 2003} (ou 2009), {BHU 2003) ICPNT 2003) D), Delki9. Jharoda. (Near Burari by-pass), Delhi-84. wanu.vidvakendra.com2. Atomic Structure {o) Ground stale (b) Excited state {e) Anionic stale (4) Allo these 154. Which ofthe following sets is possible for quantum numbers IRPET 2003), (0) n=4=3m (o) n= 4l=4y fa n=40=4m= (a) n=4)=3m=-2504 155. For principle quantum number n=4 the total number of orbitals having !=3 aunts 2004) (a) 3 () 7 5 a9 156. The number of 2p electrons having spin quantum number s=-1/2 are [KCET 200} (a) 6 (0) 0 (2 (a) 3 1157. Which of the folowing sels of quantum numbers is corect foran electronin 4f orbital [AIEEE 2008) 1 J=3m=Hs2s2 massa ) 1 () adda dme nds 03 eam=sdsa4) (9) nedleamasdsn5 158, Consider the ground stale of (2=24). The numbers of clectrons withthe azimuthal quantum numbers, !=1 and 2 [AIEEE 2003) a, respectively (a) 16 and4 (b) 12and5. (6) 12and4 (@) 16and5 159. The four quantum numbers of the valence electron of potassium are (DPMT 2008) “th 4,1,00nd 3 (by 4,0,1and 3 1 1 4,0,0and +>. (d) 4,1, 1and > ) 2 (a nd 5 160. Which of the following electronic configuration is not possible acording to Hund's rule- [Kerala PMT 2008) (a) 1s*2s? (b) 1872s (6) 1s#2s"2pl2plap! —(d)_s*2s°2p? fe) 18?2s*2pf2p} 2p} 161. The ground state term symbol for an electronic state is governed by [UPSEAT 2003} (a) Heisenbers's principle (b) Hund’s rule {c) Aufbau principle by S.K. Singh (FMS, IIT & BARC)*, honoured by “ 162. 163. 164. 165. 166. 167. 168. 169. 170, in. 172, 35 | Vidva kendrA - Head Off: 108, Kingsway camp (Near GTB Nar Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph.011-47024312, M. 9312 10 2014. iksha Ratna” (a) Pauli exclusion principle The electronic configuration of element with atomic number 2his Pb. CET 2004] (a) 1<2,25?2p".35?ap*ad* As? (b) 1s?,25?2p".3s"3ptad™ {c) 1s°,25? 2p 36? 3ptaa® (a) 1s2,25?2p%.35?3p"3d° as! The maximum number of electrons in p-otbitol with n=5.m=1is Pb. CeT 2003) (0) 6 () 2 (14 (a) 10 Number of two electron can have the same values of ‘quantum numbers IUPSEAT 2004} (a) One (b) Two (0) Three (4) Four ‘The numberof orbitals present inthe shell ith n= 4 is [UPSEAT 2004} (2) 16 (o) 8 (18 (a) 32 ‘Which of te folowing electronic configuration snot posible MHCET 2003) (a) 1522s? (by 152.25%2p® fc) [Ari3d"°.4s?4p?——(d)_1s°.25?2p?.3s" Px orbital con accommodate IMNR 1990; IT 1983; MADT Bihar 1995; BCECE 2005) (2) 4 electrons, (©) 6 electrons {c} 2 electrons wih parallel spins (4) 2 electrons with opposite spins The maximum number of electrons that can be accommodated in *f' sub shell is ICPMT 1983, 84; MP PET/PMT 1988; BITS 1988) (0) 2 () 8 () 32 (a) 14 ‘The number of electrons which can be accommodated in an [DPMT 1981; AFC 1988) orbital is (2) One (b) Two (c) Three (a) Four ‘The number of electrons in the atom which has 20 protons inthe nucleus ICPMT 1981, 93; CBSE PMT 1989) (0) 20 (&) 10 () 30 (a) 40 ‘The maximum number of electrons accommodated in 5f orbitals are IMP PET 1996) (2) 5 (v) 10 14 (a) 18 ‘The maximum number of electrons in an atom with 1 = and n=3 is (MP PETPMT 1998) fa) 2 (0) 6 () 12 (a) 10 wunw.vidyakendra.comeee eat eee teet 173. The configuration 1s?2s?2p°3st shows _{AIIMS 1997) (a). Ground state of fuorine atom (b) Esciled state of uorine atom (c}_ Excited state of neon atom (d) Excited state of ion Oj 174. For sodium atom the number of electrons with m=0 will be IRPMT 1999) (2 7 9 8 175. The number of electrons that can be accommodated in ds? otbital is [Wurukshetra CEE 2002} fe) 10 1 4 (2 176. Number of unpaired electrons in 1s?2522p? is = (CPT 1982; MP PMT 1987; BHU 1987; ‘CBSE PMT 1990; CET Pune 1998; AIIMS 2000) (a) 2 tb) 0 a3 (a) 177. Tolal number of unpeired electrons in an atom of atomic ‘number 29's ICPMT 1984, 93) (a) 1 3 4 (@ 2 178. The number of unpaired electrons in 1s?.25?2p4 is INCERT 1984; CPMT 1991; MP PMT 1996, 2002) (e) 4 {) 2 @o (ay 1 179. The maximum number of electrons that can be ‘ccommodated in a 3d subshellis (0) 2 (o) 10 6 (4 180. The maximum number of electrons which each sub-shell can occupy is (Pb. CET 1989) — (0)_2n® (b) an (©) ate) (@) (2+) 1B1. Number of unpoired clecrons in the ground state of = beryl atom is (a) 2 1 0 (3) All the above 182. How many unpaired electrons are present in Ni? cation (etomic number = 28) (ONT 1981; MNR 1984; MP PMT 1995; Kerala PMT 2003) () 0 (o) 2 (a4 (6 185. The number of unpeied electron in an Oy molecule is IMNR 1983), (a) 0 (o) 1 (2 (3 184. The number of unpaired electrons {atomic number = 24) is (a 6 in a chromic fon Cy? IMNR 1986; CPMT 1992) (o) 4 185. 186. 187, 188. 189. 190, 191, 192, 193, 194, 195. 196, M.-9555 87 50 87, 9312 10 2014. —=—= eves tonoured by “Shiksha Rat nar (9 3 (aya 344s eectonic coniguation exibis by fo) Zn" ©) cw fe) ca (@) Hg Which of the follwing metal ions wl have numberof unpaired electrons Terns (a) Fe? (b) co? q (nie (8) Mn? Which of the metal ion will ‘unpaired electrons (a) cu (Fe ‘The maximum number of un in dorbitals are ove hides rumba (b) Fe (6) Co® ried econ canbe egy (1 (b) 3 (5 (@)7 ‘The molecule having one unpaired electron is fa) NO (%) co fe) CN (@) 0, A filled or hallilled set of p or d-orbita sis phere Summetic. Point out the species which has shy symmetry INERT 1553, ~ (2) No wc @ cr (a) Fe {he stom ofthe element having atomic number 14 shou have TAMU 1589) (2) Oneunpaired electron (b) Two unpaired electors (€) Three unpeired electrons (4) Four unpaired elections An atom hes 2 electrons in K shel 8 elections in_L shel and 6 electrons in M_ shell. The number of s-clechere resent in that element is {PONT 1955 6) 6 OR @7 (@) 10 The number of unpaired electrons in carbon atom in exc sfoleis (sive 1987) (One {b) Two. (9) Thee (¢) Four Maximum numberof electrons present in ‘N*shelis UEAMCET 1984 (a) 18 (b) 32 @2 8 The number Of d_electtons in Fe"? (atomic number of Fe = 26) isnot equal to that ofthe TNR 1983) {)_p-clectrons in Ne (At. No.= 10) (0) s-elections in Mg (At. No.= 12) (0) deetectronsin Fe (2) p-electrons in CI (At.NNo.of Cl = 17) ‘A transition metal X has a configuration [Ar}3d* ins «3 oxidation state. Ils atomic numberis_{EAMCET 1950) (@) 25 () 26 1), Delhi. .. (Near Burari by-pass), Delhi-84. wow vidyakendra.com2, Atomic Structure 197, The total numberof eletrons present in all the p -orbitals of bromine are [oP PET 1999 (o) Fre (0) Eighteen (6) Seventeen (@) Thin five 198. Which of the following has the maximum number of unpaired electrons (ur 1996) fo) Ma® () Ti ov (a) Fe® 199. Which ofthe following has more unpaired d-clectrons [CBSE PMT 1999) (0) 2n (b) Fe? (ne ta) cur 200. Maximum elecionsina d-orbital are (CPMT1999) (2 (b) 10 6 (ay a4 201. The-oumberof unpaid secrone in Fe™(2 = 26) ore {KCET 20001 (os (6 a3 (a) 4 202. How many unpaired electrons are present in cotalt (Co) metal . [RMT 2002) (e) 2 (o) 3 a (7 203. The number of unpaired elarons in nitrogen (Pb. cer 2002) (1 (13 @2 (4) None of these 208. Which of the following has the least energy (2p (b) 3p — Ag - id) ad 1205, Poulis exclusion principle states that (CPNT 1989, 84) {a}, Nucleus ofan atom contains no negative charge (6) Electrons move in cular orbits around the nucleus (0) Electrons occupy orbitals of lowest energy ~1@)°All the four quantum numbers ‘of two electrons in an atom cannot be equal 206. For the energy levels in an atom, which one ofthe following _stalements is comect AIMS 1983} (2) There are seven principal electron eneray levels (6) The second principal energy level can have four sub- energy levels and conains a maximum of eight electrons (2) The M energy level can have maximum of 32 electrons (d) The 4s sub-energy level is at a higher energy than the 83d subsenergy level : 207. The statements tans 1982) (In filing a group of orbitals of equal energy, it is ‘energetically preferable to assign electrons to empty orbitals rather than pair them into a particular orbital (i) When two electrons are placed in two diferent orbitals, ‘energy is lower if he spins are parallel, are valid for (a) Aufbau principle (0) Hund’s rule Corp: Offic 208. 209. 210. 211 212. 213. 214. 215. 216. 217. 05 Kingevay ‘camp (Near GTB Ngr Metro station Gate No- }2, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi Ph-011-47024312, M. 9312 10 2014, Na daieeiaiaeg by SK. Singh (FMS, IIT & BARC)", honoured by “Shiksha Ratna” (e) Paulis exclusion principle (2) Uncertainty principle Accoxding to Aufbou's principle, which of the three 4d.5p ‘and 5s willbe filled with elections frst (MADT Bihar 1984) (a) ad () 5p fe) 5s (8) 4d and 5s willbe filled simutaneoushy ‘The energy of an electron of 2p, orbitalis (AMU 1984] (a) Greater than that of 2p, orbital (b) Less thon thot of 2p, orbital (e) Equal to that of 2s orbital (4) Same asthat of 2p, orbital Which ofthe following principlesfutes limits the maximum number of elections in an orbital fo two [CBSE PMT 1989) (a) Aufbau principle () Pauls exclusion principle (€) Hand's rule of maximum multiplicity {@) Heisenberg’ uncertainty principle The electrons. would goto lower energy levels fist and then to higher eneray levels according to which of te following [BHU 1990; MP PMT 1993) (o) Aufbau principle (b) Pauls exclusion principle {c}_Hune's rule of maximum multiplicity (a) Heisenberg’s uncertainty principle Energy of atomic orbitals in a particular shel isin the order [ARNC 1990) (a) sepedes fe) s>p>d>f () pedefes (8) fod>s>p ‘Aufbau principle isnot satisfied by (op PMT 1997) (2) Cr and Cr (&) Cu and Ag (0) Cr and Mg (a) Cu and No Which of the following explains the sequence of fling the clectrons in different shells__{AHMS 1998; BHU 1999) (2) Hund’s rule 16) Octet rule (0) Aufbau principle (4) Allof these ‘Aufbau principle is obeyed In which of the following ‘electronic configurations [APMC 1999) (0) 1s?25?2p° (b) 1s?3p"3s? (o) 15?3s?3p> (a) 1s?2s?as? Following Hund's rule which element contains six unpaired. ‘lectron [RPET 2000} (a) Fe (&) Co (ON (cr Electron enters the subsbell for which (a+I) value is ‘minimum. This is enunciated as RPM 2000) (2) Hund’s rule {b) Aufbau principle (a) Heisenberg uncertainty principle (d) Paul's exclusion principle -3), Delhi-9. aw vidvakenda comAtomic Structure in order of 218, The atomic orbiials are progressively filled in 0 * increasing energy. Ths principle i called as [ip PET 2001) fo) Aufbau principle * (0) Hand's le f rc le) Exclesion principle (d)_de-Brogie rl sng energy of atomic orbitals 218, Themed ode aeingenp sonot (0) Spc6s< df ed (a) SpSdcaf<6s la) Sp<4fcbs<5d (6) MeSp, & © 14, Te @ o 15. The ne from cone fo fo 16. The soot @ - W< 17. They 1 On ~The 18. The thi trast (9) 55 a5 19. Which of econ ( (0) Fe (0 Fe The frequ hydrogen Ny which (6 (a4 Wich of tom wil re 39] Vi 20. a,2. Atomic Structure 11, The foal number of valence elections in 42am of 5 jon is (Np is the Avogadro's number) [CBSE PMT 1994} (0) 16N, () 32N, (0) 21Ny (8) 42Nq 12, The Bobr orbit radius for the hydrogen atom (n=1) i: epproximately 0.5304. The radius forthe first excited state (n= 2} orbits (CBSE PMT 1998; BIIY 1999) {o) 013A (b) 1.054 (477A (a) 222A 13, The frequency of 0 wave of ght is 1210'S", The wave number associated with this ight is 1b. PMT 1999) (0) 5x107m (b) 4x10%em {9 2x107m? = (8) 4108 em 14., The series limit fr BolmerSres of H'spectra is — [AMU (Eras) 1999) (2) 3300 (b) 4200 (0 3646 (@) 4000 15. The ionization energy of hydrogen atom is -13.6eV. The ‘energy required to excite the electron in a hydrogen atom {rom the ground state tothe fist excited stale is (Avogadto's constant = 6,022 x 10) [BHU 1999) {fe} 1.69105 (b) 1.691077 (9 169x107 (4) 1.694104 16. The energy required to dislodge electron from excited 13.6 eV is IDCE 2000), isolated H-atom. IE, (a) =13.6eV (b) >13.6eV {) <136and>34eV — (d) <3.4eV 17. The number of nodal planes ina p, is IT Screening 2000) (2) One (b) Two — (c) Three. (4) Zero 18. The third line in Balmer series corresponds to an electronic transition between which Bohr’s orbits in hydrogen é IMP peer 2001), () 593 (b) 532 (493 (a) 42 19. Which of the following has maximum number of unpaired electron (atomic numberof Fe 26) (4 PMT 2001) (e) Fe () Fei) (@ Fen (d) Fea) 20. The frequency of one of the lines in Paschen series of hydrogen atom is 2.340%10"He. The quantum number ‘My which produces this transition is {DPMT 2001) (a) 6 (b) S a4 (a) 3 Which of the following electron transition in 2 hydrogen ‘atom will require the largest amount of energy 3Q | Vidya kendrA - Head Off: 108, by S.K. Singh (FMS, IIT & BARC)*, honoured by “ ingsway camp (Near GTB Nar Metro station Gate No.3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014. www.vidvakendra.com hiksha Ratna” [UPSEAT 1999, 2000, 01} (a) From n= 110 (b) Flom n=2 ton=3 fe) From n= tonz1 (4) Fromn=3 to 22. In Bohr series of lines of hydrogen spectrum, the third line fiom the red end corresponds to which one of the folowing interorbit jumps of the electron for Bohr orbits in an stom of hydogen [AIEEE 2003) (2) 392 (b) 592 (9) 41 (a) 2-95 23. The volue of Planck's consant is 66310" Js. The velocity of light is 3.010% ms ?. Which value is closest to the \wavelenghh in nanometre of a quantum of ight with frequency of 8x10%5"? [CBSE PMT 2003] (a) 3x10" (b) 2x10 (9 5x10 (a) 4x10" 24. As clecron moves away from the nucleus, its potential eneray [UPSEAT 2003} (2) Increases. () Decreases. {c) Remains constant _(d)_ None of these Assertion & Reason eee Read the assertion and reason carefully to mark the correct option (out ofthe options given below = (o) If both assertion ond reason ore true and the reason is the correct explanation ofthe assertion. (&) If both assertion and reason are true but reason isnot the correct explenation ofthe assertion (6) Sfassertion is true but reoson is fle. (a) Ifthe ascerion ond reeson both ore false — - fe) Wassertion is false but reason is true. 1, Assertion : The position of an electron can be determined exactly with the help of an electron microscope. Reason: The product of uncertainty inthe a ‘measurement of its momentum and the uncertainty in the. measurement of the position cannot be less than a finite limit. INDA 1999] 2, Assetion : A spectral fine will be seen for a 2p, ~2p, transition. Reason Energy is released in the form of wave of light” when the electron drops from 2p, -2p, oitital. Alms 1996) Assertion: The cation energy of an electron is largely determined by its principal quantum number. Reason: The principal quantum number n is a measure of the most probable distance of finding the electron around the nucleus. TAIMS 1996) 12 iS less stable than * Cay 4. Assertion: Nuclide ™.ee Structure: 10. Reason Assertion Peason Assertion Reason Assertion Reason Assertion Reason ‘Assertion Reason Assertion Reason Assertion ‘Reason Assertion Reason, Reason Assertion Reason ldes having odd number of protons and neutrons are generally unsable tur 1995) The atoms of diferent elements having same mas number but deren alomie ‘umber are knoun a isobars ‘The sum of rotons and neutrons, inthe isobar is abn dierent taums 2000) Two lectons in an atom can have the same vols of our quantum number. Tio elecons in an atom can be present in the same shel, sub-shell and onital and have the some sin tains 2001) ‘The valu ofn fora line in Balmer stes of hydrogen specrum having the highest ‘wavelengths 4 and 6 For Balmer series of hydrogen spectrum, the value =2 and ny=3. 4,5 tains 1992) Absomtin spectrum cons of some bight line separated by dai spaces Enision spectrum consists of dark nes, (aims 2002) A resonance hybrid is ahways more sible than anyofiscanoical sites. This sabiliy is due to delocalization of electrons. (ams 1999) Cothode rays dono raven straight nes Gathede rays penetrate though thick sheets (alin 1986) Electrons reveling around the nucleus do ‘ot fall info the nucleus because of centafuge fore. Revolving electrons ae planetary electrons, (aims 1996) Thieshald hequency is a charatricfora mel, Threshold frequency is a maximum Frequency requited for the ejecion of election from the metal surface. ‘he ros ofthe fist orbit of hyekogen ‘atom is 0.5290. Radius for each circular orbit tr) = 05294, (1/2), where n= 12:3 and 22 atomic number. Sp orbit is spherically symmetical 3p otitis the only d orbital which ig spherical in shape, Shin quantum number ean have the valve #1Ror -12. (+) sign here signifies the wave funtion, Corporate Office (FMS, IIT & BARC)*, honoured by “g; » Kingsway camp D.32, Hardev Nagar, Jharoda, (Ne: ha Rata 16. Aeeton Tole number of erbias a : Ptepl annum unter nat ah Reon + Nanbe clotting shee a 17. salon: Enel ec ncene U2 Spd ag, FHF en Reason Enrol the eeton depend ‘on principal quantum number oP, 18 Aeron + Spliting of the spectaltngg in te Presence of magnetic fly i ty slrkeiect “a Reson + Une speciun i simplest fo atom ‘sea 19 Aston Thomon's stole medel i iy ‘tin pudding’ mode, nits Reson The oom is vied a5 pug ra ae embedded init 20+ Aeon”: Ato oti non slom seg, dim and m, ahd feeson + These oe ell in desgnating ecton resent in anoxia 2h ‘Aserion— >— The transition ofeecrons my in atom will emit greater os Fe%Sy than nos Ranson: ny and ny are coer to nce an oa 23. Asetion Cathode rays area stream of 4 -partcles, Feoion They ore generated under high Presse and high voltage 23. Assertion {n ca of ioeectonic ions the ionic sap east te ince toni number, The seat the atraction of races ‘reater is the ionie ads, Reason Ans. of Fundamental Topic Wise Q ee mae Discovery and Properties of anode, cathode rays __.Reutron and Nuclear structure station Gate No.-1), Delhi-9, a Burari by-pass), Delhi-84, Ph-O1 1-47024312, M.-9555 87 50 87,9312 10 2014. ‘aw. vidvakendra.com SEE EEL EET2. Atomic Structure by S.K. Singh (FMS, IIT & BARC)*, honoured by “Shiksha Ratna” ‘Guantum number, Electronic configuration and Shape of orbitals > ime@ 5 © ” Bo D< Be fame B we wee a Be we ew) | m Ta a wd ® ® at a Li ie a fee Boe ¢ Gi > fishg b ie ia Uncertainty principle & Schrodinger wave equation A] | Vidya kendrA - Head Off: 108, Kingsway camp (Near GTB Ngr Metro station Gate No.-3), Delhi-9. Corp. Office: D-32, Hardev Nagar, Jharoda Mazra (Near Burari by-pass), Delhi-84. Ph-011-47024312, M. 9312 10 2014. wwww.vidyakendra.com-2Atonste Siructire oh FMS, HT & BAWLY", NOnOUFed BY "Shisha ay . Atomic Stra es